金属有机化学国家重点实验室2005年年度进展报告.doc
金属有机化学国家重点实验室2005年年度进展报告.doc
金属有机化学国家重点实验室 学科带头人现状与需求 现有人员 目前学科方向 陆熙炎院士 戴立信院士 麻生明院士 侯雪龙研究员 唐 勇研究员 丁奎玲研究员 姜 标研究员 施 敏研究员 刘元红研究员 邓敏智研究员 陈家碧研究员 李玉学副研究员 金属有机，有机合成 不对称催化，有机合成 金属有机，有机合成 不对称催化，有机合成 金属有机，高分子化学 金属有机，有机合成 不对称催化，有机合成 金属有机，有机合成 金属络合物化学 军工，金属有机 金属络合物化学 金属计算化学 发展学科方向 需求计划人数 配位化学 金属络合物的反应化学 金属催化的材料化学 金属络合物的结构化学 1 1 1 1 1 2OO5 年重大记事 一. 2004－2005 年基金项目资助 继续资助 2004－2005 年的实验室基金项目 31 个，其中有机所 14 个，外单位 17 个，新增加 2 个外单位的回国年轻学科带头人的项目，资助总额 110.4 万。 二．中科院创新团队 6 月 14~15 日中国科学院上海有机所“均相催化研究”国际合作伙伴计划团队 召开了团队启动后的第一次工作讨论会，会议邀请到了中国科学院高技术与发展局 化工处彭辉处长和景震强同志参加。团队海外成员：美国 The Pennsylvania State University 的张绪穆教授、美国 University of Virginia 的蒲林教授、美国 The Ohio State University 的王鹏教授、美国 Texas Tech University 的李桂根教授、香港中文大 学的谢作伟教授、香港科技大学的贾国成教授和团队有机所成员：麻生明、侯雪龙、 唐勇、丁奎岭、施敏、刘元红全体共 12 位成员在会上分别作了 20 分钟学术报告， 主要交流团队实施 6 个月来的工作进展及将来的工作打算。会上彭辉处长重点介绍 了中科院实施团队计划的主要目的，希望我们团队能够可持续发展。大家一致认为 我们团队在基础研究方面一定要参与世界前沿的研究领域，同时又要为我国的国民 经济和战略需求解决一些科学基础问题。目前整个团队工作进展良好。 三. 组织召开第一届 Joint China-US Green Chemistry Workshop 和 2005 年 China-France Workshop in the Field of Molecular Catalysts and Catalysis 由中美双方国家自然科学基金委员会主办，美国 Alabama 大学的 Robin D. Rogers 教授和我室麻生明研究员共同组织的第一届 Joint China-US Green Chemistry Workshop 于 2005 年 5 月 27 日~31 日在北京外国专家大厦召开，会议邀请了 24 名 中美科学家参加(双方各 12 名)。会上每位报告人都作了 30 分钟的学术报告，并安 排了 5 分钟的讨论。在会议期间与会代表就绿色化学的各方面问题进行了充分地交 流。 由中法双方国家自然科学基金委员会主办，法国 Rennes 大学的 Pierre Dixneuf 教授和我室侯雪龙研究员共同组织的 2005 年 China-France Workshop in the Field of 2 Molecular Catalysts and Catalysis 于 2005 年 11 月 2 日~5 日在苏州西山宾馆召开，会 议邀请了 20 名中法科学家参加(双方各 10 名)。会上每位报告人都作了 30 分钟的学 术报告，并安排了 5 分钟的讨论。在会议期间与会代表就分子催化方面进行了讨论 和交流。 四. 实验室承担的科研项目运行正常 由吉林大学裘式纶教授和我室麻生明研究员作为首席科学家的 973 项目“创造 新物质的分子工程学研究” 9 月 6 日-7 日在吉林大学友谊会馆召开了本项目 7 个课 题的结题验收会议，会议高兴地请到了朱道本、袁权、戴立信、佟振合、黄宪、倪 嘉缵和李灿 7 位院士、中科院基础局黄勇副局长、教育部科学技术司雷朝滋副司长 及张斌同志和科技部 973 联合办公室韩苍穹同志作为结题验收会议的专家，项目首 席科学家裘式纶和麻生明教授与专家组成员一起认真听取了每个课题负责人的结题 汇报，会上每个课题汇报 30 分钟，提问讨论 10 分钟。随后，专家组经过认真讨论， 对每个课题进行了逐个评议，并填写了评议表。在此基础上，专家组还对每个课题 给出了具体的验收意见，肯定了每个课题在项目实施过程中取得的成绩，提出了大 家今后努力的方向。10 月 20 日项目首席科学家裘式纶和麻生明教授等参加了科技 部组织的在北京铁道大厦召开的项目结题验收汇报会，会上裘式纶教授汇报了整个 项目 5 年的工作，麻生明教授和于吉红教授分别汇报了项目的两个代表性成果。 唐勇主持的国家“863”计划“新型烯烃聚合催化剂的中试及工业化应用研究” 今年 12 月 28 日在北京验收。 以我室学术带头人为主的题为“导向有机合成的金属有机化学”国家基金委创 新研究群体项目 2005 获得延续资助，资助期限为 3 年，目前进展顺利。另外麻生明 和唐勇研究员分别主持的基金委重点项目“过渡金属催化的含碳化学键的活化和反 应性控制”和“导向有机合成的杂原子化学”以及麻生明研究员主持的基金委国际 合作重大项目“金属催化的化学键形成和断裂的调节和控制”今年也进展顺利。丁 奎岭和施敏研究员主持的中国科学院知识创新工程重要方向性项目“重污染的硝化、 氧化和还原反应清洁新工艺研究与开发”今年进展良好，完成和部分超额完成了项 目结点目标。 实验室今年还新申请到一项由侯雪龙主持的基金委重点项目“有机化学反应中 的选择性控制”，一项由侯雪龙和丁奎岭共同主持的上海市科委重点实验室专项“清 3 洁催化氢化和烯烃氢甲酰化”，一项由施敏主持的上海市科委重点项目“有机功能小 分子催化的反应 ”。另外，香港科技大学化学系副教授贾国成依托实验室申请的国 家基金委杰出青年基金 B“联烯的金属有机化学及其催化反应”项目今年启动。 实验室固定人员通过上述等项目的研究，共发表 126 篇论文，其中 SCI 收录 113 篇，I 区论文有 13 篇。同时实验室客座人员在实验室基金资助下共发表 74 篇论文， 其中 SCI 收录 73 篇，I 区论文有 4 篇。 五．基金委的国家重点实验室国际合作项目资助下的对外交流 在基金委的国家重点实验室国际合作项目资助下，实验室今年按计划邀请了瑞 士 ETH 的 Antonio Togni 教授、荷兰 Univ. of Groningen 的 B. L. Feringa 教授和德国 马普煤炭研究所的 A. Fürstner 教授来室作短期工作访问，不仅作了相关的学术报告， 还分别与我室科研人员进行了广泛的学术交流。 六．实验室学术委员会工作 实验室今年 11 月 29－30 日在海南召开了 2005 年度学术委员会会议， 会上荣幸 地邀请到了科技部和基金委的领导参加，他们为实验室的发展提了不少建设性意见。 同时本届学术会上很高兴地邀请到长春应化所的李悦生研究员和北京大学的王剑波 教授分别作了题为“非茂过渡金属配合物催化烯烃聚合反应”和“卡宾化学的成就 与挑战”的学术报告。会议就实验室今后的学术发展方向、队伍建设和体制机制的 建设展开了热烈讨论。 七．获奖情况 戴立信院士 获宝洁优秀研究生导师奖 唐勇研究员 获中科院优秀研究生指导教师称号 周剑博士 获中科院优秀博士学位论文奖 何绮雯博士 获中国科学院院长奖学金优秀奖 俞瞻前博士 获得全国优秀百篇博士学位论文奖 麻生明研究员 获 OMCOS 13 Award，当选为中国科学院院士 4 金属有机化学国家重点实验室学术委员会 第二届第一次会议简报 金属有机化学国家重点实验室第二届学术委员会第一次会议于今年 11 月 29－ 30 日在海南召开，新一届学术委员会的十八位委员中有十四位出席会议，国家科技 部基础司基地建设处黄珍东老师，国家基金委化学部梁文平老师和杜灿屏老师与会 指导。会议由实验室学术委员会主任席振峰教授主持。这次会议的议程是 1) 室主 任作实验室年度工作报告，2) 专家学术报告和交流，3) 部分课题组工作进展情况 汇报，4) 国际学术会议介绍，5)实验室今后工作讨论。 一.实验室主任麻生明研究员汇报了实验室一年来的工作 麻生明主任首先欢迎并感谢各位领导和专家的到会，并感谢大家在过去一年中 对我们实验室工作的大力指导和支持。 然后他首先介绍了 2004 年评估完换届后实验 室新的领导班子和学术委员的情况，接着汇报了实验室一年来的工作，包括实验室 一年来在项目申请及执行、研究工作及其水平、论文发表情况、国际任职、科研梯 队建设和人才培养、主办学术会议、课题管理、设备和发展思路等九个方面的工作。 主要对实验室一年来的重要科研进展作了较为详尽的报告。 二．专家学术报告和交流 会上由中国科学院长春应化所李悦生研究员和北京大学王剑波教授分别作了题 为“非茂过渡金属配合物催化烯烃聚合反应”和“卡宾化学的成就与挑战”两个精 彩的学术报告，与会代表对每一个报告都进行了充分的讨论和交流。 三. 课题组工作进展汇报和讨论 这次会上共有六个课题组进行科研工作进展汇报，分别由上海有机所丁奎岭 研究员(不对称催化研究的一些新方法：从“组合”到“组装”)、复旦大学金国新 教授(有机金属碳硼烷化学以及有机金属大环化合物)、中山大学苏成勇教授 （ Coordination Molecular Architecture---Metalated Container Molecules and Supramolecular Isomerism）、北京大学施章杰教授(金催化高选择性氧化研究)、复旦 大学吴劼教授(芳基磺酸酯的偶联反应研究)和上海有机所李玉学副研究员(计算化学 5 在金属有机中的应用)到会汇报交流工作。委员们认真听取了他们的进展情况和今后 工作设想，并就研究工作中的问题提出了中肯的意见和建议，进行了广泛的学术交 流。 四．国际学术会议介绍和讨论 本次会上共介绍了三个国际会议的内容： 1、 上海有机所的丁奎岭研究员介绍了今年 7 月在瑞士日内瓦召开的 2005 年 OMCOS 13 会议的情况, 重点介绍了 23 个大会报告和 1 个大会获奖报告，这次的 OMCOS 13 Award 是由我室的麻生明研究员获得的。 2、上海有机所的刘元红研究员介绍 2005 年 10 月在北京召开的中日双边会议和 11 月在苏州召开的中法双边会议的情况, 重点介绍了和金属有机化学相关的一些大会 报告。 通过这些介绍和讨论，使到会代表及时了解国际上金属有机化学研究的热点和 掌握目前文献还来不及报道的热门学科前沿资料，对拓宽工作思路起到了一定的作 用。 五．今后工作讨论 会上委员们就事先酝酿的三个议题： 议题一：学术方向 1、金属有机化学学科自身的发展与创新 2、金属有机化学与有机合成、材料科学及环境科学的关系 议题二：队伍建设 议题三：体制机制 进行了充分的讨论，大家一致认为作为一个国家重点实验室，一定要坚持基础 研究，尤其是坚持一些有特色的基础研究，应用研究也应要求从源头上创新。实验 室目前在络合物方面尤其是具有良好研究背景的稀土化学方面相对薄弱，在今后的 人才引进中要特别强调这点。实验室应该继续保持良好的传统，排除社会上的浮躁 情绪，营造一个宽松的学术环境，在国内起到领头羊的作用。 6 2004～2005 资助课题一览表 序 号 姓 名 单 位 题 目 2004-01 陆熙炎 上海有机所 钯催化反应选择性的控制研究 2004-02 钱长涛 上海有机所 含卤素取代基的新型非茂过渡金属烯烃聚合 催化剂的研究 2004-03 麻生明 上海有机所 金属参与的碳-碳键形成反应研究 2004-04 侯雪龙 上海有机所 苄位取代配体的设计，合成及不对称烯丙基 取代反应和 Heck 反应中的应用 2004-05 沈延昌 上海有机所 金属有机参与的高选择性合成方法学研究 2004-06 陈家碧 上海有机所 氮杂烯配位的金属卡宾和卡拜络合物及其 在合成中的应用 2004-07 邓敏智 上海有机所 新型 Suziki-Miyaura 类型偶联反应的研究 2004-08 姜 标 上海有机所 三类新型手性配体在几种重要的催化不对称 反应中的应用研究 2004-09 施 敏 上海有机所 二氧化碳反应学的研究 2004-10 丁奎岭 上海有机所 手性有机-无机高分子组装体的设计、合成 及其在催化不对称反映中的应用 2004-11 唐 勇 上海有机所 边臂策略在手性催化剂设计中的应用 2004-12 张兆国 上海有机所 烯丙基铑、钯物种的反应研究 2004-13 刘元红 上海有机所 利用前过渡金属茂类配合物开拓新型有机 合成反应与方法研究 2004-14 许 旭 上海有机所 有机合成产物的半制备液相色谱分离 2004-15 宋礼成 南开大学 新颖碟状铁硫簇合物的合成及反应化学研究 2004-16 黄 宪 浙江大学 过渡金属参与下亚甲基环丙烷衍生物的高 选择性反应 2004-17 沈 琪 苏州大学 结构限定的非茂基稀土配合物的合成及催化 7 可控聚合反应 2004-18 张永敏 浙江大学 金属钐及其试剂介入的有机合成反应 2004-19 席振峰 北京大学 双金属有机合成试剂的合成与应用 2004-20 周锡庚 复旦大学 稀土有机化合物促进的烯酮转化反应研究 2004-21 王佰全 南开大学 茂金属催化的活性自由基聚合反应研究 2004-22 王绍武 安徽师范大学 新型含杂原子取代茚基二价稀土金属配合物 的合成及催化活性研究 2004-23 秦金贵 武汉大学 金属有机和元素有机光电功能高分子的设计、 合成与性能 2004-24 甘良兵 北京大学 路易斯酸促进的富勒烯开环反应 2004-25 朱成建 南京大学 手性双核金属有机配合物的合成及其导引的 有机反应研究 2004-26 陈忠宁 福建物构所 炔基桥联金属有机光电分子材料 2004-27 王 磊 淮北煤炭 有机－无机杂化材料负载镍催化剂的制备 师范学院 及应用 2004-28 金国新 复旦大学 有机金属大环配合物分子材料的设计与制备 2004-29 周永贵 大化所 具有-重叠效应手性配体的合成和应用研究 2004-30 苏成勇 中山大学 杂氮环金属配位功能分子的控制合成 2004-31 郎建平 苏州大学 含硫杂核金属有机簇合物的合成，结构和 物性研究 2004-32 施章杰 北京大学 双过渡金属协同催化的 C-O 键活化 2004-33 吴 劼 复旦大学 金属催化的苯磺酸芳基/烯基酯的偶联反应研究 8 2005 年全室专利申请、授权一览表 2005 年申请专利 编 号 专利名称 申请日 专利号 1 含卤素取代基的酮亚胺类过渡金 属钛配合物、合成方法和用途 2005.07.22 200510028047.X 2 乙烯聚合催化剂、合成方法和用 途 2005.07.29 200510028284.6 4 乙烯共聚催化剂、合成方法和用 途 2005.07.29 α-甲基-β,β-双吲哚酮类化合物、 合成方法及其用途 2005.01.27 5 β,β-双吲哚酮类化合物、合成方 法及其用途 2005.01.27 200510023634.X 6 甾体骨架化合物、合成方法及其 用途 2005.04.14 200510025089.8 7 含碳氧醚键有机硅化合物、合成 方法及其应用 2005.07.01 200510027452.X 8 非均相钯催化剂、制备方法及其 应用 2005.09.20 200510029802.6 2005.08.12 200510028739.4 2005.06.10 200510026663.1 2005.07.15 200510027759.X 2005.01.27 200510023632.0 2005.11.16 200510110419.3 3 9 10 11 12 13 一种具有中心手性和平面手性二 茂铁口袋配体、合成方法及用途 使用金属盐催化苯酚类及本醚类 化合物的硝化方法 全氟烷磺酸盐催化均三甲苯的绿 色硝化方法 过渡金属络合物、合成方法及其 用途 双核金属络合物的合成及其催化 的二氧化碳和环氧化合物共聚合 9 200510028280.8 200510023633.5 发明人 谢光勇、 钱长涛、 姜卫华 谢光勇、 钱长涛、 姜卫华 谢光勇、 钱长涛、 姜卫华 麻生明、 余世超 麻生明、 余世超、 彭志华 麻生明、 陆平、 侯海荣、 韦捷敏、 何绮雯、 陆梁华、 顾振华、 姜雪峰、 金鑫 麻生明、 杨青、 肖丰收 麻生明、 杨青、 肖丰收 侯雪龙、 严小霞、 梁春根 施敏、 尹万坡 施敏、 尹万坡 丁奎岭、 荆庆 丁奎岭、 肖友利 和环加成反应 14 15 16 17 18 19 20 乙烯齐聚催化剂、合成方法及其 用途 2005.04.21 一种制备 2-芳基乳酸酯及萘普生、 布洛芬的方法 2005.05.27 4,4-二取代的-3,4-二氢-2(1H)-喹 唑啉酮类化合物 2005.07.22 制备乙氰菊酯前体的方法 An Amino Alcohol Ligand and Its Use in Preparation of Chiral Proparglic Tertiary Alcohols An Amino Alcohol Ligand and Its Use in Preparation of Chiral Proparglic Tertiary Alcohols An Amino Alcohol Ligand and Its Use in Preparation of Chiral Proparglic Tertiary Alcohols 2005.08.05 2005.09.30 2005.10.03 10 200510028570.2 唐勇、 郭阳辉、 孙秀丽 姜标、 司玉贵、 陈君、 刘家峰、 李凡、 李金华、 秦叶军 姜标、 董佳家 姜标、 司玉贵、 陈君、 李凡、 李金华、 秦叶军 EP03816495.0 姜标、 司玉贵 1060/MUMNP/2005 姜标、 司玉贵 US10/551,770 姜标、 司玉贵 200510025276.6 200510026269.8 200510028046.5 2005 年授权专利 编 号 专利名称 专利号 1 含给电子基团有机配体的二价稀土配合物、合成 方法与应用 02136621.7 2 一种合成β-氟胺化合物的方法 03141761.2 3 复合型金属络合物催化芳香族化合物的绿色硝 化方法 02111062.x 4 在氟相中芳香族化合物的绿色硝化法 使用 Hf 化合物催化酚类及芳香醚类化合物的绿 色硝化方法 01112801.1 6 外消旋的联二酚的光学拆分方法 02111829.9 7 新型烯烃聚合催化剂 02110844.7 8 1,3'-双(氧基苯氧基)苯的合成 98122045.2 9 一种不对称合成二级丙炔醇类化合物的方法 01105779.3 10 手性氨基醇配体及其在端炔对亚氨的不对称加 成中的应用 03116192.8 5 11 200310108236.9 发明人 钱长涛、 陈耀峰、 邹刚、 李楠、 李杨、 邹丰楼 侯雪龙、 范仁华、 戴立信 施敏、 崔世聪 施敏、 崔世聪 施敏、 崔世聪 丁奎岭、 杜海峰 唐勇、 胡蔚秋、 孙秀丽、 王聪、 张玉良 姜标、 谭龙泉 姜标、 熊文南、 陈自立 姜标、 司玉贵 2005 年金属有机化学国家重点实验室来访人员名单 周其林教授 南开大学 2005,1,21 雷爱文博士 美国 Stanford 大学 2005,3,2 Dr. Li Jia 美国 Lehigh Univ. 吴云东教授 香港科技大学 游书立博士 美国 Genomics Institute of the Novartis 2005,3,2 2005,4,6 Research Foundation 2005,4,5 Prof. H. Bönnemann 德国马普学会煤炭研究所 2005,4,8 Prof. Henri Rudler 法国巴黎大学 2005,4,18 贾国成教授 香港科技大学 2005,4,21 Prof. Ken Feldman Pennsylvania State Univ. 2005,5,9 Prof. Antonio Togni Swiss Federal Institute of Technology(ETH) 2005,5,12; 2005,5,13 蒲林教授 美国 Univ. of Virginia 2005,6,9 Prof. Joseph M. O’Connor 美国 univ. of California 2005,6,9 Prof. Benjamin List 德国马普学会煤炭研究所 2005,9,2 Prof. Björn Åkermark Stockholm University 2005,9,12 Prof. Walter Weissensteiner Univ. of Vienna 2005,9,14 Dr. Michael Pucheberger Univ. of Vienna 2005,9,14 Prof. Walter Siebert 德国 Univ. of Heidelberg 2005,9,19 Prof. B. L. Feringa 荷兰 Univ. of Groningen 2005,10,10 Prof. Keiji Maruoka 日本 Kyoto Univ. 2005,10,10 Dr. Ronald Hage 荷兰 Unilever Research, Vlaardingen 12 2005,10,11 Prof. Yoshio Okamoto 日本 Nagoya Univ. Prof. Shun-Ichi Murahashi 日本 Okayama Univ. of Science 2005,10,19 Prof. Johannes G. de Vries 荷 兰 DSM 2005,10,14 Pharma Chemicals 2005,10,21 Dr. Yusheng Wu 美国 Schering-Plough Research Institute 2005,10,26 2005,10,28 陈建添教授 台湾师范大学化学系 Prof. A. Fürstner 德国 Max-Planck-Institut für Kohlenforschung 2005,11,1 Prof. Harry Gray 美国 California Institute of Technology 2005,11,7 Prof. Hisashi Yamamoto 美国 The University of Chicago 2005,11,10 Prof. George A. O’Doherty 美国 West Virginia University 13 2005,12,13 二 00 五年专著目录 专著(章节)题目 作者 第五章 稀土配合物和 金属有机化合物 倪嘉瓒 钱长涛 第七章 稀土 Lewis 酸催化的有机反应 邹刚 钱长涛 专著名称 出版社名称 年份 页码 主编姓名 中国科学院 科学出版社 稀土研究五十 年 绿色有机催化 中国石化出版 社 2005 57-80 倪嘉瓒 洪广言 2005 244303 赵刚 Palladium(II)-Catalyz Zhao, L.; Catalysts for John Wiley 2004 ed Cyclization of Lu, X.* Fine & Sons Alkynes with Chemical Aldehydes, Ketones Synthesis, or Nitriles Initiated Vol. 3, Metal by Catalysed Acetoxypalladation Carbon-Carb of Alkynes on Bond-Formin g Reactions Pd-Catalyzed two or Shengming Topics in Springer 2005 three-component Ma Organometall cyclization of ic Chemistry functionalized Allenes 185-1 Roberts, 90 S. M.; Xiao, J.; Whittall, J.; Pickett, T. 2005 pp. 吴毓林，麻 61-93 生明，戴立 信 合成反应方法学-主族 和后过渡元素催化的有 机合成反应 麻生明 现代有机合成 化学工业出版 化学进展 183-2 Tsuji, J. 10 Xue Long Progress in Elservier 2005 G. W. Hou, Zhen Heterocyclic Gribble and Chemistry J. A. Joule, Furan and Benzofuran Yang and H. N. C. Wong 有机功能小分子催化有 施敏 绿色有机催化 中国石化出版 2005 8－40 赵刚 机反应 社 不对称催化研究进展 郭红超、丁奎 现代有机合成 化学工业出版 2005 174-21 吴毓林、麻 6 年8月 岭， 化学进展， 社 生明、戴立 信 组合不对称催化研究进 郭红超、丁奎 不对称有机反 化学工业出版 2005 39-91 李月明，范 年1月 展， 岭 应， 社 青华，陈新 滋 14 二 00 五年论文目录 课题负责人：陆熙炎 课题编号： 2004-01 1. Cycloisomerization of 1,6-Enynes Using Acetate as a Nucleophile under Palladium(II) Catalysis Zhang, Q.; Xu, W.; Lu, X*. J. Org. Chem. 2005, 70, 1505-1507. 40 2. Palladium(II)-Catalyzed Enyne Coupling Reaction Initiated by Acetoxypalladation of Alkynes and Quenched by Protonolysis of the Carbon-Palladium Bond Zhao, L.; Lu, X.*; Xu, W. J. Org. Chem. 2005, 70, 4059-4063. 43 3. A Phosphine-Catalyzed [3+6] Annulation Reaction of Modified Allylic Compounds and Tropone Du, Y.; Feng, J.; Lu, X*. Org. Lett. 2005, 7, 1987-1989. 48 4. Control of the β-Hydride Elimination Making Palladium-Catalyzed Coupling Reactions More Diversified Lu, X. Topics in Catalysis 2005, 35, 73-86. 51 5. Pd(II)-Bipyridine Catalyzed Conjugate Addition of Arylboronic Acid to β-Unsaturated Carbonyl Compounds Lu, X.*; Lin, S. J. Org. Chem. 2005, 70, 9651-9653. 65 6. Synthetic Methodology Using Tertiary Phosphines as Nucleophilic Catalysts Lu, X.*; Du, Y.; Lu, C. Pure Appl. Chem. 2005, 77, 1985-1990. 68 7. 钯催化反应中的β-氢消除反应 韩秀玲、刘桂霞、陆熙炎* 有机化学 2005, 25, 1182-1197. 课题负责人：钱长涛 74 课题编号： 2004-02 1. A Convenient Synthesis of α,α’-Bis (substituted benzylidene) cycloalkanones Catalyzed by Yb(OTf)3 Under Solvent-Free Conditions Limin Wang,*a Jia Sheng, aHe Tian,a Jianwei Han,a Zhaoyu Fan,a Changtao Qianb Synthesis, 2004, 18, 3060–3064. 90 15 2. The effect of coordination on the reaction of N-tosyl imines with diethylzinc Feifeng Gao, Minzhi Deng and Changtao Qian* Tetrahedron, 2005, 61, 12238–12243. 95 3. Homolysis of the Ln–N bond: Synthesis, characterization and catalytic activity of organolanthanide(II) complexes with furfuryl- and tetrahydrofurfuryl-functionalized indenyl ligands Yongyong Wu a, Shaowu Wang a,b,*, Changtao Qian b,*, Enhong Sheng a, Meihua Xie a, Gaosheng Yanga, Qiqing Feng a, Lijun Zhang a, Xinliang Tanga J. Organometallic Chem, 2005, 690, 4139–4149. 101 4. One-Pot Synthesis of cis-Isoquinolonic Acid Derivatives via Three-Component Reaction of Homophthalic Anhydride with Aldehydes and Amines using Ytterbium(III) Triflate as Catalyst Limin Wang,a,* Jijun Liu,a He Tian,a Changtao Qian,b Jie Sunb Adv. Synth. Catal. 2005, 347, 689 –694. 112 5. Facile Yb(OTf)3 promoted one-pot synthesis of polyhydroquinoline derivatives through Hantzsch reaction Li-Min Wang,a,* Jia Sheng,a Liang Zhang,a Jian-Wei Han,a Zhao-Yu Fan,a He Tiana and Chang-Tao Qianb Tetrahedron, 2005, 61, 1539–1543. 118 课题负责人：麻生明 课题编号： 2004-03 1. Study on halolactamization-γ-hydroxylation 2,3-alkadienamides Shangming Ma*, and Hexin Xie Tetrahedron, 2005, 61, 251-258. or haloiminolactonization of 123 2. NaI-Catalyzed Highly Regioselective Ring-Opening [1+2] Cycloaddition Reaction of Cyclopropenes with Imines. Highly Stereoselective Synthesis of cis-Vinylic Aziridines Shengming Ma, Junliang Zhang, Lianghua Lu, Xin Jin, Yangjun Cai, and Hairong Hou Chem. Commun. 2005, 909-911. 131 3. I--Catalyzed Methyl-Oxygen Bond Cleavage in 2-Methoxyfurans. An Efficient Synthesis of Butenolides Shengming Ma*, Lianghua Lu and Ping Lu J. Org. Chem. 2005, 70, 1063-1065. 134 4. Pd(II)-Catalyzed Oxidative Dimeric Cyclizative Coupling Reaction of 2,3-Allenoic Acids. An Efficient Synthesis of Bi-butenolide Derivatives Shengming Ma*, Zhanqian Yu, and Zhenhua Gu Chem. Eur. J. 2005, 11, 2351-2356. 137 16 5. Tunable 1,3-Lithium Shift of Propargylic / Allenylic Lithiums Formed by Conjugate Addition of 4-Aryl-3-butyn-1-enes with Organolithiums and the Subsequent Transmetalation / Pd(0)-Catalyzed Coupling Reaction with Aryl Halides Shengming Ma*, Qiwen He, and Xin Jin Synlett , 2005, 514-516. 143 6. Studies on Pd(II)-Catalyzed Synthesis of (Z)--Haloalkylidene--lactones from Cyclocarbonylation of 2-Alkynols and the Subsequent Coupling Reactions Shengming Ma*, Bin Wu, Xuefeng Jiang, and Shimin Zhao J. Org. Chem. 2005, 70, 2568-2575. 146 7. PdCl2-Catalyzed Efficient Transformation of Propargylic Amines to (E)--Chloroalkylidene--lactams Shengming Ma*, Bin Wu and Xuefeng Jiang J. Org. Chem. 2005, 70, 2588-2593. 154 8. Studies on t-BuOK-Catalyzed Michael Addition of 1, 2-Allenic Ketones with 2-Substituted Diethyl Malonates: Highly Selective Synthesis of , -Unsaturated Enones Shengming Maa,b*, Shichao Yua a and Wenjian Qianb Tetrahedron 2005, 61, 4157-4164. 160 9. Sc(OTf)3-Catalyzed Efficient Synthesis of -Bisindolyl Ketones by the Double Indolylation of Acetic Acid 2-Methylene-3-oxobutyl Ester Shengming Ma,* Shichao Yu and Zhihua Peng Org. & Biomol. Chem. 2005, 3, 1933-1936. 168 10. Pd(0)-Catalyzed Highly Selective Synthesis of 1,1-Diarylpropadienes and 1,3-Diarylpropynes From 1-Aryl-1-propynes and Aryl Halides Shengming Ma*, Qiwen He, and Xiuhui Zhang J. Org. Chem. 2005, 70, 3336-3338. 172 11. Synthesis of Butenolides via Transition Metal-Catalyzed Cyclization Reaction of 2,3-Allenoic Acids Shengming Ma and Zhanqian Yu Journal of the Graduate School of the Chinese Academy of Sciences 2005, 22, 110-121. 175 12. PdCl2-Catalyzed Two-Component Cross-coupling Cyclization of 2,3-Allenoic Acids and 2,3-Allenols. An Efficient Synthesis of 4-(1’, 3’-Dien-2’-yl)-2-furanone Derivatives Shengming Ma* and Zhenhua Gu J. Am. Chem. Soc. 2005, 127, 6182-6183. 187 13. Probing the Mechanism of Palladium-Catalyzed Addition of Organoboronic Acids 17 to Allenes in the Presence of AcOH with ESI-FTMS Rong Qian, Hao Guo, Yuanxi Liao, Yinlong Guo* and Shengming Ma* Angew. Chem. Int. Ed. 2005, 44, 4771-4774. 189 14. What Can a Metal Catalyst Do with Allenes? One-Step Building Up of New Steroid Scaffold from Easily Available Starting Materials Shengming Ma*, Ping Lu, Lianghua Lu, Hairong Hou, Jiemin Wei, Qiwen He, Zhenhua Gu, Xuefeng Jiang and Xing Jin Angew. Chem. Int. Ed. 2005, 44, 5275-5278. 193 15. A Palladium Catalyzed Efficient Synthesis of γ-Methylene-α, β-unsaturated γ-Lactones via Cyclization of 3,4-Alkadienoic Acids Shengming Ma* and Fei Yu Tetrahedron 2005, 61, 9896-9901. 197 16. Sc(OTf)3-Catalyzed Indolylation of 1, 2-Allenic Ketones: Controlled Highly Selective Synthesis of -Indolyl-α,β-Unsaturated (E)-enones and ，-Bisindolyl Ketones Shengming Ma * and Shichao Yu Org. Lett. 2005, 7, 5063-5065. 203 17. Intramolecular Double or Triple Suzuki Coupling Reaction of Substituted Di- or Tribromobenzenes. An Easy Synthesis of Fused Tri- or Tetracycles with a Benzene Core Shengming Ma*, Bukuo Ni, Shaohui Lin and Zhiqiang Liang J. Organnomet. Chem. 2005, 690, 5389-5395. 206 18. 1,4-Migration of Rhodium and Palladium in Catalytic Organometallic Reactions Shengming Ma* and Zhenhua Gu Angew. Chem. Int. Ed. 2005, 44, 7512-7517. 213 19. Pd(CH3CN)2Cl2-Catalyzed Oxidative Heterodimerization Reaction of 2,3-Allenamides and 1,2-Allenyl Ketones: An Efficient Synthesis of 4-(Furan-3’-yl)-2(5H)furanimines Shengming Ma,* Zhenhua Gu, and Zhanqian Yu J. Org. Chem. 2005, 70, 6291-6294. 219 20. An Efficient Stereoselective Synthesis of 4,5-trans-1,5-cis-3-Oxabicyclo[3.1.0]hexan-2-ones via the Iodolactonization of Alkylidenecyclopropyl Esters Shengming Ma* and Lianghua Lu J. Org. Chem. 2005, 70, 7629-7633. 223 21. ESI-MS Studies on the Mechanism of Pd(0)-Catalyzed Three-Component Tandem Double Addition-Cyclization Reaction Hao Guo,a Rong Qian,b Yuanxi Liao,b Shengming Ma,a* and Yinlong Guob* J. Am. Chem. Soc. 2005, 127, 13060-13064. 228 18 22. Observation of the First Heck-Type Cross-Coupling Reaction of Allenes with Aryl Halides. Synthesis of Polysubstituted 1,2-Allenyl Sulfones Chunling Fu and Shengming Ma Org. Lett. 2005, 7, 1605-1607. 233 23. Highly Regio- and Stereoselective Synthesis of 2(E),4-Alkadienoates via the Pd(0)-Catalyzed Reaction of Aryl Halides with 3,4-Alkadienoates Chunling Fu and Shengming Ma* Org. Lett. 2005, 7, 1707-1709. 236 24. Efficient Synthesis of 3-Halo-3-enals from Propargylic Bromides via Unique Cationic 1,2-Aryl Shift in Electrophilic Addition Reaction of 2,3-Allenols with X+(X= Br and I) Chunling Fu, a Jing Li a and Shengming Ma a ,b* Chem. Commun. 2005, 4119-4121. 239 25. 26. 27. Some Typical Advances in the Synthetic Applications of Allenes Shengming Ma Chem. Rev. 2005, 105, 2829-2871. 242 Stereoselective Z-Iodoalkoxylation of 1,2-Allenyl Sulfides or Selenides Chunling Fu,a Guofei Chen,a Xiaoyi Liu, a and Shengming Ma a ,b* Tetrahedron 2005, 61, 7768-7773. 285 Efficient Preparation of 4-Iodo-2(5H)-furanones via the Iodolactonization of 2,3-Allenoates with I2 Chunling Fu and Shengming Ma* Eur. J. Org. Chem. 2005, 3942-3945. 291 28. NaSO2Ph – Induced Exclusive Isomerization of 1,2-Allenyl Sulfoxides to 2-Acetylenic Phenyl Sulfoxides FU, Chun-Ling and MA, Sheng-Ming Chin. J. Chem. 2005, 23, 729-732. 295 课题负责人：侯雪龙 课题编号： 2004-04 1. A Mild and Convenient Procedure for Desulfinylation of p-Toluenesulfinyl Amines Bin Feng Li, Ke Yuan, Ming Jie Zhang, Li Xin Dai, and Xue Long Hou Synlett 2005, 535-537. 299 19 2. Enantioselective Transition-Metal Catalyzed Carbon-Carbon Bond Formation Reactions Using Novel Chiral Ferrocenes and Cyclophanes Xue Long Hou,* Shu Li You, Tao Tu, Wei Ping Deng, Xun Wei Wu, Ming Li, Ke Yuan , Tang Zhi Zhang and Li Xin Dai* Topics in Catalysis 2005, 35, 87-103. 302 3. A Highly Efficient Palladacycle Catalyst for Hydroarylation of C-, N- and O-Substituted Bicyclic Alkenes under Aerobic Condition Yuan, K.; Zhang, T. K.; Hou, X. L. J. Org. Chem. 2005, 70, 6085-6088. 319 4. Highly Enantioselective Pd-Catalyzed Asymmetric Allylic Alkylation of Acyclic Ketones with Bis-N-[2-(diphenylphosphino)ferrocylidene]diiminocyclohexane Ligand Yan, X. X.; Liang, C. G.; Zhang, Y.; Hong, W.; Cao, B. X.; Dai, L. X.; Hou, X. L.* Angew. Chem. Int. Ed. 2005, 44, 6544-6546. 323 5. A Convenient and Efficient Ring-Opening Reaction of Aziridines with Acetylenes and Synthesis of dihydropyrroles Ding, C. H.; Dai, L. X.; Hou, X. L.* Tetrahedron 2005, 61, 9586-9593. 326 6. Highly Regio- and Enantioselective Palladium-Catalyzed Allylic Alkylation and Amination of Dienyl Esters with 1,1’-P,N-Ferrocene Ligands Zheng, W. H.; Sun, N.; Hou, X. L. Org. Lett. 2005, 7, 5151-5154. 334 课题负责人：沈延昌 1 课题编号： 2004-05 Stereospecific Synthesis of Trifluoromethylated Vinyl sulfides Yanchang Shen, Guoping Wang Synthesis 2005, 2183-2187. 2. “One-pot” Synthesis of Trifluoromethylated 4-Cyanoalka-1,4-dienes with Predominant Z-selectivity Yanchang Shen, Guoping Wang Synth. Commun. 2005, 35, 2521-2527. 课题负责人：陈家碧 338 343 课题编号： 2004-06 1. Cyclooctatatraene (COT)-Coordinated Diiron Carbene Complexes and Their Remarkable Thermolysis Reactions Lei Zhang, Shu Zhang, Qiang Xu, Jie Sun, and Jiabi Chen* Organometallics, 2005, 24, 933-944. 350 20 2. Unusual Reactions of Cationic Carbyne Complexes of Manganese and Rhenium with Carbonylmetal Anions [Ir(CO4)]- and [Ru(CO4)]2-. Novel Route to Heteropolymetallic Bridging Carbyne Complexes Lei Zhang,† Nu Xiao,† Qiang Xu,*‡ Jie Sun,† and Jiabi Chen*,† Organometallics, 2005, 24, 5807-5816. 362 3. Synthesis, struture and reactivity of novel pyridazine-coordinated diiron bridging carbene complexes Lei Zhang,a Qiang Xu,*b Jie Sun,a and Jiabi Chen*,a Dalton Trans., 2005, 3250-3258. 372 课题负责人：邓敏智 课题编号： 2004-07 1．Palladium-Catalyzed Cross-Coupling Chloroformate or Carbamoyl Chloride Ya-Zheng Duan, Min-Zhi Deng Synlett, 2005, 2, 355-357. 课题负责人：姜 标 Reaction of Arylboronic Acids with 381 课题编号： 2004-08 1. Resolution of ()-[2.2] paracyclophane-4,12-dicarboxylic acid. Biao Jiang, Xiao-Long Zhao and Xiang-Ya Xu Tetrahedron: Asymmetry 2005, 16, 1071-1074. 384 2. Synthesis of -(3-Indolyl)glycine Derivatives via Spontaneous Friedel-Crafts Reaction between Indoles and Glyoxylate Imines Biao Jiang, Zuo-Gang Huang. Synthesis 2005, 13, 2198-2204. 388 3. Progress in the Study of Marine Bromopyrrole Alkaloids. Liu, Jia-Feng, GUO, Song-Po, Biao Jiang Chin. J. Org. Chem. 2005, 25(7), 788-799. 课题负责人：施 敏 395 课题编号： 2004-09 1. Synthesis of an Axially Chiral Ir-NHC Complex Derived from BINAM. Min Shi* and Wei-Liang Duan Applied Organomet. Chem. 2005, 19, 40-44. 407 2. Catalytic, asymmetric aza-Baylis-Hillman reaction of N-sulfonated imines with activated olefins by quinidine-derived chiral amines. Min Shi,* Yong-Mei Xu and Yong-Ling Shi Chem. Eur. J. 2005, 11, 1794-1802. 412 21 3 Chiral phosphine Lewis bases catalyzed asymmetric aza-Baylis-Hillman reaction of N-sulfonated imines with activated olefins. Min Shi,* Lian-Hui Chen, and Chao-Qun Li J. Am. Chem. Soc. 2005, 127, 3790-3800. 421 4. Lewis Acid Mediated Reactions of Cyclopropyl Aryl Ketones with Arylaldehydes, Atom-economic Preparation of 2-(2-Hydroxyethyl)-1,3-diarylpropenone. Min Shi,* Yong-Hua Yang, and Bo Xu Tetrahedron 2005, 61, 1893-1901. 432 5. Carbolithiation of gem-Aryl Disubstituted Methylenecyclopropanes Jin-Wen Huanga and Min Shi,b* Org. Bio. Chem. 2005, 3, 399-400. 441 6. Asymmetric 1,4-Addition of Diethylzinc to Cyclic Enones Catalyzed by Cu(I)-Chiral Sulfonamide-thiophosphoramide Ligands and Lithium Salts. Min Shi* and Wen Zhang Adv. Synth. & Catal. 2005, 347, 535-540. 443 7. Highly Efficient Catalytic Nitration of Phenolic Compounds with Recoverable and Reusable Zr or Hf Oxychloride Complex and KSF. Min Shi,* Shi-Cong Cui, and Wan-Po Yin Eur. J. Org. Chem. 2005, 2379-2384. 449 8. Catalytic, asymmetric aza-Baylis-Hillman reaction of N-sulfonated imines with 2-cyclohexen-1-one and 2-cyclopeten-1-one in the presence of a chiral phosphine Lewis base. Min Shi* and Chao-Qun Li Tetrahedron:Asymmetry 2005, 16, 1385-1391. 455 9. A New Dimeric Bidentated NHC-Pd(II) Complex from trans-Cyclohexane-1,2-diamine for Suzuki Reaction and Heck Reaction Min Shi* and Heng-xin Qian Tetrahedron 2005, 61, 4949-4955. 462 10. Mannich-type Reaction of (1-Methoxy-2-methylpropenyloxy)trimethylsilane with Arylaldehydes and Aromatic Amines Catalyzed by Perfluorinated Rare Earth Metal Salts in Fluorous Phase. Min Shi,* Shi-Cong Cui and Ying-Hao Liu Tetrahedron 2005, 61, 4965-4970. 469 11. Manganese(III)-Mediated Oxidative Annulation of Methylenecyclopropanes with 1,3-Dicarbonyl Compounds. Jin-Wen Huang and Min Shi* J. Org. Chem. 2005, 70, 3859-3863. 475 22 12. DABCO Catalyzed Addition of Selenosulfonates to ,-Unsaturated Ketones. Yong-Ling Shi and Min Shi* Org. Bio. Chem. 2005, 3, 1620-1621. 480 13. Facile Synthesis of Multisubstituted Buta-1,3-dienes via Suzuki-Miyaura and Kumada Cross-Coupling Strategy of 2,4-Diiodo-buta-1-enes with Arylboronic Acids and Grignard Reagents. Li-Xiong Shaoa and Min Shi b Org. Bio. Chem. 2005, 3, 1828-1831. 482 14. Palladium-catalyzed isomerization of methylenecyclopropanes in acetic acid. Min Shi,a* Bao-Yu Wang,b and Jin-Wen Huang,a J. Org. Chem. 2005, 70, 5606-5610. 486 15 Chiral phosphine Lewis bases bearing perfluoroalkanes as “pony tails” catalyzed asymmetric aza-Morita-Baylis-Hillman reaction of N-sulfonated imines with methyl vinyl ketone. Min Shi,a,b* Lian-Hui Chena and Wen-Dong Tengb Adv. Synth. & Catal. 2005, 347, 1781-1789. 491 16. Ring-opening Reactions of Arylvinylidenecyclopropanes with Diaryl Diselenide upon Heating: Formation of 1,2-Diarylselenylcyclopentene Derivatives. Min Shi,* Jian-Mei Lu and Guang-Cai Xu Tetrahedron Lett. 2005, 46, 4745-4748. 500 17. DABCO-Catalyzed Reaction of Allenic Esters and Ketones with Salicyl N-Tosylimines: Synthesis of Highly Functionalized Chromenes. Yong-Ling Shi and Min Shi* Org. Lett. 2005, 7, 3057-3060. 504 18. Enynylation of 2-Iodo-4-phenylchalcogenyl-1-butenes via Intramolecular Chelation: Approach to the Synthesis of Conjugated Dienynes or Trienynes. Min Shi,a* Le-Ping Liub and Jie Tangb Org. Lett. 2005, 7, 3085-3088. 508 19. Transamidation Catalyzed by a Recoverable and Reusable PolyDMAP-Based Hafnium Chloride and Montmorillonite KSF. Min Shi* and Shi-Cong Cui Synth. Commun. 2005, 2847-2858. 512 20. A Stable Dimeric Mono-Coordinated NHC-Pd(II) Complex. Synthesis, Characterization, and Reactivity in Suzuki-Miyaura Cross-coupling Reaction. Min Shi* and Heng-xin Qian Applied Organometal. Chem. 2005, 19, 1083-1089. 524 21. Halogen Effects in Robinson-Gabriel Type Reaction of Cyclopropanecarboxylic 23 Acid N'-Substituted-hydrazides with PPh3/CX4. Yong-Hua Yang and Min Shi* Tetrahedron Lett. 2005, 46, 6285-6288. 22. 531 Reactions of Vinylidenecyclopropanes with Diaryl Diselenide Catalyzed by Iodosobenzene Diacetate and Further Transformation of the Adducts Min Shi* and Jian-Mei Lu Synlett 2005, 2352-2356. 535 23 Ring-expanding Reaction of Cyclopropyl Amides with Triphenylphosphine and Carbon Tetrahalide. Yong-Hua Yang and Min Shi* J. Org. Chem. 2005, 70, 8645-8648. 540 24. Baylis-Hillman Reactions of N-Tosyl Aldimines and Aryl Aldehydes with 3-Methylpenta-3,4-dien-2-one. Gui-Ling Zhao and Min Shi* Org. Bio. Chem. 2005, 3, 3686-3694. 544 25. Facile Synthesis of 2-Alkynyl Buta-1,3-dienes via Sonogashira Cross-Coupling Strategy Li-Xiong Shao and Min Shi* J. Org. Chem. 2005, 70, 8635-8637. 553 26. Synthesis of Functionalized 2H-1-Benzopyrans by DBU-Catalyzed Reactions of Salicylic Aldehydes with Allenic Ketones and Esters. Gui-Ling Zhao, Yong-Ling Shi, and Min Shi* Org. Lett. 2005, 7, 4527-4530. 556 27. Palladium-catalyzed Typical Cross-coupling Reactions of 2-Iodo-4-(phenylchalcogenyl)-1-butenes. Min Shi,a* Le-Ping Liu,b and Jie Tangb J. Org. Chem. 2005, 70, 10420-10425. 560 28. Aza-Baylis-Hillman Reactions of N-Tosylated Aldimines with Activated Allenes and Alkynes in the Presence of Various Lewis Base Promoters. Gui-Ling Zhao and Min Shi* J. Org. Chem. 2005, 70, 9975-9984. 566 29. Lewis Acid Mediated Reactions of Cyclopropyl Aryl Ketones with -Ketoesters: Facile Preparation of 5,6-Dihydropyran-2-ones. Yong-Hua Yang and Min Shi* J. Org. Chem. 2005, 70, 10082-10085. 576 30. Highly Efficient and Seteroselective Construction of 1-Iodo- or 1-Phenylselenenyl-2-aryl-3-oxabicyclo[3.1.0]hexane from the Reaction of 24 Arylmethylidenecyclopropylcarbinols with Iodine or Diphenyldiselenide. Bao-Yu Wang, Jin-Wen Huang, Le-Ping Liu and Min Shi* Synlett 2005, 421-424. 580 31. Sulfinatodehalogenation reactions of gem-aryl disubstituted methylenecyclopropanes with perfluoroiodoalkanes. Min Shia,b* and Jin-Wen Huangb J. Fluoro. Chem. 2005, 126, 809-817. 584 32. A Novel Rearrangement of Arylvinylidenecyclopropanes to Naphthalene Derivatives Catalyzed by Lewis Acids or Brønsted Acids. Guang-Cai Xu,a Ming Ma,a Le-Ping Liub and Min Shia* Synlett 2005, 1869-1872. 593 33. Ring-opening Reactions of Diarylvinylidenecyclopropanes by Iodine and Bromine. Min Shi,a* Ming Maa and Li-Xiong Shaob Tetrahedron Lett. 2005, 46, 7609-7613. 597 34. Lewis Acid-Catalyzed Rearrangement of Multi-Substituted Arylvinylidenecyclopropanes Guang-Cai Xu,a Le-Ping Liu,b Jian-Mei Lu,b and Min Shia.b* J. Am. Chem. Soc. 2005, 127, 14552-14553. 课题负责人：丁奎岭 602 课题编号： 2004-10 1. One Catalyst for Two Distinct Reactions: Sequential Asymmetric Hetero Diels-Alder Reaction and Diethylzinc Addition Haifeng Du, Xue Zhang, Zheng Wang, Kuiling Ding* Tetrahedron 2005, 61, 9465-9477. 604 2. Heterogenization of Shibasaki’s Catalyst for Enantioselective Epoxidation of ,-Unsaturated Ketones Using Multitopic BINOL Ligands: The Impact of Bridging Spacers Xingwang Wang, Lei Shi, Mingxing Li and Kuiling Ding* Angew. Chem. Int. Ed. 2005, 44, 6362-6366. 617 3. Ten Years of Research on NOBIN Chemistry Kuiling Ding*, Xin Li, Baoming Ji, Hongchao Guo, Masato Kitamura Curr. Org. Synth. 2005, 2, 499-545. 622 4. A New Type of Bisphosphine Ligands for Palladium-Catalyzed Desymmetrization of meso-Cyclopent-2-en-1,4-diol Bis(carbamate) Zhao Dongbo, Zheng Wang, Kuiling Ding* Synlett 2005, 2067-2071. 669 5. Modular Monodentate Phosphoramidite 25 Ligands for Rhodium Catalyzed Enantioselective Hydrogenation Yan Liu and Kuiling Ding* J. Am. Chem. Soc. 2005, 127, 10488-10489. 674 6. Bulky Achiral Triarylphosphanes Mimick BINAP in Ru(II) Catalyzed Asymmetric Hydrogenation of Ketones Qing Jing, Xue Zhang, Jie Sun and Kuiling Ding* Adv. Synth. Cat. 2005, 347, 1193-1197. 676 7. Programmed Assembly of Two Different Ligands with Metallic Ions: Generation of Self-Supported Noyori-Type Catalysts for Heterogeneous Asymmetric Hydrogenation of Ketones Yuxue Liang, Qing Jing, Xin Li, Lei Shi, and Kuiling Ding* J. Am. Chem. Soc. 2005, 127, 7694-7695. 681 8. Self-Supported Heterogeneous Titanium Catalysts for Enantioselective Carbonyl-ene and Sulfoxidation Reactions Xisheng Wang, Xingwang Wang, Hongchao Guo, Zheng Wang and Kuiling Ding* Chem. Eur. J. 2005, 11, 4078-4088. 683 9. Highly Regio- and Enantioselective Thermal [2+2] Cycloaddition of Coumarin in a Crystalline Inclusion Complex under High Vacuum Yongqiang Wen, Yanlin Song*, Dongbo Zhao, Kuiling Ding*, Jiang Bian, Xuezhang, Jingxia Wang, Yang Liu, Leijiang, Daoben Zhu Chem. Commun., 2005, 2732-2734. 694 10. PEG Polymer Supported Liquid-Phase Combinatorial Synthesis of Structurally Diverse 2,3-Dihydro-4-pyridones Hongchao Guo, Zheng Wang, Kuiling Ding* Synthesis, 2005, 1061-1068. 697 11. Copolymerization of Cyclohexene Oxide with CO2 Using Intramolecularly Dinuclear Zinc Catalysts Youli Xiao, Zheng Wang, Kuiling Ding* Chem. Eur. J. 2005, 11, 3668-3678. 705 12. Combinatorial approach to the discovery of chiral catalysts for asymmetric reactions Kuiling Ding Pure Appl. Chem. 2005, 77, 1251-1257. 716 13. Synthesis of NOBIN derivatives for asymmetric catalysis Kuiling Ding*, Hongchao Guo, Xin Li, Yu Yuan, Yi Wang Topics in Catalysis, 2005, 35, 105-116. 课题负责人：唐 勇 课题编号： 2004-11 26 723 1. The Michael Addition-Elimination of Ylides to r,â-Unsaturated Imines. Highly Stereoselective Synthesis of Vinylcyclopropanecarbaldehydes and Vinylcyclopropylaziridines Jun-Cheng Zheng, Wei-Wei Liao, Yong Tang*, Xiu-Li Sun, and Li-Xin Dai J. Am. Chem. Soc., 2005, 127, 12222-12223. 735 2. The development and application of chiral trisoxazolines in asymmetric catalysis and molecular recognition. Zhou, J.; Tang, Y.* Chem. Soc. Rev., 2005, 34, 664-676. 737 3. Telluronium and Sulfonium Ylides for Organic Transformation Yong Tang,*a Song Ye,b Xiu-Li Suna Synlett, 2005, 2720–2730.03. 750 4. Highly Stereoselective Synthesis of Trisubstituted Vinylcyclopropane Derivatives via Arsonium Ylides Hong Jiang, Xianming Deng, Xiuli Sun, Yong Tang* and Li-Xin Dai J. Org. 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Telluronium Salts Mediated Aziridination of Chiral N-tert-Butylsulfinylimines: Highly Stereoselective Synthesis of Optically Active Vinylaziridines Jun-Cheng Zheng, Wei-Wei Liao, Xiao-Xia Sun, Xiu-Li Sun, Yong Tang*, Li-Xin Dai, and Jin-Geng Deng Org. Lett., 2005, 7, 5789-5792. 778 课题负责人：张兆国 课题编号： 2004-12 1. Ru-catalyzed asymmetric hydrogenation of alpha-ketoesters with CeCl3 7H2O as 27 additive Sun, Y.; Wan, X.; Wang, J.; Meng, Q.; Zhang, H.; Jiang, L.; Zhang, Z Org. Lett. 2005, 7, 5425-5427. 2. cis-chloropalladation of 1,6-enynes Zhu G.; Zhang Z. J. Org. Chem. 2005, 70, 3339-3341. 782 785 3. Palladium-catalyzed tandem cyclization/Suzuki coupling of 1,6-enynes: Reaction scope and mechanism Zhu, G.; Tong, X.; Cheng, J.; Sun, Y.; Li, D.; Zhang, Z. J. Org. Chem. 2005, 70, 1712-1717. 788 4. Synthesis of a bulky and electron-rich derivative of SEGPhos and its application in Ru-catalyzed enantioselective hydrogenation beta-ketoesters Wan, X.; Sun, Y.; Luo, Y.; Li, D.; Zhang, Z. J. Org. 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Gold-catalyzed Cyclization of (Z)-2-En-4-yn-1-ols: Highly Efficient Synthesis of Fully Substituted Dihydrofurans and Furans. Liu, Y.; Song, F.; Song, Z.; Liu, M.; Yan, B. Org. Lett. 2005, 7，5409-5412. 813 28 课题负责人：许 旭 课题编号： 2004-14 1. 美拉德反应研究进展 郑文华，许旭* 化学进展，2005,17(1):122-129. 817 2. HPLC 同时测定一清胶囊中黄芩苷、大黄酸和小檗碱的含量 李奕，许旭* 中成药，2005,7(2):155-157. 825 3. 抗凝血酶效价法测定蛭萸颗粒剂中的水蛭成分 毛平，吴婉静，许旭*，虞桂珍 中成药，2005,27(2):282-285. 828 4. 正相高效液相色谱法拆分舒必利对映体和分析左舒必利有关物质 王建忠，许旭*，胡建国，李劲 药物分析杂志，2005,25(5):490-492. 832 5. Simultaneous determination of baicalin, berberine and rhein in the traditional Chinese patent medicine San-Huang-Pian tablet by HPLC Li Yi, Gao Jian-Ping, Xu Xu Journal of Chinese Pharmaceutical Sciences, 2005, 14(2):110-114 835 6. 高效液相色谱紫外检测器性能差异的评价 法洋，许旭*，雷晓玲 分析仪器, 2005,(4): 39-41. 840 7. 高效液相色谱整体柱技术的进展 鲍笑岭，许旭 分析化学, 2005,33(11): 1653-1658. 843 课题负责人：宋礼成 课题编号： 2004-15 1. 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Carbon-Bridged Bisphenolate Lanthanide Alkoxides: Syntheses, Structures and their Application in the Controlled Polymerization of -Caprolactone Yingming Yao, Xiaoping Xu, Bao Liu, Yong Zhang, Qi Shen, Wing-Tak Wong Inorg. Chem., 2005, 44(14), 5133-5140. 891 30 2. Synthesis, Reactivity and Characterization of Amine Bis(phenolate) Lanthanide Complexes and their Application in the Polymerization of -Caprolactone Yingming Yao, Mengtao Ma, Xiaoping Xu, Yong Zhang, Qi Shen, Wing-Tak Wong Organometallics, 2005, 24, 4014-4020. 899 3. Homo- and Copolymerization of 2, 2-Dimethyltrimethylene Carbonate Promoted by Samarium Thiolate Derivatives: The Novel and Versatile Initiators Huangrong Li, Yingming Yao, Changsheng Yao, Hongting Sheng, Qi Shen J. Polym. Sci., Part A: Polym. Chem., 2005, 43, 1312-1316. 906 4. Homoleptic Lanthanide Guanidinate Complexes: The Effective Initiators for the Polymerization of Trimethylene Carbonate and Its Copolymerization with -Caprolactone Liying Zhou, Hongmei Sun, Jinlei Cheng, Yingming Yao, Qi Shen J. Polym. Sci., Part A: Polym. Chem., 2005, 43, 1778-1786. 911 5. Polymerization of N-phenyl maleimide by lanthanide complexes Bei Zhao, Yaorong Wang, Chengrong Lu, Qi Shen, Mingyu Deng J. Polym. Sci., Part A: Polym. Chem., 2005, 43, 3966-3972. 920 6. Synthesis, structure, luminescent properties of guanidinate-based terbium complexes Xingan Pang, Hongmei Sun, Yong Zhang, Qi Shen, Hongjie Zhang Eur. J. Inorg. Chem., 2005, 1487-1491. 927 7. The salt-free diamido complexes of lanthanide supported by -diketiminate: Synthesis, characterization, and their catalytic activity for the polymerization of acrylonitrile and -caprolactone Xue Mingqiang, Yao Yingming, Shen Qi, Zhang Yong J. Organomet. Chem., 2005, 690(21-22), 4685-4691. 932 8. Synthesis, reactivity and structural characterization of linked bis(amidinate) ytterbium complexes Junfeng Wang, Yingming Yao, Jinlei Cheng, Xing’an Pang, Yong Zhang, Qi Shen J. Mol. Struct., 2005, 743(1-3), 229-235. 939 课题负责人：张永敏 课题编号： 2004-18 1. Metallic samarium and iodine promoted facile and efficient syntheses of trisubstituted alkenes from the acetates of Baylis-Hillman adducts. Jian Li，Hua Xu and Yongmin Zhang Tetrahedron Lett. 2005, 46, 1931-1934. 946 2. Remarkable rate acceleration of water-promoted nucleophilic substitution 31 of Baylis-Hillman acetate: A facile and highly efficient synthesis of N-substituted imidazole Jian Li, Xiaoxia Wang and Yongmin Zhang Tetrahedron Lett. 2005, 5233-5237. 950 3. Sml2-mediated facile syntheses of N-(2,2-dichlorovinyl)amides from acetates of chloralamide. Jian Li, Xiaoxia Wang and Yongmin Zhang J. Chem. Res. 2004, 738-739. 955 4. Direct and highly efficient synthesis of (Z)-allyl iodides from Baylis-Hillman adducts promoted by TMSCl/NaI system Jian Li, Xiaoxia Wang and Yongmin Zhang Synlett 2005, 1039-1041. 957 5．The reductive addition reaction of Substituted 2-chloromethyl-1,3,4-oxadiazole to Aldehydes and ketones promoted by samarium diiodide Xiaoliang Xu, Weimin Zhu and Yongmin Zhang Chin. Chem. Lett. 2005, 16(12), 1566-1568. 960 6. Synthesis of 1,3-diaryl-3-aminopropyne via the dethiolation of thilamides promoted by the samarium/samarium diiodide mixed reagent Weimin Zhu, Weixing Qian and Yongmin Zhang J. Chem. Res. 2005, 410-412. 963 7. A novel stereospecific aminocyclopropanation via the dethiolation of thioamides promoted by the samarium/samarium diiodide mixed reagent Weimin Zhu, Weixing Qian and Yongmin Zhang J. Chem. Res. 2005, 164-166. 966 8. One-Pot Preparation of Amides from Azo Compounds by Sm/TiCl4 Xue Li, Yongmin Zhang J. Chin. Chem. Soc. 2005, 52 (6) 1-4. 969 9. Crystal Structure of (E, E)-1,10-Bis-(4-fluoro-phenyl)-3,8- dimethyldeca-3,7-diene-1,10-dione Yongjun Liu, Jianming Gu, Yongmin Zhang Chin. J. Struct. Chem. 2005, 24, 135-138. 973 课题负责人：席振峰 1. 课题编号： 2004-19 Zirconocene-mediated intermolecular coupling of Si-tethered diynes with alkynes, ketones, aldehydes, and isocyanates via novel skeletal rearrangement of zirconacyclobutene-silacyclobutene and zirconacyclohexadiene-silacyclobutene fused ring intermediates Tao Yu, Xiaohua Sun, Congyang Wang, Liang Deng, and Zhenfeng Xi* 32 Chem. Eur. J. 2005, 11, 1895-1902. 977 2. Cleavage of C-Si bond by intramolecular nucleophilic attack: lithiation-promoted formation of siloles from 1-bromo-4-tetrasubstituted silyl-1,3-butadiene derivatives Zhihui Wang, Hongyun Fang, and Zhenfeng Xi* Tetrahedron Lett. 2005, 46, 499-501. 985 3. Preparation and Electrophilic Cyclization of Multi-substituted Dienamides Leading to Cyclic Iminoethers Congyang Wang, Jiang Lu, Guoliang Mao, and Zhenfeng Xi* J. Org. Chem. 2005, 70, 5150-5156. 988 4. Lewis acid-promoted reactions of zirconacyclopentadienes with isocyanates. One-pot three-component synthesis of multiply substituted iminocyclopentadienes from one isocyanate and two Alkynes Jiang Lu, Guoliang Mao, Wenxiong Zhang, and Zhenfeng Xi* Chem. Commun. 2005, 4848-4850. 995 5. Concise Synthesis of Multiply Substituted Stereodefined cis, cis-2,4-diene-1,6-dials, cis, cis-2,4-diene-1,6-diols and further applications Guoliang Mao, Congyang Wang, Jinglong Chen, Ayako Muramatsu, and Zhenfeng Xi* Tetrahedron Lett. 2005, 46, 5369-5372. 998 课题负责人：周锡庚 课题编号： 2004-20 1. Selective O2 oxidation of air-sensitive lanthanocene thiolates and thioether chelate Xigeng Zhou*, Ming Zhu, Libei Zhang, Zhenyu Zhu, Chengfu Pi, Zhen Pang, Linhong Weng, Ruifang Cai Chem. Commun. 2005, 2342-2344. 1002 2. Facile Transformations of Lanthanocene Alkyls to Lanthanocene Thiolate, Sulfide and Disulfide Derivatives by Reaction with Elemental Sulfur Yanrong Li, Chengfu Pi, Jie Zhang, Xigeng Zhou*, Zhenxia Chen, and Linhong Weng Organometallics, 2005, 24, 1982-1988. 1005 3. Substituent Effects on Isocyanate Insertion into a LanthanideSulfur Bond. Unexpected Construction of Coordinated Thiazolate Ring Jie Zhang, Liping Ma，Ruifang Cai, Linhong Weng, Xigeng Zhou* Organometallics, 2005, 24, 738-742. 1012 4. Modification of mesoporous silicate SBA-15 with tris[bis(trimethylsilyl)amido]samarium and its utility in Tishchenko reaction Y. H. Chen, Z. Y. Zhu, J. Zhang, X. G. Zhou J. Organomet. Chem. 2005, 690, 3783-3789. 1017 33 课题负责人：王佰全 课题编号： 2004-21 1. Synthesis and structures of dinuclear iron, molybdenum and tungsten complexes derived from (PhCHCHPh)-coupled bis(cyclopentadiene) Li, B.; Wang, B.; Xu, S.; Zhou, X. J. Organomet. Chem. 2005, 690, 5309-5317. 1024 课题负责人：王绍武 课题编号： 2004-22 1. A solvent-free synthesis of ,’-bis(substituted benzylidene) cycloalkanones catalyzed by lanthanide amides [(Me3Si)2]3Ln(-Cl)Li(THF)3 under microwave irradiation Lijun Zhang, Shaowu Wang*, Enhong Sheng, Shuangliu Zhou Green Chem. 2005, 7, 683-686. 1033 2. Homolysis of the Ln-N bond: Synthesis, characterization and catalytic activity of organolanthanide(II) complexes with furfuryl- and tetrahydrofurfuryl-functionalized indenyl ligands Yongyong Wu, Shaowu Wang*, Changtao Qiang* J. Organomet. Chem. 2005, 690, 4139-4149. 1037 3. Synthesis and Crystal Structure of {5:1-[(2-Methoxyphenyl)-isopropyl]indenyl}dimethoxyethylene)lithium Qiqing Feng, Yimei Li, Shaowu Wang*, Shuangliu Zhou, Enhong Sheng, Zixiang Huang Chin. J. Struct. Chem. 2005, 24, 1046 -1048. 1048 课题负责人：秦金贵 课题编号： 2004-23 1. Synthesis and optical properties of a series of chromophore functionalized polysilanes H. Tang, Y. Liu, B. Huang, J. Qin, C. Fuentes-Hernandez, B. Kippelen, S. Li and C. Ye J Mater. Chem., 2005, 15, 778 -784. 1051 2. Second-order nonlinear optical property of polyphosphazenes charge-transporting agents and indole-based chromophore Zhen Li, Wei Gong, Jingui Qin,, Zhou Yang, Cheng Ye Polymer 2005, 46, 4971–4978. 3. Synthesis containing 1058 of novel poly{methyl-[3-(9-indolyl)propyl]siloxane}-based nonlinear optical polymers via postfunctionalization Zhen Li, Jianli Hua, Qianqian Li, Cheng Huang, Anjun Qin, Cheng Ye, Jingui Qin Polymer 2005, 46, 11940–11948. 1066 34 课题负责人：甘良兵 课题编号： 2004-24 1. Preparation of [5,6]- and [6,6]-oxahomofullerene derivatives and their interconversion by lewis acid assisted reactions of fullerene mixed peroxides Huang, SH; Xiao, Z; Wang, FD; Zhou, J; Yuan, G; Zhang, SW; Chen, ZF; Thiel, W; Schleyer, PV; Zhang, X; Hu, XQ; Chen, BC; Gan, LB Chem. Eur. J. 2005, 11, 5449-5456. 1075 2. Regiochemistry of [70]fullerene: Preparation of C-70((OOBu)-Bu-t)(n), (n = 2, 4, 6, 8, 10) through both equatorial and cyclopentadienyl addition modes Xiao, Z; Wang, FD; Huang, SH; Gan, LB; Zhou, J; Yuan, G; Lu, MJ; Pan, JQ J. Org. Chem. 2005, 70, 2060-2066. 1083 课题负责人：朱成建 课题编号： 2004-25 1. Highly Enantioseletive Biginelli Reaction Using a New Chiral Ytterbium Catalyst: Asymmetric Synthesis of Dihydropyrimidines Yijun Huang, Fengyue Yang, Chengjian Zhu J. Am. Chem. Soc. 2005, 127, 16386-16387. 1090 2. Enantioselective ring opening reaction of meso epoxides with ArSeH catalyzed by heterometallic Ti-Ga-Salen system Minghua Yang, Chengjian Zhu, Fang Yuan, Yijun Huang, Yi Pan Org. Lett. 2005, 7, 1927-1930. 1092 3. The first asymmetric addition of organogallium to aldehydes catalyzed by chiral titanium catalyst Zhenya Dai, Chengjian Zhu, Minghua Yang, Yunfa Zheng, Yi Pan Tetrohedron: Asymmtry 2005, 16, 605-608. 1096 4. Utilization of organogallium and organoindium compounds as alkylation reagents in organic synthesis: the addition of trialkylgallium and trialkylindium to aldehydes catalyzed by Lewis acids Zhenya Dai, Mingran Shao, Xianshan Hou, Chengjian Zhu, Yuhua Zhu and Yi Pan Appl. Organomet. Chem. 2005, 19, 898-902. 1100 课题负责人：陈忠宁 课题编号： 2004-26 1. Syntheses and Characterization of Oxo-Centered Triruthenium Compounds with Orthometalated Bipyridine Jing-Lin Chen, Xu-Dong Zhang, Li-Yi zhang, Lin-Xi Shi, Zhong-Ning Chen* Inorg. Chem. 2005, 44, 1037-1043. 1105 35 2. Syntheses, Characterization, Rdox Properties, and Mixed-valence Chemistry of Tetra- and Hexanuclear Diyndiyl Complexes Li-Bin Gao, Li-Yi Zhang, Lin-Xi Shi, Zhong-Ning Chen* Organometallics 2005, 24, 1678-1684. 课题负责人：王 磊 1112 课题编号： 2004-27 1. Application of recoverable nanosized palladium(0) catalyst in Sonogashira reaction. Pinhua Li, Lei Wang* and Hongji Li. Tetrahedron 2005, 61, 8633-8640. 1119 2. A Simple Copper Salt-Catalyzed Synthesis of Unsymmetrical Diaryl Selenides and Tellurides from Arylboronic Acids with Diphenyl Diselenide and Ditelluride. Lei Wang,* Min Wang and Fuping Huang. Synlett 2005, (13), 2007-2010. 1127 3. The Effects of Amines on Oxidative Homo-coupling of Terminal Alkynes Promoted by Copper Salt. Tuning of Reactivity towards Glaser or Sonogashira Coupling Depending on the Reaction Medium. Lei Wang,* Jincan Yan, Pinhua Li, Min Wang and Caina Su. J. Chem. Res. 2005, (2), 112-115. 1131 4. Mercuous Chloride Catalyzed Mannich Condensation of Terminal Alkynes with Secondary Amines and Aldehydes. Pinhua Li and Lei Wang.* Chin. J. Chem. 2005, 23(8), 1076-1080. 1135 5. First Example of Transition-Metal-Free Glaser-Type Coupling Reaction. Jincan Yan and Lei Wang.* Synth. Commun. 2005, 35, 2333-2338. 课题负责人：金国新 1140 课题编号： 2004-28 1. Binuclear complexes of rhodium (I) bridged by 1,2-dicarba-closo-dodecaborane-1,2-dichalcogenolato ligands: molecular structures of the complexes [Rh2(COD)2(l2-E2C2(B10H10))] [E = S, Se] and [Rh2(CO)4(l2-S2C2(B10H10))] Shuyi Cai a, Xiufeng Hou a, Lin-Hong Weng a, Guo-Xin Jin a,b*-J. Organomet. Chem., 2005, 690, 910-915. 1146 课题负责人：周永贵 课题编号： 2004-29 1. Bifunctional AgOAc-Catalyzed Asymmetric [3+2] Cycloaddition of Azomethine 36 Ylides Wei Zeng, Yong-Gui Zhou* Org. Lett., 2005, 7, 5055-5058. 课题负责人：苏成勇 1152 课题编号： 2004-30 1. 3D Coordination Polymers with Nitrilotriacetic and 4,4’-Bipyridyl Mixed Ligands: Structual Variation Based on Dinuclear Subunits Assisted by Na-O and/or O-H…O Interactions Lü, X.-Q.; Jiang, J.-J.; C.-L.; Kang, B.-S.; Su, C.-Y.* Inorg. Chem. 2005, 44(13), 4515-4521. 1156 2. A Three-Dimensional Silver(I) Framework Assembled from Nitrilotriacetate(NTA) Chen, C.-L.; Zhang, Q.; Jiang, J.-J.; Wang, Q.; Su, C.-Y.* Aust. J. Chem. 2005, 58(2), 115-118. 1163 3. Tris(1H-benzimidazol-2-ylmethyl)amine-solvent adducts X.-L. Zhang, S.-R. Zheng, Y.-R. Liu, X.-L. Zheng and C.-Y. Su Acta Crystallogr. C. 2005, 61 o533-o536. 1167 4. N,N’-Bis(4-pyridinylmethylene)-1,5-naphthalenediamine Liu, Y.-R.; Li, X.-P.; Zhang, J.-A.; Su, C.-Y.* Acta Crystallogr. E. 2005, 61 o2089-o2090. 1171 课题负责人：郎建平 课题编号： 2004-31 1. Construction of Polymeric and Oligomeric Lanthanide(III) Thiolates from Preformed Complexes [(TMS)2N]3Ln(Ì-Cl)Li(THF)3 (Ln ) Pr, Nd, Sm; (TMS)2N ) Bis(trimethylsilyl)amide) Hong-Xi Li,† Zhi-Gang Ren,† Yong Zhang,† Wen-Hua Zhang,† Jian-Ping Lang,*,†,‡ and Qi Shen† J. Am. Chem. Soc. 2005, 127, 1122-1123. 1173 2. Acetic Acid Induce Self-Assemble of Supramolecular Compounds [Et4N]3[(WS4Cu2)2(μ-CN)3].2MeCN and [PPh4][WS4Cu3(μ-CN)2].MeCN from Performed Clusters [A]2[WS4(Cucn)2] (A=Et4N, PPh4) Jian-Ping Lang*†,‡, Chang-Mei Jiao†, Shan-Bao Qiao†, Wen-Hua Zhang†, and Brendan F. Abrahams* Inorg. Chem., 2005, 44, 3664-3668. 1175 3. Syntheses, crystal structures, and third-order nonlinear optical properties of two novel Mo/Cu/S clusters: [MoS4Cu4(α-MePy)5Br2].2(α-MePy)0.5 and {[MoS4Cu4(α-MePy)3Br](μ-Br).(α-MePy)}n (α-MePy = α-methylpyridine) Wen-Hua Zhang a , Jin-Xiang Chen a , Hong-Xi Lia, Bin Wu a, Xiao-Yan Tang a , Zhi-Gang Ren a, Yong Zhang a , Jian-Pin Lang *,a,b , Zhen-Rong Sun c 37 J. Organomet. Chem., 2005, 690, 394-402. 1180 4. Di-μ-iodo-bis-{[1,1’-methylenebis(3,5-dimethyl-1H-pyrazole-KN2)]copper(I)} Ying Xu a, Hong-Xi Li a, Wen-Hua Zhang a , Yong Zhang a and Jian-Pin Lang *a,b Acta Crystallogr. C. 2005, 61, m4-m6. 1189 5. Synthesis of Novel Binuclear Samarium Thiolate Complexs [(THF)3I2Sm(μ-SAR)]2 (Ar = Ph, 4-Me2NC6H4) Crystal Structure of [(THF)3I2Sm(μ-S-4-Me2NC6H4)]2 LI, Hong-Xi a ZHANG, Yong a REN, Zhi-Gang a CHENG, Mei-Ling a WANG, Jing a LANG, Jian-Ping * a, b Chin. J. Chem., 2005, , 23, 1499-1502. 1192 课题负责人：施章杰 课题编号： 2004-32 课题负责人：吴 课题编号： 2004-33 劼 1. An Expeditious Approach to Quinolines via Friedländer Synthesis Catalyzed by FeCl3 or Mg(ClO4)2 Jie Wu,* Liang Zhang, and Tian-Ning Diao Synlett 2005, 2653-2657. 1196 2. Tertiary Amines as Highly Efficient Catalysts in the Ring-opening Reactions of Epoxides with Amines or Thiols in H2O: Expeditious Approach to -Amino Alcohols and -Aminothioethers Jie Wu,* and Hong-Guang Xia Green Chem. 2005, 7, 708-710. 1201 3. DABCO: An Efficient Organocatalyst in the Ring-Opening Reactions of Aziridines with Amines or Thiols Jie Wu,* Xiaoyu Sun, and Yizhe Li Eur. J. Org. Chem. 2005, 4271-4275. 1204 课题负责人：曹卫国 1. Simple Approach to the High Stereoselective Synthesis of trans-2,3-Dihydrofuran Derivatives Weiguo Cao, Guodong Chen, Jie Chen, Rongqing Chen Synth. Commun. 2005, 35(4). 527-533. 1209 2. Solvent-Free, One-Pot Synthesis of Pyrano[2,3-c]pyrazole Derivatives in the Presence of KF-2H2O by Grinding Zhongjiao Ren, Weiguo Cao,Weiqi Tong and Zhu Jin 38 Synth. Commun. 2005, 35(19), 2509-2513. 1216 3. One-Pot Method for Stereoselective Cyclopropanation of Electron Deficient Olefins with Methyl Bromoacetate and Phenacyl Bromide in the Presence of Triphenylarsine Zhongjiao Ren, Weiguo Cao, Weiyu Ding and Yu Wang Synthesis 2005, 16, 2718-2722. 1221 4. Stereoselective Synthesis of Cis-1-Aryl-2-Benzoyl-3,3-Dicyanocyclopropanes in Water Zhongjiao Ren, Weiguo Cao, Jie Chen, Yu Wang and Weiyu Ding Synth. Commun. 2005, 35(24),3099-3104. 1226 5. Solvent-free Synthesis of 2-Arylideneindan-1,3-Diones in the Presence of Magnesium Oxide or Silica Gel under Grinding Danyi Wu, Zhongjiao Ren , Weiguo Cao and Weiqi Tong Synth. Commun. 2005, 35(24),3157-3162. 1232 6. Study on the Reaction of Electron-Deficient Cyclopropane Derivatives with Arsonium Ylides Yali Chen, Weiguo Cao, Weiyu Ding and Xiaohua Sun Chin. J. 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