金属有机化学国家重点实验室2002年年度进展报告.doc
金属有机化学国家重点实验室2002年年度进展报告.doc
金属有机化学国家重点实验室 第一届学术委员会名单 学术委员会主任 副主任 委 员 钱长涛研究员 中科院上海有机化学研究所 康北笙教授 中山大学化学化工学院 席振峰教授 北京大学化学系 陆熙炎院士 中科院上海有机化学研究所 戴立信院士 中科院上海有机化学研究所 沈之荃院士 浙江大学化学系 游效曾院士 南京大学配位化学国家重点实验室 支志明院士 香港大学化学系 黄宪教授 浙江大学化学系 宋礼成教授 南开大学化学系 侯雪龙研究员 中科院上海有机化学研究所 麻生明研究员 中科院上海有机化学研究所 秦金贵教授 武汉大学化学系 沈琪教授 苏州大学 金国新教授 复旦大学化学系 外籍委员 Prof. Sharpless 美国 scripps 研究所 Prof. Bönnemann 德国马普煤炭研究所 Prof. Otsuka 日本大阪大学 1 金属有机化学国家重点实验室 学科带头人现状与需求 现有人员 目前学科方向 陆熙炎院士 戴立信院士 麻生明研究员 侯雪龙研究员 唐 勇研究员 丁奎玲研究员 姜 标研究员 施 敏研究员 邓敏智研究员 张兆国研究员 陈家碧研究员 金属有机，有机合成 不对称催化，有机合成 金属有机，有机合成 不对称催化，有机合成 金属有机，材料化学 金属有机，有机合成 不对称催化，有机合成 金属有机，有机合成 军工，金属有机 金属有机，有机合成 金属络合物化学 发展学科方向 需求计划人数 配位化学 金属络合物的反应化学 金属催化的材料化学 金属络合物的结构化学 1 1 1 1 2 2OO2 年重大记事 一. 完成 2002－2003 年基金申请 共资助了 32 个项目，其中有机所 14 个，外单位 18 个，资助总额 79.8 万。 二．实验室设备更新 完成了两批设备更新计划论证，第一批经费已经批准，准备购置园二色散仪 一台，原位红外仪一台，分析和制备液相色谱仪一台，和有机所共同购置 SGI 图形 工作站和高分辨质谱一台，现这些购置计划正在实施中，将于 2003 年 6 月验收。第 二批设备购置计划经费还没有落实，将努力争取。 三．创新群体 2001 年申请的以我室学术带头人为主的题为“导向有机合成的金属有机化学” 创新研究群体已于 2002 年正式启动，三年共 360 万元。此项目还得到上海市科委的 匹配支持。 四. 实验室承担的科研项目运行正常 今年由吉林大学裘式纶教授和我室麻生明研究员作为首席科学家的 973 项目 “创造新物质的分子工程学研究”完成了中期评估，得到科技部组织的专家组的好评， 并完成了后三年计划和经费预算的上报，现后三年经费资助额度已得到批准，比原 计划略有增加。另外麻生明主持的基金委重点项目“用金属有机化学研究绿色化学 中的基本问题”和基金委优秀实验室重点项目“金属催化的对映选择性合成”两个 项目在年初都通过了基金委的中期评估，专家组一致认为，该两个项目实施两年来， 出色地完成了原订的研究计划，取得了一系列创新性的丰硕研究成果。同时施敏和 丁奎岭主持的中科院知识创新方向性重大项目、唐勇主持的国家“863”计划等由实 验室学术带头人共同承担的项目运行正常，发表了不少高质量的论文。今年实验室 3 发表的论文中 I 区论文有 10 篇。 五．实验室学委会工作 实验室经常与学术委员保持联系，听取他们对实验室发展的建议，请他们为实 验室出谋划策。实验室在今年第 12 届全国金属有机会议在福州召开之际于 10 月 24 －25 日召开了 2002 年度学委会会议，会上荣幸地邀请到了基金委和中科院的领导 参加，请他们为实验室的发展提了不少建设性意见。同时本届学术会上很高兴的邀 请到南京大学化学系游效曾院士作了题为“光电功能配合物的组装”的学术报告， 同时游先生已应邀同意成为我们实验室学术委员会委员中的一员，他的加盟必将推 动我们实验室今后在配位化学方面的发展。 六．庆贺黄耀曾院士九十华诞 今年是我室德高望重的黄耀曾院士九十华诞，我们实验室在第 12 届全国金属有 机化学会议上组织了祝贺黄耀曾先生九十华诞学术报告会， 会议由戴立信院士主持， 钱长涛研究员介绍黄耀曾院士的科学业绩，会上有香港中文大学黄乃正和谢作伟教 授、浙江大学黄宪教授、日本东京工业大学 Jiro Tsuji 教授、南开大学周其林教授 和上海有机所的唐勇研究员作了专题学术报告。另外，台湾大学彭旭明教授、台湾 中研院化学研究所陆天尧教授和上海有机所的麻生明研究员都在他们的大会报告中 祝贺黄耀曾院士九十华诞。 同时有机所还在所内举行了庆贺黄耀曾先生生日的活 动。 七、对外开放 实验室今年继续出资和课题组共同邀请一些国外学者专家到有机所进行顺访 外，并以实验室名义邀请了一些比较著名的科学家到实验室进行专门的访问，在作 学术报告后，还与所内尤其是实验室内的科学家进行面对面的工作访谈，使我们科 研人员在有机所就了解了一些国际学科发展动态。 4 金属有机化学国家重点实验室学术委员会 第一届第二次会议简报 金属有机化学国家重点实验室第一届学术委员会第二次会议于今年 10 月 23－ 26 日在福州武夷山邮电宾馆召开。十四位委员中有九位出席会议，中科院高技术局 化工处白路娜老师和国家基金委化学部杜灿屏老师、陈拥军老师与会指导。会议由 学术委员会主任钱长涛研究员主持。这次会议的议程是 1) 室主任汇报实验室一年 来的工作情况，2) 专家学术报告和交流，3) 部分课题组工作进展情况汇报，4) 国际学术会议介绍，5)今后工作讨论。 一.实验室主任麻生明研究员汇报了实验室室一年来的工作 麻生明主任首先欢迎并感谢各位领导和专家的到会，并感谢大家在过去一年中 对我们实验室工作的大力指导和支持。然后麻生明研究员汇报了实验室一年来的工 作，重点介绍实验室一年来在仪器装备的更新、2002－2003 年实验室基金申请及最 后资助情况、实验室所承担的国家重大项目的检查情况、成果、论文发表和具体工 作进展、人才培养和课题管理等方面的工作。 二．专家学术报告和交流 会上由南京大学游效曾院士和上海有机所戴立信院士、唐勇研究员分别作了题 为“光电功能配合物的组装” 、“不对称分子内 Heck 反应的区域选择性问题”、 “镍系 铁系烯烃聚合催化剂的研究进展、机遇与挑战”三个精彩的学术报告，与会代表对 每一个报告都进行了充分的讨论和交流，大家觉得受益非浅。 三. 课题组工作进展汇报和讨论 这次会上共有五个课题组进行工作汇报， 分别由上海有机所许旭副研究员(手性 合成新产物的色谱分析方法)、上海有机所侯雪龙研究员(手性配体合成及其在不对 称反应中的应用)、北京大学甘良兵教授(金属催化下富勒烯氧化物的合成)、中科院 福建物构所陈忠宁研究员(金属炔基簇化学及其光电性能研究)、淮北煤炭师范学院 王磊教授(绿色有机合成反应方法学)到会汇报工作。委员们认真听取了他们的进展 情况和今后工作设想，并就研究工作中的问题提出了中肯的意见和建议，进行了广 5 泛的学术交流。 四．国际学术会议介绍和讨论 本次会上共介绍了三个国际会议的内容： 1. 上海有机所的钱长涛研究员介绍了 2002 年 7 月在希腊科呼岛召开的第 20 届国际 金属有机化学会议的情况, 重点介绍了 5 个大会报告的内容。 2. 上海有机所的麻生明研究员介绍了今年 7 月中旬在新西兰基督城召开的 14th 有机 合成国际会议的基本情况， 重点介绍了大会报告中我们实验室比较感兴趣的问题。 3. 上海有机所的戴立信院士介绍了今年 4 月底在香港召开的亚洲手性会议的情况。 本次会议参加人数大约为 100 人，其中工业界代表较多，工作很出色，戴先生 本人在这次香港会议上代表上海有机所作了大会报告，介绍上海有机所在这方 面的最新工作。 通过这些介绍和讨论，使到会委员们及时了解国际上金属有机化学研究的热点 和掌握目前文献还来不及报道的热门资料，对拓宽工作思路起到了一定的作用。 五．今后工作讨论 会上委员们对实验室的学术方向、发展方针、研究课题设置和国际学术交流、 实验室的建设和管理等方面进行了讨论，尤其是对实验室今后的发展提出了不少建 设性建议。 总之，本次学委会会议讨论热烈，交流充分，学术气氛浓厚，与会者都认为收获 较大。最后大家一致认为国家重点实验室来之不易，今后一定要坚持“金属有机化学” 的学术方向作为学科发展的目标，保持实验室在反应方法学方面的特色，利用外单位 优势，进行材料化学方面的合作，吸引国内外最优秀的人才到实验室来工作。即坚持 基础研究的特点不变，又要多考虑把研究工作与国家现代化建设和国民经济发展需求 相结合。希望金属有机化学国家重点实验室成为一个国际一流的金属有机化学研究基 地，为国家解决重大科学问题，发展金属有机化学。 6 2002～2003 资助课题一览表 序 号 姓 名 单 位 题 目 2002-01 陆熙炎 上海有机所 具有高合成效率的新有机合成反应的研究 2002-02 钱长涛 上海有机所 新型后期过渡金属催化剂的设计与合成及其 催化烯烃聚合反应研究 2002-03 麻生明 上海有机所 金属参与的碳-碳键形成反应研究 2002-04 侯雪龙 上海有机所 平面手性环芳烷配体的设计、合成及其应用 2002-05 沈延昌 上海有机所 金属有机参与的高选择性合成方法学研究 2002-06 陈家碧 上海有机所 多金属桥卡宾和桥卡拜络合物及其在催化 反应中的应用研究 2002-07 邓敏智 上海有机所 新型 Suziki 偶联反应及一些生物活性产物 的全合成 2002-08 姜 标 上海有机所 不对称 Pauson-Khand 反应研究及在复杂 生物碱合成中的应用 2002-09 施 敏 上海有机所 Baylis-Hillman 反应的研究 2002-10 丁奎岭 上海有机所 新型 C2 对称性手性配体的设计、合成及其 金属络合物在催化不对称反应中的应用研究 2002-11 唐 勇 上海有机所 新型硫、碲叶立德的合成、设计及其在有机 合成中的应用 2002-12 张兆国 上海有机所 碳－氧键的反应化学研究 2002-13 赵 刚 上海有机所 芳基锌试剂参与的不对称碳碳键形成反应研究 2002-14 许 旭 上海有机所 手性合成新产物的色谱分析方法研究 2002-15 宋礼成 南开大学 巴基球碳簇过渡金属有机化合物的合成及非 线性光学性质研究 2002-16 黄 宪 浙江大学 过渡金属参与下聚合物负载有机硒化合物的 固相反应 7 2002-17 沈 琪 苏州大学 非茂基稀土配合物的合成及其反应性能的研究 2002-18 康北笙 中山大学 间隔基团调控的多齿杂氮配位化合物及螺旋 结构规律 2002-19 张永敏 浙江大学 稀土金属、过渡金属介入的选择性有机合成反应 2002-20 席振峰 北京大学 双金属有机合成试剂的发现与发展 2002-21 曹卫国 上海大学 利用胂叶立德立体选择性合成多官能基有机 环化合物 2002-22 周锡庚 复旦大学 稀土烃硫基化合物的氧化反应研究 2002-23 庞 复旦大学 手性半活性配体对金属有机化合物反应性的 震 影响及其应用 2002-24 王佰全 南开大学 桥连茂金属化合物的合成结构及催化烯烃 聚合研究 2002-25 王绍武 安徽师范大学 新型立体位阻诱导单电子还原反应研究 2002-26 秦金贵 武汉大学 聚二茂铁基硅烷的设计、合成与固体磁性 2002-27 殷元骐 兰化所 非环戊二烯基配位的铑手性簇合物的合成 2002-28 甘良兵 北京大学 金属促进的多加成富勒烯环氧化物 C60(0)n 的合成 2002-29 范青华 化学所 基于树状大分子手性催化剂的氟两相催化 反应研究 2002-30 朱成建 南京大学 手性镓、铟金属有机化合物的合成及其导向的 有机反应研究 2002-32 陈忠宁 福建物构所 金属有机分子导线、分子簇和分子笼 不对称合成中的应用 2002-34 王 磊 淮北煤炭 微波促进纳米钯粉催化无溶剂有机合成反应 师范学院 的研究 8 2002 年全室专利申请、授权一览表 2002 年申请专利 编 号 1 专利名称 乙烯齐聚催化剂、合成方法和用途 3 含给电子基团有机配体的二价稀土配合 物、合成方法与应用 一种平面手性[2.2]对环芳烷恶唑啉膦配 体、合成方法及用途 4 外消旋的联二酚的光学拆分方法 2 申请 日 专利号 020520 PCT/CN02/00337 020823 02136621.7 020830 02136741.8 020524 02111829.9 13 14 一种顺式卤代菊酸的生产方法 020719 02136131.2 一种合成氮杂环化合物的方法 020925 02137124.5 一种二氢呋喃杂环化合物及其合成方法 020925 02137123.7 2,5-cis-二取代的吡咯烷衍生物、合成方 法及其用途 020719 02136129.0 光学活性 2，3－联烯醇和联烯醇脂、合 成方法及其用途 020625 02112225.3 光学活性 2,3－联烯醇和联烯醇酯、合成 方法及其用途 0212 过渡金属络合物和有机碱协同催化 CO2 与杂环化合物反应的新方法 020125 02110653.3 合成环状碳酸酯或恶唑酮类化合物的新 方法 020125 02110652.5 复合型金属络合物催化芳香族化合物的 绿色硝化方法 020315 02111062.x 苯酚类化合物的绿色硝化方法 021114 02145268.7 15 烯烃聚合及共聚合催化剂、合成方法及 其用途 5 6 7 8 9 10 11 12 020617 PCT/CN02/00425 020209 02110844.7 17 新型烯烃聚合催化剂 具有手性的多齿恶唑啉配体及其与主族 金属或第三族到第十三族过渡金属的配 合物、合成方法及其用途 020712 02112354.3 18 19 烯烃聚合催化剂、合成方法及其用途 高选择性地制备手性仲醇的新方法 021213 020329 02151294.9 02111215.0 16 9 发明人 钱长涛、陈耀 峰 钱长涛、陈耀 峰、邹刚、李 楠、李杨、邹 丰楼 巫循伟、侯雪 龙、戴立信 丁奎岭、杜海 峰 姜标、张小兵、 魏慧玲、高红兰 陆琤、陆熙炎 陆琤、陆熙炎 麻生明、焦宁 麻生明、徐代 旺、李祖义 麻生明等 沈玉梅、段伟 良、施敏 沈玉梅、段伟 良、施敏 施敏、崔世聪 施敏、崔世聪 孙秀丽、胡蔚 秋、王聪、唐 勇、张玉良、 夏春安 唐勇、胡蔚秋、 孙秀丽、王聪、 张玉良 唐勇、周剑 张玉良、唐勇 等 赵刚、胡建兵 2002 年授权专利 编 号 1 2 3 4 5 专利名称 专利号 一种具有多种手性中心的二茂铁恶唑啉配体、合成方 法及用途 （1－三氟甲基）烯基硼酸的制备及其应用 一种通过气相光氯化反应制备氯甲基三甲基硅烷的方 法和装置 三氟乙酰基苯乙酮肟及其衍生物的合成方法 一种合成 B－卤代丁烯酸内酯的方法 10 发明人 00125767.6 游书力、侯雪 龙、戴立信 姜标等 00119457.7 姜标等 99113670.5 99119945.6 姜标等 麻生明等 00127948.3 2002 年金属有机化学国家重点实验室来访人员名单 Dr. Fuquan Song University of East Anglia, UK 2002.03 Prof. J. M. Basset The French Academy of Sciences 2002.03.03-03.05 Prof. Walter Weissensteiner The Institute of Organic Chemistry University of Vienna 2002.05.13-05.19 Dr. Lukas Hintermann Tokyo Institute of Technology, Japan 2002.05.20-05.26 Prof. Lin Pu Virginia University, USA 2002.05.20-05.23 Prof. Chao-Jun Li Tulane University, USA 2002.05 Prof. Xumu Zhang The Penn. State University, USA 2002.07 Prof. Guigen Li Texas Tech. University 2002.07 Prof. Ziling Xue University of Tennessee, USA 2002.08.14-08.15 陈小华博士 上海华远分析仪器有限公司 2002.09.04 Prof. H. Schumann 柏林工业大学 2002.09.26-09.28 Prof. Hans-Guenther Schmalz University of Cologne, Germany 2002.10.09-10.10 Prof. Merritt Andrus Brigham Young University, USA 2002.11.20-11.24 Dr. Tony Y. Zhang Eli Lilly Company 2002.12 Prof. Kotohiro Nomura Nara Institute of Science and Technology 熊照明 Bochringer-Ingelheins 药业公司 11 2002.11 2002.12.25 二 00 二年论文目录 课题负责人：陆熙炎 课题编号： 2002-01 1. Palladium(II)-Catalyzed Highly Regio- and Diastereoselective Cyclization of Difunctional Allylic N-Tosylcarbamates. A Convenient Synthesis of Optically Active 4-Vinyl-2-oxazolidinones and Total Synthesis of 1,4-Dideoxy-1,4-imino-L-xylitol Lei, A.; Liu, G.; Lu, X.* J. Org. Chem. 2002, 67, 974-980. 39 2. Palladium(II)-Catalyzed Coupling Reactions of Intramolecular Carbopalldation of Alkyne with Allylic Compounds Liu, G.; Lu, X.* Tetrahedron Lett. 2002, 43, 6791-6794. 46 3. Palladium(II)-Catalyzed Three-Component Coupling Reaction Initiated by Acetoxypalladation of Alkynes: An Efficient Route to ,-Unsaturated Carbonyls Zhao, L.; Lu, X.* Org. Lett. 2002, 4, 3903-3906. 50 4. PdII-Catalyzed Intramolecular Cyclization of Alkynes with Aldehydes, Ketones or Nitriles Initiated by Acetoxypalladation of Alkynes Zhao, L.; Lu, X.* Angew. Chem. Int. Ed. 2002, 41, 4343-4345. 54 5. Highly Regioselective Construction of Spirocycles via Phosphine-Catalyzed [3+2] Cycloaddition Du, Y.; Lu, X.*; Yu, Y. J. Org. Chem. 2002, 67, 8901-8905. 57 6. Tandem reactions to Construct Heterocycles via Phosphine-Catalyzed Umpolung Addition and Intramolecular Conjugate Addition Lu, C.; Lu, X.* Org. Lett. 2002, 4, 4677-4679. 62 7. An Unexpected Reaction of Allylic Propynoate underPalladium(II) Catalysis1 Zhang, Z.; Lu, X.*; Lang, S. Chin. J. Chem. 2002, 20, 1287-1290. 65 课题负责人：钱长涛 1. 课题编号： 2002-02 Synthesis and crystal structure of one carbon-atom bridged lutetium complex 12 [Ph2C(Flu)(Cp)]LuN(TMS)2 and catalytic activity for polymerization of polar monomers Changatao Qian, Wanli Nie, Yaofeng Chen, Jie Sun J. Organometal. Chem., 2002, 645, 82-86. 69 2. Synthesis, structural characterization and catalytic behavior of one-atom bridged fluorenyl cyclopentadienyl lanthanocene complexes with Cs-or C1-symmetry Wanli Nie, Changtao Qian, Yaofeng Chen, Sun Jie J. Organometal. Chem., 2002, 647, 114-122. 74 3. One-Pot Synthesis of Tetrahydroquinolines Catalyzed by Dy(OTf)3 in Aqueous Solution Ruifang Chen, Changtao Qian Synth. Commun., 2002, 32, 2543-2548. 83 4. La(O-I-Pr)3 Catalyzed Three-Component Condensation Reaction:A Convenient Synthesis of N,N-Dialkyl-a-cyanoamines Peipei Sun, Changtao Qian, Limin Wang and Ruifang Chen Synth. Commun., 2002, 32, 2973-2978. 89 5. One-Pot Syntheses of 3,4-Dihydropyrimidine-2 (1 H)-thiones Catalyzed by La(OTf )3 Ruifang Chen, Changtao Qian Chin. J .Chem., 2002, 20, 427-430. 95 6. Recent Advances in Organic Reaction Catalyzed by Lanthanide(III) Complexes Ruifang Chen, Changtao Qian Chin. J. Chem., 2002, 20, 407-419. 99 7. Synthesis,Structure and Reactivity of Lanthanocene Complexes Changtao Qian, Chengjian Zhu Chin. J. Chem., 2002, 20, 519-535. 课题负责人：麻生明 112 课题编号： 2002-03 1．Efficient Synthesis of 2,3-Dihydrofurans via the Highly Selective Pd(0)-Catalyzed Coupling-Cyclization Reaction of 3,4-Allenols with Aryl Iodides Shengming Ma* and Wenzhong Gao Synlett 2002, 65-68. 129 2． Mechanistic Switch Leading to Highly Efficient Chirality Transfer in Pd(0)-Catalyzed Coupling-Cyclization of Aryl Iodides with 1:1 Acid-Base Salts of 2,3-Allenoic Acids and L-(-)-Cinchonidine or D-(+)-/L-(-)--Methylbenzylamine. Enantioselective Synthesis of Highly Optically Active 3-Aryl Polysubstituted Butenolides Shengming Ma* and Zhangjie Shi 13 Chem. Commun. 2002, 540-541. 133 3. Control of Regioselectivity in Pd(0)-Catalyzed Coupling-Cyclization Reaction of 2-(2’,3’-Allenyl)malonates with Organic Halides Shengming Ma*, Ning Jiao, Shimin Zhao, and Hairong Hou J. Org. Chem. 2002, 67, 2837-2847. 135 4. K2CO3-Catalyzed Michael Addition-Lactonization Reaction of 1,2-Allenyl Ketones with Electron-withdrawing Group Substituted Acetates. An Efficient Synthesis of -Pyrone Derivatives Shengming Ma,* Shaohu Yin, Lintao Li, and Fenggang Tao Org. Lett. 2002, 4, 505-507. 146 5. Tuning of Regioselectivity in the Coupling Reaction Involving Allenic/Propargylic Palladium Species Shengming Ma* and Aibin Zhang J. Org. Chem. 2002, 67, 2287-2294. 149 6. Palladium(0)-Catalyzed Coupling-Cyclization Reaction of Polymer-Supported Aryl Iodides with 1,2-Allenyl Carboxylic Acids. Solid Phase Parallel Synthesis of Butenolides Shengming Ma,* Dehui Duan, and Yizhong Wang J. Combin. Chem. 2002, 4, 239-247. 157 7. Unexpected Dramatic Substituent Effect for Tuning of the Selectivity in the Double Ring-Closing Metathesis Reaction of N-Containing Tetraenes. An Efficient Synthesis of Bicyclic Izidine Alkaloid Skeletons Shengming Ma* and Bukuo Ni Org. Lett. 2002, 4, 639-641. 166 8. Efficient Synthesis of Benzocyclohexanes via Intramolecular Friedel-Crafts Reaction of Halogen Free 6-Acetoxy-4-alkenyl Arenes Shengming Ma* and Junliang Zhang Tetrahedron Lett. 2002, 43, 3435-3438. 169 9. Efficient Synthesis of 4-(2'-Alkenyl)-2,5-dihydrofurans, 5,6-Dihydro-2H-pyrans via the Pd-Catalyzed Cyclizative Coupling Reaction of 2,3- or 3,4-Allenols with Allylic Halides Shengming Ma* and Wenzhong Gao J. Org. Chem. 2002, 67, 6104-6112. 173 10. Novel Oxidative Cyclization/Dimerization Reaction of 2,3-Allenoic Acids and 1,2-Allenyl Ketones. An Efficient Synthesis of 4-(3’-Furanyl)butenolide Derivatives Shengming Ma* and Zhanqian Yu Angew. Chem. Int. Ed. 2002, 41, 1775-1778. 182 14 11. Unexpected Sequential Addition-Elimination Reaction of 1-Aryl-2,3-allenols with LiX. Synthesis and Synthetic Application of 1-Aryl-3-Halo-1,3-dienes Shengming Ma* and Guanwei Wang Tetrahedron Lett. 2002, 43, 5723-5726. 186 12. Steric Hindrance-Controlled Pd(0)-Catalyzed Coupling-Cyclization of 2,3-Allenamides and Organic Iodides. An Efficient Synthesis of Iminolactones and -Hydroxy--lactams Shengming Ma* and Hexin Xie J. Org. Chem. 2002, 67, 6575-6578. 190 13. Efficient Preparation of Highly Optically Active S-(-)-2,3-Allenols and R-(+)-2,3-Allenyl Acetates via a Clean Novozyme-435-Catalyzed Enzymatic Separation of Racemic 2,3-Allenols. Daiwang Xu, Zuyi Li, and Shengming Ma* Chem. Eur. J. 2002, 8, 5012-5018. 194 14. Efficient Synthesis of Optically Active 2,3-Allenols via the Simple CuBr-Mediated Reaction of Optically Active Propargylic Alcohols with Paraformadehyde Shengming Ma*, Hairong Hou, Shimin Zhao, and Guangwei Wang Synthesis 2002, 1643-1645. 201 15. Tuning the Reaction Paths in Palladium(0)-Catalyzed Coupling-Cyclization Reaction of Amino Allenes with Organic Halides. A Substituent Switch Shengming Ma* and Wenzhong Gao Org. Lett. 2002, 4, 2989-2992. 204 16．ntramolecular Triple Heck Reaction. An Efficient Entry to Fused Tetracycles with a Benzene Core Shengming Ma* and Bukuo Ni J. Org. Chem. 2002, 67, 8280-8283. 208 17. Palladium(0)–Catalyzed Three-Component Tandem Double Addition-Cyclization Reaction: A Facile One–Pot Highly Chemo-, Regio- and Stereo-selective Synthesis of Cis-Pyrrrolidine Derivatives from 2-(2’,3’-Dienyl)malonates, Organic Halides, and Imines Shengming Ma* and Ning Jiao Angew. Chem. Int. Ed. 2002, 41, 4737-4740. 212 18. 联烯化学进展 麻生明* 中国科学进展，2001，15，30-31. 216 19. 1,2-联烯亚砜和 1,2-联烯砜的反应 Qi Wei and Shengming Ma* 15 Chin. J. Org. Chem. (有机化学) 2002, 22, 254-261. 218 20. Ru 催 化的 C-H 键的活化反 应 Activation Reactions of Ru-catalyzed Arylic or Olefinic C-H Bonds Shicao Yu and Shengming Ma* Chin. J. Org. Chem. (有机化学) 2002, 22, 307-317. 226 21. 光学活性炔丙醇的合成 Synthesis of Optically Active Propargylic Alcohols Qiwen He and Shengming Ma* Chin. J. Org. Chem. (有机化学) 2002, 22, 375-387. 237 22. Accurate Mass Determination of Amino Alcohol Turboionspray/Time-of-Flight Mass Spectrometry Geng Yu, Yin-Long Guo*, Shimin Zhao, and Shengming Ma* Chin. J. Chem. 2002, 20, 272-276. Derivatives by 250 23. Dramatic Solvent Effect in the Reduction of 2,3-Allenoic Acid Esters. A Simple Synthesis of 2,3-Allenols from 2,3-Allenoates Shaohu Yin, Shengming Ma,* Ning Jiao, and Fenggang Tao Chin. J. Chem. 2002, 20, 707-710 . 255 24. The Synthesis of (+) or (-)-2-(8'-Diphenylphosphinonaphthyl-1')oxazoline Ligands and Their Application in Pd-Catalyzed Allylic Alkylation Reaction Shengming Ma* and Dehui Duan Chin. J. Chem. 2002, 20, 1363-1368. 259 课题负责人：侯雪龙 课题编号： 2002-04 1. A Facile Synthesis of Enantiopure 2-Aziridinesulfinimines and Their Highly Diastereoselective Reactions with Phosphite Anions Bin-Feng Li, Ming-Jie Zhang, Xue-Long Hou* and Li-Xin Dai J. Org. Chem., 2002, 67, 2902-2906. 265 2. Tributylphosphine: A Remarkable Promoting Reagent for Ring Opening Reaction of Aziridines Xue Long Hou*, Ren-Hua Fan, Li-Xin Dai J. Org. Chem., 2002, 67, 5295-5300. 270 3. The Role of Planar Chirality of S, N- and P, N-Ferrocene Ligands in Palladium-Catalyzed Allylic Substitutions Shu-Li You, Xue-Long Hou,*, Li-Xin Dai,*, Yi-Hua Yu and Wei Xia J. Org. Chem., 2002, 67, 4684-4695. 276 4. Stereocontrolled Aziridination of Imines via Sulfonium Ylide Route and the 16 Mechanistic Study Xiao-Fang Yang, Ming-Jie Zhang, Xue-Long Hou* and Li-Xin Dai J. Org. Chem., 2002, 67, 8097-8103. 288 5. Reaction of -Carbanion of Imines with N-Tosylimines: A Facile Route to -Amino Aldehydes and 1,3-Diamines Xue-Long Hou* Yu-Mei Luo, Ke Yuan and Li-Xin Dai J. Chem. Soc., Perkin 1, 2002, 1487-1490. 295 6. New Chiral N, S-Ligands with Thiophenyl at Benzylic Position Palladium (II)-Catalyzed Enantioselective Allylic Alkylation Hao Wu, Xun-Wei Wu, Xue-Long Hou*, Li-Xin Dai and Quan-Rui Wang Chin. J. Chem., 2002, 20, 816-818. 299 课题负责人：沈延昌 课题编号： 2002-05 1. New Polyfluorinated Organotin Reagents. Stereoselective Synthesis of Z--fluoro--trifluoromethylvinylstannanes Yanchang Shen, Guoping Wang Org. Lett. 2002, 4, 2083-2085. 2. A Convenient Synthesis of Perfluoroalkylated Indolizinylphosphonates Yanchang Shen, Yuming Zhang, Guo-Fang Jiang Synthesis 2002, 714-716. 302 305 3. A Convenient Stereocontrolled Route to Trifluoromethylated Penta-2E,4E- or 2Z,4E-dienenitriles Yanchang Shen, Yuming Zhang, Jie Sun Synthesis 2002, 2674-2680. 308 4. Regiospecific Synthesis of Perfluoroalkylated Pyrrolo[2,1-a]isoquinolinyl phosphonates Yanchang Shen, Yuming Zhang, Jie Sun J. Fluorine Chem. 2002, 116, 157-161. 315 5. “One-pot” Synthesis of (Z)-2-Aryl-1-(2-cyanoethyl)ethenylphosphonates via Hexamethylphosphoramide-promoted Sequential Transformation Guoping Wang, Yanchang Shen Heteroatom Chem. 2002, 13, 116-119. 320 6. Regiocontrolled Reaction of Allylic Phosphonate: Synthesis of 3-Methoxycarbonyl1,3-dienylphosphonates and 1-[(3-Methoxycarbonyl)-allyl-vinylphosphonates Yanchang Shen, Guo-Fang Jiang Heteroatom Chem. 2002, 13, 373-376. 324 7. Reaction of Grignard reagents with Diethyl Perfluoroacyl(1-cyanoethnyl) 17 phosphonates. Synthesis of Perfluoroalkylated -Unsaturated Nitriles with Predominant Z-Selectivity Shen, Yanchang Jiang, Guo-Fang Chin. J. Chem. 2002, 20, 1375-1378. 328 课题负责人：陈家碧 1. 课题编号： 2002-06 Remarkable Reactions of Cationic Carbyne Complexes of Manganese, Rhenium,and Diiron with Carbonylmetal Anions. Jiabi Chen*, Ruitao Wang Coordination Chemistry Reviews, 2002, 231(1-2), 109-149. 332 2. Novel Reactions of Cationic Carbyne Complexes of Manganese and Rhenium with Polymetal Carbonyl Anions. An Approach to Trimetal Bridging Carbyne Complexes Nu Xiao, Qiang Xu, Susumu Tsubota, Jie Sun and Jiabi Chen* Organometallics, 2002, 21, 2764-2772. 373 3. Remarkable Nucleophilic Addition to and Ring-breaking of Cycloheptatrienyl ligand in Reactions of -[1-3-:4-7--Cycloheptatrienyl]tricarbonylirontricarbonylmanganeseand -rhenium with Aryllithium Reagents Nu Xiao, Shu Zhang, Zhilei Qiu, Ronghua Li, Beihan Wang, Qiang Xu, Jie Sun and Jiabi Chen* Organometallics, 2002, 21, 3709-3715. 382 4. Novel N-Nucleophilic Addition to and Ring-Breaking of Coordinated Cyclooctatetraene in Diiron Bridging Carbyne Complexes Shu Zhang, Qiang Xu, Jie Sun, and Jiabi Chen*, Organometallics, 2002, 21, 4572-4574. 389 5. Unusual Reactions of Cationic Bridging Carbyne Complexes of Dimethylsilane-bridged Bis(5-cyclopentadienyl)diiron Tricarbonyl with Carbonylmetal Anions. Ruitao Wang, Jie Sun, Jiabi Chen*, Qiang Xu, Yoshie Souma J. Organomet. Chem., 2002, 658, 214-227. 392 课题负责人：邓敏智 课题编号： 2002-07 1． Remarkable co-catalystis by copper(I) oxide in the palladium catalyzed cross-coupling of arylboronic acid with ethyl bromoacetate Xing-xin Liu and Ming-zhi Deng Chem. Commun., 2002, 622-623. 2． A Novel Method for the Construction of (Z,E)- or (Z,Z)-Conjugated 18 406 Alkadienyl Carboxylates Rong He and Ming-zhi Deng Org. Lett, 2002, 4, 2759-2762. 408 3． Rong He and Ming-zhi Deng, Selective reduction of stereodefined cyclopropyl substituted acrylate esters to the corresponding propionate esters Rong He and Ming-zhi Deng Tetrahedron, 2002, 58, 7613-7617. 412 4． Facile Stereoselective Syntheses of Aryl Substituted ,-Unsaturated Esters Containing a Trifluoromethyl Group Rui-qi Pan, Ping-an Wang and Ming-zhi Deng Heteroatom Chemistry, 2002, 13, 287-290. 417 5． 高能量密度材料二硝基氧化偶氮呋咱的合成研究 王家坡，邓敏智 含能材料，2002, 10(2), 56-58. 6． 四唑类铅铜锶盐的制备及其在固体推进剂中的应用试探 杜恒，邓敏智 固体火箭技术，2002, 4, 147-149. 7． 4-羟基-3,5-二硝基吡啶氮氧化物铅及铜盐的合成 郑玉梅，邓敏智 火炸药学报，2002, 25(4), 51-52. 课题负责人：姜 标 课题编号： 2002-08 1. Enantioselective Synthesis of Marine Indole Alkaloid Hamacanthin B Jiang Biao; Yang Cai-Guang; Wang Jun J. Org. Chem. 2002, 67, 1396-1398. 421 2. High Diastereoselectivity in Intermolecular Carbonyl Ylide Cycloaddition with Aryl Aldehyde Using Methyl Diazo(trifluoromethyl)acetate Jiang Biao; Zhang Xiaobing; Luo Zhaohui Org. Lett. 2002, 4, 2453-2455. 424 3. Structure-Based 3-D-QSAR Analysis of Marine Indole Alkaloids Jiang Biao; Xiong Wen-Nan; Yang Cai-Guang; Jiang Hua-Liang; Cheng Feng; Chen Kai-Xian Bioorganic and Medicinal Chemistry 2002, 10, 2775-2778. 427 4. Enantioselective alkynylation of a prochiral ketone catalyzed by C2-symmetric diamino diols 19 Jiang Biao; Feng Yan Tetrahedron Letters 2002, 43, 2975-2977. 431 5. Asymmetric aminohydroxylation of vinyl indoles: a short enantioselective synthesis of the bisindole alkaloids dihydrohamacanthin A and dragmacidin A, Yang Cai-Guang; Wang Jun; Tang Xiao-Xia; Jiang Biao Tetrahedron: Asymmetry 2002, 13, 383-394. 434 6. Enantioselective synthesis of the aminoimidazole segment of dragmacidin D Yang Cai-Guang; Wang Jun; Jiang Biao Tetrahedron Letters 2002, 43, 1063-1066. 446 7. Regio- and stereoselective synthesis of chiral (S)-(Z)-trifluoromethyl--arylenamines Jiang Biao; Zhang Fangjiang; Xiong Wennan Tetrahedron 2002, 58, 261-264. 450 8. Stereoselective synthesis of (Z)-trifluoromethyl enamines and their Lewis acid-mediated conversion into (E)-isomers Jiang Biao; Zhang Fangjiang; Xiong Wennan Tetrahedron 2002, 58, 265-270. 454 9. The regio- and stereoselective addition of carbon nucleophiles to trifluoromethyl phenylsulfanyl acetylene: a novel and expeditious approach to 3-trifluoromethyl furans Jiang Biao; Zhang Fangjiang; Xiong Wennan Tetrahedron Letters 2002, 43, 665-667. 460 10. Highly Enantioselective Alkynylation of Keto Ester: An Efficient Method for Constructing a Chiral Tertiary Carbon Center Jiang, Biao; Chen, Zili; Tang, Xiaoxia Org. Lett. 2002, 4, 3451-3453. 463 11. Highly enantioselective alkynylation of aldehydes catalyzed by a readily available chiral amino alcohol-based ligand Biao Jiang, Zili Chen, Wennan Xiong Chem. Commun. 2002, 1524-1525. 466 12. Zn(ODf)2: preparation and application in asymmetric alkynylation of aldehydes Zili Chen, Wennan Xiong, Biao Jiang Chem. Commun. 2002, 2098-2099. 468 13. Methyl 3,3-difluoro-2-trimethylsilyloxyacrylate: preparation and Mukaiyama-type aldol condensation as a novel route to difluoro-keto ester derivatives Biao Jiang, Xiaobing Zhang and Guoqiang Shi Tetrahedron Letters 2002, 43, 6819 – 6821. 470 20 14. Alkynylation of carbonyl compounds with terminal acetylenes promoted by ZnCl2 and Et3N: simple, mild and efficient preparation of propargylic alcohols Biao Jiang and Yu-Gui Si Tetrahedron Letters 2002, 43, 8323-8325. 473 15. Enantioselective Synthesis of Slagenins A-C Jiang, Biao; Liu, Jia-Feng; Zhao, Sheng-Yin Org. Lett. 2002, 3951-3953. 476 16. Catalytic Diastereoselective Pauson-Khand Reaction: an Efficient Route to Enantiopure Cyclopenta[c]proline Derivatives Jiang Biao; Xu Min Org. Lett. 2002, 4077-4080. 479 17. A Convenient Synthesis of N-Fluorenylmethoxycarbonyl-N-Methyl-L-Cysteine Derivatives [Fmoc,Me-Cys(R)-OH] Jia-Feng Liu, Xiao-xia Tang, Biao Jiang Synthesis 2002, 1499-1501. 483 18. A Convenient Procedure for Preparation of a Novel Allylphenoxytriazine Monomer and the Properties of Its Copolymer with Bismaleimide(BMI) Qiang Fang, Biao Jiang, Yi-Hua Yu, Xiao-Bing Zhang, Lu-Xia Jiang J. Appl. Polym. Sci. 2002, 86, 2279-2284. 486 19. Preparing Functional Bis(indole) Pyrazine by Stepwise Cross-coupling Reactions: An Efficient Method to Construct the Skeleton of Dragmacidin D Cai-Guang Yang, Gang Liu, and Biao Jiang J. Org. Chem. 2002, 67, 9392-9396. 492 20. Zn(II)-Mediated Alkynylation-Cyclization of o-Trifluoroacetyl Anilines: One-Pot Synthesis of 4-Trifluoromethyl-Substituted Quinoline Derivatives Biao Jiang and Yu-Gui Si J. Org. Chem. 2002, 67, 9449-9451. 497 课题负责人：施 敏 课题编号： 2002-09 1. Titanium(IV) Bromide and Boron(III) Tribromide Promoted Baylis-Hillman Reactions of Arylaldehydes with 3-Butyn-2-one. Min Shi* and Chun-Jiang Wang Helv. Chim. Acta, 2002, 85, 841-846. 500 2. The Reaction of Amines with Benzyl Halides Under CO2 Atmosphere. Min Shi* and Yu-Mei Shen Helv. Chim. Acta, 2001, 84, 3357-3365. 21 506 3. C2-Symmetric Dialkoxyphosphoramide and Dialkoxythiophosphoramide Derivatives of (1R, 2R)-1,2-Diaminocyclohexane as Chiral Ligands for the Titanium(IV) Alkoxide-promoted Asymmetric Addition Reactions of Diethylzinc to Arylaldehydes. Min Shi,* Xiao-Feng Wu, and Guobin Rong Chirality, 2002, 14, 90-95. 515 4. Lewis Base and L-Proline Co-Catalyzed Baylis-Hillman Reaction of Arylaldehydes with Methyl Vinyl Ketone. Min Shi,* Jian-Kang Jiang, and Chao-Qun Li Tetrahedron Lett., 2002, 43, 127-130. 521 5. The Synthesis of New Chiral Rhodium Complexes and Their Crystal Structures Min Shi* and Gui-Xin Lei Applied Organometa. Chem., 2002, 16, 55-60. 525 6. Titanium(IV) Chloride, Boron(III) Chloride, Amine-Promoted Baylis-Hillman Reaction. Min Shi,* Jian-Kang Jiang, and Shi-Cong Cui Molecules, 2001, 6, 852-868. Zirconium(IV) Chloride and 531 7. Transition Metal Catalyzed Reactions of Propargylamine with Carbon Dioxide and Carbon Disulfide. Min Shi* and Yu-Mei Shen J. Org. Chem., 2002, 67, 16-21. 548 8. Perfluorinated rare earth metals catalyzed nitration of aromatic compounds. Min Shi* and Shi-Cong Cui J. Fluor. Chem., 2002, 113, 207-209. 554 9. VO(acac)2 Catalyzed Oxidative Coupling Reactions of Phosphonium Salts. Min Shi* and Bo Xu J. Org. Chem., 2002, 67, 294-297. 557 10. Axially Dissymmetric Binaphthyldiimine Chiral Salen Type Ligands For Copper-Catalyzed Asymmetric Aziridination. Min Shi,* Chuan-Jiang Wang, and Albert S. C. Chan Tetrahedron:Asymmetry, 2001, 12, 3105-3111. 561 11. Reactions of 5,5-dimethyl-4-methylene-1,3-dioxolan-2-one with amines in the presence of palladium catalyst. Min Shi,* Yu-Mei Shen, and Ya-Jun Chen Heterocycles, 2002, 57, 245-257. 568 12. Lewis base effects in the Baylis-Hillman reaction of imines with methyl vinyl ketones. 22 Min Shi* and Yong-Mei Xu Eur. J. Org. Chem., 2002, 696-701. 581 13. The reactions of thiols and diphenyldisulfide with the terminal substituted methylenecyclopropanes. Bo Xu, Yu Chen† and Min Shi* Tetrahedron Lett., 2002, 43, 2781-2784. 587 14. Baylis-Hillman Reaction of Arylaldehydes with Phenyl Vinyl Ketone, Phenyl Acrylate and Phenyl Thioacrylate. Min Shi,* Chao-Qun Li, and Jian-Kang Jiang Helv. Chim. Acta, 2002, 85, 1051-1057. 15. Synthesis of a Novel Copper(II) Complex and Its Crystal Structure. Min Shi,* and Jian-Kang Jiang J. Organometa. Chem., 2002, 650, 274-278. 591 598 16. Axially Dissymmetric (R)-(+)-5,5’,6,6’,7,7’,8,8’-Octahydro-[1,1’] binaphthyldiimine Chiral Salen Type Ligands For Copper-Catalyzed Asymmetric Aziridination. Min Shi* and Chun-Jiang Wang, Chirality, 2002, 14, 412-416. 603 17. A Novel Reaction of 1,8-Diazabicyclo[5.4.0]undec-7-ene [DBU] or 1,5-Diazabicyclo -[4.3.0]non-5-ene [DBN] with Benzyl Halides in the Presence of Water. Min Shi* and Yu-Mei Shen Helv. Chim. Acta, 2002, 85, 1355-1363. 608 18. Electrophilic Aromatic Nitration Using Perfluorinated Rare Earth Metal Salts in Fluorous Phase. Min Shi* and Shi-Cong Cui Chem. Commun., 2002, 994-995. 617 19. Baylis-Hillman reactions of N-arylidenediphenylphosphinamides with methyl vinyl ketone, methyl acrylate, and acrylonitrile. Min Shi* and Gui-Ling Zhao Tetrahedron Lett., 2002, 43, 4499-4502. 619 20. Synthesis of Mixed Carbonate via a Three-Components Coupling of Alcohol, CO2, and Alkyl Halide in the Presence of K2CO3 and Tetrabutylammonium Iodide. Min Shi* and Yu-Mei Shen Molecules, 2002, 7, 386-393. 623 21. The Lewis acids catalyzed ring opening reactions of methylenecyclopropanes with alcoholic or acidic nucleophiles. Min Shi* and Bo Xu Org. Lett., 2002, 4, 2145-2148. 631 23 22. The diastereoselective Baylis-Hillman reaction of chiral non-racemic N-sulfinimines with cyclopent-2-en-1-one. Min Shi* and Yong-Mei Xu Tetrahedron:Asymmetry, 2002, 13, 1195-1200. 635 23. Friedel-Crafts reaction catalyzed by perfluorinated rare earth metals. Min Shi*, Shi-Cong Cui J. Fluor. Chem., 2002, 116, 143-147. 641 24. Catalytic asymmetric Baylis-Hillman reaction of imines with methyl vinyl ketone and methyl acrylate. Min Shi* and Yong-Mei Xu Angew. Chem. Int. Ed. Engl. 2002, 41, 4507-4510. 646 25. The First Synthesis and Isolation of Bis(aryloxy)phosphorothioylsulfenyl Iodides' (=Bis(aryloxy)phosphinesulfenyl Iodide P-Sulfides) from the Reaction of S,S’ -(Diphenylstannylene) O,O,O’,O’-Tetraaryl Bis[phosphorodithioates] (=[(Diphenylstannylene)bis(thio)]bis[bis(aryloxy)phosphine P-Sulfides]) with N-Iodosuccinimide. Min Shi* and Shinji Kato† Helv. Chim. Acta, 2002, 85, 2559-2563. 650 26. A Novel Chiral Silver(I) Complex via the Reaction of Thiaxazolidinethione with AgOAc. Min Shi,* Jian-Kang Jiang and Gui-Ling Zhao Eur. J. Inorg. Chem., 2002, 3264-3267. 655 27. Lewis base effects in the Baylis-Hillman reaction of arylaldehydes and N-arylidene-4-methylbenzenesulfonamides with -unsaturated cyclic ketones. Min Shi,* Yong-Mei Xu, Gui-Ling Zhao and Xiao-Feng Wu Eur. J. Org. Chem., 2002, 3666-3679. 659 28. Titanium(IV) Bromide and Boron(III) Tribromide Promoted Reactions of Arylaldehydes with 3-Butyn-2-one, Methyl Propiolate and Propynenitrile. Min Shi* and Chun-Jiang Wang Tetrahedron, 2002, 58, 9063-9074. 673 29. A Novel Ring-Opening Reaction of Methylenecyclopropanes with Aromatic Amines Catalyzed By Lewis Acids. Min Shi,*a Yu Chen,b Bo Xua and Jie Tang,b Tetrahedron Lett., 2002, 43, 8019-8024. 685 30. An Exploration of Asymmetric Baylis-Hillman Reaction Catalyzed by Quinidine Derived Chiral Amine. Min Shi* and Jian-Kang Jiang 24 Tetrahedron:Asymmetry, 2002, 13, 1941-1947. 691 31. Axially Dissymmetric Binaphthyldiimine Chiral Salen-Type Ligands For Catalytic Asymmetric Addition of Diethylzinc to Aldehyde. Min Shi* and Chun-Jiang Wang Tetrahedron:Asymmetry, 2002, 13, 2161-2166. 698 32. One pot aza-Baylis-Hillman reaction of arylaldehyde, diphenylphosphinamide with methyl vinyl ketone in the presence of TiCl4, PPh3, and Et3N. Min Shi* and Gui-Ling Zhao Tetrahedron Lett., 2002, 43, 9171-9174. 704 33. The Reactions of DMSO with Arylaldehydes in the Presence of Sodium Hydride Min Shi* and Yu-Mei Shen J. Chem. Res., 2002, 422-427. 708 34. Boron(III) Tribromide or Titanium(IV) Bromide and Lewis Base Promoted Baylis-Hillman Reaction. Min Shi* and Shi-Cong Cui Chin. J. Chem., 2002, 20, 277-285. 714 35. Axially Dissymmetric Chiral (R)-N,N′-Bis(2-hydroxy-3,5-di-tert-butyl-arylmethyl)1,1′- binaphthalene-2,2′-diamine as Chiral Ligands in the Reaction of Diethylzinc to aldehydes. Min Shi,* Wei-Liang Duan,† and Rong, Guo-bin,† Chin. J. Chem., 2002, 20, 1319-1325. 723 课题负责人：丁奎岭 课题编号： 2002-10 1. Molecular assembly in an inclusion crystal of tris(2-benzimidazylmethyl)amine with 4-nitrobenzoic acid B. Ji, C. Du, Y. Zhu, K. Ding* J. Chem. Cryst. 2000, 30, 783-788. (该文章去年因抽印件未到，没有列入，今年抽印件刚到)。 730 2. Discovery of Exceptionally Efficient Catalysts for Solvent-free Enantioselective Hetero-Diels-Alder Reaction J. Long, J. Hu, X. Shen, B. Ji, K. Ding J. Am. Chem. Soc. 2002, 124, 10-11. 736 3. To Probe the Origin of Activation Effect of Carboxylic Acid and (+)-NLE in Tridentated Titanium Catalyst Systems Yu Yuan, Xin Li, Jie Sun, and Kuiling Ding* J. Am. Chem. Soc. 2002, 124, 14866-14867. 738 4. Dramatically Synergetic Effect of Carboxylic Acid Additive on Tridentate Titanium 25 Catalyzed Enantioselective Hetero-Diels-Alder Reaction: and Nonlinear Effect Yu Yuan, Jiang Long, Jie Sun, and Kuiling Ding* Chem. Eur. J., 2002, 8, 5033-5042. Additive Acceleration 740 5. 3,3’-Br2BINOL-Zn Complex: A highly Efficient Catalyst for Enantioselective Hetero-Diels-Alder Reaction Haifeng Du, J. Long, J. Hu, X. Li, K. Ding Org. Lett., 2002, 4, 4349-4352. 750 6. Acid-free Hetero-Diels-Alder Reaction of Danishefsky’s Diene with Imines Y. Yuan, X. Li, K. Ding Org. Lett., 2002, 4, 3309-3311. 754 7. Synthesis of A New Type of Chiral Amino Phosphine Ligands for Asymmetric Catalysis Yi Wang, Xin Li and Kuiling Ding* Tetrahedron Asymmetry, 2002, 13, 1291-1297. 757 8. A New Method for Optical Resolution of BINOL by Molecular Complexation with (S)-5-Oxopyrrolidine-2-carboxanilide Haifeng Du, Yang Wang, Jie Sun, Jiben Meng and Kuiling Ding* Tetrahedron Lett., 2002, 43, 43, 5273-5276. 764 9. The synthesis of a new generation of MAP ligands containing two types of chiral elements for asymmetric catalysis Y. Wang, X. Li, K. Ding* Tetrahedron Lett., 2002, 43, 159-161. 768 10. The Synthesis of Aminophosphine Ligands with Binaphthyl Backbones for Silver(I)-catalyzed Enantioselective Allylation of Benzaldehyde Yi, Wang, Baoming Ji, Kuiling Ding* Chin. J. Chem. 2002, 20, 1300-1312. 771 课题负责人：唐 勇 课题编号： 2002-11 1. A novel Chiral Sulfonium Ylide: Highly Enantioselective Vinylcyclopropanes S. Ye, Zheng-Zheng Huang, Chun-An Xia, Y. Tang*, L.-X. Dai J. Am. Chem. Soc. 2002, 124, 2432-2433. Synthesis of 784 2. Side Arm Approach in Ligand Design and Pseudo-C3-symmetry in Asymmetric Catalysis Jian Zhou, Yong Tang* J. Am. Chem. Soc. 2002, 124, 9030-9031. 786 3. Wittig-Type Olefination Catalyzed by PEG-telluride 26 Zheng-Zheng Huang, Song Ye, Wei Xia, Yi-Hua Yu, Yong Tang* J. Org. Chem. 2002, 67, 3096-3103. 788 4. An Unexpected Catalyst for Wittig-type Reaction and Dehalogenation Zheng-Zheng Huang, Yong Tang* J. Org. Chem. 2002, 67, 5320-5326. 796 5. Telluronium Ylides in Cyclopropanation and Catalytic Olefination Yong Tang*, Song Ye, Zheng-Zheng Huang, Yao-Zeng Huang Heteroatom Chem. 2002, 13, 463-466. 803 课题负责人：张兆国 课题编号： 2002-12 1．钯催化的酰胺羰基化反应 王峰,张兆国 有机化学, 2002, 8, 536-542. 807 课题负责人：赵 刚 课题编号： 2002-13 1. Enantioselective reduction of –keto sulfones using NaBH4/ Me3SiCl system catalyzed by polymer-supported chiral sulfonamide Gang Zhao*, Jian-bing Hu, Zhan-shan Qian and Wei-xing Yin Tetrahedron Asymmetry, 2002, 13, 2095-2098. 814 课题负责人：许 旭 课题编号： 2002-14 1. 美国药典中的毛细管电泳法 王前，许旭* 药学进展，2002，26(5)：308-310. 818 课题负责人：宋礼成 课题编号： 2002-15 1. Reactions of Butterfly Complex Anions of Type [(-RTe)(-CO)Fe2 (CO)6]- with Electrophiles. A New Route to 4-Se-Containing Double-Butterfly Clusters. Crystal Structures of (-p-MeC6H4Te)(-PhCH2S C=S)Fe2(CO)6 and [(-RTe)Fe2(CO)6]2 (4-Se) (R = Ph, p-BrC6H4 ) Li-Cheng Song, Qing-Mei Hu, Hong-Tao Fan, Ming-Yi Tang , Zhi-Yong Yang and Guo-Liang Lu Organometallics, 2002, 21(12), 2468-2472 . 821 2. Syntheses and structural characterization of transition metal tetrahedral clusters (5-RC5H4)(CO)8MoRu2H(3-S) and [(5-RC5H4) (CO)4MoRu(3-S)]2 generated by isolobal reactions Li-Cheng Song, Guang-Huai Zeng, Qing-Mei Hu, Hua-Wei Cheng, Hong-Tao Fan J. Organomet. Chem., 2002, 656, 228-233. 826 27 3. Syntheses and Characterizations of Novel One-dimensional Coordination Polymers Self-assembling from Co(NCS)2 and Flexible Diester-bridged Pyridine-based Ligands SONG, Li-Cheng, ZHANG, Wen-Xiong, HU, Qing-Mei Chin. J. Chem., 2002, 20, 1421-1429. 832 课题负责人：黄 宪 课题编号： 2002-16 1. Polystyrene-Supported Benzyl Selenide; An Efficient Reagent for Highly Stereocontrolled Synthesis of Olefins and allylic Alcohols Huang, X.; Xu, W. M. Tetrahedron Lett., 2002, 43, 5495-5497. 841 2. Polystyrene-Supported Selenosulfonates: Efficient Reagents for the Synthesis of Acetylenic Sulfones Qian, H.; Huang, X. Tetrahedron Lett., 2002, 43, 1059-1061. 844 3. Solid-Phase Synthesis of 4 (1H) –Quinolone and Pyrimidine Derivatives on a new Scaffold-Polymer-Bound Cyclic Malonic Acid Ester Huang, X.; Liu, Z.-X. J. Org. Chem., 2002, 67 (19), 6731-6737. 847 4. Stereoselective Michael-Aldol Tandem Reaction of Phenylselenomagnesium Bromide with Acetylenic Sulfones and Aldehydes. An Efficient Synthesis of Polyfunctionalized Allylic Alcohols Huang, X.; Xie, M.-H. Organic Lett., 2002, 4(8), 1331-1334. 854 5. Highly Stereoselective Three-Component Reactions of Phenylselenomagnesium Bromide, Acetylenic Sulfones, and Saturated Aldehydes/ketones or , -unsaturated Enals or Enones Huang, X.; Xie, M.-H. J. Org. Chem., 2002, 67 (25), 8895-8900. 858 6. Novel Tunable CuX2-mediated Cyclization Reaction of Cyclopropylideneacetic Acid, and Ester for the Facil Synthesis of 4-Halomethyl-2 (5H) – furanones and 4-Halo-5,6-dihydro-2H-pyran-2-ones Huang, X.; Zhou, H.-W. Organic Lett., 2002, 4, 4419-4422. 864 7. (Z)--Silyl-, -Unsaturated Ketones and Their Application in the Synthesis of 1, 4-Diketones Zheng, W. X.; Huang, X. Synthesis, 2002, 2497-2502. 868 28 8. Polystyrene-bound phenylseleninic acid: catalytic oxidation of aldehydes to carboxylic acids with hydrogen peroxide Qian H.; Shao L.-X.; Huang X. J. Chem. Research (S) 2002, 514-515. 874 课题负责人：沈 琪 课题编号： 2002-17 1 Synthesis, Reactivity, and Structure of Mixed-Ligand Ytterbium Complexes Supported by -Diketiminate Yingming Yao, Yong Zhang, Qi Shen, Kaibei Yu Organometallics, 2002, 21(5), 819-824. 876 2 The Reactivity of (CH3C5H4)2LnNPh2(THF) (Ln = Y, Yb) with CS2 and PhNCS: Synthesis and Crystal Structures Huanrong Li, Yingming Yao, Qi Shen, Linghong Weng Organometallics, 2002, 21(12), 2529-2532. 882 3 Lanthanocene Amide Complexes as Single-Component Polymerization of (Dimethylamino)ethyl Methacrylate Qi Shen, Yaorong Wang, Keda Zhang, Yingming Yao J. Polym. Sci., Part A, Polym. Chem., 2002, 40(4), 612-616. Initiators for the 886 4 Synthesis, characterization of homoleptic lanthanide amidinate complexes and their catalytic activity for the ring-opening polymerization of -caprolactone Yunjie Luo, Yingming Yao, Qi Shen, Jie Sun, Linhong Weng J. Organomet. Chem., 2002, 662, 144-149. 891 5 Synthesis and Reactivity of Organolanthanoid Complexes Containing N and S Ligands Qi Shen, Yingming Yao J. Organomet. Chem., 2002, 647, 180-189. 897 6 Synthesis and Structure of 1-Cyclopentylindenyl Lanthanide(II) Complexes and Their Catalytic Behavior for Polymerization of Acrylonitrile Qi Min-Hua, Shen Qi, Gong Xin-Qiang, Shen Zhi-Quan, Weng Lin-Hong Chin. J. Chem., 2002, 20(6), 564-569. 907 课题负责人：康北笙 课题编号： 2002-18 1. Chair- and boat-configurations of silver(I) complexes of ditopic ligand involving benzimidazolyl substituents Cai, Y. P., Su, C. Y., Zhang, H. X., Zhou, Z. Y., Zhu, L. X., Chan, A. S. C., Liu, H. Q., Kang, B. S. 29 Z. Anorg. Allg. Chem., 2002, 628 (11), 2321-2328. 2. 913 Supramolecular Architectures Based on trans-Oxamidato-Bridged Copper(II) Synthons and Intramolecular Synergism Zhang, H. X., Kang, B. S., Chen, Z. N., Xu, A. W., Liu, H. Q. Comments Inorg. Chem., 2002, 23 (3), 231-248. 921 3. Silver(I) complex of 1,6-bis(benzimidazol-2-yl)-2,5-dioxa-hexane with network structure self-assembled by hydrogen bond and … stacking Cai, Y. P., Chen, C. L., Zhang, L., Xu, A. W., Liu, J., Su, C. Y., Zhang, H. X., Zhang, L., Kang, B. S. Inorg. Chim. Acta, 2002, 342, 107-113. 939 4. Diphosphine mediated assembly of multinuclear silver complexes containing the thiolato ligand 2-mercaptobenzoxazole (Hmbo) Kang, B. S., Zhang, L., Deng, L. R., Wang, X. J., Zhang, H. X., Liu, H. Q. Sci. in China, (Eng), 2002, 45(5), 488-493. 946 5. 芳基柔性二齿配体在金属超分子自组装中的结构调控作用 刘 俊，谭海燕，陈春龙，刘红科，康北笙 化学通报，2002，65 (6)，385-390. 6. 952 Synthesis, structure, and characterization of an Ag complex of a hetero-armed tripodal ligand with diphosphine participation Zhang, L., Liu, J., Deng, L. R., Zhang, H. X., Cai, Y. P., Liu, H. Q., Kang, B. S., Acta Chim. Sinica, 化学学报，2002，60 (4), 566-568. 958 课题负责人：张永敏 课题编号： 2002-19 1. Synthesis of sulfones from arenesulfonyl chlorides and alkyl halides using the Sm/HgCl2 bimetallic system Zhang JM, Zhang YM* J. Chem. Res.(S) 2001, 516-517. 961 2. Direct construction of a quaternary carbon center utilizing an organosamarium reagent Li ZF, Zhang YM* Tetrahedron Lett. 2001, 42, 8507-8510. 963 3. Samarium diiodide promoted reductive cyclization of nitrodisulfides with nitriles: A new route to benzothiazoles Zhong WH, Zhang YM*, Chen XY J. Indian Chem. Soc. 2001, 78, 316-318. 967 30 4. Samarium diiodide mediated reductive addition reaction of 1-(phenylsulfonylmethyl) benzotriazole and 1-(benzoyloxymethyl) benzotriazole to aldehydes and ketones Li ZF, Zhang YM* J. Chem. Res.(S) 2001, 522-524. 970 5. A novel method for the synthesis of vicinal disulfonamides promoted by metallic samarium in aqueous media Liu X, Liu YK, Zhang YM* Tetrahedron Lett. 2002, 43, 6787-6789. 973 6. Synthesis of 3H-pyrroles promoted by samarium/iodine (cat.) system Xu XL, Zhang YM* Synth. Commun. 2002, 32, 2643-2650. 976 7. Sm/TiCl4 system induced reductive coupling reactions: synthesis of tetraarylfurans Li ZF, Zhang YM*, Liu YK J. Indian Chem. Soc. 2002, 79, 188-189. 984 8. Low-valent titanium induced cyclization of dimeric dianions of anils with triphosgene: A safe and efficient method for the syntheses of substituted imidazolidine-2-ones Li ZF, Zhang YM* Synth. Commun. 2002, 32, 2613-2618. 986 9. Coupling reaction of aryl halides promoted by NiCl2/PPh3/Sm0 Zheng XL, Zhang YM* J. Chem. Res.(S) 2002, 562-563. 992 10. Intermolecular deoxygenative coupling of diarylketones and arylamides induced by Sm/SmI2 system Xu XL, Zhang YM* Tetrahedron 2002, 58, 503-505. 994 11. Direct construction of quaternary carbon center utilizing an allylsamarium bromide reagent Li ZF, Zhang YM* Tetrahedron 2002, 58, 5301-5306. 997 12. Preparation of dihomoallylic secondary amines through samarium mediated allylation of oximes Fan XS, Zhang YM* Tetrahedron Lett. 2002, 43, 5475-5478. 1003 13. The synthesis of N-(1-allyl-3-butenyl)-N-aryl amines by addition of organosamarium reagents to formanilides Li ZF, Zhang YM* 31 J. Chem. Res.(S) 2002, 297-298. 1007 14. Tetrahydrofuran ring opening with acyloxyphosphonium bromide catalysed by allylsamarium bromide: a novel and effective method for the preparation of 4-bromobutyl esters Liu YK, Zhang YM* J. Chem. Res.(S) 2002, 15-16. 1009 15. New procedure for the preparation of 2,3-dihydro-1,5-benzothiazepin-4(5H)-ones promoted by samarium diiodide Zhong WH, Chen XY, Zhang YM* Synth. Commun. 2002, 32, 1085-1090. 1011 16. Conversion of bis(o-nitrophenyl)diselenides to heterocycles containing selenium and nitrogen with the aid of samarium diiodide Chen XY, Zhong WH, Zhang YM* Heteroatom Chem. 2002, 13, 302-306. 1017 17. Formation of 1,2-diketones by samarium diiodide promoted reaction of N-acylbenzotriazoles Wang XX, Zhang YM* Tetrahedron Lett. 2002, 43, 5431-5433. 1022 18. SmI2-mediated facile one-pot preparation 3-aryl-2,1-benzisoxazoles Fan XS, Zhang YM* Tetrahedron Lett. 2002, 43, 7001-7003. of 2,4-diarylquinolines 19. Samarium diiodide mediated reductive 2-nitro-1,3-diphenyl-2-propen-1-one: synthesis of quinolines Wang XX, Zhang YM* Synth. Commun. 2002, 32, 3617-3620. from 1025 coupling 20. SmI2-mediated synthesis of 2,4-diarylpyrroles from phenacyl azides Fan XS, Zhang YM* Tetrahedron Lett. 2002, 43, 1863-1865. of 1028 1032 21. Facile synthesis of polysubstituted cyclopentenylamines or γ-hydroxyamides by samarium diiodide Xu XL, Zhang YM* Synth. Commun. 2002, 32, 1891-1897. 1035 22. Michael additions of active methylene compounds to chalcones promoted by samarium(III) iodide Ma YM, Zhang YM* Synth. Commun. 2002, 32, 819-823. 1042 32 23. A novel tandem reaction of chalcone with malononitrile or ethylcyanoacetate promoted by samarium (III) iodide and followed by samarium (II) iodide Ma YM, Zhang YM* J. Chem. Res.(S) 2002, 288-290. 1047 24. Samarium trriodide mediated dethiocyanation of phenacyl thiocyanates and its application in carbon-carbon bond formation reactions Fan XS, Zhang YM* J. Chem. Res(S). 2002, 439-441. 1050 25. Tetrahydrofuran ring-opening with acyloxyphosphonium iodide catalyzed by samarium triiodide Liu YK, Zhang YM* Org. Prep. Proced. Int. 2002, 34, 213-217. 1053 26. Samarium chlorides catalysed Biginelli 3,4-dihydropyrimidin-2(1H)-ones Fan XS, Zhang YM* J. Chem. Res.(S) 2002, 79, 436-438. reaction: one-pot synthesis of 1058 27. Sm/BiCl3 system mediated Reformatsky type reactions of α-bromoacetophenone with aldehydes in THF-H2O solvent Zhang JM, Zhang YM* Chin. J. Chem. 2002, 20, 111-113. 1061 28. Sm0/AlCl3•6H2O 体系促进叠氮化合物的化学选择性还原：一种制备胺的新方法。 张纪明，张永敏 合成化学, 2002, 498-500. 1064 29. Samarium-promoted chemoselective reduction of aromatic nitro compounds in ionic liquid Zheng XL, Zhang YM* Chin. J. Chem. 2002, 20, 925-928. 1067 30. Efficient debromination of vicinal α, β-dibromo carboxylic acid derivatives with the Sm/HOAc system Wang XX, Zhang YM* Chin. Chem. Lett. 2002, 13, 499-500. 1071 31. Reductive cleavage. of the Te-Te bond in diphenyl ditelluride by the Sm/CrCl3(cat.) system: Preparation of telluroesters and unsymmetrical phenyltellurides Liu YK, Zhang YM* Chin. J. Chem. 2002, 20, 202-206. 1073 32. Catalytic HgCl2-samarium system induced reductive coupling of nitriles with nitro 33 compounds Zhang JM, Zhang YM* Chin. Chem. Lett. 2002, 13, 97-100. 1078 33. Reductive coupling cyclization of 1,1-dicyanoalkenes promoted by Sm0/HgCl2 (cat.) system Zhang JM, Zhang YM* Chin. J. Chem. 2002, 20, 688-691. 1082 34. Facile preparation of homoallyl β ',γ '-unsaturated amines via 1,2-addition of α,β-unsaturated imines with allylsamarium bromide Chen J, Zhang YM* Chin. J. Chem. 2002, 20, 103-106. 1086 35. An efficient Mg/SmI2 catalytic system for the intermolecular deoxygenative coupling of amides and ketones Xu XL, Zhang YM* Chin. J. Chem. 2002, 20, 1463-1465. 1090 36. A simple access to chalcones via modified mukaiyama aldol condensation promoted by SmI3/TMSCl Fan XS, Zhang YM* Chin. J. Chem. 2002, 20, 198-201. 1093 37. Facile formation of ytterbium diiodide and its use in the synthesis of allyl selenides Su WK, Zhang YM*, Zheng YF, et al. Chin. J. Chem. 2002, 20, 174-177. 1097 38. Indium mediated conjugate addition of allyl bromide to nitroalkenes in DMF-H2O media Zhang JM, Zhang YM* Chin. J. Chem. 2002, 20, 296-298. 1101 39. Organic reactions mediated by low-valent vanadium reagents and their applications in organic synthesis Fan XS, Zhang YM* 有机化学 2002, 22, 1-10. 1104 课题负责人：席振峰 课题编号： 2002-20 1. One-pot synthetic route to homoallylketones via selective combination of alkyne, ethylene and aldehyde mediated by AlCl3 and zirconocene Changjia Zhao, Tao Yu and Zhenfeng Xi Chem. Commun., 2002, 142-143. 1114 2. Novel reaction patterns of carbon disulfide with organolithium compounds via 34 cleavage of C=S bonds or via cycloaddition reaction Jinglong Chen, Qiuling Song and Zhenfeng Xi Tetrahedron Letters, 2002, 43, 3533-3535. 1116 课题负责人：曹卫国 课题编号： 2002-21 1. The Knovenagel Condensation Reaction of Aromatic Aldehydes with Malononitrile in the Absence of Solvent and Catalyzed by Grinding Ren Zhongjiao, Cao Weiguo and Tong Weiqi Synth. Commun., 2002, 32(22), 3475-3479. 1119 2. Stereoselective Synthesis of Cis-1-carbomethoxy-2-aryl-3,3dicycanocyclo-propanes Ren Zhongjiao, Ding Weiyu, Cao Weiguo, Wang Sihui and Huang Zhijing Synth. Commun., 2002, 32(20), 3143-3148. 1124 3. Stereoselective Synthesis of trans--Methoxycarbonyl--aryl--butyrolactones Chen Yali, Ding Weiyu, Cao Weiguo and Lu Cheng Synth. Commun., 2002, 32(13), 1953-1960. 1130 4. A Simple Approach to Highly Stereoselective Synthesis of N,N’-substituted Bis(trans--Bisubstituted--butyrolactam) Sun Xiao-Hua, Chen Ya-Li, Ding Wei-Yu and Cao Wei-Guo 合成化学(Chin. J. Synth. Chem.), 2002, 10(3), 216-219. 1138 课题负责人：周锡庚 课题编号： 2002-22 1. Insertion of Carbodiimide into the LnC -Bond of Organolanthanide Complexes. Synthesis, Reaction and Characterization of Organolanthanide Amidinates (C5H5)2Ln[tBuNC(nBu)NtBu] (Ln = Er, Gd, Y) Jie Zhang, Ruyi Ruan, Zehuai Shao, Ruifang Cai, Linhong Weng, Xigeng Zhou*, Organometallics, 2002, 21, 1420-1424. 1142 2. Novel Cp2LnXMediated CouplingCyclization of Propargyl Bromide: A New Construction of Benzene Ring Skeleton Ruyi Ruan, Jie Zhang, Xigeng Zhou, Ruifang Cai Chem. Commun., 2002, 538-539. 1147 3. Insertion into lanthanide-ligand bonds in organolanthanide chemistry Xigeng Zhou, Ming Zhu J. Organomet. Chem., 2002, 647, 28-49. 1149 4. Synthesis, structure and reactivity of ethylthioethylcyclo- pentadienyl lanthanide complexes Cpt2LnCl (Ln = Sm, Gd, Er) and CptLnCl2(THF)3 ( Ln = Gd, Er) 35 Xigeng Zhou, Lixin Zhang, Chunmei Zhang, Jie Zhang, Ming Zhu, Ruifang Cai, Zu-En Huang, Zixiang Huang, Qiangjin Wu J. Organomet. Chem., 2002, 655, 120-126. 1171 课题负责人：庞 震 课题编号： 2002-23 课题负责人：王佰全 课题编号： 2002-24 1. Synthesis and structures of cycloalkylidene-bridged biscyclopentadienyl tetracarbonyl diiron complexes C(CH2)n[(5-C5H4)Fe(CO)]2(-CO)2 ( n = 4, 5 and 6) Xu, S., Zhang, J., Zhu, B., Wang, B., Zhou, X., Weng, L. Transition Met.Chem., 2002, 27, 58-61. 1178 2. Synthesis, structure and polymerization catalytic properties of doubly bridged bis(cyclopentadienyl) dinuclear titanium and zirconium complexes Xu, S., Dai, X., Wu, T., Wang, B., Zhou, X., Weng, L. J. Organomet.Chem., 2002, 645, 212-217. 1182 3. Synthesis, structure and polymerization catalytic properties of germyl bridged bis(cyclopentadienyl) metallocenes Xu, S., Dai, X., Wang, B., Zhou, X. J. Organomet.Chem., 2002, 645, 262-267. 1188 4. A study of the reaction between phenyl substituted cyclopentadiene and iron pentacarbonyl: The unusual structure of –complex (4-C5Ph4H)Fe(CO)3 Xu, S., Yuan, F., Zhuang, Y., Wang, B., Li, Y., Zhou, X. Inorg.Chem.Commun., 2002, 5, 102-104. 1194 5. Synthesis and polymerization catalytic properties of aryl-substituted tetramethylcyclopentadienyl zirconocenes Deng, X., Wang, B., Xu, S. Zhou, X., Yang, L., Li, Y., Hu, Y., Li, Y., Zou, F. J. Mol. Catal. A: Chem., 2002, 184, 57-64. 1197 6. 柄型金属有机化合物(V)锗桥连茚基及取代茚基锆化合物的合成及催化烯烃聚 合 徐善生, 田公路, 王佰全, 周秀中, 梁波, 赵亮 高等学校化学学报, 2002, 23, 595-599. 1205 7. Synthesis and structure of a novel cluster with trigonal-bipyramidal Ge2Ru3 core accompanied by unusual cleavage of Ge-C bonds Zhang, Y., Wang, B., Xu, S., Zhou, X. Chin. J. Chem, 2002, 20, 1388-1392. 1210 36 8. 柄型金属有机化合物(VI)四甲基二硅氧桥连不对称茂金属化合物的合成, 结构 及催化乙烯聚合 徐善生, 吴涛, 崔惠玲, 王佰全, 周秀中, 邹丰楼, 李杨 高等学校化学学报, 2002, 23, 1891-1895. 1215 9. 联苯基桥连双核茂锆化合物的合成及催化乙烯聚合 邓小斌, 徐善生, 王佰全, 周秀中, 杨玲, 李于飞, 胡友良 高等学校化学学报, 2002, 23, 2089-2092. 1220 10. 四甲基二硅桥连双环戊二烯基四羰基二铁的芳香异腈取代及热重排反应 徐善生, 杨柳, 李颖, 王佰全, 周秀中 化学学报, 2002, 60, 2197-2202. 1224 课题负责人：王绍武 课题编号： 2002-25 1. 含茂基稀土金属有机络合物催化剂在有机合成中的应用 杨高升，盛恩宏，程林，周双六，孙益民，王绍武* 中国稀土学报，2002， 20， 97-106. 1230 课题负责人：秦金贵 课题编号： 2002-26 1. Synthesis and Characterization of a Series of New Functional Poly(ferrocenylenesilanes) for Nonlinear Optics Liu Yun-Yang, Zhang Xuan, Tang Hong-Ding, Wang Ting-Jun, Qin Jin-Gui, Liu Dao-Yu, Li Shao-Jun, Ye Cheng Chin. J. Chem. 2002, 20, 1199-1204. 1240 课题负责人：殷元骐 课题编号： 2002-27 课题负责人：甘良兵 课题编号： 2002-28 1. Fullerenes as t-butylperoxy radical trap, metal catalysed reaction of t-butyl hydroperoxide with fullerenes and formation of the first fullerene mixed peroxides C60(O)(OOt-Bu)4 and C70(OOt-Bu)10 Liangbing Gan, Shaohua Huang ， Xiang Zhang, Aixin Zhang, Bichu Cheng, Hao Cheng, Xiaolei Li, Gao Shang J. Am. Chem. Soc., 2002, 124, 13384-13385. 1246 课题负责人：范青华 课题编号： 2002-29 37 课题负责人：朱成建 课题编号： 2002-30 课题负责人：陈忠宁 课题编号： 2002-32 1. Utilizing Diruthenium Components for the Design of Cyanide-linked Tri-and Trtranuclear Organometallic Complexes with Multistep One-electronRedox Processes Li-Yi Zhang, Jing-Lin Chen, Lin-Xi Shi, Zhong-Ning Chen* Organometallics 2002, 21, 5919-5925. 1248 课题负责人：王 磊 课题编号： 2002-34 1. A novel metal samarium promoted reduction of sodium alkyl thiosulfates without activating agent in water Wang Lei, Li Pinhua and Zhou Li Tetrahedron Lett., 2002, 43, 8141-8143. 1255 课题负责人：廖世健 1. Extremely Active Catalysts for the Hydrogenation of Terminal Alkenes Yin-Heng Fan, Shi-Jian Liao, Jie Xu, Fu-Dong Wang, Yan-Long Qian, Ji-Ling Huang J. Cat. 2002, 205, 294-298. 2. 1258 Thermal Stability of Nano-KH Particles and Their Chemical Reactivities Fan Yin-Heng, Liao Shi-Jian, Li Wei-Na, Xu Jie, Wang Fu-Dong 物理化学学报，2002， 18，55－58. 1263 38