金属有机化学国家重点实验室2012年年度进展报告.doc

金属有机化学国家重点实验室 学科带头人现状与需求 现有人员 目前学科方向 陆熙炎院士 过渡金属有机化学 戴立信院士 不对称催化 麻生明院士 过渡金属有机化学 侯雪龙研究员 不对称催化 施敏研究员 过渡金属有机化学 丁奎玲研究员 不对称催化 唐勇研究员 主族金属有机化学，高分子化学 刘元红研究员 钛、锆金属有机化学，过渡金属催化 陈耀峰研究员 稀土金属有机化学 游书力研究员 过渡金属有机化学，不对称催化 刘国生研究员 过渡金属有机化学 邓亮研究员 廉价金属有机化学 李玉学研究员 计算金属有机化学 黄正研究员 金属有机化学和催化 段伟良副研究员 过渡金属催化 余金权研究员 碳氢键活化反应 发展学科方向 需求计划人数 金属催化的小分子活化 1 金属络合物及反应化学 1 后过渡金属有机化学 1 前过渡金属有机化学 1 主族元素金属有机化学 1 金属有机计算化学 1 1 一、科研工作与成果 按照国家科技部最新要求和规定，2012 年实验室自主研究课题共计资助 660.5 万元，包括自由探索课题 14 项，资助 140 万，重点课题 5 项，资助 520.5 万元。 今年实验室主持的国家和省部委的重大重点项目有：(1)科技部 973 项目 1 项，科技支撑项目 1 项；(2) 国家基金委创新群体项目 1 项、重大研究计划重点 支撑项目 1 项、重点项目 2 项、国际合作项目 1 项；(3)中科院知识创新方向性 重大项目 1 项、海外团队项目 1 项；(4)上海市资助项目 6 项。作为课题骨干参 加的国家和省部委的重大重点项目有：(1) 973 项目 5 项；(2)国家基金委重点项 目 1 项；另外实验室还承担了(1)国家基金委其他项目 22 项；(2)其他省部委及中 科院项目 13 项；横向项目 8 项。 实验室 2012 年共发表了 282 篇论文（含客座人员发表论文），其中 J. Am. Chem. Soc. 12 篇，Angew. Chem. Int. Ed. 26 篇。其中金属室固定成员发表了 122 篇论文，包括 J. Am. Chem. Soc. 5 篇，Angew. Chem. Int. Ed. 12 篇，Chem. Soc. Rev. 3 篇 ， Acc. Chem. Res. 1 篇 ， Chem. Sci. 1 篇 ， Adv. Synth. Catal. 10 篇 ， Chem. Commun. 10 篇，Chem. Eur. J. 5 篇，Org. Lett. 18 篇，J. Org. Chem. 3 篇， Organometallics 7 篇等。 实验室今年在金属有机配合物合成、结构及反应化学、不对称催化、过渡金 属催化的新反应等方面取得了一些突出的成果： 1. 在金属有机配合物合成、结构及反应化学的研究方面，成功地合成了第 一例稀土金属末端氮卡宾化合物-钪末端氮卡宾化合物，研究了其反应性能和反 应模式 (Chem. Commun. 2012, 48, 3403)；以 2-三丁基锡基呋喃作为金属转移试 剂，实现了金催化的 1,6-二炔-4-烯-3-醇环化/金属转移反应，并通过呋喃锡与阳 离子型金络合物的当量实验分离得到的二金物种直接证明了金属转移反应的发 生，同时也揭示了金催化的反应体系中可能广泛存在二金中间体(Angew. Chem. Int. Ed. 2012, 51, 6181)；深入研究了 In-TOX/Ni(II)催化下的不对称合成反应，通 过三噁唑啉配体 In-TOX’与高氯酸镍的配合物单晶，研究了边臂上单噁唑啉在催 化体系中的重要作用，发现边臂上的手性基团对反应的活性以及对映选择性控制 有着重要的影响 (J. Am. Chem. Soc. 2012, 134, 9066)。 2 2. 在不对称催化的研究方面，通过 SpinPhox/Iridium(I)络合物催化 α, α’-二 (2-羟基亚芳基)酮的不对称催化氢化-缩酮化，首次实现了芳香螺缩酮化合物的催 化不对称合成，该反应在温和的条件下，能够以高的收率、优秀的非对映和对映 选择性得到目标化合物，工作发表在 Angew. Chem. Int. Ed. 2012, 51, 936 上，并 先后被 SYNFACTS 和 Angew. Chem. Int. Ed.积极评价；进一步研究了过渡金属铱 催化的去芳构化反应，将铱催化的不对称烯丙基去芳构化反应成功地运用到了取 代吡咯中(Chem. Sci. 2012, 3, 205)，并通过铱催化的吲哚体系分子内烯丙基去芳 构化实现了具有 5 元螺环结构骨架的 Spiroindolenine 衍生物的不对称合成 (Angew. Chem. Int. Ed. 2012, 51, 1680)。 3. 在过渡金属催化的新反应方面，研究了两价钯催化的通过芳烃 C-H 活化 启动的串联环化反应或碳-碳偶联反应；研究了 CuBr 催化和 ZnI2 促进的轴手性 联烯的不对称合成，筛选了一系列仲胺，发现当使用吡咯烷时，通过简单的过滤 操作后再加入 ZnI2 即可成功实现从炔丙基胺到联烯的转化；深入研究了金催化 下的羟甲基亚甲基环丙烷的分子内环化反应和亚乙烯基环丙烷的开环反应，并对 张力分子在金催化下的 C-C 键的断裂模式 (Chem. Soc. Rev. 2012, 41, 3318) 和亚 甲基环丙烷张力分子的反应新模式(Acc. Chem. Res. 2012, 45, 641)进行了总结；研 究了钯催化的活性烯烃氧化芳三氟甲基化反应，以活性烯烃为底物，TMSCF3 为三氟甲基源，在室温条件下以较高收率得到芳三氟甲基化产物，从而构建含三 氟甲基的氧化吲哚骨架并进行了初步的机理研究(J. Am. Chem. Soc., 2012, 134, 878)。 今年实验室的重大研究成果有： 1. “基于边臂策略的立体化学控制与催化反应研究”项目获国家自然科学二等 奖 现代合成反应要求经济、高效、环境友好的化学。发展新型催化剂(试剂)以 实现选择性控制与提高催化效率成为现代有机合成化学研究中最重要和最具挑 战性的领域之一。“基于边臂策略的立体化学控制与催化反应研究”围绕叶立德反 应和不对称催化中选择性控制与催化问题，在科技部“973”、国家基金委重点项 目、杰出青年基金和创新研究群体、中科院“百人计划”等项目资助下开展了系统 的创新性研究。项目运用“边臂策略”设计新的催化剂(试剂)，成功应用于高选择 3 性的有机合成反应和功能分子的合成中，发展了一些调控有机合成反应选择性和 提高催化效率的新策略、新方法及新反应，为新型催化剂（试剂）的设计和反应 选择性控制提供了新思路和途径： （1） 采用“边臂策略”首次设计合成了假C3-对称性手性噁唑啉配体(TOX), 发现TOX/ 金属体系在傅-克反应、Kinugasa 反应、环加成与环丙烷化反应等多 个重要的不对称催化反应中表现出对映选择性提高、配体加速、杂质容忍性好和 催化剂用量低等优异性能，阐明了“边臂”的作用；首次实现了Cu(II) 催化的不 对称Kinugasa 反应；首次通过反应条件的改变实现了吲哚和硝酮对亚烷基丙二 酸酯的不对称傅-克反应和环加 成反应立体选择性的调控。该策 略和配体多次被国际同行应用于 不对称催化反应中。 （2） 高效催化和高选择性控制 是叶立德化学面临的挑战性课 题 。 利 用“ 边 臂 策 略 ” 设 计 了 PEG-Te 催化剂，将叶立德烯基 化反应的催化剂用量降至最低0.5 mol ％，是迄今为止叶立德反应催化剂效率最 高的例子 ； 利用“羟基”或“锂离子”边臂经叶立德途径实现了乙烯基环丙烷化合物的 多样性和高选择性的直接合成，发展了调控该类反应立体化学的新方法和新策略， 并实现了催化的不对称叶立德环 丙烷化反应；发现了一些叶立德 启动的新的串联环化反应，为合 成杂、并环化合物提供了新途径。 这些方法被成功地应用于一些生 物活性分子的全（表观）合成中。 （3） 利用"边臂策略"设计 的新型吡咯烷-脲双功能催化剂 实现了高效催化的环酮对硝基烯的Michael 加成反应（最高达dr > 99/1 和98% ee）。该催化剂被国际同行成功应用于(+)-trachyspic acid 的全合成中。 4 研究成果在多种国际重要化学期刊发表，包括Acc. Chem. Res.1 篇, J. Am. Chem. Soc. 7 篇，Angew. Chem. Int. Ed. 2 篇，影响因子> 9.0 的12 篇，所发展 的催化剂和手性配体被国际同行成功应用于有机合成反应和功能分子的合成。20 篇核心论文的总影响因子202.9 （以2010 年计)，篇均影响因子10.1；SCI 他引 1070 次，篇均他引53.5 次，单篇最高他引183 次。培养了15 名博士，其中1 人获中国科学院院长特别奖和全国百篇优秀论文，1 人获中国科学院50 篇优秀 论文和全国百篇优秀论文提名奖。这15 名博士中，目前1 人入选中国科学院百 人计划，5 名已成为985 高校教授或副教授（其中1 名入选青年千人）。项目负 责人应邀在包括IUPAC 国际金属有机等系列会议上作邀请或大会报告11 次，在 双边会议上做邀请报告5 次，2002 年获国家杰出青年基金，2004 年获Thieme Journal Award，2006 年获第九届中国青年科技奖。本研究丰富和发展了有机合 成化学中选择性调控和催化的方法和途径，在一定程度上推动了有机合成化学的 发展，项目主要成果处于国际领先水平。 2. “手性膦氮配体的设计合成及在不对称催化中的应用” 项目获上海市自然科 学一等奖 手性化合物在生命和材料等领域的地位举足轻重，不对称催化则为获得手性 物质的最理想方法之一。金属催化不对称反应中配体的作用至关重要。 该项目 从手性配体作用的认识和不对称催化过程的理解着手，设计合成和改造了一系列 手性膦氮配体，围绕不对称催化一些反应中的挑战，重要不对称催化新反应的实 现以及反应选择性调控、配体中多手 性因素的相互关系等开展研究，取得 了如下重要成果： （ 1 ）设 计 了 新 型 膦 氮 配 体 SIOCPhox，对类型广泛的单取代烯丙 基底物实现了高区域、 高对映选择性， 为国际最好结果；实现了开链酮、酰 胺等羰基 α-碳负离子等“硬”碳负离子 的高对映选择性烯丙基烷基化反应，成果具国际领先；实现了钯催化高选择性不 对称环丙烷化反应，为该领域一个重大突破；实现了对碳亲核试剂的动力学拆分， 5 提供了简便获得各种光学活性化合物的新途径。 （2）首次实现了铜催化硝基烯 烃与甲亚胺叶立德的不对称 1,3-偶 极环加成反应和铱催化 α,β- 不饱和 酮碳碳双键不对称氢化。实现了铜 催 化 不 对 称 1,3- 偶 极 环 加 成 及 Mannich 反应的非对映选择性调控 和钯催化不对称 Heck 反应中产物构 型调控，解决了 Mannich 反应中难 以实现 anti-选择性的难题。 （3）阐明了二茂铁配体中 平面手性对于不对称诱导的作 用及其作用方式。 相关成果已在重要国际刊 物上发表。20 篇重要论文被他 引 1154 次，单篇最高他引 210 次。编著专著一部。 5 项发明专 利获授权。在重要国际会议做 大会报告、邀请报告 10 余次。 所获成果对有机化学特别是不对称催化领域的发展起到了重要推动作用。 二、 队伍建设与人才培养 实验室的学术骨干队伍以中国科学院院士、杰出青年基金获得者和中科院百 人计划入选者为主体。现有在职人员 81 人，副高级以上研究人员 38 人，这其中 包括研究员 15 名(含院士 3 名)，国家杰出青年基金获得者 8 名，科学院“百人计 划”入选者 8 名，“青年千人计划”入选者 1 名，“千人计划(创新人才短期项目)” 入选者 1 名。 2012 年实验室固定人员中余金权研究员获 “千人计划（创新人才短期项 目）”；刘国生研究员获 “国家杰出青年基金”；邓亮研究员获 “优秀青年科学基 金”；丁奎岭研究员获 “上海市优秀院所长奖上海市优秀院所长奖”； 唐勇研究 6 员获“ 黄耀曾金属有机化学奖” ；游书力研究员获“Asian Core Program Lectureship Award (Japan, Singapore)” 、“AstraZeneca Excellence in Chemistry Award ”、 “中 国科学院优秀导师奖”、 “中国科学院研究生院 BHP Billiton 奖学金导师科研奖”。 2012 年实验室在读硕士研究生 34 名，博士研究生 72 名，在站博士后 3 名； 毕业硕士 4 名，博士 23 名。 三、对外开放与学术交流 今年实验室面向所外单位设立的开放课题有 4 项，资助总额 130.6 万元，均 按照预定的研究目标顺利执行，由开放基金资助完成的优秀成果如下： 优秀成果（一）： 首次报道了以炔丙基叠氮和酸为底物，通过直接的氧化脱氢偶联简洁高效的 形成炔丙基三级碳的碳氧键的方法，该方法条件温和，避免了卤代物的使用，具 有很高的原子经济性，且通过控制实验证明，叠氮在这一偶联中可能是一种重要 辅基。得到的含有炔，叠氮和酯的多官能团产物是一种重要的合成中间体，它可 以进一步转化成三氮唑， 苯并三氮唑和烯基醛等可能具有生物活性小分子(Angew. Chem. Int. Ed. 2012, 51, 10823)。 优秀成果（二）： 在 C-O 活化的研究方面，首次实现了苄醇 sp3 C-O 的在 Fe，Co，Ni 等催化 下与格式试剂的偶联反应，并通过机理研究进一步实现了从醇到格式试剂的转化 (J. Am. Chem. Soc. 2012, 134, 14638）。 优秀成果（三）： 利用双锂试剂的“协同效应”，建立了高效合成氮杂半瞬烯分子的2种方法， 首次测定了该类分子的活化能和单晶结构，发现了该类分子的多种化学反应类型， 该项研究结果表明该类分子存在中性同芳香性，为进一步的实验研究奠定了基础， 该工作被选为JACS Spotlights。 学术交流对于提高重点实验室的研究水平具有重要意义。实验室今年分别接 待了美国、日本、德国、英国、加拿大、西班牙、瑞典等国以及包括中国香港、 台湾在内的的 41 位科学家来室访问进行了学术交流。同时，实验室学术带头人 积极参加国际国内的重要学术会议，应邀在国内外学术会议上作邀请及大会报告 7 39 人次。 2012 年 10 月 9-12 日，由金属有机化学国家重点实验室主办的第五届国际 均相催化论坛（The Fifth International Forum on Homogeneous Catalysis）在中科 院上海有机所君谋楼一楼报告厅成功召开，麻生明院士和唐勇研究员共同担任大 会主席。国家自然科学基金委员会化学科学部主任林国强院士，中科院上海有机 所丁奎岭所长出席了开幕式。来自上海有机所、华东师范大学、华东理工大学、 复旦大学、上海交通大学、厦门大学、中国科技大学等科研院所和高校的两百多 名专家、科研工作者以及学生参加了本次论坛。 丁奎岭所长及林国强院士先后在开幕式上致辞，表达了对与会专家、学者 的热烈欢迎和诚挚感谢。本次会议共邀请了来自美国、加拿大、德国、西班牙、 日本以及中国的 19 名著名专家作了精彩的学术报告，主要围绕金属有机试剂参 与的有机合成、金属参与或催化的有机化学反应、不对称合成与催化等前沿及交 叉科学领域进行交流与探讨，突出均相催化领域的最新发展和未来态势。整个会 议反响热烈，很多听讲的学生和科研人员都表示有这样的机会了解学科前沿的相 关知识受益匪浅，同时结合自己在科研工作过程中遇到的问题与专家进行了积极 的沟通和交流。 国际均相催化论坛是由麻生明院士发起，金属有机化学国家重点实验室主办 的每两年一次的系列国际研讨会，自 2004 年以来，已在杭州、苏州、上海、昆 明等地成功举办了四届。该系列会议旨在为来自世界各地的均相催化领域的中外 科学家搭建桥梁，提供交流化学新思想、新成果的机会，共同商讨均相催化领域 的进一步发展计划，促进学术交流，探讨及建立合作。 四、实验室学术委员会工作 金属有机化学国家重点实验室第三届学术委员会第三次会议于 2012 年 10 月 23-24 日在北京召开。国家自然科学基金委化学部常务副主任梁文平研究员、 杜灿屏研究员、郑企雨处长以及中国科学院高技术研究与发展局化工处唐清研究 员应邀参加了此次会议。 在会议上，实验室主任唐勇研究员汇报了重点实验室 2012 年度工作进展， 四川大学的冯小明教授作了题为“手性氮氧金属络合物催化不对称反应研究”的专 8 家报告，北京大学的焦宁教授作了题为“Aerobic Oxidation and Oxygenation”的学 术动态介绍，刘磊教授、王春江教授、施敏研究员、肖文精教授、唐勇研究员分 别汇报了各自的课题组工作进展及研究计划，此外，游书力研究员、段伟良副研 究员、陈耀峰研究员以及施章杰教授分别进行了有关 International Conference "Catalysis in Organic Synthesis"、12th International Symposium for Chinese Organic Chemists & 9th International Symposium for Chinese Inorganic Chemists 、 XXV International Conference on Organometallic Chemistry 以 及 Innovation on Organic Synthesis: The 1st Symposium in Direct C-H Activation 的国际会议介绍。 10 月 24 日上午，与会的领导、专家、学术委员以及老师等进行了热烈的讨 论和充分的交流。大家充分肯定了金属有机化学国家重点实验室近年来取得的成 绩，实验室在保持金属有机化学学科的优势和特色基础上，在面向国家重大需求 的研究方向如聚烯烃、氢甲酰化制丁醛等领域的新型催化剂研制方面也取得了很 好的成绩。同时，大家也对实验室的发展提出了建设性的建议和意见。希望实验 室能在保持特色和优势的基础上，更上一个台阶，进一步完善和壮大科研队伍， 在人才引进方面根据实验室的发展规划，结合国家需求，从目前活跃在金属有机 化学研究领域第一线的国外研究小组引进年轻有为的研究人才。 五、2012 年度研究生获奖情况表 序号 1 2 3 4 5 6 7 8 9 10 11 12 13 14 获奖名称 2012 年度国家奖学金 2012 年度国家奖学金 2012 年度国家奖学金 2012 年度国家奖学金 布劳恩奖学金 布劳恩奖学金 布劳恩奖学金 布劳恩奖学金 上海市高校优秀毕业生 中国科学院院长优秀奖 中科院研究生院三好学生标兵 中国科学院研究生院优秀毕业生 中国科学院研究生院院长特别奖 博士研究生学术新人奖 9 获奖人员 王鹏 章迪翰 林渭龙 孙宁 王晓明 楚甲祥 章迪翰 李军 陈宜峰 陈宜峰 王鹏 蔡泉 蔡泉 武庆锋 指导教师 唐勇 施敏 麻生明 刘元红 丁奎岭 陈耀峰 施敏 唐勇 刘元红 刘元红 唐勇 游书力 游书力 游书力 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 SciFinder Future Leaders in Chemistry 中国科学院研究生院 BHP Billiton 奖学金 刘铸晋优秀博士生奖学金 中国科学院研究生院优秀学生干部 中国科学院研究生院优秀学生干部 中国科学院研究生院优秀学生干部 中国科学院研究生院优秀学生干部 中科院研究生院三好学生 中科院研究生院三好学生 中科院研究生院三好学生 中科院研究生院三好学生 中科院研究生院三好学生 中科院研究生院三好学生 中科院研究生院三好学生 中科院研究生院三好学生 中科院研究生院三好学生 中科院研究生院三好学生 中科院研究生院三好学生 中科院研究生院三好学生 中科院研究生院三好学生 中科院研究生院三好学生 中科院研究生院三好学生 10 武庆锋 武庆锋 叶克印 叶俊涛 李德尧 刘家旺 袁浙梁 王飞 林渭龙 孙宁 张攀科 陈波 楚甲祥 范国钦 李小惠 慕欣 沈坤 杨晓菲 袁渭 章迪翰 卓春祥 莫贞波 游书力 游书力 游书力 麻生明 施敏 丁奎岭 刘国生 刘国生 麻生明 刘元红 丁奎岭 麻生明 陈耀峰 刘元红 侯雪龙 刘国生 陆熙炎 戴立信 施敏 施敏 游书力 邓亮 2012 年自由探索课题（2012-2013 年） 序 号 姓 名 题 目 2012-01 陆熙炎 芳基钯物种对碳－杂原子重键的加成反应研究 2012-02 麻生明 基于末端炔烃联烯的合成化学研究 2012-03 侯雪龙 钯催化“硬”碳亲核试剂的分子内烯丙基取代反应及应用研究 2012-04 施 敏 金催化的高张力分子的反应性能研究 2012-05 丁奎岭 环状碳酸酯均相催化氢化合成甲醇和乙二醇的研究 2012-06 唐 勇 基于双噁唑啉配体的新型双功能催化剂及其在不对称合成中的应用 2012-07 刘元红 具有可互变异构结构的金属杂环化合物的形成及反应性能研究 2012-08 陈耀峰 新型稀土硼杂苯化合物的合成、反应和催化性能研究 2012-09 游书力 过渡金属催化的烯丙基芳基化与去芳构化反应研究 2012-10 刘国生 过渡金属催化氟化反应研究 2012-11 李玉学 有机小分子催化的 CO2 还原官能团化机理的理论研究 2012-12 邓 亮 活性铁络合物促进的碳-碳、碳-氮键构筑反应研究 2012-13 段伟良 过渡金属催化不对称碳氢键官能团化合成手性膦化合物方法的研究 2012-14 黄 正 发展新型的烷烃转化体系：烷烃二聚和烷烃齐聚反应 11 2012 年实验室团队重点研究课题（2012-2016 年） 项目一：基于金属有机化学的反应设计与控制 课题负责人：侯雪龙 研究队伍：戴立信，侯雪龙，丁奎岭，王正，丁昌华 经费总额: 400 万 项目二：金属配合物的合成及其促进的高选择性合成反应 课题负责人：刘元红 研究队伍：刘元红，邓亮，李玉学，孙杰 经费总额: 300 万 项目三：金属催化的不饱和烃的合成和反应研究 项目负责人：麻生明 研究队伍：陆熙炎，麻生明，韩秀玲，张雪，余世超 经费总额: 400 万 项目四：新型烯烃聚合催化剂的研究 项目负责人：唐勇 研究队伍：唐勇，陈耀锋，黄正，孙秀丽，李军方 经费总额: 350 万 项目五：惰性化学键及体系的活化与官能团化中的金属有机化学 课题负责人：游书力 研究队伍：游书力，施敏，刘国生，段伟良，张玮 经费总额: 300 万 12 2012 年实验室开放课题（2012-2014 年） 项目一：碳－碳(杂)键形成的过渡金属有机化学 项目负责人：吴劼 研究队伍：吴劼，王佰全，陈忠宁，王磊，郎建平，施章杰，张兆国 经费总额: 81 万 项目二：过渡金属参与的有机合成反应 项目负责人：王剑波 研究队伍：王剑波，张俊良，余正坤，雷爱文，焦宁，刘磊，许斌，王春江 经费总额: 87 万 项目三：主族金属有机化合物的反应化学 项目负责人：席振峰 研究队伍：席振峰，周永贵，甘良兵，曹卫国，金国新，肖文精 经费总额: 63 万 项目四：稀土金属有机物的合成、结构与反应化学 项目负责人：王绍武 研究队伍：王绍武，周锡庚， 苏成勇，朱成建 经费总额: 42 万 13 2012 年申请专利 编号 专利名称 申请号 1 高支化油状烷烃聚合物及其制法和应用 201210098399.2 2 一类由烯烃制备高支化烷烃的催化体系 3 吲哚并八元环双烯化合物的合成方法及其应 用于伊普吲哚的合成 发明人 唐勇、陶闻杰、孙秀 丽、李军方、王峥 PCT/CN2012/07 唐勇、陶闻杰、孙秀 4545 丽、李军方、王峥 201210165288.9 麻生明、朱灿、练雄 东 4 氟代异喹啉类化合物及其制备方法 201210194986.1 刘国生、徐涛 5 氟代异喹啉[a]吡咯类化合物及其制备方法 201210195020.x 刘国生、徐涛 6 光学活性轴手性 α-联烯醇、合成方法和用途 201210193176.4 麻生明、叶俊涛 7 8 9 10 11 螺缩酮骨架的双齿亚磷酰胺配体及其制备方 法和应用 手性芳香螺缩酮骨架双膦配体及其制备方法 和应用 手性芳香螺缩酮类化合物及其制备方法和应 用 一种手性 α 亚甲基 β 内酰胺类化合物及其制 备方法和应用 一种依泽替米贝的合成方法及该方法中所用 的中间体 201210243736.2 201210253896.5 201210253476.7 201210253862.6 201210253879.1 12 并四苯及并五苯类化合物的合成方法 201210359027.0 13 新型钌络合物及制备甲醇和二醇的方法 201210403332.5 14 15 一种平面手性二茂铁化合物、合成方法及用 途 新型铱络合物以及利用伯醇 α-烷基化酰胺的 方法和应用 14 201210489246.0 201210533272.9 丁奎岭、王正、贾肖 飞 丁奎岭、王晓明、韩 召斌、王正 丁奎岭、王晓明、韩 召斌、王正 丁奎岭、王晓明、孟 繁烨、王正 丁奎岭、王晓明、王 正 刘元红、陈铭、陈宜 峰 丁奎岭、韩召斌 游书力、顾庆、高得 伟、石延超、赵正乐 黄正、郭乐 2012 年授权专利 编号 专利名称 专利号 发明人 1 一种内酯类化合物 ZL 201010195202.8 蒋敏、施敏 2 乙烯齐聚催化剂、合成方法及其用途 ZL 200510025276.6 3 4 5 6 7 含锆物质在催化水杨酸类化合物的清洁硝化 方法中的应用 1-氧杂苯并杂环类化合物、合成方法和用途 β-萘甲基取代的螺环双噁唑啉配体、合成方法 及其应用 α-萘甲基取代的螺环双噁唑啉配体、合成及其 在合成吡咯烷衍生物中的应用 一种(S)-3-氟-2-(4-异丁基苯)丙酸的医药用途 ZL 200610026933.3 唐勇、郭阳辉、 孙秀丽 高骏、郭英文、 施敏 ZL 201010217729.6 游书力、贺虎 ZL 200910196167.9 舒伟、麻生明 ZL 200910051785.4 麻生明、舒伟 ZL 201110032035.x 苏红，谢雨礼， 游书力，刘文博 丁奎岭、侯雪龙、 8 ZL 200610147735.2 一种丙烯氢甲酰化催化体系和方法 李欣、朱霞珍、 吴良泉、蒋文、 赖春波、陈建伟 9 10 11 螺环骨架膦噁唑啉配体、合成方法及其在不对 称氢化反应中的应用 四氢喹晽和吲哚啉衍生的磷氮配体、合成方法 和应用 一类具有单活性中心性质的齐格勒-纳塔烯烃 聚合催化剂 ZL 200910051314.3 ZL 200910048438.6 ZL 201010108695.7 12 新型三齿氮配体及其稀土金属配合物 ZL 200910047182.7 13 单茚基稀土配合物、合成方法以及应用 ZL 200810032938.6 丁奎岭、韩召斌、 王正 游书力、刘文博 唐勇、卫兵、李 军方、孙秀丽 陈耀峰、陆而立、 甘伟 陈耀峰、徐信 丁奎玲（丁奎 14 桥链双希夫碱-钴络合物及其合成方法和用途 ZL 201010288969.5 岭） ，张志鹏，张 如周，王正 15 Catalyst for Polymerization or Copolymerization of Olefins,Preparation and Use of the same 孙秀丽、胡蔚秋、 EP1426385B1 王聪、唐勇、张 玉良、夏春安 16 一种合成氟代含氮杂环化合物的方法 ZL 200910197231.5 刘国生、吴涛 17 一种有效的吡咯胺类衍生物的合成方法 ZL 200810204867.3 唐翔鹰、施敏 15 2012 年金属有机化学国家重点实验室来访人员报告 编号 题目 报告人 单位 主持人 时间 1 低碳发展－分离科学 和工程面临的新挑战 费维扬 院士 清华大学 丁奎岭 2012-01-09 10:00 2 Palladium-Catalyzed Carbonylation Reactions Dr. Xiaofeng Wu University Rostock 刘国生 2012-02-09 10:00 3 Sythesis of Natural Products with Conformational Chirality Prof. Beaudry Oregon University 刘国生 2012-03-01 15:00 施敏 2012-03-12 15:00 陈耀峰 2012-03-16 13:30 游书力 2012-03-20 15:00 唐勇 2012-03-26 15:00 4 Supramolecular Photochirogenesis Uranium 5 Christopher Dr. Yang Cheng Osaka University Prof. Stephen T. Liddle University Nottingham Prof. Wei Wang University of New Mexico in Non-Conventional State of Ligand Enviroments 6 New Strategies in Organocatalysis C-H 7 Activation Prof. Thorsten Bach Technische Reactions at sp2- and Universität sp3-Carbon Centers 手性氮氧作为有机催 化剂和手性配体在不 对称催化反应中的应 用 München 冯小明 教授 四川大学 唐勇 2012-03-28 15:00 9 The Development of Monovalent Phosphorus Chemistry Prof. Francois Mathey Nanyang Technological University 丁奎岭 2012-04-01 10:00 10 Tunneling by Carbon. Telling Experimentalists Where to Look and What to Look for Prof. Wes Borden University of North Texas 麻生明 2012-04-09 13:30 11 Ru2-Alkynyl Molecular Wires and Attenuation of Electronic Coupling Dr. Bin Xi Harvard University 邓亮 2012-04-09 14:00 12 Multifunctional Radical Quenchers as Mitochondrial Therapeutic Agents Prof. Sidney Hecht Associate JACS 丁奎岭 2012-04-16 08:30 8 16 Editor, 13 Development of Bifunctional Allylboron Reagents via allene Hydroboration Reactions and Applications to the Synthesis of Natural Products Prof. William R. Roush Associate JACS Editor, 14 Recent Advances in the Design, Synthesis and Testing of Artificial Molecular Machines Prof. Miguel Garibay Garcia- Associate JACS Editor, 15 Synthetic and Mechanistic Aspects of Gold(I) p-Activation Catalysis Prof. Ross Widenhoefer A. 16 Stereocontrol in the Synthesis of Natural Products: New Methods toward Solanoeclepin, Gibberellin, Prostaglandin, Malyngamide, etc. Prof. Minoru Isobe 17 Precise Synthesis of Hydrocarbon Polymers with Coordination Polymerization Catalysis Prof. Takeshi Shiono 18 19 Duke University 丁奎岭 2012-04-16 08:30 丁奎岭 2012-04-16 08:30 施敏 2012-05-09 10:00 丁奎岭 2012-05-11 10:00 唐勇 2012-05-14 10:00 游书力 2012-05-17 15:00 游书力 2012-05-18 10:00 National Tsing Hua University Hiroshima University About the Ssymmetric Functionalisation of Carbonyls after the Advent of Cinchona-based Primary Amine Catalysis Prof. Paolo Melchiorre The Quest for New Asymmetric Methodologies: Searching for Untrodden Path in Organocatalysis Dr. Ramon Rios Torres Institute of Chemical Research of Catalonia University Barcelona 17 of Territory 20 Enantioselective Organocatalytic Reactions: Dual Activation Concenpt Using Hydrogen Bonding Catalysts Prof. Vinod Singh 21 Organic Photovoltaics Research Guided by New Reactions and New Molecules Eiichi Nakamura Step-Economical Organic Syntheses through C-H Bond Functionalizations Prof. Lutz Ackermann Novel Enantioselective Reactions Promoted by Bifunctional Organocatalysts Prof. Hiroaki Sasai 22 23 Kumar 张玮 2012-05-22 15:00 丁奎岭 2012-05-24 10:00 顾庆 2012-05-25 9:00 顾庆 2012-05-25 9:00 丁奎岭 2012-05-25 10:00 刘国生 2012-05-28 10:00 施敏 2012-05-30 10:00 游书力 2012-05-30 15:00 at 游书力 2012-06-15 10:00 Macmillan Scientific 游书力 2012-06-20 IISER The University of Tokyo Georg-August-Univ ersitat of Gottingen Osaka University Synthesis of Natural Products, 24 Drugs, Agrochemicals and Materials by Multiple Prof. Lutz F. Tietze Georg-August-Univ ersity of Gottingen Pd-Catalyzed Transformations Diamination 25 of Alkenes: Palladium Catalysis and Institute Prof. Kilian Muniz Gold-catalyzed Oxidative Cyclizations National Tsing-Hua Prof. R.-S. Liu University of Alkynes Minor 27 Enantiomer Recycling–a for Strategy Improving Organic Prof. Christina Moberg 28 with Visible Light 29 Science Publishing at Chemistry Royal Institute of Technology Sweden Enantioselectivity Photocatalysis Chemical Research of Catalonia Iodine(III) Reagents 26 of University Prof. Tehshik Yoon Wisconsin of Madison Dr. Matthew Salter 18 Nature Publishing 19:00 Communications Group Well-Defined 30 Base Metal Catalysts for Cross Coupling of Alkyl Halides and Prof. Xile Hu 31 in of Chemical Sciences and 游书力 2012-06-28 10:00 游书力 2012-06-29 10:00 游书力 2012-07-11 14:00 丁奎岭 2012-07-16 10:00 丁奎岭 2012-07-19 15:30 游书力 2012-08-08 10:00 游书力 2012-08-15 10:00 陈耀峰 2012-08-17 10:00 Engineering, Switzerland Direct Alkylation Advances Institute the Synthetic Chemistry of Prof. Tetrapyrroles Lindsey University Dr. Jianguang Zhou Suzhou Novartis —the Jonathan S. North Carolina State Pigments of Life Chemical 32 Process R&D: Chemistry and Beyond 33 Taming of Superacids: A Fascinating Journey 34 探讨纳米科技发展的 思路 Prof. Thomas Mathew 35 From Concepts to Prof. Dr. Southern California 家工程研究中心 Magnus Rueping Institute of Organic Chemistry, RWTH Aachen, Germany Applications From of 纳米技术及应用国 何丹农 教授 Chiral Counterion Pair Catalysis: University Selectivity Profiling technology to New Drug Discovery---A 36 Focused Scaffold 中科院合肥物质科 刘青松 研究员 学研究院 Approach to Develop Kinase inhibitors as Potential Anti-cancer Theraies Designing Non-Cp Ancillary Ligands to 37 Support Stable Thermally Rare Prof. Paul G. Hayes Earth Dialkyl Complexes 19 University Lethbridge of Merck Catalysis Needs 38 for Drug Discovery, Development and Merck Dr. Yongkui Sun Sharp & 丁奎岭 2012-08-28 09:30 丁奎岭 2012-09-28 10:00 唐勇 2012-10-16 10:00 游书力 2012-12-13 10:00 Dohme Commercialization 39 Max-Planck-Institu Synthesizing Prof. Klaus Müllen Electronic Properties 40 of Ruthenium Catalysts C-H for Polymer Research Germany Advantages in te Bond Prof. Pierre Dixneuf The University of Rennes Activation New Chemistry and 41 Chemical Sulfur Tools for Related Washington Prof. Ming Xian University Biological Problems 20 State 2012 年会议报告 1. 陈耀峰，新型稀土金属配合物的合成、结构和反应性能研究 (邀请报告)，中 国化学会第 28 届学术年会，中国成都，2012 年 4 月。 2. 陈 耀 峰 ， Scandium Terminal Imido Complexes: Synthesis, Structure and Reactivities (Invited Lecture), Münster- 上 海 - 香 港 三 边 金 属 有 机 化 学 会 议 , Shanghai, China, May. 2012. 3. 邓 亮 ， Iron and Cobalt Complexes with Monodentate N-Heterocyclic CarbeneLigation: Synthesis, Structure, and Reactivity Study (Invited Lecture), XXV International Conference on Organometallic Chemisty, Lisboa, Portugal, Sep. 2012. 4. 丁 奎 岭 ， Chiral Catalyst Evolution: Rational Design and Serendipity (Invited Lecture), 4th Dalton Transactions International Symposium: Organometallic Chemistry and Catalysis, Shanghai, China, Nov. 2012. 5. 丁奎岭，Chiral Catalyst Evolution: Rational Design and Serendipity (大会报告)， 中国化学会第十七届全国金属有机化学学术讨论会，中国北京，2012 年 10 月。 6. 丁 奎 岭 ， Chiral Catalyst Evolution: Rational Design and Serendipity (Invited Lecture), The 5th International Forum on Homogeneous Catalysis, Shanghai, China, Oct. 2012. 7. 丁 奎 岭 ， Chiral Catalyst Evolution: Rational Design and Serendipity (Invited Lecture), 1st International Symposium on the Natural Product Synthesis and Process Methods for Drug Manufacture, Chongqing, China, Sep. 2012. 8. 丁 奎 岭 ， Chiral Catalyst Evolution: Rational Design and Serendipity (Invited Lecture), The 6th Takeda Science Foundation Symposium on PharmaSciences, Osaka, Japan, Sep. 2012. 9. 丁 奎 岭 ， Chiral Catalyst Evolution: Rational Design and Serendipity (Plenary Lecture), 12th International Symposium for Chinese Organic Chemists (ISCOC-12), Lanzhou, China, Aug. 2012. 21 10. 丁 奎 岭 ， Chiral Catalyst Evolution: Rational Design and Serendipity (Invited Lecture), Chiral China 2012 Symposium, Lanzhou, China, Aug. 2012. 11. 丁奎岭，Chiral Catalyst Evolution: Rational Design and Serendipity (大会报告)， 中国化学会第十届全国有机合成化学学术讨论会，中国长春，2012 年 8 月。 12. 丁奎岭，Chiral Catalyst Evolution: Rational Design and Serendipity (邀请报告)， 河南大学百年校庆“有机功能材料专题研讨会，中国开封，2012 年 4 月。 13. 丁 奎 岭 ， Chiral Catalyst Evolution: Rational Design and Serendipity (Invited Lecture), 19th International Conference on Phosphorus Chemistry (ICPC 2012), Rotterdam, The Netherlands, Jul. 2012. 14. 丁 奎 岭 ， Chiral Catalyst Evolution: Rational Design and Serendipity (Invited Lecture), 3th International Symposium on Organic Synthesis and Drug Development (ISOSDD’2012), Changzhou, China, May 2012. 15. 侯雪龙，Pd-Catalyzed Asymmetric Allylic Alkylation with “Hard” Carbonanions (Invited Lecture), Tarragona, Spain, July 2012. 16. 侯 雪 龙 ， Some Advances in Pd-Catalyzed Asymmetric Allylic Substitution(Invited Lecture)，Chiral China 2012 Symposium, Lanzhou, China, Aug. 2012. 17. 刘国生，过渡金属催化的氟化反应研究 (邀请报告)，第 28 届全国化学会年 会，中国成都，2012 年 4 月。 18. 刘国生，金属银催化的氟化反应研究 (邀请报告)，第 7 届中美有机化学家会 议，中国昆明，2012 年 7 月。 19. 刘国生，过渡金属催化 (邀请报告)，第 9 届有机化学合成会议，中国长春， 2012 年 8 月。 20. 刘 国 生 ， Pd-catalyzed C-H Activation: Oxidative Functionalization of Alkenes (Invited Lecture), The 1st International Symposium on C-H Activation, Beijing, China, Oct. 2012. 21. 刘国生，过渡金属催化氟化 (邀请报告)，第 11 届全国氟化学会议，中国南 昌，2012 年 10 月。 22. 刘国生，过渡金属催化氟化 (邀请报告)，第 17 届全国金属有机化学会议， 中国北京，2012 年 10 月。 23. 刘 国 生 ， Transition Metal -catalyzed Fluorination (Invited Lecture), The 7th 22 International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-6), Asian Core Program (ACP), Singapore, Dec. 2012. 24. 麻生明，Nucleophilic Additions of 2,3-Allenoates with Organometallic Reagents (Invited Lecture), The First International Conference on Organometallics and Catalysis (OM&Cat), Beijing, China, Oct. 2012. 25. 唐勇，Bystander as a Remote Control of Enantioselectivity in Bisoxazoline-based Asymmetric Catalysis (Invited Lecture)，OBC 2012, 上海，2012 年 4 月。 26. 唐 勇 ， Sidearm-Performance Control of Titanium Imino-enolates in Olefin Polymerization (Invited Lecture)，第五届高分子化学国际学术研讨会 (PC 2012)，中国长春，2012 年 6 月。 27. 唐勇，Sidearm Approach to Olefin Polymerization Catalysts Based on Titanium Imino-Enolates (Plenary Lecture), The International European Cooperation in Science and Technology Workshop, Regensburg, Germany, Aug. 2012. 28. 唐勇，A New Approach to Catalysis-Sidearm Effects and Applications (Keynote Lecture), XXV International Conference on Organometallic Chemisty, Lisboa, Portugal, Sep. 2012. 29. 唐勇，边臂调控-手性催化剂设计的策略与应用 (大会报告)，第 17 届全国金 属有机化学会议，中国北京，2012 年 10 月。 30. 游书力，Selective C-H Bond Direct Funcationalization (Invited Lecture), 2011 AstraZeneca Excellence in Chemistry Award Symposium, Bangalore, India, Jan. 2012. 31. 游书力，Catalytic Asymmetric Dearomatization Reaction (Invited Lecture), 2011 AstraZeneca Excellence in Chemistry Award Symposium, Bangalore, India, Feb. 2012. 32. 游书力，Catalytic Asymmetric Dearomatization Reaction (Invited Lecture), The First Nagoya Symposium on Green Synthesis & Catalysis (NSGSC-1), Nagoya, Japan, Mar. 2012. 33. 游书力，Exploring Dearomatization Reactions in Asymmetric Catalysis (Invited Lecture), Catalysis and Sensing for our Environment 2012 (CASE12), Shanghai, China, Apr. 2012. 34. 游书力，Catalytic Asymmetric Dearomatization Reaction (Invited Lecture), The 23 3rd International Symposium on Organic Synthesis and Drug Development (3rd ISOSDD), Changzhou, China, May 2012. 35. 游书力，Catalytic Asymmetric Dearomatization Reaction (Invited Lecture), The 2nd Hong Kong-Münster-Shanghai Joint Trilateral Symposium on Organometallic Chemistry, Shanghai, China, May 2012. 36. 游书力，Asymmetric Allylic Dearomatization Reactions (Invited Lecture), The 8th Sino-US Chemistry Professors Conference, Kunming, China, Jul. 2012. 37. 游书力，Asymmetric Allylic Dearomatization Reactions (Invited Lecture), 2nd International Conference on Molecular & Functional Catalysis (ICMFC-2), Singapore, Jul. 2012. 38. 游 书 力 ， Ir-Catalyzed Asymmetric Allylic Dearomatization Reactions (Invited Lecture), Chiral China 2012, Lanzhou, China, Aug. 2012. 39. 游 书 力 ， Ir-Catalyzed Asymmetric Allylic Dearomatization Reactions (Invited Lecture), International Conference (ICCOS-2012), Moscow, Sep. 2012. 24 “Catalysis in Organic Synthesis”, 2012 年发表专著(章节) 专著(章节)题目 作者 Organic Chemistry-Breakthroughs and Perspectives DFT Studies 专著名称 Kuiling Ding, Lixin Dai Chemistry-Breakthroughs Wiley-VCH Computational Yuxue Li Organometallic Chemistry Reactions Chemical Organic and Perspectives on Zirconium-Mediated of Jianmei Lu, Vinylidenecyclopropanes Min Shi Springer-Verlag Berlin Heidelberg Spring Briefs in Transformation Lixiong Shao, Benzylidenecyclopropane 出版社 Molecular Science Zhen Zhang, EROSMS Min Shi Iridium-Catalyzed Wenbo Asymmetric Allylic Jibao Xia, Substitutions Shuli You Reduction: Asymmetric Transfer Hydrogenation with Hantzsch Esters Liu, Chao Zheng, Shuli You Springer-Verlag Top. Organomet. Chem. Berlin Heidelberg Comprehensive Chirality 25 Elsevier 2012 年论文目录 一、 固定人员论文目录（按通讯作者姓氏首字母排序） 1. Reactivity of Scandium Terminal Imido Complexes towards Metal Halides. Erli Lu, Qinghai Zhou, Yuxue Li, Jiaxiang Chu, Yaofeng Chen*, Xuebing Leng, Jie Sun Chem. Commun. 2012, 48, 3403-3405. 2. C−P or C−H Bond Cleavage of Phosphine Oxides Mediated by an Yttrium Hydride. Erli Lu, Yaofeng Chen*, Jiliang Zhou, Xuebing Leng Organometallics 2012, 31, 4574-4578. 3. Synthesis, Structure, and Reactivity Study of Iron(II) Complexes with Bulky Bis(anilido)thioether Ligation. Jie Xiao, Liang Deng* Organometallics 2012, 31, 428-434. 4. Dinuclear Iron Complex-Catalyzed Cross-Coupling of Primary Alkyl Fluorides with Aryl Grignard Reagents. Zhenbo Mo, Qiang Zhang, Liang Deng* Organometallics 2012, 31, 6518-6521. 5. Dinuclear Iron-Imido Complexes with N-Heterocyclic Carbene Ligation: Synthesis, Structure, and Redox Reactivity. Qiang Zhang, Li Xiang, Liang Deng* Organometallics 2012, 31, 4537-4543. 6. C-H Bond Amination by Iron-imido/nitrene Species. Long Zhang, Liang Deng* Chin. Sci. Bull. 2012, 57, 2352-2360. 7. Intramolecular C(sp3)–H Bond Activation Reactions of Low-Valent Cobalt Complexes with Coordination Unsaturation. Zhenbo Mo, Dake Chen, Xuebing Leng, Liang Deng* Organometallics 2012, 31, 7040-7043. 8. Rh(I)-Catalyzed Enantioselective Hydrogenation of α‑Substituted Ethenylphosphonic Acids. Kaiwu Dong, Zheng Wang, Kuiling Ding* J. Am. Chem. Soc. 2012, 134, 12474-12477. 9. Catalytic Asymmetric Synthesis SpinPhox/Iridium(I)-Catalyzed of Hydrogenation Aromatic and Spiroketals by Spiroketalization of a,a’-Bis(2-hydroxyarylidene) Ketones. Xiaoming Wang, Zhaobin Han, Zheng Wang*, Kuiling Ding* Angew. Chem. Int. Ed. 2012, 51, 936-940. 10. Aromatic Spiroketal Bisphosphine Ligands: Palladium-Catalyzed Asymmetric Allylic Amination of Racemic Morita–Baylis–Hillman Adducts. XiaomingWang, Fanye Meng, YanWang, Zhaobin Han, Yong-Jun Chen, Li Liu*, ZhengWang*, 26 Kuiling Ding* Angew. Chem. Int. Ed. 2012, 51, 9276-9282. 11. Asymmetric Hydrogenation of α- or β-acyloxy α, β-unsaturated Phosphonates Catalyzed by a Rh(I) Complex of Mmonodentate Phosphoramidite. Jinzhu Zhang, Kaiwu Dong, Zheng Wang, Kuiling Ding* Org. Biomol. Chem. 2012, 10, 1598-1601. 12. Access to Both Enantiomers of α-Chloro-β-keto Esters with a Single Chiral Ligand: Highly Efficient Enantioselective Chlorination of Cyclic β-Keto Esters Catalyzed by Chiral Copper(II) and Zinc(II) Complexes of a Spiro-2,2’-bischroman-Based Bisoxazoline Ligand. Jie Li, Wei Pan, Zheng Wang, Xumu Zhang, Kuiling Ding* Adv. Synth. Catal. 2012, 354, 1980-1986. 13. Highly Enantioselective Asymmetric Hydrogenation of (E)-β, β-disubstituted α, β-unsaturated Weinreb Amides Catalyzed by Ir(I) Complexes of Spin Phox Ligands. Jian Shang, Zhaobin Han, Yang Li, Zheng Wang, Kuiling Ding* Chem. Commun. 2012, 48, 5172-5174. 14. Rh(I)/DpenPhos Catalyzed Asymmetric Hydrogenation of Enol Esters and Potassium (E)-3-Cyano-5-methylhex-3-enoate. Yan Liu, Zheng Wang, Kuiling Ding* Tetrahedron 2012, 68, 7581-7585. 15. DpenPhos/Rh(I)催化的 β-脱氢氨基酸酯的不对称氢化反应. 刘龑, 王正, 丁 奎岭* 化学学报 2012, 70(13), 1464-1470. 16. Catalytic Hydrogenation of Cyclic Carbonates: A Practical Approach from CO2 and Epoxides to Methanol and Diols. Zhaobin Han, Liangce Rong, Jiang Wu, Zheng Wang, Kuiling Ding* Angew Chem. Int. Ed. 2012, 51, Diarylphosphines to 13041-13045.(VIP) 17. Palladium-Catalyzed Asymmetric 1,4-Addition of Nitroalkenes for the Synthesis of Chiral P,N-Compounds. Jianjun Feng; Miao Huang, Ziqi Lin, Weiliang Duan* Adv. Synth. Catal. 2012, 354, 3122-3126. 18. Palladium-catalyzed Asymmetric Addition of Diarylphosphines to N-tosylimines. Miao Huang, Chun Li, Jian Huang, Weiliang Duan*, Sheng Xu Chem. Commun. 2012, 48, 11148-11150. 19. Diastereo- and Enantioselective Synthesis of Fluorinated Proline Derivatives via Copper-Catalyzed Asymmetric 1,3-Dipolar Cycloaddition. Qing Li, Chag Hua Ding, Xiao Hui Li, Walter Weissensteiner, Xuelong Hou* Synthesis 2012, 265-271. 27 20. Regio- and Enantioselective Palladium-Catalyzed Allylic Alkylation of Nitromethane with Monosubstituted Allyl Substrates: Synthesis of (R)-Rolipram and (R)-Baclofen. Xiaofei Yang, Changhua Ding, Xiaohui Li, Jianqiang Huang, Xuelong Hou*, Lixin Dai, Pinjie Wang J. Org. Chem. 2012, 77, 8980-8985. 21. Palladacycle-Catalyzed Reaction of Bicyclic Alkenes with Terminal Ynones: Regiospecific Synthesis of Polysubstituted Furans. Guangcun Ge, Dongliang Mo, Changhua Ding, Lixin Dai, Xuelong Hou* Org. Lett. 2012, 14, 5756-5759. 22. Multi-carbazole Derivatives: New Dyes for Highly Efficient Dye-sensitized Solar Cells. Hua Lai, Jia Hong, Ping Liu, Chao Yuan, Yuxue Li*, Qiang Fang* RSC Advances 2012, 2, 2427-2432. 23. Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature. Xin Mu, Tao Wu, Haoyang Wang, Yinlong Guo, Guosheng Liu* J. Am. Chem. Soc. 2012, 134 (2), 878-881. 24. Highly Selective Palladium-Catalyzed Intramolecular Chloroamination of Unactivated Alkenes by Using Hydrogen Peroxide as an Oxidant. Guoyin Yin, Tao Wu, Guosheng Liu* Chem. Eur. J. 2012, 18, 451-455. 25. Transition Metal-catalyzed Fluorination of Multi Carbon–carbon Bonds: New Strategies for Fluorinated Heterocycles. Guosheng Liu* Org. Biomol. Chem. 2012, 10, 6243-6248. 26. Palladium-Catalyzed Oxidative Arylalkylation of Unactivated Alkenes: Dual C–H Bond Cleavage of Anilines and Acetonitrile. Hao Zhang, Pinhong Chen, Guosheng Liu* Synlett. 2012, 23, 2749-2752. 27. Organocatalyzed Arylalkylation of Activated Alkenes via Decarboxylation of PhI(O2CR)2: Efficient Synthesis of Oxindoles. Tao Wu, Hao Zhang, Guosheng Liu* Tetrahedron 2012, 68, 5229-5233. 28. Silver-catalyzed Fluorination Reactions. Tao Xu, Guosheng Liu* SynLett. 2012, 23, 955-958. 29. Ag(I)-Catalyzed Aminofluorination of Alkynes: Efficient Synthesis of 4-Fluoroisoquinolines and 4-Fluoropyrrolo[α]isoquinolines. Tao Xu, Guosheng Liu* Org. Lett. 2012, 14, 5416-5419. 30. Gold-Catalyzed Cyclization of 1,6-Diyne-4-en-3-ols: Stannyl Transfer from 2-Tributylstannylfuran Through Au/Sn Transmetalation. Yifeng Chen, Ming 28 Chen, Yuanhong Liu* Angew. Chem. Int. Ed. 2012, 51, 6181-6186. 31. Gold-Catalyzed Cascade Cyclizations of 1,6-Diynyl Carbonates to Benzo[b]fluorenes Involving Arylation of Oxocarbenium Ion Intermediates and Decarboxylative Etherification. Yifeng Chen, Ming Chen, Yuanhong Liu* Angew. Chem. Int. Ed. 2012, 51, 6493-6497. 32. Nucleophilic Addition of Grignard Reagents to 3-Acylindoles: Stereoselective Synthesis of Highly Substituted Indoline Scaffolds. Lu Wang, Yushang Shao, Yuanhong Liu* Org. Lett. 2012, 14, 3978-3981. 33. Highly Efficient Synthesis of cis-[3]Cumulenic Diols via Zirconocene-Mediated Coupling of 1,3-Butadiynes with Aldehydes. Xiaoping Fu, Shasha Yu, Guoqin Fan, Yuanhong Liu*, Yuxue Li* Organometallics2012, 31, 531-534. 34. Gold-Catalyzed Furan/Yne Cyclizations for the Regiodefined Assembly of Multisubstituted Protected 1-Naphthols. Chengyu Wang, Yifeng Chen, Xin Xie, Jun Liu, Yuanhong Liu* J. Org. Chem. 2012, 77, 1915-1921. 35. Titanium-Mediated Cross-Coupling Reactions of Imines with Ketones or Aldehydes: An Efficient Route for the Synthesis of 1,2-Amino Alcohols. Guoqin Fan, Yuanhong Liu* Tetrahedron Lett. 2012, 53, 5084-5087. 36. Gold-Catalyzed Cyclizations of (o-Alkynyl)phenoxyacrylates with External Nucleophiles: Regio- and Stereoselective Synthesis of Functionalized Benzo[b]oxepines. Jun Liu, Yuanhong Liu* Org. Lett. 2012, 14, 4742-4745. 37. Unexpected Zirconium-Mediated Multicomponent Reactions of Conjugated 1,3-Butadiynes and Monoynes with Acyl Cyanide Derivatives. Shasha Yu, Xu, You, Yuanhong Liu* Chem. Eur. J. 2012, 18, 13936-13940. 38. Palladium-catalyzed Highly Efficient Synthesis of Tetracenes and Pentacenes. Ming Chen, Yifeng Chen, Yuanhong Liu* Chem. Commun. 2012, 48, 12189-12191. 39. Facile Synthesis of Fully Substituted Dihydro-β-carbolines via Brønsted Acid Promoted Cascade Reactions of α-Indolyl Propargylic Alcohols with Nitrones. Lu Wang, Xin Xie, Yuanhong Liu* Org. Lett. 2012, 14, 5848-5851. 40. Cationic Pd(II)-Catalyzed Highly Enantioselective Arylative Cyclization of Alkyne-tethered Enals or Enones Initiated by Carbopalladation of Alkynes with 29 Arylboronic Acid. Kun Shen, Xiuling Han*, Xiyan Lu* Org. Lett. 2012, 14, 1756-1759. 41. Palladium(II)-Catalyzed Cyclization Reaction of 2-(Alk-2’-ynyloxy)benzonitriles or 2-(Alk-2’-ynylamino)benzonitriles: A Facile Way to 2H-Chromene and 1,2-Dihydroquinoline Derivatives. Guoqin Xia, Xiuling Han*, Xiyan Lu*Adv. Synth. Catal. 2012, 354, 2701-2705. 42. Allenes in Catalytic Asymmetric Synthesis and Natural Product Syntheses. Shichao Yu, Shengming Ma*Angew. Chem. Int. Ed. 2012, 51, 3074-3112. 43. One-Pot Approach to Installing Eight-Membered Rings onto Indoles. Can Zhu, Xue Zhang, Xiongdong Lian, Shengming Ma*Angew. Chem. Int. Ed. 2012, 51, 7817- 7820. 44. Palladium-Catalyzed Cyclization Reactions of 2,3-Allenyl Amines with Propargylic Carbonates. Juntao Ye, Suhua Li, Shengming Ma* Org. Lett. 2012, 14, 2312-2315. 45. Palladium-Catalyzed Decarboxylation of Allenyl 3-Oxoalkanoates: An Efficient Synthesis of 3,4-Allenyl Ketones. Baoqiang Wan, Guochen Jia*, Shengming Ma* Org. Lett. 2012, 14, 46-49. 46. Catalytic Asymmetric Synthesis of Optically Active Allenes from Terminal Alkynes. Juntao Ye, Suhua Li, Bo Chen,Wu Fan, Jinqiang Kuang, Jinxian Liu, Yu Liu, Bukeyan Miao, Baoqiang Wan, Yuli Wang, Xi Xie, Qiong Yu, Weiming Yuan, Shengming Ma* Org. Lett. 2012, 14, 1346-1349. 47. Tuning of Regioselectivity in Inorganic Iodide-Catalyzed Alkylation of 2-Methoxyfurans via Electronic and Steric Effects. Jie Chen, Shengjun Ni, Shengming Ma* Adv. Synth. Catal. 2012, 354, 1114-1128. 48. Electronic Effect-Directed Au(I)-Catalyzed Cyclic C2-H Bond Functionalization of 3-Allenyl Indoles Involving Dearomatization. Bo Chen, Wu Fan, Guobi Chai, Shengming Ma* Org. Lett. 2012, 14, 3616-3619. 49. CO2-Activation for γ-Butyrolactones and Its Application in the Total Synthesis of (±)-Heteroplexisolide E. Suhua Li, Shengming Ma* Chem. Asian J. 2012, 7, 2411-2418. 50. Quadri-Synergtic Effect for Highly Effective Carbon Dioxide Fixation and Its Application to Indoloquinolinone. Suhua Li, Shengming Ma* Adv. Synth. Catal. 2012, 354, 2387-2394. 30 51. Electrophilic Cyclization of 2-(2’,3’-Allenyl)acetylacetates with Iodine Using Calcium Hydride as the Base. Baoqiang Wan, Xuefeng Jiang, Guochen Jia*, Shengming Ma* Eur. J. Org. Chem. 2012, 4373-4379. 52. Efficient Synthesis of N-(buta-2,3-dienyl) amides from Terminal N-propargyl Amides and Their Synthetic Potential towards Oxazoline Derivatives. Bo Chen, Nan Wang, Wu Fan, Shengming Ma* Org. Biomol. Chem. 2012, 10, 8465-8470. 53. FeCl3-catalyzed Cyclization of α-sulfonamido-allenes with Aldehydes—the Substituent Effect. Jiajia Cheng, Xinjun Tang, Yihua Yu, Shengming Ma* Chem. Commun. 2012, 48, 12074-12076. 54. PPh2Me-Mediated Tandem Reaction of 2-Alkyl-2,3-butadienoates with Isothiocyanates: Formation of 2-Aminothiophenes. Xiaoyang Guan, Min Shi* ACS Catalysis 2011, 1, 1154-1157. 55. Preparation of Chiral Multifunctional Thiourea–Phosphanes and Synthesis of Chiral Allylic Phosphites and Phosphane Oxides through Asymmetric Allylic Substitution Reactions of Morita–Baylis–Hillman Carbonates. Hongping Deng, Min Shi* Eur. J. Org. Chem. 2012, 183-187. 56. Rhodium(I)-Catalyzed [3+2] Intramolecular Cycloaddition of Alkylidenecyclopropane-propargylic Esters. Dihan Zhang, Min Shi* Tetrahedron Lett. 2012, 53, 487-490. 57. Nitrogen- and Phosphorus-Containing Lewis Bases Catalyzed [4+2] and [3+2] Annulations of Isatins with But-3-yn-2-one. Zhong Lian, Min Shi* Eur. J. Org. Chem. 2012, 581-586. 58. LDA-Mediated Cascade Carbolithiation Reactions of Vinylidenecyclopropanes with Enones and N-Sulfonated Imines as Well as Nitroalkene and Phenylmethylidenemalononitrile. Beili Lu, Jianmei Lu, Min Shi* Eur. J. Org. Chem. 2012, 587-695. 59. Reactions of Vinylidenecyclopropanes with Diphenyl Diselenide in the Presence of AIBN and Thermal-induced Further Transformation. Wei Yuan, Yin Wei, Min Shi*, Yuxue Li* Chem. Eur. J. 2012, 18, 1280-1285. 60. HOTf Mediated Cascade Reactions of 1-Arenoylcyclopropanecarboxylic Acids with Arenes. Genqiang Chen, Xiangying Tang, Min Shi* Chem. Commun. 2012, 31 48, 2340-2342. 61. Phosphorus-Containing Lewis Base Catalyzed Highly Regioselective Cyclization of Isatin Derived Electron Deficient Alkenes with But-3-yn-2-one. Zhong Lian, Yin Wei, Min Shi* Tetrahedron 2012, 68, 2401-2408. 62. Asymmetric Catalytic Mannich-type Reaction of Hydrazones with Difluoroenoxysilanes by using Imidazoline-anchored phosphine Ligand-Zinc(II) Complexes. Zhiliang Yuan, Liangyong Mei, Yin Wei, Min Shi*, Padmanabha V. Kattamuri, Patrick McDowell, Guigen Li Org. Biomol. Chem. 2012, 10, 2509-2513. 63. Enantioselective Synthesis of Highly Functionalized Trifluoromethyl-Bearing Cyclopentenes: Asymmetric [3+2] Annulation of Morita-Baylis-Hillman Carbonates with Trifluoroethylidene Malonates Catalyzed by Multifunctional Thiourea-Phosphines. Hongping Deng, Yin Wei, Min Shi* Adv. Synth. & Catal. 2012, 354, 783-789. 64. Strained Small Rings in Gold-Catalyzed Rapid Chemical Transformations. Beili Lu, Lunzhi Dai, Min Shi* Chem. Soc. Rev. 2012, 41, 3318-3339. 65. Reduction of Activated Carbonyl Groups Using Alkyl Phosphines as Reducing Agents: A Mechanistic Study. Yin Wei, Xuguang Liu, Min Shi* Eur. J. Org. Chem. 2012, 2386-2393. 66. Gold(I)-Catalyzed Intramolecular Hydroamination and Ring-Opening of Sulfonamide-Substituted 2-(Arylmethylene)cyclopropylcarbinols. Dihan Zhang, Kang Du, Min Shi* Org. Biomol. Chem. 2012, 10, 3763-3766. 67. Rapid Generation of Molecular Complexity in the Lewis or Brønsted Acid-mediated Reactions of Methylenecyclopropanes. Min Shi*, Jianmei Lu, Yin Wei, Lixiong Shao* Acc. Chem. Res. 2012, 45, 641-652. 68. A Three-component Condensation to Construct Spiro[indoline-3,3'-piperidin]-2-one Skeleton. Haibin Yang, Xiaoyang Guan, Yin Wei, Min Shi* Eur. J. Org. Chem. 2012, 2792-2800. 69. Gold(I)-Catalyzed Cycloisomerization of Nitrogen and Oxygen-Tethered Alkylidenecyclopropanes to Tricyclic Compounds. Dihan Zhang, Yin Wei*, Min 32 Shi* Chem. Eur. J. 2012, 18, 7026-7029. 70. DABCO-mediated [4+2] Annunation of But-3-yn-2-one and Activated Ketones: Facile Preparation of 2,3-Dihydropyran-4-one. Zhong Lian, Qianyi Zhao, Yin Wei, Min Shi* Eur. J. Org. Chem. 2012, 3338-3341. 71. Rh(I)-catalyzed Pauson-Khand-type [3+2+1] Cycloaddition Reaction of Ene-vinylidenecyclopropanes and CO: A Highly Regio- and Stereoselective Synthetic Approach for the Preparation of Aza- or Oxa-bicyclic Compounds. Beili Lu, Yin Wei, Min Shi* Organometallics 2012, 31, 4601-4609. 72. Chiral Multifunctional Thiourea-Phosphine-Catalyzed Asymmetric [3+2] Annulation of Morita-Baylis-Hillman Carbonates with Maleimides. Hongping Deng, De Wang, Yin Wei, Min Shi* Beils. J. Org. Chem. 2012, 8, 1098-1104. 73. An Efficient Method for the Synthesis of Alkylidenecyclobutanones via Gold-Catalyzed Oxidative Ring Enlargement of Vinylidenecyclopropanes. Wei Yuan, Xiang Dong, Min Shi* Chem. Eur. J. 2012, 18, 10501-10505. 74. Transition Metal-catalyzed Carbocyclization of Nitrogen and Oxygen-tethered 1,n-enynes and Diynes: Synthesis of Five or Six-membered Heterocyclic Compounds. Dihan Zhang, Zhen Zhang, Min Shi* Chem. Commun. 2012, 48, 10271-10279. 75. Asymmetric [3+2] Annulation of N-protected Isatins with But-3-yn-2-one Catalyzed by DIOP: Facile Creation of Enantioenriched Spiro[furan-2,3'-indoline]-2',4(5H)-dione. Zhong Lian, Min Shi* Org. Biomol. Chem. 2012, 10, 8048-8050. 76. Yb(NTf2)3-Catalyzed [3+3] Cycloaddition between Isatin Ketonitrones and Cyclopropanes to Construct Novel Spiro[tetrahydro-1,2-oxazine]oxindoles. Haibin Yang, Min Shi* Org. Biomol. Chem. 2012, 10, 8236-8243. 77. Rh(I)-catalyzed Pauson-Khand-type Cycloaddition Reaction of Ene-vinylidenecyclopropanes with Carbon Monoxide (CO). Wei Yuan, Xiang Dong, Min Shi*, Patrick McDowell, Guigen Li* Org. Lett. 2012, 14, 5582-5585. 33 78. A Chiral Cage-like Copper(I) Catalyst for the Highly Enantioselective Synthesis of 1,1-Cyclopropane Diesters. Chao Deng, Lijia Wang, Jun Zhu, Yong Tang* Angew. Chem. Int. Ed. 2012, 51, 11620-11623. 79. Side-Arm-Promoted Highly Enantioselective Ring-Opening Reactions and Kinetic Resolution of Donor-Acceptor Cyclopropanes with Amines. Youyun Zhou, Lijia Wang, Jun Li, Xiuli Sun*, Yong Tang* J. Am. Chem. Soc. 2012, 134, 9066-9069. 80. Tridentate Ligands and Beyond in Group IV Metal α-olefin Homo-/co-polymerization Catalysis. Carl Redshaw*, Yong Tang* Chem. Soc. Rev. 2012, 41, 4484-4510. 81. Highly Diastereo- and Enantioselective Cyclopropanation of 1,2-Disubstituted Alkenes. Jun Li, Saihu Liao, Hu Xiong, Youyun Zhou, Xiuli Sun*, Yue Zhang, Xiaoguang Zhou, Yong Tang* Angew. Chem. Int. Ed. 2012, 51, 8838-8841. 82. 有机化学中新兴领域的积极开拓者——黄耀曾先生。唐勇*， 戴立信* 化 学进展 2012， 24，1623-1631. 83. Highly Efficient and Practical Catalytic Wittig Olefination. Peng Wang, Chunrong Liu, Xiuli Sun, Shuaishuai Chen, Junfang Li, Zuowei Xie, Yong Tang* Chem. Commun. 2012, 48, 290-292. 84. Highly Diastereoselective Construction Cyclopropane-1,1-dicarboxylates and of Cyclic Fused Enol Carbocycles Silyl Ethers: from Scope, Mechanism, and Origin of Diastereoselectivity. Jianping Qu, Yong Liang, Hao Xu, Xiuli Sun, Zhixiang Yu*, Yong Tang* Chem. Eur. J. 2012, 18, 2196-2201. 85. Diastereoselective and Enantioselective Desymmetrization of α-Substituted Cyclohexadienones via Intramolecular Stetter Reaction. Minqiang Jia, Chuan Liu, Shuli You*J. Org. Chem. 2012, 77, 10996-11001. 86. Ring-Closing Metathesis/Isomerization/Pictet-Spengler Cascade via Ruthenium/ Chiral Phosphoric Acid Sequential Catalysis. Quan Cai, Xiaowei Liang, Shouguo Wang, Junwei Zhang, Xiao Zhang, Shuli You* Org. Lett. 2012, 14, 5022-5025. 87. Enantioselective Construction of Pyrroloindolines via Chiral Phosphoric Acid Catalyzed Cascade Michael Addition Cyclization of Tryptamines. Quan Cai, 34 Chuan Liu, Xiaowei Liang, Shuli You* Org. Lett. 2012, 14, 4588-4590. 88. One-Pot Synthesis of Pyrrolo[1,2-a]indoles by Chiral N-Triflyl Phosphoramide Catalyzed Friedel-Crafts Alkylation of 4,7-Dihydroindole with β,γ-Unsaturated α-Keto Esters (invited paper for Special Issue “Asymmetric Catalysis” Guest Editor: Shuli You). Mi Zeng, Wei Zhang*, Shuli You* Chin. J. Chem. 2012, 30, 2615-2623. 89. Catalytic Asymmetric Dearomatization Reactions. Chunxiang Zhuo, Wei Zhang*, Shuli You* Angew. Chem. Int. Ed. 2012, 51, 12662-12686. 90. Copper(I)-Catalyzed Cascade Dearomatization of 2-Substituted Tryptophols with Arylidonium Salts. Chuan Liu, Wei Zhang, Lixin Dai, Shuli You* Org. Lett. 2012, 14, 4525-4527. 91. Palladium(0)-Catalyzed Dearomative Arylation of Indoles: Convenient Access to Spiroindolenine Derivatives. Kejia Wu, Lixin Dai, Shuli You* Org. Lett. 2012, 14, 3772-3775. 92. Cascade Dearomatization of N-Subsituted Tryptophols via Lewis Acid-Catalyzed Michael Reaction. Chuan Liu, Wei Zhang, Lixin Dai, Shuli You* Org. Biomol. Chem. 2012, 10, 7177-7183. 93. Intramolecular Alkene Electrophilic Bromination Initiated ipso-Bromocyclization for the Synthesis of Functionalized Azaspirocyclohexadienones. Qin Yin, Shuli You* Org. Lett. 2012, 14, 3526-3529. 94. Organocatalyzed Enantioselective Formal [4+2] Cycloaddition of 2,3-Disubstituted Indole and Methyl Vinyl Ketone. Quan Cai, Shuli You* Org. Lett. 2012, 14, 3040-3043. 95. Desymmetrization of Cyclohexadienones via D-Camphor-derived Triazolium Salts Catalyzed Intramolecular Stetter Reaction. Minqiang Jia, Shuli You* Chem. Commun. 2012, 48, 6363-6365. 96. Enantioselective Synthesis of Tetrahydroisoquinolines via Iridium-Catalyzed Intramolecular Friedel-Crafts-Type Allylic Alkylation of Phenols. Qinglong Xu, Lixin Dai, Shuli You* Org. Lett. 2012, 14, 2579-2581. 35 97. Iridium-Catalyzed Enantioselective Allylic Alkylation of Methyl 2-(4-nitrophenylsulfonyl)acetate and Subsequent Transformations. Qinglong Xu, Lixin Dai, Shuli You* Adv. Synth. Catal. 2012, 354, 2275-2282. 98. Asymmetric N-Allylation of Indoles via Ir-Catalyzed Allylic Alkylation of Indolines and Oxidation Strategy. Wenbo Liu, Xiao Zhang, Lixin Dai, Shuli You* Angew. Chem. Int. Ed. 2012, 51, 5183-5187. 99. Enantioselective Synthesis of 2,5-Dihydrobenzo[b]azepine Derivatives via Iridium-Catalyzed Asymmetric Allylic Amination with 2-Allylanilines and Ring-Closing-Metathesis Reaction. Keyin Ye, Lixin Dai, Shuli You* Org. Biomol. Chem. 2012, 10, 5932-5939. 100. Enantioselective Synthesis of Fluorene Derivatives by Chiral N-Triflyl Phosphoramide Catalyzed Double Friedel-Crafts Alkylation Reaction. Shouguo Wang, Long Han, Mi Zeng, Fenglai Sun, Wei Zhang, Shuli You* Org. Biomol. Chem. 2012, 10, 3202-3209. 101. Ir-Catalyzed Allylic Alkylation Reaction with N-Aryl Phosphoramidite Ligands: Scope and Mechanistic Studies. Wenbo Liu, Chao Zheng, Chunxiang Zhuo, Lixin Dai, Shuli You* J. Am. Chem. Soc. 2012, 134, 4812-4821. 102. Iridium-Catalyzed Asymmetric Allylic Etherification and Ring-Closing-Metathesis Reaction for Enantioselective Synthesis of Chromene and 2,5-Dihydrobenzo[b]oxepine Derivatives. Hu He, Keyin Ye, Qingfeng Wu, Lixin Dai, Shuli You* Adv. Synth. Catal. 2012, 354, 1084-1094. 103. Transfer Hydrogenation with Hantzsch Esters and Related Organic Hydride Donors. Chao Zheng, Shuli You* Chem. Soc. Rev. 2012, 41, 2498-2518. 104. Enantioselective Syntheses of Spiro Cyclopentane-1,3'-indoles and 2,3,4,9-Tetrahydro-1H-carbazoles via Ir-Catalyzed Allylic Dearomatization and Stereospecific Migration. Qingfeng Wu, Chao Zheng, Shuli You* Angew. Chem. Int. Ed. 2012, 51, 1680-1683. 105. Asymmetric Substitution Dearomatization Reaction: of Pyrroles Enantioselective via Synthesis Ir-Catalyzed of Allylic Spiro-2H-pyrroles. Chunxiang Zhuo, Wenbo Liu, Qingfeng Wu, Shuli You* Chem. Sci. 2012, 3, 205-208. 36 以下论文重点实验室为作者第二单位： 1. Synthesis and Catalytic Activity of Heterogeneous Rare-earth Metal Catalysts Coordinated with Multitopic Schiff-base Ligands. Yilin Sun, Guangming Wu, Dinghai Cen, Yaofeng Chen*, Limin Wang* Dalton Trans. 2012, 41, 9682-9688. 2. Spiroketal-Based Phosphorus Ligands for Highly Regioselective Hydroformylation of Terminal and Internal Olefins. Xiaofei Jia, Zheng Wang, Chungu Xia*, Kuiling Ding* Chem. Eur. J. 2012, 18, 15288-15295. 3. Pd-Catalyzed Diastereo- and Enantio-selective [3+2] Cycloaddition Reaction of Vinyl Epoxide with Nitroalkenes. Wenqiong Wu, Changhua Ding, Xuelong Hou* Synlett. 2012, 1035-1038. 4. Tempering the Reactivities of Postulated α‑Oxo Gold Carbenes Using Bidentate Ligands: Implication of Tricoordinated Gold Intermediates and the Development of an Expedient Bimolecular Assembly of 2,4-Disubstituted Oxazoles. Yingdong Luo, Kegong Ji, Yuxue Li, Liming Zhang* J. Am. Chem. Soc. 2012, 134, 17412-17415. 5. Highly Selective Activation of Vinyl C–S Bonds Over Aryl C–S Bonds in the Pd-Catalyzed Coupling of (E)-(β-Trifluoromethyl)vinyldiphenylsulfonium Salts: Preparation of Trifluoromethylated Alkenes and Dienes. Hao Lin, Xicheng Dong, Yuxue Li*, Qilong Shen,* Long Lu* Eur. J. Org. Chem. 2012, 4675-4679. 6. Benzofurans or Isochromenes via the Ring-Opening Cyclization of Cyclopropene Derivatives with Organolithiums. Yu Liu, Shengming Ma* Org. Lett. 2012, 14, 720-723. 7. Copper (I) Iodide-Catalyzed One-Step Preparation of Functionalized Allenes from Terminal Alkynes: Amine Effect. Jinqiang Kuang, Hongwen Luo, Shengming Ma* Adv. Synth. Catal. 2012, 354, 933-944. 8. Aerobic Oxidation of Propargylic Alcohols to α,β-Unsaturated Alkynals or Alkynones Catalyzed by Fe(NO3)3∶9H2O, TEMPO and Sodium Chloride in Toluene. Jinxian Liu, Xi Xie, Shengming Ma* Synthesis 2012, 44, 1569-1576. 9. CuCl-Catalyzed Aerobic Oxidation of Allylic and Propargylic Alcohols to Aldehydes or Ketones with 1∶1 Combination of Phenanthroline and Bipyridine as the Ligands. Yu Liu, Shengming Ma* Chin. J. Chem. 2012, 30, 29-34. 10. CuCl–K2CO3-Catalyzed Highly Selective 37 Borylcupration of Internal Alkynes–Ligand Effect. Weiming Yuan, Shengming Ma* Org. Biomol. Chem. 2012, 10, 7266-7268. 11. Efficient Synthesis of 4-Halo-2,5-dihydro-1,2-oxaphosphole 2-Oxides from 1,2-Allenylphosphonates and CuX2 and Subsequent Suzuki Cross-Coupling of the C–Cl Bonds. Ning Xin, Shengming Ma* Eur. J. Org. Chem. 2012, 3806-3817. 12. Ligand Controlled Highly Selective Copper-Catalyzed Borylcuprations of Allenes with Bis(pinacolato)diboron. Weiming Yuan, Shengming Ma* Adv. Synth. Catal. 2012, 354, 1867-1872. 13. Lewis Acid-catalyzed Unexpected Selective C–C Bond Cleavage: An Efficient and Mild Construction of Cyclopentenes. Qiong Yu, Shengming Ma* Chem. Commun. 2012, 48, 11784-11786. 14. Synthesis, Structure, and Ethylene Polymerization Behavior of Nickel Complexes Based on Benzoylmethylenetri(2-alkoxylphenyl)phosphorane. Dawei Wan, Yanshan Gao, Junfang Li, Qi Shen, Xiuli Sun*, Yong Tang Dalton Transactions 2012, 41, 4552-4557. 15. Tris(oxazoline)/copper-catalyzed Coupling of Alkynes with Nitrones: A Highly Enantioselective Access to Beta-lactams. Jianghua Chen, Saihu Liao, Xiuli Sun, Qi Shen*, Yong Tang* Tetrahedron 2012, 68, 5042-5045. 16. Synthesis, Characterization, and Highly Selective Ethylene Dimerization to 1-Butene of [O-NX]Ni(II) Complexes, Chongjie Xu, Qi Shen, Xiuli Sun*, Yong Tang, Chin. J. Chem. 2012, 30, 1105-1113. 17. Chiral Counteranion-Directed Silver-Catalyzed Asymmetric Synthesis of 1,2-Dihydroisoquinolines by Friedel-Crafts Alkylation Reactions. Junwei Zhang, Zhe Xu, Qing Gu, Xiaoxin Shi, Xuebing Leng, Shuli You* Tetrahedron 2012, 68, 5263-5268. 38 二、 客座人员论文目录（按通讯作者姓氏首字母排序） 1. Scope and Regioselectivity of the 1,3-Dipolar Cycloaddition of Azides with Methyl 2-Perfluoroalkynoates for An Easy, Metal-free Route to Perfluoroalkylated 1,2,3-Triazoles. Jiamei Wei, Jie Chen, Jiechao Xu, Long Cao, Hongmei Deng, Weihua Sheng, Hui Zhang*, Weiguo Cao* J. Fluorine Chem. 2012, 133, 146-154. 2. An Efficient and Highly Stereoselective Synthesis of Novel Trifluoromethylated trans-Dihydrofuro[2,3-c]pyrazoles Using Arsonium Ylides. Jiaping Zhang, Shuxin Yang, Kai Zhang, Jie Chen, Hongmei Deng, Min Shao, Hui Zhang*, Weiguo Cao* Tetrahedron 2012, 68, 2121-2127. 3. Preparation of (E)-4-Aryl-1,1,1-trifluoro-3-tosylbut-3-en-2-ones as Fluorinated Building Blocks and Their Application in Ready and Highly Stereoselective Routes to trans-2,3-Dihydrofurans Substituted with Trifluoromethyl and Sulfonyl Groups. Haigang Yu, Jing Han, Jie Chen, Hongmei Deng, Min Shao, Hui Zhang*, Weiguo Cao* Eur. J. Org. Chem. 2012, 16, 3142-3150. 4. Redox-Modulated Stepwise Photochromism in a Ruthenium Complex with Dual Dithienylethene-Acetylides. Bin Li, Jinyun Wang, Huimin Wen, Linxi Shi, Zhongning Chen* J. Am. Chem. Soc. 2012, 134, 16059-16067. 5. Gold(I)-Coordination Triggered Multistep and Multiple Photochromic Reactions in Multi-Dithienylethene (DTE) Systems. Bin Li, Yuhui Wu, Huimin Wen, Linxi Shi, Zhongning Chen* Inorg. Chem. 2012, 51, 1933-1942. 6. Vapochromic and Mechanochromic Phosphorescence Materials Based on a Platinum(II) Complex with 4-Trifluoromethylphenylacetylide. Xu Zhang, Jinyun Wang, Jun Ni, Liyi Zhang, Zhongning Chen* Inorg. Chem. 2012, 51, 5569-5579. 7. Head-to-Tail and Back-to-Back Dimerization of an Open-Cage Fullerene Derivative through π-π Interaction-Based Self-Assembly. Shuming Liu, Qianyan Zhang, Yuming Yu, Liangbing Gan* Org. Lett. 2012, 14, 4002-4005. 8. Fullerene Doping: Preparation of Azafullerene C59NH and Oxafulleroids C59O3 and C60O4. Nana Xin, Huan Huang, Jianxin Zhang, Zhifei Dai, Liangbing Gan* 39 Angew. Chem. Int. Ed. 2012, 51, 6163-6166. 9. Facile Preparation of Fullerenyl Boronic Esters. Zhifei Da, Zhongping Jiang, Gang Zhang, Nana Xin, Liangbing Gan* Tetrahedron, 2012, 68, 5193-5196. 10. Selective Synthesis of Fullerenol Derivatives with Terminal Alkyne and Crown Ether Addends. Huan Huang, Gang Zhang, Sisi Liang, Nana Xin, Liangbing Gan* J. Org. Chem., 2012, 77, 2456-2462. 11. Synthesis of RuCl3/AgOTf Decahydropyrrolo[2,1,5-cd]indolizine induced Alkene–alkene and Derivatives through Alkene–arene Double Cycloisomerizations. Peipei Cui, Liang Xu, Hao Cheng, Liangbing Gan* Tetrahedron, 2012, 68, 152-158. 12. Copper-catalyzed C-H Azidation of Anilines under Mild Conditions. Conghui Tang, Ning Jiao* J. Am. Chem. Soc. 2012, 134, 18924-18927. (Highlighted by Synform) 13. Cu-mediated Aerobic Oxidative Dehydrogenative Annulation and Oxygenation of Aldehydes and Amines for Oxazoles via C-H Functionalization and Dioxygen Activation. Xejun Xu,† Chun Zhang,† (†These two authors contributed equally to this work), Ning Jiao* Angew. Chem. Int. Ed. 2012, 51, 11367–11370 (Hot Paper). 14. Iron-Facilitated Oxidative Dehydrogenative C-O Bond Formation via Propargyl Csp3–H Functionalization. Teng Wang, Wang Zhou, Hang Yin, Jun-An Ma, Ning Jiao* Angew. Chem. Int. Ed. 2012, 51, 10823-10826. 15. Metal-Free, NHPI Catalyzed Oxidative Cleavage of C-C Double Bond Using Molecular Oxygen as Oxidant. Riyuan Lin, Feng Chen, Ning Jiao* Org. Lett. 2012, 14, 4158-4161. 16. Chemoselective Synthesis of Naphthylamides & Isoquinolinones via Rh-catalyzed Oxidative Dehydrogenative Annulation of Benzamides with Alkynes. Zhuangzhi Shi,† Conghui Tang,† (†These two authors contributed equally to this work), Ning Jiao* Adv. Synth. Cat. 2012, 354, 2695-2700. 17. FeCl2-promoted Unactivated C-C Bond Cleavage of Alkylarenes and Polystyrene: Direct Synthesis of Versatile Arylamines. Chong Qin, Tao Shen, Conghui Tang, 40 Ning Jiao*Angew. Chem. Int. Ed. 2012, 51, 6971-6975 (Hot Paper). 18. N,N-Dimethylformamide: A Multipurpose Building Block. Shengtao Ding, Ning Jiao* Angew. Chem. Int. Ed. 2012, 51, 9226-9237(review, invited contribution). 19. 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Zwitterionic Half-sandwich Rh and Ir Complexes Containing a Diphosphine Nido-carborane Ligand: Synthesis, Structure Transformation and Application in H2 Activation. Zijian Yao, Xiankuan Huo, Guoxin Jin* Chem. Commun. 2012, 48, 6714–6716. 24. Efficient Route to Organometallic Cage Formation via C-H Activation-Directed Muticomponent Assembly Accompanying Aromatic Guest Encapsulation. Yingfeng Han, Yuejian Lin, T. S. Andy Hor, Guoxin Jin* Organometallics 2012, 31, 995-1000. 25. Synthesis, Reactivity, and Structural Transformation of Mono- and Binuclear Carboranylamidinate-Based 3d Metal Complexes and Metallacarborane Derivatives. Zijian Yao, Guoxin Jin* Organometallics 2012, 31, 1767-1774. 26. Self-Assembled Hexanuclear Organometallic Cages: Synthesis, Characterization, and Host-Guest Properties. Yingfeng Han, Hao Li, Zhifang Zheng, Guoxin Jin* Chem. Asian J. 2012, 7, 1243- 1250. 41 27. 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A Versatile Ruthenium(II) NNC Complex Catalyst for Transfer Hydrogenation of Ketones and Oppenauer-Type Oxidation of Alcohols. Wangming Du, Liandi Wang, Ping Wu, Zhengkun Yu* Chem. Eur. J. 2012, 18, 11550-11554. 122. A Highly Active Ruthenium(II) Pyrazolyl-Pyridyl-Pyrazole Complex Catalyst for Transfer Hydrogenation of Ketones. Weiwei Jin, Liandi Wang, Zhengkun Yu* Organometallics 2012, 31, 5664-5667. 123. Brnsted Acid Activation Strategy in Transition Metal-Catalyzed Asymmetric Hydrogenation of Unprotected N-H Imines, Enamines and N-Heteroaromatics. Zhengkun Yu*, Weiwei Jin, Quanbin Jiang Angew. Chem. Int. Ed. 2012, 51, 6060-6072. 124. FeCl3.6H2O-Catalyzed Alkenylation of Indoles with Aldehydes. Qin Yang, Liandi Wang, Tenglong Guo, Zhengkun Yu* J. Org. Chem. 2012, 77, 8355-8361. 125. Cationic Rhodium(I)-Catalyzed Regioselective Tandem Hetero-cyclization/[3+2] Cycloaddition of 2-(1-Alkynyl)-2-alken-1-ones with Alkynes. Hongyin Gao, Junliang Zhang* Chem. Eur. J. 2012, 18, 2777-2782. 126. A Base-Promoted Tandem Cycloaddition/Air Oxidation Reaction of Electron-Deficient Conjugated Enynes and Hydrazines: Synthesis of Highly Substituted Pyrazoles. Xiuzhao Yu, Junliang Zhang* Chem. Eur. J. 2012, 18, 12945-12949. 127. Ni(ClO4)2-Catalysed Regio53 and Diastereoselctive [3+2] Cycloadditon of Indoles and Aryl Oxiranyl-Dicarboxylates/Diketones: A Facile Access to Furo[3,4-b]indoles. Jieming Zhang, Zuliang Chen, Hai-Hong Wu, Junliang Zhang* Chem. Commun. 2012, 48, 1817-1819. 128. Efficient Synthesis of Isochromanones and Isoquinolines via Yb(OTf)3-Catalyzed Tandem Oxirane/Aziridine Ring Opening/ Friedel-Crafts Cyclization. Lai Wei, Junliang Zhang* Chem. Commun. 2012, 48, 2636-2638. 129. Gold(I)-catalyzed Cyclization of 2-(1-alkynyl)-alk-2-en-1-one Oximes: A Facile Access to Highly Substituted N-alkoxypyrroles. Mei Zhang, Junliang Zhang* Chem. Commun. 2012, 48, 6399-6401. 130. Kinetic Resolution of 1-(1-alkynyl)cyclopropyl ketones by Gold(I)-catalyzed Asymmetric [4+3]cycloaddition with Nitrones: Scope, Mechanism and Applications. Yanqing Zhang, Junliang Zhang* Chem. Commun. 2012, 48, 4710-4712. 131. DBU-catalyzed Tandem Additions of Electron-deficient 1,3-conjugated Enynes with 2-aminomalonates: A Facile Access to Highly Substituted 2-pyrrolines. Xiuzhao Yu, Guanghua Zhou, Junliang Zhang* Chem. Commun. 2012, 48, 4002-4004. 132. Catalytic Oxidation/C–H Functionalization of N-arylpropiolamides by Means of Gold Carbenoids: Concise Route to 3-acyloxindoles. Deyun Qiana, Junliang Zhang* Chem. Commun., 2012, 48, 7082-7084. 133. Palladium(II)-Catalyzed Stereospecific Three-Component Domino Reactions of Diyne-enones, Nucleophiles, and Vinyl Ketones. Renrong Liu, Junliang Zhang* Chem. Asian. J. 2012. 7, 294-297. 134. Highly Substituted Pyrroles by Gold(I)-Catalyzed Tandem Reaction of 1-(1-Alkynyl)cyclopropyl Oxime Ethers with Nucleophiles. Yanqing Zhang, Junliang Zhang* Synlett, 2012, 23, 1389-1393. 135. Y(OTf)3-Catalyzed N-Tosylaziridines and Diastereoselective Imines; Efficient [3+2]Cycloaddition Synthesis of of Multisubstituted Imidazolidines. Xingxing Wu, Junliang Zhang* Synthesis 2012, 44, 2147-2154. 136. Gold(I)-Catalyzed Regio- and Stereoselective 1,3-Dipolar Cycloaddition 54 Reactions of 1-(1-Alkynyl)cyclopropyl Oximes with Nitrones: A Modular Entry to Highly Substituted Pyrrolo[3,4-d][1,2]oxazepines. Yanqing Zhang, Junliang Zhang* Adv. Synth. Catal. 2012, 354, 2556-2560. 137. Direct aza-Darzens Aziridination of N-Tosyl Imines with 2-Bromomalonates for Efficient Synthesis of Highly Functionalized Donor-acceptor Aziridines. Xingxing Wu, Lei Li, Junliang Zhang* Adv. Synth. Catal. 354, 3485-3489. 138. Ru-catalyzed Hydrogenation of 3,5-diketo Amides: Simultaneous Control of Chemo- and Enantioselectivity. Wanfang Li, Weizheng Fan, Xin Ma, Xiaoming Tao, Xiaoming Li, Xiaomin Xie, Zhaoguo Zhang* Chem. Commun. 2012, 48, 8976. 139. Ru-Catalyzed Asymmetric Hydrogenation of 3-Oxoglutaric Acids Derivatives: A Study on the Unconventional Solvent and Substituent Effects. Wanfang Li, Xiaoming Tao, Xin Ma, Weizheng Fan, Xiaoming Li, Mengmeng Zhao, Xiaomin Xie, Zhaoguo Zhang* Chem. Eur. J. 2012, 18, 16531-16539. 140. 多官能团羰基化合物的高选择性不对称氢化。马欣，李万方，范为正， 陶晓明，李晓明，姚莹，诸吕锋，陈厚和，谢小敏，张兆国* 有机化学， 2012, 32, 1353-1358. 141. Enantioselective Hydrogenation of β‑Ketophosphonates with Chiral Ru(II) Catalysts. Xiaoming Tao, Wanfang Li, Xin Ma, Xiaoming Li, Weizheng Fan, Lvfeng Zhu, Xiaomin Xie, Zhaoguo Zhang* J. Org. Chem. 2012, 77, 8401-8409. 142. Regioselective Synthesis of Substituted Naphthalenes and Phenanthrenes by Iron-promoted Annulation of Aryl and Naphthyl Acetaldehydes with Alkynes. Xiuli Bu, Longcheng Hong, Ruiting Liu, Jianquan Hong, Zhengxing Zhang, Xigeng Zhou* Tetrahedron, 2012, 68, 7960-7965. 143. MeSi Bond Cleavage of Anionic Bis(trimethylsilyl)amide in ScorpionateAnchored Rare Earth Metal Complexes. Weiyin Yi, Jie Zhang*, Zhenxia Chen, Xigeng Zhou* Inorg. Chem. 2012, 51, 10631-10638. 144. Reactivity of Scorpionate-Anchored Yttrium Alkyl Complex toward Organic Nitriles. Weiyin Yi, Jie Zhang*, Zhenxia Chen, Xigeng Zhou* Organometallics 2012, 31, 7213-7221. 55 145. Facile Synthesis of Sulfenyl-substituted Isocoumarins, Heterocycle-fused Pyrones and Regioselective 3-(inden-1-ylidene)iso-benzofuranones Annulation of by FeCl3-promoted o-(1-alkynyl)benzoates and o-(1-alkynyl)heterocyclic Carboxylates with Disulfides. Zhen Li, Jianquan Hong, Linhong Weng, Xigeng Zhou* Tetrahedron, 2012, 68, 1552-1559. 146. Dihydrophenanthridine: A New and Easily Regenerable NAD(P)H Model for Biomimetic Asymmetric Hydrogenation. Qingan Chen, Kai Gao, Ying Duan, Zhishi Ye, Lei Shi, Yan Yang, Yonggui Zhou* J. Am. Chem. Soc. 2012, 134, 2442-2448. 147. Iridium-Catalyzed Asymmetric Hydrogenation of 3-Substituted -2H-1,4-Benzoxazines. Kai Gao, Changbin Yu, Duosheng Wang, Yonggui Zhou* Adv. Synth. Catal. 2012, 354, 483-488. 148. Enantioselective Pd-Catalyzed Hydrogenation of Tetrasubstituted Olefins of Cyclic β-(Aryl-sulfonamido)acrylates. Changbin Yu, Kai Gao, Qingan Chen, Muwang Chen, Yonggui Zhou* Tetrahedron Lett. 2012, 53, 2560-2563. 149. A Highly Efficient Gold-Catalyzed Oxidative C-C Coupling from C-H Bonds Using Air as Oxidant. Jin Xie, Huamin Li, Jiecong Zhou, Yixiang Cheng, Chengjian Zhu* Angew. Chem. Int. Ed. 2012, 51, 1252-1255. 150. Metal-free, Organocatalytic Cascade Formation of C–N and C–O Bonds through Dual sp3 C–H Activation: Oxidative Synthesis of Oxazole Derivatives. Jin Xie, Honglai Jiang, Yixiang Cheng, Chengjian Zhu* Chem. Commun. 2012, 48, 979-981. 151. A Scalable, Efficient Gold-catalyzed Oxidative Phosphonation of sp3 C-H Bonds Using Air as Sustainable Oxidant. Jin Xie, Huamin Li, Qicai Xue, Yixiang Cheng, Chengjian Zhu* Adv. Synth. Catal. 2012, 354, 1646-1650. 152. Coumarin-based Chiral Fluorescence Sensor Incorporating a Thiourea Unit for Highly Enantioselective Recognition of N-Boc-protected Proline. Zhitao Xing, Yong Fu, Jiecong Zhou, Chengjian Zhu*, Yixiang Cheng Org. Biomol. Chem. 2012, 10, 4024-4028. 153. A Highly Selective Ratiometric Fluorescent Chemosensor for Zn2+ ion Based 56 on a Polyimine Macrocycle. Kang Shen, Xia Yang, Yixiang Cheng, Chengjian Zhu* Tetrahedron, 2012, 68, 5719-5723. 154. Metal-free n-Bu4NI-catalyzed direct Synthesis of Amides from Alcohols and N,N-disubstituted Formamides. Huamin Li, Jin Xie, Qicai Xue, Yixiang Cheng, Chengjian Zhu* Tetrahedron Lett. 2012, 53, 6479-6482. 155. Metal-free, One-pot Highly Selective Synthesis of (E)-vinyl Sulfones and Sulfoxides via Addition–oxidation of Thiols with Alkynes. Qicai Xue, Zhijie Mao, Yan Shi, Haibin Mao, Yixiang Cheng, Chengjian Zhu* Tetrahedron Lett. 2012, 53, 1851-1854. 156. A Novel Calixsalen Macrocycle: Metal Sensing Behavior for Zn2+ and Intracellular Imaging Application. Yong Fu, Zhitao Xing, Chengcheng Zhu, Hongwei Yang, Weijiang He, Chengjian Zhu*, Yixiang Cheng Tetrahedron Lett. 2012, 53, 804-807. 157. Efficient Synthesis of β-Enaminones and β-Enaminoesters Catalyzed by Gold (I)/Silver (I) under Solvent-Free Conditions. Ming Zhang, Ablimit Abdukader, Yong Fu, Chengjian Zhu* Molecules, 2012, 17, 2812-2822. 158. Oxidation and Amination of Benzylic sp3 C–H Bond Catalyzed by Rhenium(V) Complexes. Hao Peng, Aijun Lin, Yan Zhang, Honglai Jiang, Jiecong Zhou, Yixiang Cheng, Chengjian Zhu*, Hongwen Hu ACS Catal. 2012, 2, 163-167. 159. The Au(III)-catalyzed Coupling Reactions between Alcohols and N-heterocycles via C–H Bond Activation. Honglai Jiang, Jin Xie, Aijun Lin, Yixiang Cheng, Chengjian Zhu* RSC Adv. 2012, 2, 10496-10498. 160. Crystal structures of chiral mono- and dinuclear salan–Cu(II) complexes and the application to catalytic asymmetric Henry reaction. Yan Shi, Zhijie Mao, Qicai Xue, Chengjian Zhu*, Hongwen Hu, Yixiang Cheng Inorg. Chem. Commun. 2012, 20, 259-262. 57 固定人员代表性论文复印件目录（按通讯作者姓氏首字母排序） 1. Rh(I)-Catalyzed Enantioselective Hydrogenation of α‑Substituted Ethenylphosphonic Acids. Kaiwu Dong, Zheng Wang, Kuiling Ding* J. Am. Chem. Soc. 2012, 134, 12474-12477. 2. Catalytic Asymmetric Synthesis SpinPhox/Iridium(I)-Catalyzed of Aromatic Hydrogenation and Spiroketals by Spiroketalization of a,a’-Bis(2-hydroxyarylidene) Ketones. Xiaoming Wang, Zhaobin Han, Zheng Wang*, Kuiling Ding* Angew. Chem. Int. Ed. 2012, 51, 936-940. 3. Aromatic Spiroketal Bisphosphine Ligands: Palladium-Catalyzed Asymmetric Allylic Amination of Racemic Morita–Baylis–Hillman Adducts. XiaomingWang, Fanye Meng, YanWang, Zhaobin Han, Yong-Jun Chen, Li Liu*, ZhengWang*, Kuiling Ding* Angew. Chem. Int. Ed. 2012, 51, 9276-9282. 4. Catalytic Hydrogenation of Cyclic Carbonates: A Practical Approach from CO2 and Epoxides to Methanol and Diols. Zhaobin Han, Liangce Rong, Jiang Wu, Zheng Wang, Kuiling Ding* Angew Chem. Int. Ed. 2012, 51, 13041-13045.(VIP) 5. Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature. Xin Mu, Tao Wu, Haoyang Wang, Yinlong Guo, Guosheng Liu* J. Am. Chem. Soc. 2012, 134 (2), 878-881. 6. Gold-Catalyzed Cyclization of 1,6-Diyne-4-en-3-ols: Stannyl Transfer from 2-Tributylstannylfuran Through Au/Sn Transmetalation. Yifeng Chen, Ming Chen, Yuanhong Liu* Angew. Chem. Int. Ed. 2012, 51, 6181-6186. 7. Gold-Catalyzed Cascade Cyclizations of 1,6-Diynyl Carbonates to Benzo[b]fluorenes Involving Arylation of Oxocarbenium Ion Intermediates and Decarboxylative Etherification. Yifeng Chen, Ming Chen, Yuanhong Liu* Angew. Chem. Int. Ed. 2012, 51, 6493-6497. 8. Allenes in Catalytic Asymmetric Synthesis and Natural Product Syntheses. Shichao Yu, Shengming Ma*Angew. Chem. Int. Ed. 2012, 51, 3074-3112. 9. One-Pot Approach to Installing Eight-Membered Rings onto Indoles. Can Zhu, Xue Zhang, Xiongdong Lian, Shengming Ma*Angew. Chem. Int. Ed. 2012, 51, 7817- 7820. 10. Strained Small Rings in Gold-Catalyzed Rapid Chemical Transformations. Beili 58 Lu, Lunzhi Dai, Min Shi* Chem. Soc. Rev. 2012, 41, 3318-3339. 11. Rapid Generation of Molecular Complexity in the Lewis or Brønsted Acid-mediated Reactions of Methylenecyclopropanes. Min Shi*, Jianmei Lu, Yin Wei, Lixiong Shao* Acc. Chem. Res. 2012, 45, 641-652. 12. A Chiral Cage-like Copper(I) Catalyst for the Highly Enantioselective Synthesis of 1,1-Cyclopropane Diesters. Chao Deng, Lijia Wang, Jun Zhu, Yong Tang* Angew. Chem. Int. Ed. 2012, 51, 11620-11623. 13. Side-Arm-Promoted Highly Enantioselective Ring-Opening Reactions and Kinetic Resolution of Donor-Acceptor Cyclopropanes with Amines. Youyun Zhou, Lijia Wang, Jun Li, Xiuli Sun*, Yong Tang* J. Am. Chem. Soc. 2012, 134, 9066-9069. 14. Tridentate Ligands and Beyond in Group IV Metal α-olefin Homo-/co-polymerization Catalysis. Carl Redshaw*, Yong Tang* Chem. Soc. Rev. 2012, 41, 4484-4510. 15. Highly Diastereo- and Enantioselective Cyclopropanation of 1,2-Disubstituted Alkenes. Jun Li, Saihu Liao, Hu Xiong, Youyun Zhou, Xiuli Sun*, Yue Zhang, Xiaoguang Zhou, Yong Tang* Angew. Chem. Int. Ed. 2012, 51, 8838-8841. 16. Catalytic Asymmetric Dearomatization Reactions. Chunxiang Zhuo, Wei Zhang*, Shuli You* Angew. Chem. Int. Ed. 2012, 51, 12662-12686. 17. Asymmetric N-Allylation of Indoles via Ir-Catalyzed Allylic Alkylation of Indolines and Oxidation Strategy. Wenbo Liu, Xiao Zhang, Lixin Dai, Shuli You* Angew. Chem. Int. Ed. 2012, 51, 5183-5187. 18. Ir-Catalyzed Allylic Alkylation Reaction with N-Aryl Phosphoramidite Ligands: Scope and Mechanistic Studies. Wenbo Liu, Chao Zheng, Chunxiang Zhuo, Lixin Dai, Shuli You* J. Am. Chem. Soc. 2012, 134, 4812-4821. 19. Transfer Hydrogenation with Hantzsch Esters and Related Organic Hydride Donors. Chao Zheng, Shuli You* Chem. Soc. Rev. 2012, 41, 2498-2518. 20. Enantioselective Syntheses of Spiro Cyclopentane-1,3'-indoles and 2,3,4,9-Tetrahydro-1H-carbazoles via Ir-Catalyzed Allylic Dearomatization and Stereospecific Migration. Qingfeng Wu, Chao Zheng, Shuli You* Angew. Chem. 59 Int. Ed. 2012, 51, 1680-1683. 60