金属有机化学国家重点实验室2003年年度进展报告.doc
金属有机化学国家重点实验室2003年年度进展报告.doc
2OO3 年重大记事 一. 项目资助 继续资助 2002－2003 年的室基金项目 32 个项目，其中有机所 14 个，外单位 18 个，资助总额 102.9 万。 二．实验室设备更新 2002 年订购的园二色散仪一台，原位红外仪一台，分析和制备液相色谱仪一 台以及与有机所共同购置的 SGI 图形工作站和高分辨质谱一台今年全部到货，所有 仪器已调试完毕，现已正常运行。 三. 实验室承担的科研项目运行正常 由吉林大学裘式纶教授和我室麻生明研究员作为首席科学家的 973 项目“创造 新物质的分子工程学研究”10 月份在北京召开了 2003 年度项目汇报会，整个项目今 年较好完成了年度计划。以我室学术带头人为主的题为“导向有机合成的金属有机 化学”国家基金委创新研究群体项目今年超额完成了预订年度计划。另外麻生明研 究员主持的基金委重点项目“用金属有机化学研究绿色化学中的基本问题”和基金 委优秀实验室重点项目“金属催化的对映选择性合成”两个项目在年初和年底分别 都通过了基金委的结题验收，专家组一致认为，该两个项目都出色地完成了原订的 研究计划，取得了一系列创新性的丰硕研究成果，后者被评为特优。同时唐勇主持 的国家“863”计划“新型结构可控性烯烃聚合催化剂的研制”进展顺利，科技部今 年 11 月在南京杨子石化公司开会具体了解项目的进展，认为项目进展良好。丁奎岭 和施敏研究员主持的中国科学院知识创新工程重要方向性项目“重污染的硝化、氧 化和还原反应清洁新工艺研究与开发”通过了中国科学院高技术研究与发展局组织 的中期评估。专家一致认为经过两年的研究工作，完成和部分超额完成了项目接点 目标要求，为项目的全面完成奠定了基础。通过这些项目发表了一些论文，其中 I 区论文有 12 篇。 1 四．实验室学委会工作 实验室今年 11 月 26－27 日在苏州召开了 2003 年度学委会会议，会上荣幸地邀 请到了基金委和中科院的领导参加，请他们为实验室的发展提了不少建设性意见。 同时本届学术会上很高兴的邀请到香港中文大学黄乃正院士和北京大学的甘良兵教 授分别作了题为“Chemistry of Tetraphenylenols and Pentacenes”和“富勒烯 相关的金属有机化学”的学术报告，同时会议热烈讨论了如何做好 2004 年实验室评 估的工作。 五．获奖情况 钱长涛研究员 上海市科技进步一等奖 麻生明研究员 全国优秀留学回国人员 赵立刚博士 上海市科协第九届青年优秀科技论文奖 (导师：陆熙炎院士) 2 金属有机化学国家重点实验室学术委员会 第一届第三次会议简报 金属有机化学国家重点实验室第一届学术委员会第三次会议于今年 11 月 25－ 27 日在苏州召开，十五位委员中有十二位出席会议，中科院高技术局化工处白路娜 老师和国家基金委化学部杜灿屏老师、陈拥军老师与会指导。会议由学术委员会主 任钱长涛研究员主持。这次会议的议程是 1) 室主任作实验室年度工作报告，2) 专家学术报告和交流，3) 部分课题组工作进展情况汇报，4) 国际学术会议介绍，5) 迎接 2004 年评估准备工作讨论，6)黄耀曾金属有机化学奖的讨论。 一.实验室主任麻生明研究员汇报了实验室室一年来的工作 麻生明主任首先欢迎并感谢各位领导和专家的到会，并感谢大家在过去一年中 对我们实验室工作的大力指导和支持。然后他汇报了实验室一年来的工作，介绍实 验室一年来在仪器装备的更新、重大项目的申请和检查情况、主要科研成果、人才 培养、课题管理和中国科学院“创新团队国际合作伙伴计划”的筹备等方面的工作。 同时对实验室一年来的重要科研进展作了较为详尽的报告。 二．专家学术报告和交流 会上由北京大学甘良兵教授和香港中文大学黄乃正院士分别作了题为“富勒烯 相关的金属有机化学”和“Chemistry of Tetraphenylenols and Pentacenes”两个精彩 的学术报告，与会代表对每一个报告都进行了充分的讨论和交流。苏州大学化学化 工学院部份老师和研究生也列席了学术报告会，大家觉得受益非浅。 三. 课题组工作进展汇报和讨论 这次会上共有五个课题组进行科研工作进展汇报，分别由上海有机所刘元红研 究员(有机锆杂环化合物促进的新型碳-碳键形成反应)、上海有机所邓敏智研究员 (新型有机硼的偶联反应及在天然产物合成中的应用)、南京大学朱成建教授(手性 Salen 及 Salan 金属配合物催化的不对称反应研究)、复旦大学周锡庚教授(稀土有机 化合物的配体修饰)、 浙江大学张永敏教授(钐试剂在有机合成中的应用)到会汇报工 作。委员们认真听取了他们的进展情况和今后工作设想，并就研究工作中的问题提 3 出了中肯的意见和建议，进行了广泛的学术交流。 四．国际学术会议介绍和讨论 本次会上共介绍了三个国际会议的内容： 1. 上海有机所的唐勇研究员介绍了今年 8 月在瑞士苏黎士召开的 2003 年欧洲金属 有机化学会议的情况, 重点介绍了烯烃聚合催化剂和不对称催化方面的工作。 2. 上海有机所的麻生明研究员介绍了今年 7 月在加拿大多伦多召开的第 12 届 OMCOS 会议和 10 月在德国慕尼黑召开的第三届亚洲-德国双边会议的基本情况， 重点介绍了大会报告中我们实验室比较感兴趣的问题。 3. 上海有机所的戴立信院士介绍了今年 8 月在美国科罗拉多州召开的第 19 届国际 杂环化学会议的情况，重点介绍了有机催化方面的一些进展。 通过这些介绍和讨论，使到会代表及时了解国际上金属有机化学研究的热点和 掌握目前文献还来不及报道的热门学科前沿资料，对拓宽工作思路起到了一定的作 用。 五．今后工作讨论 会上委员们对如何做好 2004 年的实验室评估准备工作提出了许多具体的建议， 主要希望做好实验室的有关材料收集统计工作，写好评估申请；做好实验室的硬件 建设工作和安全卫生工作。 六．黄耀曾金属有机化学奖的讨论 全体到会学术委员对第一届黄耀曾金属有机化学奖进行了初步讨论。 总之，本次学委会会议讨论热烈，交流充分，学术气氛浓厚，与会者都认为收获 较大。最后大家一致希望我们认真实验室评估的准备工作，争取在 2004 年的实验室 评估中取得好成绩。 4 2002～2003 资助课题一览表 序 号 姓 名 单 位 题 目 2002-01 陆熙炎 上海有机所 具有高合成效率的新有机合成反应的研究 2002-02 钱长涛 上海有机所 新型后期过渡金属催化剂的设计与合成及其 催化烯烃聚合反应研究 2002-03 麻生明 上海有机所 金属参与的碳-碳键形成反应研究 2002-04 侯雪龙 上海有机所 平面手性环芳烷配体的设计、合成及其应用 2002-05 沈延昌 上海有机所 金属有机参与的高选择性合成方法学研究 2002-06 陈家碧 上海有机所 多金属桥卡宾和桥卡拜络合物及其在催化 反应中的应用研究 2002-07 邓敏智 上海有机所 新型 Suziki 偶联反应及一些生物活性产物 的全合成 2002-08 姜 标 上海有机所 不对称 Pauson-Khand 反应研究及在复杂 生物碱合成中的应用 2002-09 施 敏 上海有机所 Baylis-Hillman 反应的研究 2002-10 丁奎岭 上海有机所 新型 C2 对称性手性配体的设计、合成及其 金属络合物在催化不对称反应中的应用研究 2002-11 唐 勇 上海有机所 新型硫、碲叶立德的合成、设计及其在有机 合成中的应用 2002-12 张兆国 上海有机所 碳－氧键的反应化学研究 2002-13 赵 刚 上海有机所 芳基锌试剂参与的不对称碳碳键形成反应研究 2002-14 许 旭 上海有机所 手性合成新产物的色谱分析方法研究 2002-15 宋礼成 南开大学 巴基球碳簇过渡金属有机化合物的合成及非 线性光学性质研究 2002-16 黄 宪 浙江大学 过渡金属参与下聚合物负载有机硒化合物的 固相反应 5 2002-17 沈 琪 苏州大学 非茂基稀土配合物的合成及其反应性能的研究 2002-18 康北笙 中山大学 间隔基团调控的多齿杂氮配位化合物及螺旋 结构规律 2002-19 张永敏 浙江大学 稀土金属、过渡金属介入的选择性有机合成反应 2002-20 席振峰 北京大学 双金属有机合成试剂的发现与发展 2002-21 曹卫国 上海大学 利用胂叶立德立体选择性合成多官能基有机 环化合物 2002-22 周锡庚 复旦大学 稀土烃硫基化合物的氧化反应研究 2002-23 庞 震 复旦大学 手性半活性配体对金属有机化合物反应性的 影响及其应用 2002-24 王佰全 南开大学 桥连茂金属化合物的合成结构及催化烯烃 聚合研究 2002-25 王绍武 安徽师范大学 新型立体位阻诱导单电子还原反应研究 2002-26 秦金贵 武汉大学 聚二茂铁基硅烷的设计、合成与固体磁性 2002-27 殷元骐 兰化所 非环戊二烯基配位的铑手性簇合物的合成 2002-28 甘良兵 北京大学 金属促进的多加成富勒烯环氧化物 C60(0)n 的合成 2002-29 范青华 化学所 基于树状大分子手性催化剂的氟两相催化 反应研究 2002-30 朱成建 南京大学 手性镓、铟金属有机化合物的合成及其导向的 有机反应研究 2002-32 陈忠宁 福建物构所 金属有机分子导线、分子簇和分子笼 不对称合成中的应用 2002-34 王 磊 淮北煤炭 微波促进纳米钯粉催化无溶剂有机合成反应 师范学院 的研究 6 2003 年全室专利申请、授权一览表 2003 年申请专利 编 号 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 专利名称 申请日 含手性四元环骨架的新型膦配体、合成 方法及其用途 专利号 发明人 03115826.9 030723 03141761.2 030404 03116192.8 姜标、司玉贵 031119 200310108713.1 姜标、王亚平 031119 200310108712.7 姜标、王亚平 031119 200310108714.6 姜标、王亚平 030516 03117026.9 姜标、司玉贵 030516 03117027.7 姜标、储惠兰 030616 PCT/CN03/00462 姜标、司玉贵 031031 200310108345.0 030905 03150854.5 030923 03151143.0 姜标、王亚平 麻生明 吴滨 赵士民 麻生明 吴滨 马志超 031029 0312 200310108236.9 20031010 031029 200310106156.x 一种合成β-氟胺化合物的方法 手性氨基醇配体及其在端炔对亚氨的不 对称加成中的应用 新型大环内酯类药物—9-OR-红霉素 A 肟，合成方法及用途 新型大环内酯类药物—9-去氧-9α-N-取代烷或酰胺类-红霉素 A 衍生物，合成 方法及用 新 型 大 环 内 酯 类 药 物 —4 ″ - 表 -9 α -N-R-9α氮杂高红霉素 A 衍生物、合成 方法及用途 手性氨基醇配体应用于端炔对含氟烷基 芳基酮的不对称加成的方法 碘酸盐类组合物及其在环境消毒中的应 用 一种氨基醇配体及其在制备手性炔丙基 叔醇和叔胺的对应选择性加成反应中的 应用 6-取代-5-氟-4-羟基嘧啶类化合物及其中 间体、合成方法及用途 Z-a-卤代亚烷基内酯化合物、合成新方法 及其用途 3,4,5-三取代-5-羟基-2(5 氢)-呋喃酮化合 物、合成方法及其用途 使用 Hf 化合物催化酚类及芳香醚类化 合物的绿色硝化方法 乙烯齐聚催化剂、合成方法及其用途 负载型非茂金属催化剂的负载化方法的 聚合应用 复合载体负载的非茂金属催化剂的负载 化方法的聚合应用 一类有 C2 对称轴的双齿手性膦配体及 其合成 030314 丁奎岭、赵东 波 侯雪龙、范仁 华、戴立信 030924 7 200310106157.4 施敏、崔世聪 唐勇等 扬子石化 唐勇等 扬子石化 唐勇等 03151155.4 张兆国等 2003 年授权专利 编 号 1 2 3 专利名称 专利号/申请号 99127004.5 99127005.3 00127841.X 姜标等 姜标等 姜标等 00127840.1 姜标等 00119868.8 姜标等 11 一种合成 4-三氟甲基吡啶类化合物的方法 1-三氟甲基-2-烷基乙烯基苯胺衍生物及其合成 (R)-2-[3-(2-N-邻苯二甲酰亚胺基乙基)-4,5-二氢-5-异 噁唑基]-乙酸、合成及用途 (3R,5R)-3,5-二羟基-7-N-邻苯二甲酰亚胺基-庚酸叔 丁酯、合成及用途 一种通过相转移催化剂制备 4-（2-烷氧基乙基）苯酚 的方法 一种二氟甲磺酸金属试剂、合成方法及其用途 一种双酮化合物、生产方法及其用途 β位含有芳基取代基的γ-丁烯酸内酯及其固相合成 法 一种具有光学活性的β-芳基取代-2（5H）-呋喃酮 及其合成方法 一种具有光学活性的β-卤代-γ－丁烯酸酸内酯及其 合成方法 一种β－卤代-γ－羟基吡咯酮及其合成方法 12 一种β位不含取代基的丁烯酸内酯及其合成的方法 13 14 制备苯甲酸及其衍生物的环境友好的方法 用 CO2 代替剧毒的光气制备氨基甲酸酯类化合物的 方法 一种可溶性高分子催化剂、合成方法及用途 一种用可溶性高分子催化剂催化叶立德反应的方法 N，N－二取代－2，3－环氧丙胺制备方法和用途 4 5 6 7 8 9 10 15 16 17 8 01105780.7 98122044.4 ZL 00 1 15358.7 ZL 00 1 27945.9 ZL 00 1 27947.5 00125758.7 发明人 ZL 00 1 25757.9 00127516.X 00127515.1 姜标等 姜标等 麻生明，段德 慧 麻生明，施章 杰 麻生明，吴树 林 麻生明，谢贺 新 麻生明，俞瞻 前，吴树林 施敏，冯言枢 施敏，沈玉梅 CN 1112251C CN 1112250C ZL 98 1 22020.7 唐勇等 唐勇等 侯雪龙，李斌 峰，戴立信 2003 年金属有机化学国家重点实验室来访人员名单 2003 年由于非典，来访人员大幅度减少，外单位来访人员名单如下： Prof. Tamostu Takahashi Hokkaido University, Japan 2003,10,19 赵东元教授 复旦大学 2003,4,10 肖文精博士 华中师范大学 2003,10,7 殷元骐研究员 中科院兰州化物所 2003,10,13 9 二 00 三年论文目录 课题负责人：陆熙炎 课题编号： 2002-01 1. Palladium(II)-Catalyzed Allenoic Acids-,-Unsaturated Carbonyl Coupling through Tandem Intramolecular Oxypalladation and Conjugate Addition Reactions Liu, G.; Lu, X.* Tetrahedron Lett. 2003, 44, 127-130. 35 2. One-Pot Synthesis of Tetrahydrofuran Derivatives Palladium-Catalyzed Three-Component Coupling Liu, G.; Lu, X.* Tetrahedron Lett. 2003, 44, 467-470. via a Divalent 39 3. The First Example of a Catalytic Carbon-Phosphorus Ylide Reaction. A Novel Phosphine-Catalyzed [3+2] Cycloaddition of 2-Bromoor 2-Acetoxymethyl-2-alkenoates with Electron-Deficient Olefins Du, Y.; Lu, X.;* Zhang, C. Angew. Chem. Int. Ed. 2003, 42, 1035-1037. 43 4. A Phosphine-Catalyzed [3+2] Cycloaddition Strategy Leading to the First Total Synthesis of (-)-Hinesol Du, Y.; Lu, X.* J. Org. Chem. 2003, 68, 6463-6465. 46 课题负责人：钱长涛 课题编号： 2002-02 1. Fluoro-Substituted 2,6-Bis(imino)pyridyl Iron and Cobalt Complexes:High Activity EthyleneOligomerization Catalysts Yaofeng Chen, Changtao Qian, and Jie Sun Organometallics, 2003, 22, 1231-1236. 49 2. Halogen Substituted 2,6-bis(imino)pyridyl Iron and Cobalt Complexes-High Active CatalystsFor Polymerization and Oligomerization of Ethylene Yaofeng Chen, Ruifang Chen, Changtao Qian, Xicheng Dong, Jie Sun Organometallics, 2003, 22, 4312-4321. 55 3. Silica-Alumina Catalyst Support.A Efficient Catalyst for Synthesis of Halogen Substituted 2,6-Bis(imino)pyridines Changtao Qian, Feifeng Gao, Yaofeng Chen and Lijun Gao Synlett, 2003, 10, 1419-1422. 65 4. Electronic structure of organometallic complexes of f-elements. LVI. Parametric analysis of crystal-field splitting patterns of pseudo-trigonal-bipyramidal 10 coordinated O- and P-donor functionalized ethylcyclopentadienyl complexes of neodymium(III) Hanns-Dieter Amberger; Hauke Reddmann; Hans H. Kaesch; Volker W. Graf; Changtao Qian; Bing Wang J. Organomet. Chem. 2003, 677, 35-45. 69 5. Yb(OTf)3-catalyzed one-pot synthesis of quinazolin-4(3H)-ones from anthranilic acid, amines and ortho esters (or formic acid) in solvent-free conditions Wang, Limin; Xia, Jianjun; Qin, Fang; Qian, Changtao; Sun, Jie Synthesis 2003, 8, 1241-1247. 80 6. Lanthanide triflate catalyzed one-pot synthesis of dihydropyrimidine-2(1H)-thiones by a three-component reaction of 1,3-dicarbonyl compounds, aldehydes, and thiourea using a solvent-free Biginelli condensation Wang, Limin; Qian, Changtao; Tian, He; Ma, Yun Synth. Commun. 2003, 33, 1459-1468. 87 课题负责人：麻生明 1. 课题编号： 2002-03 Tuning the Regioselectivity in Palladium(II)-Catalyzed Isomerization of Alkylidenecyclopropyl Ketones. A Dramatic Salt Effect Shengming Ma* and Junliang Zhang Angew. Chem. Int. Ed., 2003, 42, 183-187. 97 2. Pd0-Catalyzed Coupling Cyclization Reaction of Aryl or 1-Alkenyl Halides with 1,2-Allenyl Ketones: Scope and Mechanism. An Efficient Assembly of 2,3,4-,2,3,5-Tri- and 2,3,4,5-Tetra-substituted Furans Shengming Ma*, Junliang Zhang and Lianghua Lu Chem. Eur. J. 2003, 9, 2447-2456. 102 3. Transition Metal-Catalyzed/Mediated Reaction of Allenes with A Nucleophilic Functionality Connected to the -Carbon Atom Shengming Ma* Acc. Chem. Res. 2003, 36, 701-712. 112 4. Regioselectivity Control by a Ligand Switch in the Coupling Reaction Involving Allenic/Propargylic Palladium Species. Shengming Ma* and Guanwei Wang Angew. Chem. Int. Ed. 2003, 42, 4215-4217. 124 5. Highly Regio- and Stereoselective Halohydroxylation Reaction of 1,2-Allenyl Phenyl Sulfoxides. Reaction Scope, Mechanism and the Corresponding Pd- or Ni-Catalyzed Selective Coupling Reactions Shengming Ma,* Hongjun Ren, and Qi Wei J. Am. Chem. Soc. 2003, 125, 4817-4830. 127 11 6. Walking of C-C--Bond over Long Distances in Pd-Catalyzed Reactions of 2,3-Allenoic Acids with (-1)-Alkenyl Halides Shengming Ma* and Zhanqian Yu Angew. Chem. Int. Ed. 2003, 42, 1955-1957. 141 7. Efficient Synthesis of Bi-butenolides Derivatives through Oxidative Dimeric Cyclizing-Coupling Reaction of 2,3-Allenoic Acids Shengming Ma* and Zhanqian Yu Org. Lett. 2003, 5, 1507-1510. 144 8. Novozym-435-Catalyzed Enzymatic Separation of Racemic Propargylic Alcohols. A Facile Route to Optically Active Terminal Aryl Propargylic Alcohols Daiwang Xu, and Zuyi Li, and Shengming Ma* Tetrahedron Lett. 2003, 44, 6343-6346. 148 9. Studies on Pd(II)-Catalyzed Coupling-Cyclization of - or -Amino Allenes with Allylic Halides Shengming Ma* , Fei Yu, and Wenzhong Gao J. Org. Chem. 2003, 68, 5943-5949. 152 10. TFA-Mediated Intramolecular Friedel-Crafts Reaction. An Efficient Metal and Halogen Free Routes to Stereoselective Synthesis of Benzocycles Shengming Ma* and Junliang Zhang Tetrahedron. 2003, 59, 6273-6283. 159 11. Pd(II)-Catalyzed Coupling Cyclization of 2,3-Allenoic Acids with Allylic Halides. An Efficient Methodology for the Synthesis of -Allylic Butenolides Shengming Ma* and Zhanqian Yu J. Org. Chem. 2003, 68, 6149-6152. 170 12. Mild and Efficient Synthesis of (Z)--Chloroalkylidene--lactones via the PdCl2-Catalyzed Cyclocarbonylation of 2-Alkynols Shengming Ma*, Bin Wu, and Shimin Zhao Org. Lett. 2003, 5, 4429-4432. 174 13. Studies on K2CO3-Catalyzed 1,4-addition of 1,2-allenic Ketones with Diethyl Malonate: Controled Selective Synthesis of –Unsaturated Enones and -Pyrones Shengming Ma*, Shicao Yu, and Shaohu Yin J. Org. Chem. 2003, 68, 8996-9002. 178 14. 2,3,4- or 2,3,5-Trisubstituted Furans: Catalyst-Controlled Highly Regioselectively Ring-Opening Cycloisomerization Reaction of Cyclopropenyl Ketones. Shengming Ma* and Junliang Zhang J. Am. Chem. Soc. 2003, 125, 12386-12387. 185 12 15. An X- (X=I, Br)-Triggered Ring-opening Coupling Reaction of Cyclopropenes with Organic Halides Shengming Ma*, Junliang Zhang, Yangjun Cai and Lianghua Lu J. Am. Chem. Soc. 2003, 125, 13954-13955. 187 16. Palladium-Catalyzed Highly Regio- and Stereoselective Addition of Organoboronic Acids to Allenes in the Presence of HOAc Shengming Ma* and Ning Jiao Chem. Eur. J. 2003, 9, 6049-6056. 189 17. Novozym-435-catalyzed efficient preparation of (1S)-ethenyl and ethynyl 2,3-allenols and (1R)-ethenyl and ethynyl 2,3-allenyl acetates with high enantiomeric excess Daiwang Xu, Zuyi Li and Shengming Ma* Tetrahedron: Asymmetry 2003, 14, 3657-3666. 197 18. Reversed Stereoselectivity in Iodohydroxylation of Allenyl Sulfides. An Efficient Synthesis of (Z)-3-Organosulfur-2-iodo-2-propenols Shengming Ma,* Xueshi Hao, and Xian Huang Org. Lett. 2003, 5, 1217-1219. 207 19. Highly Regio- and Stereoselective Four-Component Iodoamination of Se-Substituted Allenes. An Efficient Synthesis of N-(3-Organoseleno-2-iodo-2(Z)propenyl) acetamides Shengming Ma,* Xueshi Hao, and Xian Huang Chem. Commun. 2003, 1082-1083. 210 课题负责人：侯雪龙 1. 课题编号： 2002-04 Asymmetric Catalysis with Chiral Ferrocene Ligands Li Xin Dai,* Tao Tu, Shu Li You, Wei Ping Deng, Xue Long Hou* Acc. Chem. Res. 2003, 36, 659-667. 212 2. The Regioselectivity of Asymmetric Intermolecular Heck Reaction with Planar Chiral Diphosphine-oxazoline Ferrocene Ligands Tao Tu, Wei-Ping Deng, Xue-Long Hou*, Li-Xin Dai* and Xi-Cheng Dong Chem. Eur. J. 2003, 9, 3073-3081. 221 3. Novel Planar Chiral P, N-[2.2]Paracyclophane Ligands: Synthesis and application in Pd-Catalyzed Allylic Alkylation Xun-Wei Wu, Ke Yuan, Wei Sun and Xue-Long Hou* Tetrahedron: Asymmetry 2003, 14, 107-112. 230 4. Trans Effect of Different Coordinated Atoms of Planar Chiral Ferrocene Ligands with Same Chiralities in Pd- Catalyzed Allylic Substitutions 13 Tao Tu, Yong-Gui Zhou, Xue-Long Hou,* Li-Xin Dai,* Yi-Hua Yu, and Jie Sun Organometallics 2003, 22, 1255-1265. 236 5. On the role of planar chirality in asymmetric catalysis: Improvement of enantioselectivity in the addition of diethylzinc to aldehydes with planar chiral 1,1’N, O -ferrocenyl ligands Ming Li, Ke Yuan, Yang-Yang Li, Bo-Xun Cao, Jie Sun and Xue-Long Hou* Tetrahedron Asymmetry, 2003, 14, 3347-3352. 247 6. Highly Regioand Enantioselective Heck Reaction of N-methoxycarbonyl-2-pyrroline with Planar Chiral Diphosphine-oxazoline Ferrocenyl Ligands Tao Tu, Xue Long Hou,* and Li Xin Dai* Org. Lett. 2003, 5, 3651-3653. 253 7. Efficient Ring Opening Reaction of Epoxides and Aziridines Promoted by Tributylphosphine in Water Ren-Hua Fan and Xue-Long Hou,* J. Org. Chem. 2003, 68, 726-730. 256 8. Tributylphosphine-Catalyzed Ring-Opening Reaction of Epoxides and Aziridines with Anhydride Ren-Hua Fan and Xue-Long Hou* Tetrahedron Lett. 2003, 44, 4411-4413. 261 9. Tetrabutylammonium Bisulfate: A New Effective Catalyst for the Hydrolysis of Aziridines or Epoxides Ren-Hua Fan and Xue-Long Hou* Org. Biomol. Chem. 2003, 1, 1565-1567. 264 10. Highly Diastereoselective Strecker Reaction of Enolizable Aliphatic Sulfinimines Bin-Feng Li, Ke Yuan, Ming-Jie Zhang, Hao Wu, Li-Xin Dai, Quan Rui Wang and Xue-Long Hou* J. Org. Chem. 2003, 68, 6264-6267. 267 11. Asymmetric hydroesterification of styrene using catalysts with planar-chiral ferrocene oxazoline ligands Lailai Wang, Wai Him Kowk, Albert S. C. Chan, Tao Tu, Xuelong Hou and Lixin Dai Tetrahedron: Asymmetry 2003, 14, 2291-2295. 271 12. [2.2]对环芳烷类平面手性配体在不对称催化反应中的应用（综述） 巫循伟，孙威，侯雪龙 有机化学 2003, 23, 906-913. 14 276 课题负责人：沈延昌 课题编号： 2002-05 1. A Novel One-pot Conversion of Aldehydes to (E)--Fluoro--trifluoromethyl allylic Alcohols. Yanchang Shen, Guoping Wang Synthesis, 2003, 209-212. 284 2. A Novel Base-catalyzed Stereoselective Synthesis of Trifluoromethylated dienedinitriles Yanchang Shen, Guoping Wang, Jiahong Ni, Jie Sun Synthesis, 2003, 1574-1578. 288 3. Stereoselective Synthesis of Substituted Trifluoromethylated Ethenylphosphonates via Sequential transformations of Bisphosphonates Yanchang Shen, Ping Li J. Fluorine Chem. 2003, 121, 219-212. 293 4. Stereoselective Synthesis of (Z)--Cyano--Perfluoroalkyl--Unsaturated Esters Yanchang Shen, Jiahong Ni J. Fluorine Chem. 2003, 124, 65-68. 297 5. A Convenient Synthesis of Substituted 3-Alkoxycarbonyl---unsaturated Esters with Predominant Z-selectivity Yanchang Shen, Yuming Zhang Heteroatom Chem. 2003, 14, 276-279. 301 6. Consecutive Reaction of Bis[2,2,2-trifluoroethyl]phosphite. One-pot Synthesis of Substituted 3-Cyano-,-Unsaturated Nitriles with Exclusive or Predominant E-Selectivity Shen, Yan-Chang, Zhang, Yu-Ming Chin. J. Chem. 2003, 21, 907-909. 305 课题负责人：陈家碧 1. 2. 课题编号： 2002-06 Remarkable Reactions of Cyclooctatetraene Diiron-Bridging Carbyne Complexes with Amino and Amido Compounds: Nucleophilic Addition to and Breaking of Cyclooctatetraene Ring Shu Zhang, Qiang Xu, Jie Sun, and Jiabi Chen* Chem. Eur. J., 2003, 9, 5111-5122. 308 Novel Reactions of Cyclooctatetraene (COT)-Coordinated Diiron Cationic Bridging Carbyne Complexes with Nucleophiles Shu Zhang, Qiang Xu, Jie Sun, and Jiabi Chen* Organometallics, 2003, 22, 1816-1826. 320 15 3. 4. Remarkable Reactions of Cationic Carbyne Complexes of Manganese and Rhenium with Carbonylrhodium Anion [Rh(CO)4]-. A Novel Route to Heteropolymetallic Bridging Carbyne Complexes with and 3 Bridging Carbyne Ligands Lei Zhang, Baohua Zhu, Nu Xiao, Qiang Xu, Nobuko Tsumori, Jie Sun, and Jiabi Chen* Organometallics, 2003, 22, 4369-4371. Novel chiral Rh-Mn mixed-metal carbonyl cluster containing µ3 and µbridging carbyne ligands, [(µ3-CC6H5)(µ-CC6H5)Rh2Mn2Cp2(µ-CO)3(CO)3]: structure, electrochemistry and catalytic properties Baohua Zhu, Lei Zhang, Nu Xiao, Jiabi Chen,* and Yuanqi Yin* Inorg. Chem. Acta, 2003, 357, 1-5. 334 课题负责人：邓敏智 1. 2. 课题编号： 2002-07 Palladium-catalyzed Synthesis of Arylacetamides from Arylboronic Acids Duan, Y. -Z.; Deng, M. –Z Tetrahedron Lett., 2003, 44, 3423-3426. 339 Facile Access to Stereodefined Dienoates and Cyclopropylenoates Containing a Trifluoromethyl Group Wang, P. –A.; Deng, M. –Z.; Pan, R. –Q.; Zhang, S. –Y J. Fluorine Chem., 2003, 124, 93-97. 343 课题负责人：姜 1. 331 标 课题编号： 2002-08 Enantioselective Total Syntheses of Slagenins A-C and Their Antipodes Biao Jiang, Jia-Feng Liu, and Sheng-Yin Zhao J. Org. Chem. 2003, 68, 2376-2384. 348 2. Solution-Phase Synthesis of a Thiazoyl-Substituted Indolyl library via Suzuki Cross-Coupling Ning Zou, Jia-Feng Liu, and Biao Jiang J. Comb. Chem. 2003, 5, 754-755. 357 3. A convenient stereoselective synthesis of trifluoromethyl-substituted polyfunctionalized cyclopropane: synthesis of () trans-trifluoronorcoronamic acid Biao Jiang, Fangjiang Zhang and Wennan Xiong Chem. Commun. 2003, 536-537. 359 4. Lewis acid promoted alkynylation of imi8nes with terminal alkynes: simple, mild and dfficient preparation of propargylic amines. Biao Jiang and Yu-Gui Si Tetrahedron Lett., 2003, 44, 6767-6768. 361 16 5. A Facile Synthetic Method for the Preparation of -Symmetric (1, 2:4, 5)-Diepoxypentane Equivalent Jiang, Biao, Chen, Zi-Li, Shen, Min, Wang, Zhi-Min and Shi Min Chin. J. Chem. 2003, 21, 789-792. 363 课题负责人：施 敏 课题编号： 2002-09 1. Different Reaction Pattern in the Baylis-Hillman Reaction of Arylaldehydes with Phenyl Vinyl Ketone, Phenyl Acrylate and Phenyl Thioacrylate Min Shi,* Chao-Qun Li, and Jian-Kang Jiang Molecules, 2002, 7, 721-733. 367 2. Chemical Fixation of Carbon Dioxide Catalyzed by Binaphthyldiamino Zn, Cu, Co Salen Type Complexes Yu-Mei Shen, Wei-Liang Duan and Min Shi,* J. Org. Chem., 2003, 68, 1559-1562. 380 3. The Lewis acids Catalyzed aza-Diels-Alder Reaction of Methylenecyclopropanes with Imines M. Shi,* L.-X. Shao, B. Xu Org. Lett., 2003, 5, 579-582. 384 4. Pd(II) and Pd(0) Co-catalyzed Reactions of Sulfonamides with MCPs. Min Shi,* Yu Chen and Bo Xu Org. Lett., 2003, 5, 1225-1228. 388 5. Ring-opening reactions of methylenecyclopropanes promoted by metal halides. Bo Xu and Min Shi* Org. Lett., 2003, 5, 1415-1418. 392 6. Heptadecafluorooctanesulfonic acid catalyzed ring opening reactions of methylenecyclopropanes with aromatic amines, sulfonamides and alcohols in supercritical carbon dioxide. Min Shi,* Yu Chen, Bo Xu, and Jie Tang Green Chem., 2003, 5, 85-88. 396 7. Reexamination of the Traditional Baylis-Hillman Reaction Min Shi,* Chao-Qun Li, and Jian-Kang Jiang Tetrahedron, 2003, 59, 1181-1189. 400 Synthesis of two Novel Cobalt Complexes and Their Crystal Structures Min Shi,* and Wei-Liang Duan Applied Organometa. Chem., 2003, 17, 175-180. 409 8. 17 9. Phenol and Organic Bases Co-catalyzed Chemical Fixation of Carbon Dioxide with terminal epoxides to form cyclic carbonates Yu-Mei Shen, Wei-Liang Duan and Min Shi* Adv. Synth. & Catal., 2003, 345, 337-340. 415 10. An Unexpected Highly Stereoselective Double aza-Baylis-Hillman Reaction of Sulfonated Imines with Phenyl Vinyl Ketone Min Shi* and Yong-Mei Xu J. Org. Chem., 2003, 68, 4784-4790. 419 11. Chiral binaphthylthiophosphoramide-Cu(I) catalyzed asymmetric addition of diethylzinc to N-sulfonylimines Chun-Jiang Wang and Min Shi* J. Org. Chem., 2003, 68, 6229-6237. 426 12. 13. 14. Chemical Fixation of Carbon Dioxide by NaI/PPh3/PhOH Jin-Wen Huang and Min Shi* J. Org. Chem., 2003, 68, 6705-6709. 435 Polymer-Supported Lewis Bases for the Baylis-Hillman Reaction Jin-Wen Huang and Min Shi* Adv. Synth. & Catal., 2003, 345, 953-958. 440 Highly Enantioselective Allylation of Arylaldehydes Catalyzed by a Silver(I)-Chiral Binaphthylthiophosphoramide Chun-Jiang Wang and Min Shi* Eur. J. Org. Chem., 2003, 2823-2828. 446 15. The Catalytic Asymmetric Addition of Diethylzinc to Diphenylphinoyl imines Catalyzed by Cu(OTf)2-Chiral Binaphthylthiophosphoramide Ligands Min Shi* and Chun-Jiang Wang Adv. Synth. & Catal., 2003, 345, 971-973. 452 16. Lewis acids catalyzed ring-opening reactions of methylenecyclopropanes and epoxides in supercritical carbon dioxide or modified supercritical carbon dioxide with perfluorocarbon Min Shi,* Yu Chen J. Fluorine Chem., 2003, 122, 219-227. 455 17. Chiral phosphine Lewis base catalyzed asymmetric aza-Baylis-Hillman reaction of N-sulfonated imines with methyl vinyl ketone and phenyl acrylate Min Shi* and Lian-Hui Chen Chem. Commun., 2003, 1310-1311. 464 18. Synthesis of Novel Chiral Cu or Ag/S,N Cluster Complexes and Absolute Stereostructures as Determined by X-ray Crystallography Min Shi* and Jian-Kang Jiang 18 Chirality, 2003, 15, 605-608. 466 19. Montmorillonite KSF-Catalyzed One-pot, Three-component, Aza-Diels-Alder Reactions of Methylenecyclopropanes with Arylaldehydes and Aromatic Amines Li-Xiong Shao and Min Shi* Adv. Synth. & Catal., 2003, 345, 963-966. 470 20. Transition Metal Catalyzed Reactions of 5-Methylene-2-oxazolidinone and 5-Methylene-1,3-thiazolidine-2-thione with Isocyanates Yu-Mei Shen and Min Shi* Applied Organometa. Chem., 2003, 17, 767-775. 474 21. Lewis Acid-Catalyzed Reaction of Allenes with Activated Ketone Bo Xu and Min Shi* Synlett, 2003, 1639-1642. 483 22. Lewis Acids Catalyzed a Novel [3+2] Cycloaddition of Methylenecyclopropanes with Activated Aldehyde or Ketone Min Shi* and Bo Xu Tetrahedron Lett., 2003, 44, 3839-3842. 487 23. A New Method for Nitration of Phenolic Compounds Shi-Cong Cui and Min Shi* Adv. Synth. & Catal., 2003, 345, 1197-1202. 24. 491 Lewis Acid BF3.OEt2 Catalyzed Friedel-Crafts Reaction of Methylenecyclopropanes with Arenes Jin-Wen Huang and Min Shi* Tetrahedron Lett., 2003, 44, 9343-9347. 497 25. Chiral C1-symmetric diaminothiophosphoramide-Cu(I) catalyzed asymmetric addition of diethylzinc to N-sulfonylimines Min Shi* and Wen Zhang Tetrahedron:Asymmetry, 2003, 14, 3407-3414. 502 26. Synthesis of Novel Axially Chiral Rh-NHC Complexes Derived from BINAM and Application in the Enantioselective Hydrosilylation of Methyl Ketones Wei-Liang Duan,b Min Shi,a* Guo-Bin Rongb Chem. Commun. 2003, 2916-2917. 510 27. Reactions of Arylaldehydes and N-Sulfonated Imines with Dimethyl Acetylenedicarboxylate Catalyzed by Nitrogen and Phosphine Lewis bases Chao-Qun Li and Min Shi* Org. Lett., 2003, 5, 4273-4276. 512 28. Abnormal Aza-Baylis-Hillman Reaction of N-Tosylated Imines with Ethyl 19 29. 2,3-Butadienoate and Penta-3,4-dien-2-one Gui-Ling Zhao, Jin-Wen Huang, and Min Shi* Org. Lett., 2003, 5, 4737-4739. 516 二氧化碳固定研究的最新进展。 沈玉梅、施敏 有机化学, 2003, 1, 22-29. 519 课题负责人：丁奎岭 课题编号： 2002-10 1. Quasi Solvent-Free Enantioselective Carbonyl-Ene Reaction Using Extremely Low Catalyst Loading Yu Yuan, Xue Zhang, and Kuiling Ding Angew. Chem. Int. Ed. Engl., 2003, 42, 5478-5480. 527 2. Assembled Dendritic Titanium Catalysts for Enantioselective HDA Reaction of Aldehydes with Danishefsky’s Diene Baoming Ji, Yu Yuan, Kuiling Ding* and Jiben Meng* Chem. Eur. J., 2003, 9, 5989-5996. 530 3. Liquid-phase synthesis of 2,3-dihydro-4-pyridones: One-pot three-component aza Diels-Alder reaction of Danishefsky’s diene with aldehydes and PEG-supported amine Hongchao Guo, Kuiling Ding* Tetrahedron Lett., 2003, 44, 7103-7106. 538 4. A New Type of C2-Symmetric Bisphospine Ligands with Cyclobutane Backbone: Practical Synthesis and Application Dongbo, Zhao, Kuiling Ding* Org . Lett., 2003, 5, 1349-1351. 542 5. Enantioselective Catalysis of Hetero Diels-Alder Reaction and Diethylzinc Addition Using A Single Catalyst Haifeng Du and Kuiling Ding* Org . Lett., 2003, 5, 1091-1093. 545 6. Backbone Effect of MAP Ligands on Their Coordination Patterns with Palladium (II) Yi Wang, Xin Li, Jie Sun, Kuiling Ding* Organometallics, 2003, 22, 1856-1862. 548 7. Synthesis of Dendritic Schiff Base Ligands for Titanium Catalyzed Enantioselective HDA Reaction of Danishefsk’s Diene with Aldehydes Baoming Ji, Kuiling Ding*, Jiben Meng* Chin. J. Chem. 2003, 21, 727-730. 555 20 课题负责人：唐 勇 课题编号： 2002-11 1. Controllable Diastereoselective Cyclopropanation. Enantioselective Synthesis of Vinylcyclopropanes via Chiral Telluronium Ylides Wei-Wei Liao, Kai Li, Yong Tang* J. Am. Chem. Soc., 2003, 125, 13030-13031. 559 2. An efficient catalytic ylide route to vinyl epoxides Kai Li, Zheng-Zheng Huang, Yong Tang* Tetrahedron Lett., 2003, 44, 4137-4140. 561 A Facile Tetrahydrothiophene-catalyzed Ylide Route to Vinyloxiranes Kai Li, Xian-Ming Deng, Yong Tang * Chem. Commun., 2003, 2074-2075. 565 3. 4. Chiral Tris(oxazoline)/Cu(II) Catalyzed Coupling of Terminal Alkynes and Nitrones Meng-Chun Ye, Jian Zhou, Zheng-Zheng Huang, and Yong Tang* Chem. Commun., 2003, 2554-2555. 567 课题负责人：张兆国 课题编号： 2002-12 1. Novel Synthesis of 2-Oxo-3-butynoates by Copper-Catalyzed Cross-Coupling Reaction of Terminal Alkynes and Monooxalyl Chloride Guo, M.; Li, D.; Zhang, Z. J. Org. Chem., 2003, 68, 10172-10174. 569 2. Palladium-Catalyzed Cross-Coupling Reactions of Carboxylic Anhydrides with Organozinc Reagents Wang, D.; Zhang, Z. Org. Lett., 2003, 5, 4645-4648. 572 3. Palladium-Catalyzed Tandem Cyclization/Suzuki Coupling of 1,6-Enynes Zhu, G.; Zhang, Z. Org. Lett., 2003, 5, 3645-3648. 576 4. Palladium-catalyzed Suzuki–Miyaura reaction using aminophosphine as ligand Cheng, J.; Wang, F.; Xu, J.-H.; Pan, Y.; Zhang, Z Tetrahedron Lett., 2003, 44, 7095-7098. 580 5. Novel Rhodium-Catalyzed Cycloisomerization of 1,6-Enynes with an Intramolecular Halogen Shift Tong, X., Zhang, Z., Zhang, X J. Am. Chem. Soc., 2003, 125, 6370-6371. 584 课题负责人：赵 刚 课题编号： 2002-13 21 1. 6,6’-Bisperfluoroalkylated BINOLs promoted asymmetric allylation of aldehydes Yue-yan Yin, Gang Zhao*, Zhan-shan Qian, Wei-xin Yin J. Fluorine Chem., 2003, 120, 117-120. 586 2. Sn-Mediated catalytic asymmetric reduction of carbonyl groups by borohydride(or sodium borodeuteride) Zhao Gang,* Hu Jian-Bing Chin. J. Chem., 2003, 21, 819-823. 590 课题负责人：许 旭 课题编号： 2002-14 1. Chiral Separation of 2,3-Allenoic Acid by Capillary Zone Electrophoresis using Cyclodextrin Derivatives Xu Xu*, Xiao-Ling Bao, Xiao-Wei Dong, Zhang-Jie Shi, Zhan-Qian Yu, Sheng-Ming Ma Chirality, 2003, 15, 201-205. 595 2. 用于毛细管电泳 DNA 分离的合成聚合物 王前，许旭* 化学进展, 2003, 15, 275-287. 600 3. 4. 小檗碱与大黄酸沉淀作用的毛细管电泳研究 许旭*，董晓渭，毛平 药学学报, 2003, 38, 779-782. 613 DNA Separation by Capillary Electrophoresis with Ultraviolet Detection using Synthetic Polymer Qian WANG, Xu Xu* Chin. Chem. Lett.，2003, 14, 1278-1280. 617 课题负责人：宋礼成 课题编号： 2002-15 1. Synthesis and characterization of organotransition metal double 3-RCCo2M (M = Mo, W) cluster complexes containing bridged dicyclopentadienyl ligands. Crystal structure of [3–MeCCo2Mo(CO)8]2 [5–C5H4C(O)CH2]2 Li-Cheng Song,* Wen-Feng Zhu, Qing-Mei Hu, Hao Wu, Guang-Au Yu J. Organomet. Chem., 2003, 667, 143-148. 620 2. Synthesis of bridging carbyne butterfly Fe/Se cluster complexes via reaction of complex anions [(-RSe)(-CO)Fe2(CO)6]-. Crystal structure of (µ-EtOC)(µ-p-MeC6H4Se)Fe2(CO)6 Li-Cheng Song,* Yi Sun, Qing-Mei Hu, Yang Liu J. Organomet. Chem., 2003, 676, 80-84. 626 3. Synthesis, characterization and properties of new organocobalt complexes containing 22 5-functionally substituted cyclopentadienyl and [60]fullerene ligands Li-Cheng Song,* Peng-Chong Liu, Qing-Mei Hu, Guo-Liang Lu, Guang-Feng Wang J. Organomet. Chem., 2003, 681, 264-268. 631 4. Synthesis and characterization of 4-S-containing double- and triple-butterfly iron carbonyl complexes. Crystal structures of (-EtS)[-PhC(O)S][Fe2(CO)6]3(4-S)2 and (-t-BuS)2[Fe2(CO)6]3(4-S)2 Li-Cheng Song,* Qing-Mei Hu , Bao-Wei Sun , Ming-Yi Tang , Guo-Liang Lu Inorg Chim. Acta., 2003, 346, 12-18. 636 课题负责人：黄 宪 课题编号： 2002-16 1. A Facile Solid-Phase Synthesis of Substituted Polymer-Supported -Selenocarboxylic Acids Huang X; Sheng S-R J. Comb. Chem., 2003, 5(3), 273-277. 2 (5H)-Furanones from 643 2. A Novel One-Pot Three component Tandem Michael/Aldol /Horner-Wadsworth-Emmons(HWE) reaqction of Lithium Alkylselenolates with 1-alkynyl Phosphine Oxides and Aldehydes: Facile Synthesis of selenium Substituted Allenes Huang X; Xiong Z-C Chem. Commun., 2003, 1714-1715. 648 3. Use of Selenium-Bound Resin for the Solid-Phase Synthesis of Substituted Isoxazolyl-Substituted 9(E)-Olefins Huang X; Xu W-M Organic Lett., 2003, 5, 4649-4652. 650 4. Studies on Hydrozirconation of 1-Alkynyl Sulfoxides or Sulfones and the Application for the Synthesis of Stereodefined Vinyl Sulfoxides or Sulfones Huang X; Duan D-H;Zheng W-X J. Org. Chem., 2003, 68,1958-1963. 654 5. Novel CuBr.SMe2 Catalyzed Conjugate Addition of 3-Trimethyl silyl-1propenylzirconocene to Divinylketones. Stereoseletive Synthesis of Polysubstituted Cyclohexanones Huang X; Pi J-H Synlett, 2003, 481-484. 660 6. Solid Phase Synthesis of Benzothiazole and Thiophene Derivatives Base on Resin-boud Cyclic Malonic Acid Ester Huang X; Tang J Tetrahedron, 2003, 59, 4851-4856. 664 23 7. Facile Synthesis of Sulfur-substituted Allenes by a Three-component Reaction Huang X; Xiong Z-C Tetrahedron Lett., 2003, 44, 5913-5915. 670 8. The Palladium Catalyzed Hydrostannationof 1- Alkyl- phosphonates: A new approach to stereodefined α,β-disubstituted vinyphosphonates Huang X; Xiong Z-C Synth. Commun., 2003, 33, 2511-2517. 9. 673 Free Radical Reaction of Dialkyl Posphites and Organic Dichalcogenides: A New Facile and Convenient Preparation of Arylseleno- Phosphates Xu Q; Laing C-G; Huang X Synth. Commun., 2003, 33, 2777-2785. 680 10．A Convenient Synthesis of 3,5- Dialkyl-1,2,4-Selenodiazoles Huang X; Chen J-M Synth. Commun., 2003, 33, 2823-2827. 689 11. Preparation of Resin-Boud Bismethylene Cyclic Malonic Acid Ester and Faciler Solid-Phase Synthesis of 2-Alkylthio-4(1H)-quinolones and 2-Alkyl4(1H)-quinolones Tang J; Huang X Synth. Commun., 2003, 33, 3953-3959. 694 12. Convenient Synthesis of 5-(Arylamino(alkylthio) methylene) -2,2-dimethyl-1,3-dioxanes and 2-Arythio-4-quinolones Tang J; Huang X J. Chem. Res., 2003, 3, 140-141. 701 13. An Efficient Solid-Phase Synthesis of 3-Carboxycoumarins Based on a Scaffold-Polymer-Bound Cyclic Malonic Ester Tang J; Huang X J. Chem. Res., 2003, 354-355. 703 14. The Stereospecific Preraration of (Z)-α-Stannyl-1- alkenylphosphonates as Precursors of Stereodefined α-Substituted Vinyl- phosphonates Xiong Z-C; Huang X J. Chem. Res., 2003, 372-373. 705 15. Stereoselective Synthesis of (E)- and (Z)-1,2-Disubstituted Ethene from Polymer-supported Vinylic Selenide Sheng S-R; Huang X Chin. J Chem., 2003, 21, 471-473. 16. A Facile Solid Phase Synthesis of 2-Alkyl thio - 4(1H)-quinolones Tang J; Wu M-G; Huang X 24 707 Chin. J Chem., 2003, 21, 585-587. 710 17 . Reactions of Polymer-Supportedα-Selenoaldehydes with Grigrard Reagents. A Facile Solid-Phase Sreeoselective Synthesis of (E)-1,2-Disubstituted Ethenes Sheng S-R; Huang X J. Chin. Chem. Soc., 2003, 50, 893-896. 713 18. Stereoselective Synthesis of δ-Selanyl Allylic Alcohols by Hydrozirconation of Propargyl Selenides Xie M-H; Wu L-L; Huang X Chin. Chem. Lett., 2003, 14, 255-256. 717 19. Convenient Solid-phase of benzothiazole Derivatives Tang J; Wu L-L; Huang X Chin. Chem. Lett., 2003, 14, 885-886. 课题负责人：沈 琪 课题编号： 2002-17 1. Synthesis and Structural Characterization of Divalent Ytterbium Complexes Supported by -Diketiminate Ligand, and Their Catalytic Activity for the Polymerization of Methyl Methacrylate Yingming Yao, Yong Zhang, Zhenqin Zhang, Qi Shen, Kaibei Yu Organometallics, 2003, 22, 2876-2882. 719 721 2. Synthesis and characterization of -diketiminate lanthanide complexes: the effect of the bulkiness of ancillary ligand on the reaction Yingming Yao, Mingqiang Xue, Yunjie Luo, Zhenqin Zhang, Rui Jiao, Yong Zhang, Qi Shen, Wingtak Wong, Kaibei Yu, and Jie Sun J. Organomet. Chem., 2003, 678, 108-116. 728 3. Synthesis and Characterization of a New Class of Divalent Lanthanide Complexes {[C5H4(CMe2Ph)]4Ln2(X)2}[Li(DME)3]2 (Ln = Sm, X = I; Ln = Yb, X = Cl; DME = dimethoxyethane) Mingyu Deng, Yingming Yao, Shen Qi, Yong Zhang, Jianping Lang, Yufang Zhou J. Organomet. Chem., 2003, 681, 174-179. 737 4. Synthesis and Characterization of Bis(guanidinate)lanthanide Diisopropylamido Complexes: New Highly Active Initiators for the Polymerizations of -Caprolactone and Methyl Methacrylate Yingming Yao, Yunjie Luo, Jinglei Chen, Zhenqin Zhang, Yong Zhang, Qi Shen J. Organomet. Chem., 2003, 679, 229-237. 743 5. Ytterbium complexes supported by -diketiminate ligands: cyclopentadienyl, indenyl, and aryloxide derivatives Yong Zhang, Yingming Yao, Yunjie Luo, Qi Shen, Yan Cui, Kaibei, Yu Polyhedron, 2003, 22, 1241-1247. 752 25 6. Synthesis of lanthanide chlorides supported by β-diketiminate ligands and molecular structures of L1SmCl2(THF)2 and L2SmCl2(THF)2 [L1 = PhNC(Me)CHC(Me)NPh; L2 = p-ClPhNC(Me)CHC(Me)NPh(2,6-Pri2)] Yingming Yao, Yunjie Luo, Rui Jiao, Qi Shen, Kaibei Yu, Linghong Weng 759 Polyhedron, 2003, 22, 441-446. 7. Synthesis and characterization of monomeric salicylaldiminato lanthanide complexes and their catalytic behavior for polymerization of -caprolactone Yu Longbao, Yao Yingming, Shen Qi, Zhang Jing, Wu Lixin, Ye Ling Chin. J. Chem., 2003, 21, 442-445. 765 课题负责人：康北笙 课题编号： 2002-18 1. Low-dimensional framework constructed by silver trifluoromethylsulfonate with 1,5-bis(benzimidazol-2-yl)-3-oxapentane or 1,6-bis(benzimidazol-2-yl)-2,5-dioxahexane Cai, Y. P., Chen, C. L.; Zhang, L., Shi, L., Xu, A. W.; Su, C. Y., Kang, B. S.* Inorg. Chim. Acta, 2003, 342, 107-113. 769 2. Modulation of the coordination environment of silver( I ) in bis(diphenylphospho) methane complexes by selection of heterocyclic thiolato ligands Zhang,L., Zhang, H. X., Chen, C. L.Deng, L. R.,Kang, B. S. Inorg. Chim. Acta, 2003, 355, 49-56. 776 3. Multidimensional frameworks assemble from silver( I ) coordination polymers containing flexible bis(thioquinolyl) ligands:role of the intra- and intermolecular aromatic stacking interactions Chen, C. L., Su, C. Y., Cai, Y. P., Zhang, H. X., Xu, A. W., Kang, B. S., Loye H. C. Z. Inorg. Chem., 2003, 42, 3738-3750. 784 4. A non-interpenetrating 2D coordination polymer from a (CH2)8 spacer-based highly flexible linear ligand and AgCF3CO2 Chen, C. L., Su, C. Y., Cai, Y. P., Zhang, H. X., Xu, A. W., Kang, B. S. New J. Chem., 2003, 27, 790-792. 797 5. Molecular and crystal structure of 1,3,5-tris(benzimidazol- 1-ylmethyl)-2,4,6-trimethylbenzene Cai, Y. P., Kang, B. S., Su, C. Y., Zhang, H. X., Yang,X. P., Deng, L. R., Xu, A. W., Zhou, Z.Y., Chan, Albert S.C Chin. J. Struct. Chem., 2003, 22, 262-265. 800 6．Heteroaryl tripodal ligands and their metallosupramolecular complexes Tan, H.Y., Zhang, H. X., Kang, B. S. 化学通报, 2003,66,755-761. 26 804 课题负责人：张永敏 课题编号： 2002-19 1．Three-component reaction of aldehydes, -haloketones and benzoylacetonitrile and Michael addition of benzoylacetonitrile to chalcones both promoted by samarium triiodide: two routes for preparation of 1-benzoyl-1-cyano-2-aryl-3-aroylpropane derivatives Yunkui, Liu, Yongmin Zhang*, Zhifang, Li J. Indian Chem. Soc., 2002, 79, 433-436.(该文章抽印件今年刚收到) 811 2. A new strategy for the synthesis of diaroylpropionates promoted by samarium metal in DMF Yongjun Liu, Xi Liu, Yongmin Zhang* Tetrahedron Lett., 2003, 44, 1667-1670. 815 3. Formation of 1,4-diketones via bis-acylation of the conjugated carbon-carbon double bonds in acrylates, acrylamides, methyl vinyl ketones and styrenes with aroyl chlorides promoted by samarium metal in DMF Yongjun Liu, Yongmin Zhang* Tetrahedron, 2003, 59, 8429-8437. 819 4. Temperature-controlled selective reduction of arenesulfonyl chlorides promoted by samarium metal in DMF Yongjun Liu, Yongmin Zhang* Tetrahedron Lett., 2003, 44, 4291-4294. 828 5. Samarium diiodide promoted formation of 1,2-diketones and I-acylamido-2-substituted benzimidazoles from N-acylbenzotriazoles Xiaoxia Wang, Yongjun Liu, Yongmin Zhang* Tetrahedron, 2003, 59, 4201-4207. 832 6. Low-valent titanium promoted self-coupling of N-acylbenzotriazoles and their cross-coupling with diarylketones Xiaoxia Wang, Yongmin Zhang* Synth. Commun., 2003，33, 2627-2634. 839 7. Elimination of benzotriazolyl group in N-(benzotriazol-1-ylalkyl)amides and N-(benzotriazol-1-ylalkyl)sulfoamides: their self-coupling and cross-coupling reaction with carbonyl compounds Xiaoxia Wang, Yongjun Liu, Yongmin Zhang* Tetrahedron, 2003, 59, 8257-8263. 847 8. Substitution of the benzotriazoly group in N-(aminoalkyl)benzotriazoles and N-(sulfonamidoalkyl) benzotriazoles with allylsamarium Bromides. Xiaoxia Wang, Jian Li, Yongmin Zhang* Synth. Commun., 2003, 33, 3575-3581. 854 9. Highly regioselective nucleophilic addition of the allylsamarium bromide to α， 27 β-unsaturated alkynones Xingliang Zheng, Yongmin Zhang* J. Chem. Res. (S), 2003, 472-473. 861 10. Gem-diallylation of acyl azides with allylsamarium bromide under mild conditions. Jian Li, Yongjun Liu, Yongmin Zhang* J. Chem. Res. (S) ,2003, 438-439. 863 11. SmI2 mediated synthesis of 2,3-disubstituted indole derivatives Xuesen Fan, Yongmin Zhang* Tetrahedron, 2003, 59, 1917-1923. 865 12. Novel cyclization of dimeric dianions of anils or aldehydes with triphosgene: A safe and efficent synthesis of substituted imidazolidin-2-ones and 4,5-diaryl-1,3-dioxolan-2-ones Zhifang Li, Yongmin Zhang* Heteroatom Chem., 2003, 14, 46-49. 872 13. Synthesis of functionalized 2,3-dihydropyrroles promoted by samarium diiodide Xiaoliang Xu, Yongmin Zhang* Synth. Commun., 2003, 33, 1095-1101. 876 14. Facile synthesis of polysubstituted 2,3-dihydrofuran and cyclopentenylamine derivatives promoted by samarium diiodide Xiaoliang Xu, Yongmin Zhang* Synth. Commun., 2003, 33, 2643-2656. 883 15. Facile synthesis of 2H-1,4-Benzothiazin-3(4H)-ketoximes and 2H-1,4-Benzoselenoazin-3(4H)-ketoximes promoted by samarium diiodide Xiaoliang Xu, Yongmin Zhang* Synth. Commun., 2003, 33, 3537-3543. 897 16. Intermolecular reductive coupling cyclization of 1,1-diaryl-2,2-dicyanoethylenes with aldehydes or ketones to synthesize polysubstituted 2,3-dihydrofurans and cyclopentenylamines promoted by samarium metal in DMF Yongjun Liu, Yongmin Zhang* J. Chem. Res. (S), 2003, 317-319. 904 17. Intermolecular reductive coupling cyclization of 1,1-diaryl-2,2-dicyanoethylenes with aldehydes or ketones to synthesize polysubstituted 2,3-dihydrofurans and cyclopentenylamines promoted by samarium metal in DMF Yongjun Liu, Yongmin Zhang* J. Chem. Res. (M), 2003, 621-635. 907 18. Stereoselective Michael-Aldol tandem reaction of diorganyl diselenides of diorganyl disulfides with conjugated alkynones mediated by samarium diiodide 28 Xingliang Zheng, Xiaoliang Xu, Yongmin Zhang* Synlett, 2003, 2062-2064. 911 19. Samarium diiodide mediated Barbier-type reaction of 2-chloromethylbenzoxazole and 2-chloromethylbenzothiazole with carbonyl compounds: A convenient synthesis of 1-(hydroxyalkyl)benzoxazoles and 1-(hydroxyalkyl)benzothiazoles Xiaoliang Xu, Yongmin Zhang* Synth. Commun., 2003, 33, 3551-3559. 914 20. Samarium (III) iodide promoted three-component coupling reactions of aldehydes, haloketones, and active methylene or methyl compounds. Yongmin Ma, Yongmin Zhang* Synth. Commun., 2003, 33, 711-715. 923 21. A novel one-pot synthesis of 2-arylquinolines through cascade reactions mediated by Samarium reagents Xuesen Fan, Yongmin Zhang* Indian J. Chem. 2003, 42B, 655-657. 928 22. SmI3 catalyzed condensation of aliphatic cycloketones and aldehydes in ionic liquid Xingliang Zheng，Yongmin Zhang* Synth. Commun., 2003, 33, 161－165. 931 23. SmI2 mediated elimination reaction of trichloromethyl carbinols:a facile method to synthesize vinyl chlorides Jian Li, Xiaoliang Xu, Yongmin Zhang* Tetrahedron Lett., 2003, 44, 9349-9351. 936 24. Synthesis of trans-stilbenes utilizing dicarbonylation of -chloro chlorofrormates mediated by samarium diiodide Zhifang Li, Yongmin Zhang* J. Chem. Res.(S), 2003, 340-341. 939 25. Low-valent titanium induced intramolecular reductive coupling of keto-examines: A facile synthesis of 2,3,5-trisubstituted pyroles Fan, Xuesen, Zhang, Xinying, Zhang, Yongmin Zhang* Chin. J. Chem., 2003, 21, 336-338. 941 26. A new synthetic method of highly substituted cyclopentadienes from , -unsaturated alkynones Xingliang Zheng, Yongmin Zhang* Chin. J. Chem., 2003, 21, 1203-1205. 944 课题负责人：席振峰 课题编号： 2002-20 1. Alkyne and Ketone Induced Novel Cleavage of a C-C Bond and a C-Si Bond in 29 Zirconacyclobutene-silacyclobutene Fused Ring Compounds Tao Yu, Liang Deng, Changjia Zhao, Zhiping Li, and Zhenfeng Xi* Tetrahedron Lett., 2003, 44, 677-679. 947 2. Reaction of Aluminacyclopentadienes with Aldehydes Affording Cyclopentadiene Derivatives Hongyun Fang, Changjia Zhao, Guotao Li, and Zhenfeng Xi* Tetrahedron, 2003, 59, 3779-3786. 950 3. Lewis Acid Mediated Reactions of Zirconacyclopentenes with Aldehydes Affording Homoallyl Ketones via Oppenauer-type Oxidation Changjia Zhao, Jun Yan, and Zhenfeng Xi* J. Org. Chem., 2003, 68, 4355-4360. 958 4. Preparation of S-containing Heterocycles via Novel Reaction Patterns of Carbon Disulfide with 1-Lithlobutadienes and 1,4-Dilithiobutadienes Congyang Wang, Jinglong Chen, Qiuling Song, Zhiping Li, and Zhenfeng Xi* Arkivoc., 2003, part (ii) 155-164. 964 5. One-pot Four-component Synthesis of Tetrahydrofuran Derivatives Involving An Alkyne, An Ethylene and Two Aldehydes via CuCl-mediated Reactions of Oxazirconacyclopentenes with Aldehydes Changjia Zhao, Jiang Lu, Jun Yan, and Zhenfeng Xi* Tetrahedron Lett., 2003, 44, 6895-6898. 974 6. Formation of stereodefined multiply substituted all-cis octatetraenes, tricycle[4.2.0.02,5]octa-3,7-dienes and pentalenes via CuCl or FeCl3-mediated dimerization of 1-lithiobutadienes and 1,4- dilithiobutadienes Guotao Li, Hongyun Fang, and Zhenfeng Xi* Tetrahedron Lett., 2003, 44, 8705-8708. 978 7. FeCl3-mediated Reaction of 1,4-Dilithio-1,3-dienes with Alkynes Affording Benzene Derivatives Guotao Li, Hongyun Fang, Zhiping Li, and Zhenfeng Xi* Chin. J. Chem., 2003, 21, 219-221. 982 课题负责人：曹卫国 课题编号： 2002-21 1. 贫电子环丙烷的化学 袁美斐 陈雅丽 丁维钰 曹卫国 有机化学, 2003, 23, 901-905 985 课题负责人：周锡庚 课题编号： 2002-22 1. Synthesis and Studies on Reactivities of Dicyclopentadienylytterbium Derivatives 30 Containing Carbazolate and Pyrazolate Ligands Jie Zhang, Ruifang Cai, Linhong Weng, Xigeng Zhou Organometallics, 2003, 22, 5385-5391. 990 2. Insertion of Carbodiimide into the LnN -Bond of Organolanthanide Complexes. Synthesis and Characterization of Organolanthanide Guanidinates i i i (C5H5)2Ln[ PrNC(N Pr2)N Pr] (Ln= Yb, Dy, Gd) Jie Zhang, Ruifang Cai, Linhong Weng, Xigeng Zhou J Organomet. Chem., 2003, 472, 94-99. 997 3. Low-heating solid synthetic reactions of cyclopentadienyl organolanthanide complexes Zhu Ming, Li Yanrong, Luo Jun, Zhou Xigeng Chin. Sci. Bull., 2003, 48, 2041-2043. 1003 课题负责人：庞 震 课题编号： 2002-23 1. Synthesis and Reactivity Impact From Electron-withdrawing Substituent on the Cyclopentadienyl Ligand of Cobalt(I) -(III) Complexes Chong-Zhi Tang , You-Feng Xu , Zhen Pang*, Xiu-Feng Hou J. Organomet. Chem., 2003, 682, 123-130. 1006 课题负责人：王佰全 课题编号： 2002-24 1. Synthesis and thermal rearrangement of tetramethyldi- silane-bridged bis(cyclopentadienyl) diiron complexes with bis(phosphines) substitution Sun, X., Wang, B., Xu, S., Zhou, X Chin. J. Chem., 2003, 21, 332-335. 1014 2. 苯基取代的环戊二烯基锆化合物的合成及催化乙烯聚合 徐善生, 袁方, 贺双胜, 王佰全, 周秀中, 邹丰楼, 李杨 有机化学, 2003, 23, 187-191. 1018 3. 四甲基二硅桥连二(环己基环戊二烯基)四羰基二铁的合成、结构及热重排反应研 究 孙秀丽, 王佰全, 徐善生, 周秀中, 翁林红 有机化学, 2003, 23, 666-670. 1023 课题负责人：王绍武 课题编号： 2002-25 1. A New Heteroatom Coordination Promoted Homolysis of Yb-N Bond. Synthesis and Structural Characterization of a New Class of Ytterbium(II) and Ytterbium(III) Complexes with Indenyl and Amido Ligands, and Catalytic Activities of Ytterbium(II) Complexes 31 Enhong Sheng, Shaowu Wang* ，Gaosheng Yang, Shuangliu Zhou, Kehua Zhang, Lin Cheng, and Zixiang Huang Organometallics, 2003, 22, 684-692. 1028 2. Homolysis of the Eu-N Bond. Synthesis, Structurally Characterization and Catalytic Activity of Novel Europium(II) Complexes Shaowu Wang*, Shuangliu Zhou, et al Organometallics, 2003, 22, 3546-3552. 1037 3. An efficient preparation of N-per- (or N-fluoroalkanesulfonyl pyrroles Shizheng Zhu*, Xinyuan Liu, Shaowu Wang* Tetrahedron, 2003, 59, 9669-9676. 4. poly)fluorophenyl pyrroles and 1044 Synthesis, structure, and catalytic activity of tetracoordinate lanthanide amides [(Me3Si)2N]3Ln( μ-Cl)Li(THF)3(Ln = Nd, Sm, Eu) Shuang-L. Zhou, Shao-W. Wang, Gao-S. Yang, Xin-Y. Liu, En-H. Sheng, Ke-H. Zhang, Lin Cheng, Zi-X. Huang Polyhedron, 2003, 22, 1019~1024. 1052 课题负责人：秦金贵 课题编号： 2002-26 课题负责人：殷元骐 课题编号： 2002-27 1. Syntheses and characterization of the new Rh-Co mixed-metal octahedral linked clusters Bao-Hua Zhu, Bin Hu, Yu-Hua Zhang, Wei-Qiang Zhang, Yuan-Qi Yin, Jie Sun. J. Chem. Res.(S), 2002, 622-623. 1058 2. Reaction of trans-carbonyl(chlorobis(triphenylphosphine))Rhodium(I) with substituted cyclo-pentadienyl tricarbonyl molybdenum anion Bao-Hua Zhu, Wei-Qiang Zhyang, Bin Hu, Quan-Yi Zhao, Yuan-Qi Yin and Sun Jie J. Coord. Chem., 2003, 56, 817-823. 1060 3. Synthesis and characterization of new rhodium and cobalt mixed-metal octahedral liked clusters containing η2-diyne ligands Bao-Hua Zhu, Bin Hu, Wei-Qiang Zhang, Yu-Hua Zhang, Yuan-Qi Yin, Jie Sun. J. Organomet. Chem., 2003, 681, 275-279. 1067 4. Remarkable Reactions of Cationic Carbyne Complexes of Manganese and Rhenium with the Carbonylrhodium Anion [Rh(CO)4]-. A Novel Route to Heteropolymetallic Bridging Carbyne Complexes with μ- andμ3-Carbyne Ligands Lei Zhang, Baohua Zhu, Nu Xiao, Qiang Xu, Nobuko Tsumori, Jie Sun, Yuanqi Yin, 32 and Jiabi Chen Organometallics ,2003, 22, 4369-4371. 课题负责人：甘良兵 1072 课题编号： 2002-28 课题负责人：范青华 课题编号： 2002-29 1. Dendritic BINOL Ligands for Asymmetric Catalysis: Effect of the Linking Positions and Generations of the Dendritic Wedges on Catalyst Properties Guo-Hua Liu, Wei-Jun Tang, Qing-Hua Fan* Tetrahedron, 2003, 59, 8603-8611. 1075 课题负责人：朱成建 课题编号： 2002-30 1. The First Example of Enantioselective Isocyanosilylation of meso Epoxides with TMSCN Catalyzed by Novel Chiral Organogallium and Indium Complexes Chengjian Zhu, Fang Yuan, Weijin Gu, Yi Pan Chem. Commun., 2003, 692-693. 1084 2. Synthesis and Asymmetric Catalytic Activities of Chiral Organogallium and Indium Complexes with Ephedrine Derivates as Ligands. The Crystal Structure of [(1R, 2S)-(Me2Ga--OCH(C6H5)CH(CH3)--NHCH3)]2. Fang Yuan, Chengjian Zhu, Jiangtao Sun, Yongjiang Liu, Yi Pan J. Organomet., Chem. 2003, 682, 102-107. 1086 课题负责人：陈忠宁 课题编号： 2002-32 1. Luminescent heterohexanuclear complexes with platinum alkynyl and silver diphosphine as components Qiao-Hua Wei, Gang-Qiang Yin, Zhen Ma, Li-Xi Shi, Zhong-Ning Chen* Chem. Commun., 2003, 2188-2189. 1092 2. Syntheses, Structures and Electronic Interactions of Dicyanamide/Tricyanomethanide-bridged Binuclear Organometallic Complexes Li-Yi Zhang, Lin-Xi Shi, Zhong-Ning Chen* Inorg. Chem., 2003, 41, 633-640. 1094 课题负责人：王 磊 课题编号： 2002-34 1. A Novel Preparation of Methyl Ketones through One-Carbon Homologation of Aldehydes Lei Wang,* Pinhua Li, Jincan Yan and Zhongzhi Wu Tetrahedron Lett., 2003, 44, 4685-4688. 1102 33 2. Reduction of Aromatic Nitro Compounds to Aromatic Amines with Nano-sized Activated Metallic Iron Powder in Water Lei Wang,* Pinhua Li, Zongtao Wu, Jincan Yan and Min Wang Synthesis, 2003, 2001-2004. 1106 3. Unexpected Chemoselective Debromination and Hydrogenation of 1,1-Dibromo-1-alkenes Mediated by Samarium Metal in Methanol Lei Wang,* Pinhua Li, Yuanyuan Xie and Yanbin Ding Synlett, 2003, 1137-1140. 1110 4. Sonogashira Coupling Reaction with Palladium Powder, Potassium Fluoride in Aqueous Media Lei Wang* and Pinhua Li Synth. Commun., 2003, 33, 3679-3685. 1114 5. Microwave-Enhanced Mannich Condensation of Terminal Alkynes, Primary Amines with Paraformaldehyde on Cuprous Iodide Doped Alumina under Solvent Free Conditions Lei Wang* and Pinhua Li Chin. J. Chem., 2003, 21, 710-713. 1121 6. Sonogashira Coupling Reaction with Palladium Powder, Potassium Fluoride in Methanol Lei Wang* and Pinhua Li Chin. J. Chem., 2003, 21, 474-476. 1125 34