金属有机化学国家重点实验室2010年年度进展报告.doc
金属有机化学国家重点实验室2010年年度进展报告.doc
金属有机化学国家重点实验室 学科带头人现状与需求 现有人员 目前学科方向 陆熙炎院士 过渡金属有机化学 戴立信院士 不对称催化 麻生明院士 过渡金属有机化学 侯雪龙研究员 不对称催化 施敏研究员 过渡金属有机化学 丁奎玲研究员 不对称催化 唐勇研究员 主族元素有机化学，高分子化学 刘元红研究员 钛锆金属有机化学 陈耀峰研究员 稀土金属有机化学 游书力研究员 不对称催化 刘国生研究员 过渡金属有机化学 邓亮研究员 过渡金属配合物及其反应化学 Christian A. Sandoval 副研究员 不对称合成 李玉学副研究员 金属有机计算化学 段伟良副研究员 不对称催化 发展学科方向 需求计划人数 金属催化的小分子活化 1 金属络合物及反应化学 1 后过渡金属有机化学 1 前过渡金属有机化学 1 主族元素金属有机化学 1 金属有机计算化学 1 1 2010 年重大记事 一、实验室开放课题和自主课题 按照国家科技部最新要求和规定，2010 年实验室面向所外单位设立的开放 基金项目有 4 项，资助总额 86.7 万元。2010 年实验室资助课题共计资助 839.3 万元，包括自由探索课题 14 项，资助 262 万元；团队重点课题 5 项，资助 577.3 万元。 二、“基于炔烃和联烯的偶联和环化反应研究”项目获上海市自然科 学一等奖 碳-碳双键和三键在有机化学中占有重要地位，炔烃和联烯由于多重不饱和键 的存在，反应比烯烃更为复杂，关于它们的合成方法及其化学反应性质的研究是 国内外关注的热点。金属有机化学国家重点实验室麻生明课题组对基于炔烃和联 烯的偶联和环化反应进行了系统探索，详细研究了反应的化学、区域、立体选择 性控制因素，发展了一些联烯、炔烃及环状化合物的高选择性高效合成方法。主 要成果和发现点包括： 1、通过立体、电子及配体效应实现了联烯或炔烃的高选择性合成调控，解 决了这些偶联反应理论上长期存在的生成两种同分异构体产物的问题；发现了 1, 3-锂迁移反应，并实现了其对联烯或炔烃产物的选择性调控，被认为是这方面 工作的基础。 2、发展了原子经济性高立体选择性的一步合成甾体类化合物和具有广泛的 生理活性 β-内酯/内酰胺类化合物的新方法，这是目前最简洁的方法；实现了带 亲核性基团的联烯与 2-炔酸酯、丙炔醇碳酸酯、2, 3-联烯醇或简单联烯偶联环 化生成具有广泛生理活性的丁烯酸内酯类化合物，同时发展了一般方法难以合成 的八元环的合成反应, 被认为是一个通用的反应。 3、发展了钯催化的联烯及其衍生物和硼酸的偶联反应，为多取代烯烃的立 体选择性合成提供了新方法；较早建立利用 ESI-MS 方法捕获反应过程中产生的 活性中间体的方法，这些中间体的分离由于他们活性太高、在反应体系中的寿命 短而难以实现，以此阐明了钯催化的联烯与硼试剂加成反应的机理，这一方法目 2 前被广泛应用于机理研究。 此成果共发表论文 64 篇（SCI 61 篇，SCI-E 63 篇），总影响因子 316.228， 其中影响因子>5 的有 19 篇，包括 J. Am. Chem. Soc. 5 篇，Angew. Chem. Int. Ed. 9 篇，Chem. Eur. J. 5 篇；撰写英文专著章节 2 章，中文专著 1 部和章节 1 章； 论著被他引 878 次，单篇他引最高 220 次，平均每篇他引 12.9 次；多篇论文被 选为 Hot Paper 或被国际刊物专题评论、被 Highlights 栏目摘录，有 11 篇文献的 工作中称此工作为 Leading reference，34 篇文献中对此成果发展的反应效率及意 义进行了较高层次或较大幅度的评述；获授权专利 6 项；ESI-MS 方法在追踪反 应中间体的应用研究为这一分析手段的普及及应用奠定了重要基础，钯催化的联 烯与硼试剂加成反应被应用于实现 Enokipodins A 和 B 的全合成，国外同行在一 些工作中用了此成果发展的方法来合成所需化合物；在 IUPAC 在内的国际会议 上作邀请报告 10 次，并在 Pure & Appl. Chem.发表 IUPAC 系列会议大会邀请报 告内容 3 篇，在双边会议上做邀请报告 3 次，麻生明 5 次担任国际会议或双边会 议的会议执行主席；培养 15 名博士、2 名博士后，其中 1 人获全国百篇优秀博 士论文、1 人获中科院院长奖学金特别奖、3 人获中科院院长奖学金优秀奖。 本项目的工作丰富了炔烃及联烯化学，一定程度上推动了有机化学的发展， 项目成果处于国际领先水平。项目部分研究内容曾获 2004 年的 Mr. & Mrs. Sun Chan Memorial Award in Organic Chemistry 和 2005 年的 IUPAC-OMCOS 奖。 三、“超高分子量聚乙烯”项目成功签约 超高分子量聚乙烯(UHMWPE）具有优异的抗冲击、耐磨损、自润滑、耐化 学腐蚀、不易粘附、低温柔性等性能，如 UHMWPE 机械性能高于一般的高密 度聚乙烯，耐冲击性和耐磨损性是目前所有塑料中最好的，其耐磨性超过碳钢， 低温性好，可以在零下 269°C 使用。 金属有机化学国家重点实验室的唐勇课题组在单中心 Ziegle-Natta 催化剂的 研究方面取得了突破性的进展，开发了新型易加工高性能超高分子量聚乙烯的催 化剂技术，并成功转让，实现了 UHMWPE 树脂的工业化生产。 四、组织召开第四届均相催化论坛暨第一届中国-加拿大催化双边会 3 议、第一届烯烃配位聚合与高性能聚烯烃产学研研讨会等学术会议 实验室今年参与举办了第四届均相催化论坛暨第一届中国-加拿大催化双边 会议、“长江论坛 2010”学术研讨会、第十六届全国金属有机化学学术讨论会以 及第一届烯烃配位聚合与高性能聚烯烃产学研研讨会等学术会议。 第四届均相催化论坛暨第一届中国-加拿大催化双边会议： 在中加双方国家自然科学基金委员会和上海有机所资助下，由金属有机化学 国 家 重 点 实 验 室 麻 生 明 院 士 发 起 组 织 的 The 4th International Forum on Homogeneous Catalysis and The First China-Canada Bilateral Symposium on Catalysis 于 2010 年 10 月 7 日~11 日在云南昆明召开，会议邀请到了 21 名科学 家分别作 30 分钟的学术报告，并安排了 5 分钟的讨论。其中中方代表分别是中 国科学院上海有机化学研究所的唐勇、侯雪龙和游书力研究员，北京大学的席振 峰教授和焦宁教授，武汉大学的雷爱文教授、四川大学的陈迎春教授以及清华大 学的席婵娟教授；加拿大方面代表分别是 York University 的 Michael G. Organ 教 授 ， University of Toronto 的 Andrei K. Yudin 教 授 、 Mark Lautens 教 授 和 Vy Maria Dong 教授，McGill University 的 Bruce A. Arndtsen 教授和 Chao-Jun Li 教 授，University of British Columbia 的 Jennifer A. Love 教授和 Laurel L. Schafer 教 授，Universite Laval 的 Jean-Francois Paquin 教授，Universite de Montreal 的 Andre B. Charette 教授；还有德国 Universitat Heidelberg 的 Lutz H. Gade 教授，Dortmund University of Technology 的 Norbert Krause 教授以及日本 Nagoya University 的 Kazuaki Ishihara 教授。 “长江论坛 2010”学术研讨会： 2010 年 8 月 20 日至 22 日，由中国科学院上海有机化学研究所金属有机化 学国家重点实验室和四川大学化学学院共同发起的“长江论坛 2010”学术研讨会， 在四川峨眉山大酒店隆重召开。国家自然科学基金委化学部的梁文平、陈拥军副 主任和有机化学处的杜灿屏处长应邀参加了会议并作重要讲话，参加会议的有中 科院上海有机所丁奎岭所长、唐勇副所长及金属有机化学国家重点实验室的学术 带头人和研究骨干等 12 人，四川大学有机化学领域的胡常伟、冯小明、秦勇、 4 余孝其、游劲松、陈应春等 16 位教授，以及中科院成都生物所的孙健、唐卓、 罗应刚 3 位研究员。 四川大学化学学院院长胡常伟教授在开幕式上致欢迎辞并简要介绍了四川 大学化学及有机化学近几年来学科建设、人才培养、科学研究等方面的情况。基 金委化学部常务副主任梁文平研究员对会议的召开表示了充分的肯定，他希望以 上海有机化学研究所“化学键活化与可控性重组研究” 国家自然科学基金委创新 研究群体和四川大学“高选择性有机合成新反应与新策略”国家自然科学基金委创 新研究群体为主体主办的论坛越办越好，积极推动我国有机化学学科的可持续发 展。 本次会议针对手性科学技术、合成化学和手性药物等前沿领域作了精彩演讲 和讨论。唐勇研究员、冯小明教授就论坛的组织工作、论坛章程（讨论稿）等做 了说明，并请教授们进一步完善。梁文平常务副主任又给大家通报了相关的信息， 陈拥军副主任对会议进行了简短的总结，并提出了新的希望。会议取得了圆满的 成功。 本次论坛对促进各参加单位在人才培养、科学研究的相互合作和促进学科 发展具有很重要的意义。 第十六届全国金属有机化学学术讨论会： 2010 年 10 月 22 至 25 日，为期三天的第十六届全国金属有机化学学术讨论 会在浙江温州隆重召开。 全国金属有机化学研究工作者 600 余人参加了此次会议。 此次会议由中国化学会主办，温州大学和中国科学院上海有机化学研究所金 属有机化学国家重点实验室共同承办。国家自然科学基金委化学部常务副主任梁 文平以及有机化学处处长杜灿屏等出席了会议。会议专家包括宋礼成院士、吴养 洁院士、麻生明院士等著名学者 40 余人。 本届会议共设 6 个大会报告，3 个“黄宪院士纪念专场报告”，2 个“黄耀曾金 属有机奖获奖报告”，22 个邀请报告和 26 个口头报告。美国 Scripps 研究所的 Jin-Quan Yu 教授，香港大学支志明院士，台湾清华大学郑建鸿教授等分别做了 精彩的大会报告。 5 会议期间，与会代表交流了最新研究成果、展望了学科未来发展趋势。在金 属络合物的合成和反应性能、导向有机合成的金属有机化学、不对称金属催化、 新型金属有机试剂的合成与反应等研究方向展开了热烈的讨论。 第一届烯烃配位聚合与高性能聚烯烃产学研研讨会： 2010 年 10 月 29 日至 31 日，由中国科学院上海有机化学研究所金属有机化 学国家重点实验室和华东理工大学化学工程联合国家重点实验室共同承办的“第 一届烯烃配位聚合与高性能聚烯烃产学研研讨会”，在上海有机所成功召开。 上海有机所唐勇副所长主持了开幕式，丁奎岭所长在开幕式上致欢迎辞。他 首先代表上海有机所对前来参加会议的各位专家、代表表示热烈欢迎，对大会的 顺利召开表示热烈祝贺。丁奎岭所长向各位专家简要介绍了上海有机所近几年来 在聚烯烃学科建设、科学研究等方面的情况。他表示，在基金委和有关部门的领 导下，这样的学术研讨会对加强我国聚烯烃产业界和学术界的技术对接和合作具 有积极的推动和促进作用。 国家自然科学基金委化学部的董建华处长应邀参加了会议并作了精彩报告。 中科院长春应化所、中科院化学所、浙江大学、吉林大学、复旦大学、中山大学、 华东理工大学、上海有机所、北京化工研究院、中石化扬子石化研究院、中石化 齐鲁分公司研究院、中石油化工研究院大庆化工研究中心、中国石油化工股份有 限股份公司中石油兰州化工研究中心、中石化燕山石化等 22 位学术界和产业界 专家代表出席了本次会议。出席此次会议的还有戴立信院士等有机所的科学家， 以及众多有机所的研究生。 此次会议针对烯烃配位聚合与高性能聚烯烃的基础研究、产业应用等领域进 行了广泛的研讨与交流，对促进我国聚烯烃领域的产学研交流与合作，实现聚烯 烃核心技术的自主创新具有积极的意义。 五. 实验室承担的科研项目运行正常 今年实验室主持的国家和省部委的重大重点项目有：(1)科技部 973 项目 1 项，重大新药创制专项项目 1 项； (2)国家基金委创新群体项目 1 项、重点项目 3 项；(3)中科院知识创新方向性重大项目 2 项；(4)上海市资助项目 7 项，其中人 才计划 3 项。作为课题骨干参加的国家和省部委的重大重点项目有：(1)973 项目 6 3 项；(3)中科院知识创新方向性重大项目 1 项；(2)国家基金委重点项目 2 项；另 外实验室还承担了(1)国家基金委其他项目 18 项；(2)其他省部委及中科院项目 6 项。 实验室 2010 年共发表了 221 篇论文（含客座人员发表论文），其中 J. Am. Chem. Soc. 12 篇，Angew. Chem. Int. Ed. 12 篇。其中金属室固定成员发表了 102 篇论文，包括 Chem. Rev.1 篇，Acc. Chem. Res. 1 篇，J. Am. Chem. Soc. 7 篇， Angew. Chem. Int. Ed. 7 篇，Chem. Eur. J. 9 篇，Adv. Synth. Catal. 2 篇，Chem. Commun. 2 篇，Org. Lett. 13 篇，J. Org. Chem. 9 篇，Organometallics 5 篇等。 唐勇研究员和侯雪龙研究员分别主持的 973 项目“物质创造与化学转化过程 中的若干前沿科学问题研究”中的两个课题“金属参与的化学键断裂和形成研 究”(项目编号：2006CB806105)和“手性分子的构筑及相关规律研究”(项目编号： 2006CB806106)，已于 2010 年顺利通过结题验收。2009 年启动的 973 项目“惰性 化学键的选择性激活、重组及其控制”中的课题四“小分子二氧化碳、一氧化碳和 氧气等的活化”(项目编号：2009CB825304)由施敏研究员主持，顺利完成了 2010 年度的工作计划。以丁奎岭研究员为项目首席科学家的科技部 973 项目“手性催 化的重要科学基础”(项目编号：2010CB833305)于 2010 年正式启动，目前进展顺 利。侯雪龙研究员和邓亮研究员分别主持的 973 项目“若干功能体系的定向设计 与构筑”中的两个课题“共价键选择性构建及相关规律研究”和“金属有机化合物的 定向合成与功能调控”获得批准，将于 2011 年正式启动。丁奎岭研究员主持的科 技部重大新药创制专项“手性药物及其中间体的不对称合成与生物活性评价技 术”(项目编号：2009ZX09501-016)于 2009 年正式启动，目前进展顺利。 唐勇研究员主持的国家自然科学基金委创新群体项目“化学键活化与可控性 重组研究”（项目编号：20821002）进展顺利。丁奎岭研究员主持的基金委重点 项目“手性催化剂负载化中若干新方法研究”（项目编号：20632060）已经结题。 施敏研究员主持的基金委重点项目“有机合成中的串联及多组分反应”（项目编号： 20732008）今年进展良好。唐勇研究员主持的基金委重点项目“调控有机合成反 应选择性的新方法”（项目编号：20932008）于 2010 年正式启动，目前进展顺利。 丁奎岭研究员、唐勇研究员及孙秀丽副研究员分别主持的中科院知识创新方 向性重大项目“手性诱导、传递与放大中的科学问题研究”（项目编号： KJCX2-YW-H07）、“新型乙烯聚合催化剂技术的工业化应用研究”（项目编号： 7 KGCX2-YW-209-1）及方向性项目子课题“超高分子量聚乙烯纤维制备与应用-结 构可控 UHMWPE 催化剂技术的研制” （项目编号：KGCX2-YW-237-2）今年均 进展良好。 六．对外交流 实验室今年分别接待了美国、俄罗斯、德国、法国、英国、加拿大等国的 52 位科学家来室访问进行了学术交流；另外，包括台湾在内的 9 位国内专家应邀到 实验室作了精彩学术报告，具体情况见 18-24 页。同时实验室学术带头人积极参 加国际国内的重要学术会议，应邀在国内外学术会议上作邀请报告 34 次。 七．实验室学术委员会工作 2010 年 10 月 20 日-22 日，金属有机化学国家重点实验室第三届学术委员 会第一次会议在温州召开。除 6 名学术委员因故未能参加外，其余委员均参加了 会议。会议邀请到了中国科学院高技术与发展局化工处唐清副处长、白路娜老师， 国家自然科学基金委化学部二处处长杜灿屏参加。 在会议上，实验室主任唐勇研究员向委员会汇报了金属室 2010 年度的工作 总结，余金权、余志祥教授分别作了题为“sp3 碳-氢键活化的现状及展望”、 “Rh(I)-Catalyzed [(5+2)+1], [3+2], [(3+2)+1] Cycloadditions: Methodology Development and Application in Total Synthesis”的专家报告，邓亮、唐勇、侯雪龙 及席振峰教授分别介绍了国际金属有机化学会议、高分子会议、第十七届国际均 相催化会议及第十一届国际四面体大会的会议情况。邓亮、陈耀峰、陈忠宁、朱 成建、周永贵教授在会上分别汇报了各自的工作。与会老师进行了充分的交流。 2010 年 10 月 22 日，到会的学术委员及被邀请的领导、专家就实验室今后的人 才引进、课题组队伍梯队建设、研究方向和人才培养等方面展开了热烈讨论，并 提出了建设性的意见。 八．获奖情况 获奖成果表 序号 获 奖 题 目 类别(国家/部委) 8 等级 完成时间 获奖时间 1 基于炔烃和联烯的 一些反应化学研究 上海市自然科学奖 一等 2007.9 2010.12 个人(包括研究生)获奖表 序号 获奖姓名 获奖名称 获奖时间 1 丁奎岭 第八届上海市自然科学牡丹奖 2010 2 丁奎岭 上海市领军人才 2010 3 游书力 Thieme Chemistry Journals Award 2010 4 游书力 国家杰出青年科学基金 2010 5 侯雪龙 中国化学会黄耀曾金属有机化学奖 2010 6 舒伟 中国科学院院长奖学金优秀奖 2010 7 贺虎 中国科学院院长奖学金优秀奖 2010 8 张伟 中国科学院院长奖学金优秀奖 2010 9 蒋敏 中国科学院朱李月华奖学金 2010 10 刘旭 中国科学院研究生院优秀学生干部 2010 11 李青 2009-2010 年度中科院研究生院三好学生 2010 12 李跃辉 2009-2010 年度中科院研究生院三好学生 2010 13 蔡泉 2009-2010 年度中科院研究生院三好学生 2010 14 余旭芬 2009-2010 年度中科院研究生院三好学生 2010 15 曲剑萍 2009-2010 年度中科院研究生院三好学生 2010 16 陈敬金 2009-2010 年度中科院研究生院三好学生 2010 17 王新科 2009-2010 年度中科院研究生院三好学生 2010 18 陈建平 2009-2010 年度中科院研究生院三好学生 2010 19 贺虎 2009-2010 年度中科院研究生院三好学生 2010 20 付晓平 2009-2010 年度中科院研究生院三好学生 2010 21 周友运 2009-2010 年度中科院研究生院三好学生 2010 22 吴蕾 2009-2010 年度中科院研究生院三好学生 2010 23 刘旭 2009-2010 年度中科院研究生院三好学生 2010 24 张伟 2009-2010 年度中科院研究生院三好学生 2010 25 陈建平 中国科学院研究生院优秀毕业生 2010 26 汪海明 2010 年度上海市高校优秀毕业生 2010 27 贺虎 2010 年度上海市高校优秀毕业生 2010 28 贺虎 上海市青少年科技创新市长奖 2010 29 吴涛 GSK 二等奖学金 2010 9 2010 年自由探索课题（2010-2011 年） 序 号 姓 名 2010-01 陆熙炎 题 目 氢钯化启动的烯基钯对碳-杂原子重键的加成反应 (韩秀玲) 2010-02 麻生明 联烯的锂化反应及其金属参与的偶联反应研究 2010-03 侯雪龙 通过钯催化烯丙基取代反应进行的去对称化反应及其在合成中的应 用 2010-04 施 敏 金催化的高张力分子的反应性能研究 2010-05 丁奎岭 双金属协同催化体系的设计合成及其在某些反应中的应用研究 2010-06 唐 勇 双噁唑啉基配体的设计及其在不对称催化反应中边臂效应的研究 2010-07 刘元红 金催化的呋喃/炔的环化反应研究 2010-08 陈耀峰 烯土末端氮卡宾络合物的合成、结构和反应性能研究 2010-09 游书力 铱催化的新型烯丙基化反应及其机理研究 2010-10 刘国生 金属催化不饱和烃的氢胺化反应的研究 2010-11 李玉学 Cu 催化机理的理论研究 2010-12 邓亮 过渡金属络合物促进的小分子的活化及其在合成化学中的应用 2010-13 段伟良 双核金属络合物的合成及其在催化反应中的应用 2010-14 王春江 新型手性配体 TF-Biphamphos 的合成及其在构建手性季碳的不对称 1, 3-偶极环加成反应中的应用 10 2010 年实验室团队重点研究课题（2007-2011 年） (1) 惰性碳－碳键和碳－氢键的活化与官能团化中的金属有机化学 课题负责人：游书力 研究队伍：游书力，刘国生，段伟良 (2) 反应选择性的控制中的金属有机化学 课题负责人：侯雪龙 研究队伍：戴立信，侯雪龙，丁奎岭，王正，Christian A. Sandoval (3) 金属配合物的结构、合成及反应化学 课题负责人：刘元红 研究队伍：刘元红，施敏，李玉学，孙杰 (4) 含碳－过渡金属键的中间体的形成和反应研究 项目负责人：麻生明 研究队伍：麻生明，陆熙炎，韩秀玲 (5) 新型单中心烯烃聚合催化剂的研究 项目负责人：唐勇 研究队伍：唐勇，陈耀锋，孙秀丽 11 2010 年实验室开放课题（2007-2011 年） 项目一：碳－碳(杂)键形成的的过渡金属有机化学 项目负责人：黄宪 研究队伍：黄宪，吴劼，王佰全，朱成建，陈忠宁，王磊，郎建平，施章杰，张兆 国 研究时间: 2007-2011 年 经费总额: 185 万 项目二：过渡金属卡宾化学 项目负责人：王剑波 研究队伍：王剑波，张俊良，余正坤，雷爱文，焦宁 研究时间: 2007-2011 年 经费总额: 102.5 万 项目三：主族金属有机化合物的反应化学 项目负责人：席振峰 研究队伍：席振峰，周永贵，甘良兵，曹卫国 研究时间: 2007-2011 年 经费总额: 81.25 万 项目四：稀土金属有机物的合成、结构与反应化学 项目负责人：沈琪 研究队伍：沈琪，王绍武，苏成勇，周锡庚 研究时间: 2007-2011 年 经费总额: 81.25 万 12 2010 年授权专利 编号 1 2 专利名称 专利号 一种非茂金属聚烯烃催化剂在合 成乙烯/极性单体的共聚物中的 ZL200610028958.7 用途 烯烃聚合催化剂 ZL200710045131.1 3 4 5 6 7 具有手性中心的苄位取代的噁唑 啉膦配体、合成方法和应用 含氮配体稀土催化剂及在聚酯合 成中的应用 一种合成 3,3'-联中氮茚类化合物 的方法 一种合成3-位取代内酰胺类化合 物的方法 具有樟脑骨架的多手性中心氮杂 环卡宾前体盐、合成方法及用途 13 ZL200710037085.0 ZL200710170829.6 ZL200810040388.2 ZL200710041247.8 ZL200810033107.0 发明人 唐勇、王聪、郭 阳辉、孙秀丽、 刘博、高原 唐勇、杨小红、 刘博、孙秀丽、 王峥 侯雪龙、 武文琼、 吕伟静 陈耀峰、徐信 游书力、夏纪宝 游书力、李公强 游书力、李毅、 冯桢 2010 年金属有机化学国家重点实验室来访人员报告 编号 题目 报告人 1 Asymmetric Catalysis Using Organocatalysts and Metal Complex Catalysts 冯小明 教授 2 Mechanism of Enantioselection in C-C and C-N Bonds Forming Reactions Catalyzed by Bifunction Ru and Ir Complexes 3 主持人 时间 四川大学 唐勇 2010-01-04 10:00 Dr. Ilya Gridnev Graduate School of Science and Engineering Tokyo Institute of Technology 施敏 2010-01-19 10:00 德国生物炼制新技术的 发展趋势 华克曼 博 士/会长 德国生物技术与 化学工程协会 丁奎岭 2010-03-05 09:00 4 微生物源农药申嗪霉素 的研制与生物技术的应 用 许煜泉 教 授 上海交通大学 丁奎岭 2010-03-05 09:00 5 Recent Advances From Dublin In Asymmetric Synthesis and Catalysis Prof. Pat Guiry University College Dublin 丁奎岭 2010-03-12 9:30 6 N-heterocyclic Carbenes in Transition Metal Chemistry: Challenging the Norm Prof. Martin Albrecht University College Dublin 丁奎岭 2010-03-12 9:30 7 Adventures in Catalytic Nitrogenation of Hydrocarbons Dr. Kenneth M. Nicholas University Oklahoma 施敏 2010-03-15 10:00 8 Development of new phosphine-catalyzed reactions Dr. Ohyun Kwon University of California 施敏 2010-03-22 9:30 using allenes acetylenes 单位 of and 9 Publishing for China Dr. Daping Zhang Royal Society of Chemistry 丁奎岭 2010-03-24 14:00 10 Thermodynamics of Carbon-Hydrogen and Carbon-Carbon Bond Activation at Rhodium and Nickel Prof. William Davidson Jones University Rochester 刘国生 2010-04-07 10:00 11 Asymmetric Reaction with 邓力 丁奎岭 2010-04-15 布兰迪斯大学 14 of Bifunctional Catalysts Organic 14:00 教授 12 Catalysis and Cascades in Complex Target Synthesis Prof. Darren J. Di xon University of Oxford 刘元红 2010-04-19 10:00 13 Regioselective Diels-Alder Reaction of Benzynes: Construction of Highly Functionalized Fused Aromatic Compounds Prof. Shuji AKAI University Shizuoka of 施敏 2010-04-26 14:30 14 New Strategies for the Synthesis of Unusual Peptides and Alkaloids Prof. Steven L. Castle Brigham Young University 游书力 2010-05-05 15:00 15 Stereoselective Synthesis of MetallocenesApplication to Asymmetric Catalysis Prof. C. J. Richards University of East Anglia 侯雪龙 2010-05-08 10:00 16 Highly Reactive Alkyl and Hydrido Complexes of Rare-earth Metals Supported by N, NLigands Prof. Alexander A. Trifonov Institute of Organometallic Chemistry, Russian Academy of Sciences 陈耀峰 2010-05-10 10:00 17 New Methods for C–C, C–O, and C–N Bond Formation with Zinc and Palladium Prof. Patrick J. Walsh University Pennsylvania of 邓亮 2010-05-11 10:00 18 An Efficient and Chemoselective Iron Catalyst for the Hydrogenation of Ketones Prof. Charles P. Casey Univeristy Wisconsin Madison of at 刘国生 2010-05-12 15:00 19 RSC Publishing & the organic journals Dr. Richard Kelly Editor, Organic & Biomolecular Chemistry (OBC) and Natural Product Reports (NPR)，Managing Editor of 丁奎岭 2010-05-13 14:00 15 MedChemComm 20 Catalytic Nitrene Transfer: a wonderful tool for the development of selective C-N bond forming reactions Prof. Philippe Dauban CNRS Research Director，Institut de Chimie des Substances Naturelles, FRANCE 游书力 2010-05-14 10:00 21 From Sigmatropic Rearrangements to New Chemical Reactions Prof. Patrick Perlmutter Monash University Christian Sandoval 2010-05-17 10:00 22 Asymmetric Transition Metal Catalyzed Reaction: Synthetic Applications Dr. Virginie Vidal Ecole Nationale Superieure de Chimie de Paris 侯雪龙 2010-05-17 15:00 23 Catalytic Electron Transfer Reactions for Organic Synthesis Prof. Koichi Narasaka Nanyang Technological University 侯雪龙 2010-05-19 10:00 24 Development & Application of FI Catalysts for Olefin Polymerization: Unique Catalysis & Distinctive Polymer Formation Dr. Terunori Fujita Mitsui Chemicals, Inc. 唐勇 2010-05-21 10:00 手性超分子组装体-对超 分子手性的若干认识 刘鸣华 中科院 丁奎岭 研究员 化学研究所 2010-05-21 08:30 电化学储能中的有机化 学问题 田昭武 厦门大学 丁奎岭 2010-05-27 15:00 27 Diastereoselective and asymmetric [4+3] cycloadditons via epoxy enol silanes: applications to the synthesis of bioactive molecules Prof. Pauline Chiu the University of Hong Kong 侯雪龙 2010-05-31 15:00 28 Expanding the code from an perspectives Texas A&M University 游书力 2010-06-01 14:00 25 26 genetic organic 院士 Assistant Prof. Wenshe Liu 16 29 Calix[4]arenes : leaders in catalysis Université de Strasboug 唐勇 2010-06-09 15:00 30 Catalysis Research Center, Technical University Munich, Germany Prof. Notker Roesch Director, Catalysis Research Center TU München 丁奎岭 2010-06-10 09:30 31 Development of New Methodologies in Bio-macromolecule Synthesis Prof. Xuechen Li the University of Hong Kong 侯雪龙 2010-06-11 10:00 32 The Development of Chiral Phosphoric Acid-Catalyzed Methodology Prof. Jon C. Antilla University of South Florida 游书力 2010-06-11 15:00 33 Complexity Building Reactions in Organic Synthesis: Recent Case Studies Prof. Jeffrey S. Johnson University of North Carolina 唐勇 2010-06-13 10:00 34 The Borabenzene Coordination Chemistry Revisited Prof. Frédéric- Université Laval 陈耀峰 2010-06-13 15:00 35 Development of Catalytic Methods for Synthesizing Nitrogen Containing Compounds Prof. Nan Zhang University of Arkansas 刘国生 2010-06-18 10:00 36 Publishing Chemistry-an Editor’s Perspective Dr. Haymo Ross Deputy Editor, Angew Chemie Editor, Eur J Org Chem 丁奎岭 2010-06-21 10:00 37 Homogeneous Catalysis: A Key Technology for Green Chemistry and Benign Energy Technologies Prof. Matthias Beller 刘国生 2010-06-21 15:00 38 New Strategies for Organic Synthesis Using Stereoselecttive C-H Prof. Huw Davies 游书力 2010-06-23 10:00 New Prof. David Semeril Georges Fontaine 17 University at Buffalo, the State University of New Functionalization 39 York University of Basel 游书力 2010-06-23 10:00 乔金樑 中石化 唐勇 教授 北京化工研究院 2010-06-25 15:00 Directed Evolution of C4-Symmetric Metal Vanadate-Centered Helical Quadruplexes: Synergistic Ion-specific Transport and Asymmetric Prof. Chien-Tien Chen National Tsing Hua University 游书力 2010-06-28 10:00 42 New Vistas in the Synthesis of Complex Natural Products Prof. Andrew Evans University of Liverpool 游书力 2010-06-28 15:00 43 Pd-Catalyzed Cross-Coupling Prof. E. Negishi University of Purdue 刘元红 2010-07-09 10:00 44 Thiolate-bridged Dinuclear Fe(CO)3-Ni,Fe(CO)2(CN) 2-Ni,and Fe(CO)(CN)2-Ni Complexes as Structural Models of the [NiFe] Hydrogenase Active Site Prof. Kazuyuki Tatsumi Nagoya University 丁奎岭 2010-08-16 10:00 45 Lessons in Chemoselectivity: Total Synthesis of Polyphenolic Natural Products Prof. Scott Snyder Columbia University 侯雪龙 2010-08-18 15:00 46 Overview of Chemical Abstracts Service (CAS) Databases and Technology Dr. Matthew J. Toussant Senior Vice President 丁奎岭 2010-09-10 10:00 47 Controlled Synthesis and Properties of Hierarchical Molecular Materials Prof. Hak-Fun Chow Chinese University of Hong Kong 侯雪龙 2010-09-13 10:00 Bioinspired Chemistry Using the Many Faces of Peptides-Molecular Scaffolds, Asymmetric Catalysis, Silver-Nanoparticles Prof. Helma Wenneners 高分子材料开发中需要 解决的若干科学和技术 问题 41 40 18 48 New Catalytic Strategies for Stereoselective Organic Synthesis Prof. Christopher Frost University of Bath 游书力 2010-09-14 15:30 49 New Synthetic and Catalytic Methodology for Organic Synthesis Prof. Steven Bull University of Bath 游书力 2010-09-14 15:30 50 Catalysis with Pincer Iridium Complexes Dr. Huang Zheng University of Illinois at Urbana- 唐勇 2010-09-22 15:00 Champargn 51 Contemporary Methods in Organic Synthesis Prof. Steven Ley University of Cambridge 丁奎岭 2010-09-17 10:00 52 Biomimetic Diiron Catalysts for Hydrogen Production Prof. Richard Steven Glass University of Arizona 唐勇 2010-10-11 10:00 53 Novel Synthetic Approaches to Monofluoroalkenes Prof. Jean- Universite Laval 刘国生 2010-10-11 10:00 54 Recent Advances in Chiral Diene Ligands Prof. Tamio Hayashi Kyoto University 侯雪龙 2010-10-13 10:00 55 New C-H Activation Methods for Streamlined Heterocycle Synthesis Dr. Michael Greaney University of Edinburgh 丁奎岭 2010-10-13 10:00 56 Chemistry of Concerto Molecular Catalysis Prof. Takao Ikariya Tokyo Institute of Technology 丁奎岭 2010-10-20 10:00 57 Why Did Nature Select Phosphate for its Dominant Chemical Roles in Biology Prof. G.M. Blackburn University of Scheffield 丁奎岭 2010-10-28 10:00 58 Macrocyclic and Supramolecular Chemistry with Poly-NHC Ligands Prof. Franz Ekkehardt Hahn University of Munster 陈耀峰 2010-10-29 10:00 59 Metal Catalyzed Copolymerization of Olefins with Polar Prof. Richard F. Jordan University of Chicago 唐勇 2010-11-10 14:30 Francois Paquin 19 60 How Well Do We Know the Old Classics: Baeyer-Viliiger, Beckmann, Erlenmeyer, Perkin, et al.? Prof. Sosale Chandrasek -har Indian Institute of Science Bangalore 侯雪龙 2010-12-23 10:00 61 Discovering Small Molecules of Inhibiting Protein-Protein Interaction via the Combination of MCR and Computational Approach 王巍 博士 匹兹堡大学 唐勇 2010-12-30 14:00 20 2010 年发表专著 专著(章节)题目 作者 Chiral Amines from Lun-Zhi Dai Asymmetric and Min Shi, aza-Morita-Baylis-H illman Reaction 专著名称 出版社名称 年份 页码 主编姓名 In Handbook of Chiral Amine Synthesis, Wiley-VCH: Weinheim, 2010,. 397-428 Eds, Thomas C. Nugent, synthesis electrocyclic reaction by L.-M. Lu, L.-X. Shao, M. Shi Science of Synthesis Georg Thieme Verlag KG, Stuttgart 2010 755-766 A. de. Meijere 碳-碳键的活化 施敏 10000 个科学 难题 科学出版社 2010 251-253 徐光宪 Palladium-Catalyzed You, Shu-Li; Aryl–Aryl Bond Xia, Ji-Bao Formation Through Double C–H Activation Chiral Wiley-VCH Ferrocenes in Asymmetric CatalysisSynthesis and Applications 2010 Top Curr Chem 2010 21 Springer Li-Xin Dai, Xue-Long Hou 165-194 Yu, Jin-Quan; Shi, Zhang-Jie 2010 年论文目录 一、 固定人员论文目录（按通讯作者姓氏首字母排序） 1. A Scandium Terminal Imido Complex: Synthesis, Structure and DFT Studies. Erli Lu, Yuxue Li, Yaofeng Chen* Chem. Commun. 2010, 46, 4469. (Front cover) 2. Synthesis and Structural Features of Boratabenzene Rare-earth Metal Alkyl Complexes. Yuanyuan Yuan, Yaofeng Chen*, Guangyu Li, Wei Xia Organometallics 2010, 29, 3722. 3. Half-sandwich Mono(indenyl) Rare-earth Metal Dialkyl Complexes: Syntheses, Structures and Catalytic Reactivities of (1,3-(SiMe3)2C9H5)RE(CH2SiMe3)2(THF). Xin Xu, Yaofeng Chen*, Jian Feng, Gang Zou, Jie Sun Organometallics 2010, 29, 549. 4. Neodymium(III) Phosphinidene Complexes Supported by Pentamethylcyclopentadienyl and Hydrotris(pyrazolyl)borate Ligands. Peng Cui, Yaofeng Chen*, Maxim V. Borzov Dalton Trans. 2010, 39, 6886. (Invited for the themed issue entitled “New Horizons in Organo-f-element Chemistry”) 5. Synthesis, and Structural Characterization of Solvent-free Divalent Ytterbium Bis(boratabenzene) and (Cyclopentadienyl)(Boratabenzene) Complexes. Peng Cui, Yaofeng Chen*, Qiang Zhang, Guangyu Li, Wei Xia J. Organomet. Chem. 2010, 695, 2713. (Invited for the special issue of Organ-f-element Chemistry at Pacifichem 2010) 6. An Efficient Titanium Catalyst for Enantioselective Cyanation of Aldehydes: Cooperative Catalysis. Zhi-Peng Zhang, Zheng Wang, Ru-Zhou Zhang, Kui-Ling Ding* Angew. Chem. Int. Ed. 2010, 49, 6746-6750 7. Directed Orthogonal Self-Assembly of Homochiral Coordination Polymers for Heterogeneous Enantioselective Hydrogenation. Li-Ting Yu, Zheng Wang, Jiang Wu, Shu-Jiang Tu, Kui-Ling Ding* Angew. Chem. Int. Ed. 2010, 49, 3627-3630. 22 8. Enantioselective Ring Opening Reaction of meso-Epoxides with Aromatic and Aliphatic Amines Catalyzed by Magnesium Complexes of BINOL Derivatives. Hong-Li Bao, Jiang Wu, Hong-Ji Li, Zheng Wang, Tian-Pa You, Kui-Ling Ding* Eur. J. Org. Chem. 2010, 6722–6726. 9. Charge-Transfer Effect on Chiral Phosphoric Acid Catalyzed Asymmetric Baeyer-Villiger Oxidation of 3-Substituted Cyclobutanones Using 30% Aqueous H2O2 as the Oxidant, Sen-Miao Xu, Zheng Wang, Xu-Mu Zhang, Kui-Ling Ding* Chinese J. Chem. 2010, 28, 1731-1735. 10. 螺[4, 4]-1, 6-壬二烯骨架手性双膦配体的合成, 韩召斌，王正，张绪穆，丁奎 岭* 中国科学：化学, 2010, 40, 950-955. 11. Synthesis of a new type of P, N-ligand with a spiro skeleton for Ir-catalyzed asymmetric hydrogenations. Zhao-Bin Han, Zheng Wang, Xu-Mu Zhang, Kui-Ling Ding* Tetrahedron: Asymmetry. 2010, 21, 1529–1533. 12. 手性自负载催化剂研究新进展. 汪海明、王正、丁奎岭* 化学进展, 2010, 22, 1471-1481. 13. Synthesis of novel chiral bisoxazoline ligands with a Spiro[4, 4]-1, 6-nonadiene skeleton. Zhao-Bin Han, Zheng Wang, Xu-Mu Zhang, Kui-Ling Ding* Chinese Sci. Bull. 2010, 55, 2840-2846. 14. Mechanistic Investigation of Chiral Phosphoric Acid Catalyzed Asymmetric Baeyer–Villiger Reaction of 3-Substituted Cyclobutanones with H2O2 as the Oxidant. Sen-Miao Xu, Zheng Wang, Yu-Xue Li*, Xu-Mu Zhang, Hai-Ming Wang, Kui-Ling Ding* Chem. Eur. J. 2010, 16, 3021-3035. 15. Highly enantioselective hydrogenation of alpha-aryl-beta-substituted acrylic acids catalyzed by Ir-SpinPHOX . Yi Zhang, Zhao-Bin Han, Fu-Ying Li, Kui-Ling Ding*, Ao Zhang*. Chem. Commun. 2010, 46, 156-158. 16. Palladium-Catalyzed Asymmetric Addition of Diarylphosphines to Enones toward the Synthesis of Chiral Phosphines ， Feng. J.-J.; Chen. X.-F.; Shi, M.; Duan, W.-L.* J. Am. Chem. Soc. 2010, 132, 5562-5563. 17. Highly Enantioselective Iridium-Catalyzed Hydrogenation of Trisubstituted Olefins, α, β-Unsaturated Ketones and Imines with Chiral Benzylic Substituted P, 23 N-Ligands. Wei-Jing Lu, Yun-Wei Chen and Xue-Long Hou* Adv. Synth. Catal. 2010, 352, 103-107. 18. Highly Enantioselective Recognition of Structurally Diverse Hydroxycarboxylic Acids by a Fluorescent Sensor. Hai-Lin Liu, Di Chen, Xue-Long Hou,* Michal Sabat, and Lin Pu* Angew. Chem. Int. Ed. 2010, 49, 602-606. 19. Diastereo- and Enantioselective Synthesis of α, -Diaminobutyric Acid Derivatives via Cu-Catalyzed Asymmetric Michael Reaction Qing Li, Chang-Hua Ding, Xue-Long Hou* and Li-Xin Dai Org. Lett. 2010, 12, 1080-1083. 20. Ag-Catalyzed Diastereo- and Enantio-selective Synthesis of β-Substituted Tryptophans from Sulfonylindole. Bao-Hui Zheng, Chang-Hua Ding, Xue-Long Hou* and Li-Xin Dai Org. Lett. 2010, 12, 1688-1691 21. Palladium-Catalyzed Regio- and Enantio-selective Allylic Substitution Reaction of Monosubstituted Allyl Substrates with Benzyl Alcohols. Ping Fang, Chang-Hua Ding, Xue-Long Hou* and Li-Xin Dai Tetrahedron: Asymmetry 2010, 21, 1176-1178 22. Development of Benzylic Substituted Ligands for Asymmetric Catalysis (Accounts invited). Chang-Hua Ding and Xue-Long Hou* Bull. Chem. Soc. Jpn 2010, 83, 992-1003. 23. Cu-Catalyzed Asymmetric Michael Addition of Glycine Derivatives to α, β-Unsaturated Malonates. Xue-Long Hou*, Qing Li, Jun Yao and Li-Xin Dai Chinese J. Chem. 2010, 28, 1761-1764 24. Highly Enantioselective Fluorescent Recognition of Serine and Other Amino Acid Derivatives. Hai-Lin Liu, Hu-Ping Zhu, Xue-Long Hou,* Lin Pu* Org. Lett. 2010, 12, 4172-4175 25. Palladium Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation of Acylsilanes with Monosubstituted Allyl Substrates. Jian-Ping Chen, Chang-Hua Ding, Wei Liu, Xue-Long Hou* and Li-Xin Dai J. Am. Chem. Soc. 2010, 132, 15493-15495 26. Palladium-catalyzed allylic C-H bond functionalization of olefins. Guosheng 24 Liu*, Yichen Wu, Top Curr. Chem. 2010, 292, 195-209. 27. Palladium-catalyzed intermolecular amimofluorination of styrenes, Shuifa Qiu, Tao Xu, Juan Zhou, Yinlong Guo, Guosheng Liu*, J. Am. Chem. Soc. 2010, 132, 2856-2857. 28. Scope and mechanism of allylic C-H amination of terminal alkenes by the palladium/PhI(OPiv)2 catalyst system: insights into the effect of naphthoquinone. Guoyin Yin, Yichen Wu, Guosheng Liu*, J. Am. Chem. Soc., 2010, 132, 11978-11987. 29. Palladium-catalyzed inter- and intramolecular hydroamination of styrenes coupled with alcohol oxidation using N-fluorobenzene- sulfonimide as the oxidant. Tao Xu, Shuifa Qiu, Guosheng Liu*, J. Organomet. Chem., 2011, 696, 46-49. 30. Gold-Catalyzed Cyclization of Alkynylaziridines as An Efficient Approach Toward Functionalized N-Phth Pyrroles, Xiangwei Du, Xin Xie and Yuanhong Liu*, J Org. Chem, 2010, 75, 510-513. 31. 过渡金属催化的呋喃合成。卢玉华，宋飞杰，贾学顺*，刘元红*，化学进展， 2010, 22, 58-70. 32. Highly Stereoselective Synthesis of Trisubstituted cis-[3]Cumulenols from Alkynylated Oxatitanacycles in the Presence of Lewis acids ， Jingjin Chen and Yuanhong Liu*, Organometallics 2010, 29, 505–508. 33. Gold-Catalyzed Benzannulation of 3-Alkoxy-1,5-enynes: Access to Functionalized BenzenesGuijie Li and Yuanhong Liu*, J. Org. Chem. 2010, 75, 2903–2909. 34. Gold-Catalyzed Intramolecular Indole/Alkyne Cyclization Cascades through a Heterolytic Fragmentation: 1, 5-Indole Migration and Allenylation, Guijie Li and Yuanhong Liu*, J. Org. Chem. 2010, 75, 3526–3528. 35. Aldehyde Addition to Zirconacyclocumulenes:Stereoselective 1, Synthesis 3-Butadiyne-Derived of cis-[3]Cumulenols. Xiaoping Fu, Yuanhong Liu* and Yuxue Li*, Organometallics 2010, 29, 3012–3018. 25 36. Stereoselective synthesis of enynones via base-catalyzed isomerization of 1, 5-disubstituted-2, 4-pentadiynyl silyl ethers or their alcohol derivatives. Jingjin Chen, Guoqin Fan and Yuanhong Liu*, Org. Biomol. Chem., 2010, 8, 4806–4810. 37. Control of Chemoselectivity by Counteranions of Cationic Palladium Complexes: A Convenient Enantioselective Synthesis of Dihydrocoumarins Han, X.; Lu, X.* Org. Lett. 2010, 12, 108-111. Synfacts 2010, 287. 38. Cationic Pd(II)/Bipyridine-Catalyzed Conjugate Addition of Arylboronic Acids to- Disubstituted Enones: Construction of Quaternary Carbon Centers Lin, S.; Lu, X.* Org. Lett. 2010, 12, 2536-2539. 39. Cationic Pd(II)-Catalyzed Tandem Reaction of 2-Arylethynylanilines and Aldehydes: An Efficient Synthesis of Substituted 3-Hydroxymethyl Indoles Han, X.; Lu, X.* Org. Lett. 2010, 12, 3336-3339. 40. Pd(II)-Catalyzed Annulation of N-Benzyl-N-Aroylmethyl-2-Alkynamides with Arylboronic acids: An Efficient Synthesis of Highly Substituted α-Alkylidene-βHydroxy-γ-Lactams Wang, H.; Han, X.*; Lu, X.* Tetrahedron 2010, 66, 9129-9134. 41. Synthesis of polyfunctionalized vinyl cyclopropanes via the NaI-catalyzed ringopening cyclization of doubly activated cyclopropenes with 1,1bis(phenylsulfonyl) ethylene. Jie Chen , Ning Xin , Shengming Ma* Tetrahedron Letters 2009, 50, 3175-3177. 42. Ligand Effects on the Pd-Catalyzed Cross-Coupling Reaction of 3-Iodoalk-2-enoates with Propargyl/1, 2-Allenylic Metallic Species: An Efficient Regiodivergent Synthesis of 2, 4, 5-TrienoatesJinbo Zhao, Yihua Yu and Shengming Ma* Chem. Eur. J. 2010, 16, 74-80. 43. Carbon-Carbon Double-Bond Isomerization and Diels-Alder Reaction of Dimethyl 5-Methylene-4-isopropylidene-2-cycloheptene-1,1-dicarboxylate with Dienophiles Ping Lu, Jinqiang Kuang, Shengming Ma* Synlett 2010, 227-230. 44. Palladium-catalyzed synthesis of 1, 3, 4-alkatrien-2-yldihydrofurans from 2, 3llenylacetylacetates and propargylic carbonates and their application to synthesize polysubstituted dihydrofurylcyclopentenones Wei Shu, Shengming Ma* 26 Tetrahedron 2010, 66, 2869-2874. 45. Palladium(II)-Catalyzed Highly Stereoselective Sandwich-type Triple Cyclization Reaction of 1, 5-Bisallenes and 2, 3-Allenoic Acids. Xiongdong Lian and Shengming Ma* Chem. Eur. J. 2010, 16, 7960-7964. 46. Catalyst-Controlled Ring-Opening Cycloisomerization Reactions of Cyclopropenyl Carboxylates for Highly Regioselective Synthesis of Different 2-Alkoxyfurans. Jie Chen and Shengming Ma* Chem. Asian J. 2010, 5, 2415 – 2421. 47. The [2＋2]-Cycloaddition Reaction of Bisallenes: A Dramatic Substituent Effect. Ping Lu and Shengming Ma* Chin. J. Chem. 2010, 28, 1600-1606. 48. LDA-Mediated Domino Carbolithiation Reactions of Vinylidenecyclopropanes with But-3-yn-2-one and 1-Phenylprop-2-yn-1-one. Bei-Li Lu, Jian-Mei Lu and Min Shi* Tetrahedron Lett. 2010 51, 321-324. 49. Rhodium(I)-Catalyzed Intramolecular Ene Reaction of Vinylidenecyclopropanes and Alkenes for the Formation of Bicyclo[5.1.0]octylenes. Wei Li, Wei Yuan, Min Shi* Erik Hernandez and Guigen Li, Org. Lett. 2010, 12, 64-67. 50. A Gold(I)-catalyzed Tandem C-H and C-C Activation (Cleavage). Min Jiang, Le-Ping Liu, Min Shi* and Yuxue Li,* Org. Lett. 2010, 12, 116-119. 51. Yb(OTf)3-Catalyzed Construction of Indole Derivatives through Formal [3+3] Cycloaddition of 1,1-Vinylidenecyclopropanediesters with Nitrones. Lei Wu and Min Shi* Chem. Eur. J. 2010, 16, 1149-1152. 52. A Synthetic Protocol of trans-Substituted Cyclopentenes via the Ring-opening Rearrangement of MCP Alkenyl Derivatives. Xiang-Ying Tang and Min Shi* J. Org. Chem. 2010, 75, 902-905. 53. Gold(I) and Yb(OTf)3 Cocatalyzed Rearrangements of Epoxy Alkynes: Observation of Transfer of Carbonyl Group in a 5-Membered Carbocycle. Lun-Zhi Dai and Min Shi* Chem. Eur. J. 2010, 16, 2496-2513. 54. Au/Ag-Catalyzed Intramolecular Ring Opening of Vinylidene-cyclopropanes (VDCPs): an easy Access to Functional Tetrahydropyrans.Wei Li, Wei Yuan, Surech Pindi, Min Shi* and Guigen Li* Org. Lett. 2010, 12, 920-923. 27 55. Catalytic Asymmetric Addition of Arylboronic Acids to N-Boc Imines Generated in Situ Using C2-Symmetric Cationic N-Heterocyclic Carbenes (NHCs) Pd2+ Diaquo Complexes. Zhen Liu and Min Shi* Tetrahedron 2010, 66, 2619-2623. 56. 1, 3-Dipolar Cycloaddition Reactions of Vinylidenecyclopropane-diesters with Aromatic Diazomethanes Generated in Situ. Lei Wu and Min Shi* J. Org. Chem. 2010, 75, 2296-2301. 57. Acetoxylation and Hydroxylation of Diarylmethylenecycloalkanes via Radical Approach. Min Jiang, Yin Wei* and Min Shi* J. Org. Chem. 2010, 75, 2528-2533. 58. BF3.Et2O-catalyzed Intermolecular Reactions of Vinylidenecyclopropanes with Bis(p-alkoxyphenyl)methanols, a Novel Cationic 1, 4-Aryl Migration Process. Lei Wu, Min Shi* and Yuxue Li* Chem. Eur. J. 2010, 16, 5163-5172. 59. Lewis acid catalyzed reactions of methylenecyclopropylcarbinols with acetals for the construction of 3-oxabicyclo[3.1.0]hexane derivatives. Li-Xiong Shao and Min Shi* Tetrahedron 2010, 66, 4551-4554. 60. Lewis acid-catalyzed Cycloaddition of Methylenecyclopropanes with Salicylaldehydes. Min Jiang and Min Shi* Org. Lett. 2010, 12, 2606-2609. 61. Palladium Acetate-Catalyzed Oxidative Aromatization of Methylenecyclopropanes. Min Jiang, Yin Wei and Min Shi* Eur. J. Org. Chem. 2010, 3307-3311. 62. Privileged Chiral Catalysts in Asymmetric Morita-Baylis-Hillman/aza-Morita-Baylis-Hillman Reaction. Yin Wei & Min Shi* 科学通报, 2010, 1699-1711. 63. Catalytic Enantioselective Addition of Cyclic β-Ketoesters with Activated Olefins and N-Boc Imines Using Chiral C2-Symmetric Cationic N-Heterocyclic Carbenes (NHCs) Pd2+ Diaqua Complexes. Zhen Liu and Min Shi* Organometallics 2010, 29, 2831-2834. 64. Asymmetric Aza-Morita-Baylis-Hillman Reaction of Alkyl Vinyl Ketones with N-Protected Imines or In Situ Generated N-Protected Imines. Xiao-Yang Guan, Yin Wei* and Min Shi* Eur. J. Org. Chem. 2010, 4098-4105. 28 65. HOTf-catalyzed Intramolecular Rearrangement of MCP Aryl- and Alkylalcohols. Xiang-Ying Tang and Min Shi* Eur. J. Org. Chem. 2010, 4106-4110. 66. Multifunctional Chiral Phosphine Organocatalysts in Catalytic Asymmetric Morita-Baylis-Hillman and Related Reactions. Yin Wei and Min Shi* Acc. Chem. Res. 2010, 43, 1005-1018. 67. Reactions of Vinylidenecyclopropanes with Xanthydrol and Xanthene. Wei Yuan and Min Shi* Tetrahedron 2010, 66, 7104-7111. 68. Gold(I) and Brønsted Acid Catalyzed Different Intramolecular Rearrangements of Vinylidenecyclopropanes. Bei-Li Lu, Yin Wei* and Min Shi* Chem. Eur. J. 2010, 16, 10975-10979. 69. C(Sp3)-C(Sp3) Bond Breaking of Methylenecyclopropanes Involving in AuI/AuIII Catalytic Cycle. Di-Han Zhang, Lun-Zhi Dai and Min Shi* Eur. J. Org. Chem. 2010, 5454-5459. 70. Chemistry of Vinylidenecyclopropanes. Min Shi*, Li-Xiong Shao, Jian-Mei Lu, Yin Wei, Kazuhiko Mizuno* Hajime Maeda, Chem. Rev. 2010, 110, 5883-5913. 71. Ring-opening Reaction of Methylenecyclopropanes Derived from Methylenecyclopropyl Aldehydes through Cope Rearrangement. Xiang-Ying Tang, Yin Wei and Min Shi* Eur. J. Org. Chem. 2010, 6038-6043. 72. Phosphine-catalyzed Tandem Reaction of Allenoates with Nitroalkenes. Xiao-Yang Guan, Yin Wei and Min Shi* Org. Lett. 2010, 12, 5024-5027. 73. Palladium-Catalyzed Reactions of 3-Substituted Methylenecyclopropanes.Li-Xiong Shao, Jia Li, Bao-Yu Wang and Min Shi* Eur. J. Org. Chem. 2010, 6448-6452. 74. Thermally-induced electrocyclic reaction of methylenecyclopropane (MCP) methylene diketone derivatives: a facile method for the synthesis of spiro[2.5]octa-3, 5-dienes. Xiang-Ying Tang, Yin Wei* and Min Shi* Org. Lett. 2010, 12, 5120-5123. 75. Asymmetric Nazarov Reaction Catalyzed by Chiral Tris(oxazoline)/Copper(II), Peng Cao, Chao Deng, You-Yun Zhou, Xiu-Li Sun, Jun-Cheng Zheng, Zuowei Xie, Yong Tang* Angew. Chem. Int. Ed. 2010, 49, 1–5. 29 76. Iron carbenoid-mediated ylide reactions. Xiu-Li Sun, Jun-Cheng Zheng, Yong Tang* Pure Appl. Chem. 2010, 82, 625-634. 77. A Tandem Intramolecular Michael Addition/Wittig Reaction for the Synthesis of Fused Cyclohexadiene Derivatives. Qing-Gang Wang, Jun-Cheng Zheng, Xiu-Li Sun, Yong Tang* Chin. J. Chem. 2010, 28, 1618-1622. 78. Catalytic Asymmetric Intramolecular Cascade Reaction for the Construction of Functionalized Benzobicyclo [4.3.0] Skeletons. Remote Control of Enantioselectivity. Qing-Gang Wang, Shou-Fei Zhu, Long-Wu Ye, Chang-Yue Zhou, Xiu-Li Sun, Yong Tang*, Qi-Lin Zhou* Adv. Synth. Catal. 2010, 352, 1914-1919. 79. Highly Selective Ylide-Initiated Michael Addition/Cyclization Reaction for Synthesis of Cyclohexadiene Epoxide and Vinylcyclopropane Derivatives. Ben-Hu Zhu, Rui Zhou, Jun-Cheng Zheng, Xian-Ming Deng, Xiu-Li Sun, Qi Shen*, Yong Tang* J. Org. Chem. 2010, 75, 3454-3457. 80. Pyrrolidine-ureas as bifunctional organocatalysts for asymmetric Michael addition of ketone to nitroalkenes: unexpected hydrogen bonding effect. Xiao-Yu Cao, Jun-Cheng Zheng, Yu-Xue Li*, Zhen-Cao Shu, Xiu-Li Sun, Bi-Qin Wang*, Yong Tang*, Tetrahedron 2010, 66, 9703-9707. 81. One-Pot Highly Diastereoselective Synthesis of cis-Vinylaziridines via the Sulfur Ylide-Mediated Aziridination and Palladium(0)-Catalyzed Isomerization. Ben-Hu Zhu, Jun-Cheng Zheng, Chang-Bin Yu, Xiu-Li Sun, Yong-Gui Zhou, Qi Shen*, Yong Tang*, Org. Lett., 2010, 12, 504-507. 82. Enantioselective Synthesis of Unsymmetrical Triarylmethanes by Chiral Brønsted Acids. Sun, F.-L.; Zheng, X.-J.; Gu, Q.; He, Q.-L.; You, S.-L.* Eur. J. Org. Chem. 2010, 47-50. 83. Enantioselective Synthesis of 2-Aryl-2,3-dihydro-4-quinolones by Chiral Brønsted Acid Catalyzed Intramolecular Aza-Michael Addition Reaction. Feng, Z.; Xu, Q.-L.; Dai, L.-X.; You, S.-L.* Heterocycles 2010, 80, 765-771. (Invited paper for Professor Akira Suzuki’s Special Issue on the occasion of his 80th birthday). 30 84. Asymmetric Intramolecular Oxa-Michael Addition of Activated α,β-Unsaturated Ketones by Chiral N-Triflyl Phosphoramide. Feng, Z.; Zeng, M.; Xu, Q.-L.; You, S.-L.* Chin. Sci. Bull. 2010, 55, 1723-1725. (Invited paper for Special Issue on Oranocatalysis). 85. Enantioselective Synthesis of 2,3-Dihydro-1H-benzo[b]azepines via Ir-Catalyzed Tandem Allylic Vinylation/Amination Reaction. He, H.; Liu, W.-B.; Dai, L.-X.; You, S.-L.* Angew. Chem. Int. Ed. 2010, 49, 1496-1499. 86. Tandem Ir-Catalyzed Allylic Substitution Reaction of Allyl Sulfinates and Isomerization. Xu, Q.-L.; Dai, L.-X., You, S.-L.* Org. Lett. 2010, 12, 800-803. 87. A theoretical investigation into chiral phosphoric acid-catalyzed asymmetric Friedel-Crafts reactions of nitroolefins and 4,7-dihydroindoles: reactivity and enantioselectivity. Zheng, C.; Sheng, Y.-F.; Li, Y.-X.*; You, S.-L.* Tetrahedron 2010, 66, 2875-2880. 88. Asymmetric Friedel-Crafts Alkylation of Indoles: Enantio- and Regioselective Control. Zeng, M.; You, S.-L.* Synlett 2010, 1289-1301. (Account) 89. Desymmetrization of Cyclohexadienones via Brønsted Acid-Catalyzed Enantioselective Oxo-Michael Reaction. Gu, Q.; Rong, Z.-Q.; Zheng, C.; You, S.-L.* J. Am. Chem. Soc. 2010, 132, 4056-4057. 90. Enantioselective Synthesis of 3-Azabicyclo[4.1.0]heptenes and 3-Azabicyclo[3.2.0]heptenes via Ir-Catalyzed Asymmetric Allylic Amination of N-Tosyl Propynylamine and Pt-Catalyzed Cycloisomerization Reaction. Xia, J.-B.; Liu, W.-B.; Wang, T.-M.; You, S.-L.* Chem. Eur. J. 2010, 16, 6442-6446. 91. One-Pot Palladium-Catalyzed Allylic Alkylation of Phosphorus Ylides and Wittig Reaction. Liu, W.-B.; He, H.; Dai, L.-X.; You, S.-L.* Chem. Eur. J. 2010, 16, 7376-7379. 92. Intramolecular Michael Addition Reaction for the Synthesis of Benzylbutyrolactones. He, H.; Dai, L.-X.; You, S.-L.* Org. Biomol. Chem. 2010, 3207-3210. 31 93. Ir-Catalyzed Enantioselective Allylic Substitution of O-Allyl Carbamothioates. Xu, Q.-L.; Liu, W.-B.; Dai, L.-X.; You, S.-L.* J. Org. Chem. 2010, 75, 4615-4618. 94. Enantioselective Palladium-Catalyzed Direct Alkylation and Olefination Reaction of Simple Arenes Peng, H. M.; Dai, L.-X.; You, S.-L.* Angew. Chem. Int. Ed. 2010, 49, 5826-5828. (Highlights) 95. Enantioselective Construction of Spiroindolenines by Ir-Catalyzed Allylic Alkylation Reactions. Wu, Q.-F.; He, H.; Liu, W.-B.; You, S.-L.* J. Am. Chem. Soc. 2010, 132, 11418-11419. 96. Enantioselective Intramolecular Aza-Michael Additions of Indoles Catalyzed by Chiral Phosphoric Acids. Cai, Q.; Zheng, C.; You, S.-L.* Angew. Chem. Int. Ed. 2010, 49, 8666-8669. 97. Synthesis of Cyclopropane-containing Building Blocks via Ir-Catalyzed Enantioselective Allylic Substitution Reaction. Xia, J.-B.; Zhuo, C.-X.; You, S.-L.* Chin. J. Chem. 2010, 28, 1525-1528. (Invited paper for celebrating the 60th Anniversary of SIOC). 32 以下论文重点实验室为作者第二单位 1. Polymerization of Naturally Renewable Methylene Butyrolactones by Half-Sandwich Indenyl Rare Earth Metal Dialkyls with Exceptional Activity. Yangjian Hu, Xin Xu, Yuetao Zhang, Yaofeng Chen*, Eugene Y.-X. Chen* Macromolecules 2010, 43, 9328. 2. Single, Double and Triple Deprotonation of a β-Diketimine Bearing Pendant Pyridyl Group and the Corresponding Rare-earth Metal Complexes. Xin Xu, Yaofeng Chen*, Gang Zou, * Jie Sun Dalton Trans. 2010, 39, 3952. 3. Magnesium, Zinc, and Calcium Complexes Based on Tridentate Nitrogen Ligands: Syntheses, Structures, and Catalytic activities to the Ring Opening Polymerization of rac-Lactide. Xin Xu, Yaofeng Chen*, Gang Zou,* Zhi Ma, Guangyu Li J. Organomet. Chem. 2010, 695, 2713. 4. New low bandgap molecules based on ethylene-separated benzothiadiazoles: synthesis and bandgap comparison, Yanmei Liu, Hua Lai, Hongliang Zhong, Erjian Xu, Junping Du, Yuxue Li *, Qiang Fang *, Tetrahedron Letters 2010, 51, 4462-4465. 5. One-Pot Synthesis of 1, 3-Disubstituted Allenes from 1-Alkynes, Aldehydes, and Morpholine. Jinqiang Kuang and Shengming Ma* J. Am. Chem. Soc. 2010, 132, 1786-1787. 33 二、客座人员论文目录（按通讯作者姓氏首字母排序） 1. Cycloaddition of Nitrones with Arynes Generated from Benzobisoxadisilole or 2, 3- Naphthoxadisilole. Kaicheng Wu, Yali Chen*, Yibei Lin, Weiguo Cao, Min Zhang, Jie Chen, Albert W. M. Lee Tetrahedron 2010, 66(1), 578-582. 2. Palladium-Catalyzed Cross-Coupling of 2,3-Naphthoxadisilole with Aryl Halides. Han Ding, Yali Chen*, Weiguo Cao, Kaicheng Wu, Jie Chen, Albert W. M. Lee Synth. Commun. 2010, 40(7), 984-991. 3. One-Pot Approach for Stereoselective Construction of Spirocyclopropyl Oxindoles from Isatins and Arsonium Salts. Haigang Yu, Ying Liu, Hui Zhang, Jie Che , Hongmei Deng, Min Shao, Zhongjiao Ren, Weiguo Cao* Tetrahedron 2010, 66(14), 2598-2601. 4. Highly Stereoselective Synthesis of trans-4-Trifluoromethylsulfonyl-2,3dihydrofurans from Arsonium Ylides and (E)-α-Trifluoromethylsulfonyl-α, β-unsaturated ketones. Zhenqi Chen, Jiaping Zhang, Jie Chen, Hongmei Deng, Min Shao, Hui Zhang, Weiguo Cao* Tetrahedron 2010, 66(32), 6181-6187. 5. A New Stereoselective Approach for the Synthesis of Substituted 3Cyclopropylmethylene-1, 3-dihydro-indol-2-one via the Condensation Reaction of cis-1-Aryl-2-benzoyl-3,3-dicyanocyclopropanes with Oxindole in Water. Dong Zhou, Haigang Yu, Ying Liu, Jie Chen, Hongmei Deng, Min Shao, Zhongjiao Ren, Weiguo Cao* Tetrahedron Lett. 2010, 51(41), 5473-5475. 6. Stereoselective Synthesis of Cyclopropyl Indolyl Ketones with Indolylidene and Arsonium Ylide. Dong Zhou, Zhongjiao Ren, Weiguo Cao*, Jie Chen, Ying Liu and Hongmei Deng J. Heterocyclic Chem. 2010, 47(5), 1116-1122. 7. 含三氟甲基的螺[环丙烷-1,3-吲哚啉]-2-酮和螺[环丙烷-1,2-茚]-1,3二酮衍生物的高立体选择性简易合成, 杨树新 陈杰 吴小余 邓红梅 邵敏 张慧 曹卫国* 有机化学 8. 2010, 30(10), 1521-1528. Spectroscopic and Luminescence Studies on Square-Planar Platinum(II) 34 Complexes with Anionic Tridentate 3-Bis(2-pyridylimino)-isoindoline Derivatives, Hui-Min Wen, Yu-Hui Wu, Yang Fan, Li-Yi Zhang, Chang-Neng Chen*, Zhong-Ning Chen* Inorg. Chem. 2010, 49, 2210–2221. 9. A sensitive phosphorescent thiol chemosensor based on an iridium(III) complex with , -unsaturated ketone functionalized 2,2’-bipyridyl ligand, Na Zhao, Yu-Hui Wu, Lin-Xi Shi, Qi-Pu Lina and Zhong-Ning Chen*, Dalton Trans. 2010, 39, 8288–8295. 10. The Chemistry of Open-cage Fullerene, Hydroxylamine Mediated Hole-closing and -opening Reactions. Jianxin Zhang, Dazhi Yang, Zuo Xiao, Liangbing Gan*, Chin. J. of Chem. 2010, 28 (9), 1673-1677. （庆祝上海有机所六十周 年专刊） 11. Fullerenyl azide: synthesis and reactivity. Zhongping Jiang, Zuo Xiao, Gaihong Zhang, Liangbing Gan*, Dian Wang, Wenxiong Zhang*, Tetrahedron Lett. 2010, 51 (2), 415-417. 12. Synthesis and Reactivity of 2H-Pyran Moiety in [60]Fullerene Cage Skeleton, Dazhi Yang, Lijun Shi, Huan Huang, Jianxin Zhang, Liangbing Gan* J. Org. Chem. 2010, 75, 4567-4573. 13. Carving two adjacent holes on [60]fullerene through two consecutive epoxide to diol to dione transformations.Zuo Xiao, Jiayao Yao, Yuming Yu, Zhenshan Jia, Liangbing Gan* Chem. Commun. 2010, 46, 8365–8367. 14. Facile Synthesis Three-Component of Tetrahydro-1H-isoindolones Copper-Catalyzed via a Sequential Coupling/Propargyl-Allenyl Isomerization/[4 + 2] Cyclization Reaction, Cao J; Huang X*, Org. Lett., 2010, 5048-5051. 15. Cascade Nucleophilic Addition−Cyclic Michael Addition of Arynes and Phenols/Anilines Bearing Ortho α, β-Unsaturated Groups: Facile Synthesis of 9-Functionalized Xanthenes/Acridines, Huang X*; Zhang T-X, J. Org. Chem., 2010, 506-509. 16. Facile and Efficient Synthesis of Hydrophenanthren-1(2H)-ones and Naphtho [2,1-c]furan-3(1H)-ones by a Palladium-Catalyzed Aryne Annulation Strategy, 35 Huang X*; Sha F; Tong J-W, Adv. Synth. & Catal., 2010, 352, 379-385. 17. Chong Qin, and Ning Jiao*, Iron-Facilitated Direct Oxidative C−H Transformation of Allylarenes or Alkenes to Alkenyl Nitriles. J. Am. Chem. Soc. 2010, 132, 15893-15895. 18. Wang Zhou, Jiaojiao Xu, Liangren Zhang, and Ning Jiao*, An Efficient Transformation form Benzyl or Allyl Halides to Aryl and Alkenyl Nitriles. Org. Lett. 2010, 12, 2888-2891. 19. Zhuangzhi Shi, Bo Zhang, Yuxin Cui, and Ning Jiao*, Palladium-Catalyzed Ring-expansion Reaction of Indoles with Alkynes: From Indoles to Tetrahydroquinoline Derivatives Under Mild Conditions. Angew. Chem. Int. Ed. 2010, 49, 4036-4041. 20. Chun Zhang, and Ning Jiao*, Dioxygen Activation at Ambient Conditions: Cu-catalyzed Oxidative Amidation-Diketonization of Terminal Alkynes Leading to α-Ketoamides. J. Am. Chem. Soc. 2010, 132, 28-29. 21. Shengtao Ding, Zhuangzhi Shi, and Ning Jiao*, Pd(II)-Catalyzed Synthesis of Carbolines by Iminoannulation of Internal Alkynes via Direct C-H Bond Cleavage Using Dioxygen as Oxidant. Org. Lett. 2010, 12, 1540-1543. 22. Construction of [Ag2X2]-based complexes from reactions of Ag(I) salts with N-diphenylphosphanylmethyl-4-aminopyridine: isolation, structures, and luminescent properties, N. –Y. Li, Z. –G. Ren, D. Liu, R. –X. Yuan, L. –P. Wei, L. Zhang, H. –X. Li, J. –P. Lang*, Dalton Trans., 2010, 39, 4213-4222. 23. Cracking the framework of bulk CuCN with flexible bipyrazolyl-based ligands to assemble [CuCN]n-based coordination polymers, L. –L. Li, L. –L. Liu, A. –X. Zheng, Y. –J. Chang, M. Dai, Z. –G. Ren, H. –X. Li, J. –P. Lang*, Dalton Trans., 2010, 39, 7659-7665. 24. How Does a Non-C3-Symmetry Guest Molecule Fit into a C3-Symmetry Host Cavity? W. –H. Zhang, D. Liu, H. –X. Li, Z. –G. Ren, Y. Zhang, J. P. Lang*, Cryst. Growth Des., 2010, 10, 3-6. 25. Solvent effects on the assembly of Ni/Na coordination polymers from reactions of [Ni(acac)2(H2O)2] with sodium dicyanamide, X. Chen, S. –B. Qiao, D. Liu, J. 36 –P. Lang*, Y. Zhang, C. Xu, S. –L. Ma*, CrystEngComm, 2010, 12, 1610-1616. 26. pH-Dependent Solvothermal Formation of Two Different 3D Multiple Interpenetrating Nets from the Same Components, D. Liu, Z. –G. Ren, H. –X. Li, Y. Chen, J. Wang, Y. Zhang, J. –P. Lang*, CrystEngComm, 2010, 12, 1912-1919. 27. How do substituent groups in the 5-position of 1,3-benzenedicarboxylate affect the construction of supramolecular frameworks? D. Liu, H. –X. Li, L. –L. Liu, H. –M. Wang, N. –Y. Li, Z. –G. Ren, J. –P. Lang*, CrystEngComm., 2010, 12, 3708-3716. 28. Organocatalysis in Cross-Coupling: DMEDA-Catalyzed Direct C-H Arylation of Unactivated Benzene, Liu, Wei; Cao, Hao; Zhang, Hua; Zhang, Heng; Chung, Kin Ho; He, Chuan; Wang, Haibo; Kwong, Fuk Yee; Lei, Aiwen J. Am. Chem. Soc. 2010, 132, 16737-16740. 29. Iron-Catalyzed Direct Arylation of Unactivated Arenes with Aryl Halides, Liu, Wei; Cao, Hao; Lei, Aiwen Angew. Chem., Int. Ed. 2010, 49, 2004-2008. 30. Transmetalation is the Rate-Limiting Step: Quantitative Kinetic Investigation of Nickel-Catalyzed Oxidative Coupling of Arylzinc Reagents, Jin, Liqun; Xin, Jie; Huang, Zhiliang; He, Jun; Lei, Aiwen J. Am. Chem. Soc. 2010, 132, 9607-9609. 31. Heterobimetallic complexes of lanthanide and lithium metals with dianionic guanidinate ligands: Syntheses, structures and catalytic activity for amidation of aldehydes with amines. Cunwei Qian , Xingmin Zhang , Yong Zhang , Qi Shen* J. Organomet. Chem. 2010, 695, 747–752. 32. A Comparative Study on the Reactivity of Tris-β-Diketiminate Ytterbium Complexes: Steric Effect of β-Diketiminato Ligands. Rui Jiao, Mingqiang Xue, Xiaodong Shen, Yong Zhang, Yingming Yao, and Qi Shen* Eur. J. Inorg. Chem. 2010, 2523–2529. 33. Quinoline Ring C-H Bond Activation in Bis(3,5-di-tert-butylsalicylidene)-8aminoquinoline Bis(trimethylsilyl)amido Lanthanide Complexes. Fubin Han, 37 Bangyu Li, Yong Zhang, Yaorong Wang, and Qi Shen* Organometallics 2010, 29, 3467-3470. 34. Heterobimetallic clusters of Na8Ln(OtBu)10(OH) as homogeneous catalysts for amidation of aldehydes with amines CAI ChengYi , LI Lan , XU Fan & SHEN Qi Chinese Sci. Bull. 2010, 55, 3641–3643. 35. Organopalladium(IV) chemistry. Ling-Min Xu, Bi-Jie Li, Zhen Yang and Zhang-Jie Shi*. Chem. Soc. Rev., 2010, 39, 712-733. 36. Biaryl Construction through Kumada Coupling with Diaryl Sulfates as One-by-One Electrophiles under Mild Conditions. Bing-Tao Guan, Xin-Yu Lu, Yang Zheng, Da-Gang Yu, Tong Wu, Kunlin Li, Bi-Jie Li, and Zhang-Jie Shi*, Org. Lett. 2010, 12, 396-399. 37. Direct Application of Phenolic Salts to Nickel-Catalyzed Cross-Coupling Reactions with Aryl Grignard Reagents. Da-Gang Yu, Bi-Jie Li, Shu-Fang Zheng, Bing-Tao Guan, Bi-Qin Wang and Zhang-Jie Shi*, Angew. Chem. Int. Ed. 2010, 49, 4566-4570. 38. Oxidative Dimerization of N-Protected and Free Indole Derivatives toward 3,3´- Biindoles via Pd-catalyzed Direct C–H Transformations. Yang Li, Wen-Hua Wang, Shang-Dong Yang, Ni-Jie Li, Chun Feng, Zhang-Jie Shi*. Chem. Commun. 2010, 46, 4553. 39. An Efficient Organocatalytic Method for Constructing Biaryls through Aromatic C-H Activation. Chang-Liang Sun, Hu Li, Da-Gang Yu, Miao Yu, Xiao Zhou,Xin-Yu Lu, Kun Huang, Shu-Fang Zheng, Bi-Jie Li, Zhang-Jie Shi*. Nat. Chem. 2010, 2, 1044- 1049. 40. 基于钯催化的 C—H 选择性官能团化构建 C—C 键. 李湖, 施章杰*. 化学 进展. 2010, 22, 1414-1433. 41. LiCl-Promoted Pd(II)-Catalyzed ortho Carbonylation of N,N-Dimethylbenzylamines. Hu Li, Gui-Xin Cai, Zhang-Jie Shi*, Dalton Trans. 2010, 39, 10442-10446. 38 42. An unexpected palladium migration from vinylic sp2 carbon to allylic sp3 carbon, Bijie Li and Zhangjie Shi*, Chinese Science Bulletin, 2010, 55, 2807-2810 43. Palladium-Catalyzed C-C Bonds Formation Reactions via Selective C-H Bonds Functionalization, Hu Li and Zhangjie Shi*, Progress in Chemistry, 2010, 22, 1414-1433. 44. Nickel-Catalyzed Efficient and Practical Suzuki-Miyaura Coupling of Alkenyl and Aryl Carbamates with Aryl Boroxines, Li Xu, Bi-Jie Li*, Zhen-Hua Wu, Xing-Yu Lu, Bing-Tao Guan, Bi-Qin Wang, Ke-Qing Zhao, and Zhang-Jie Shi*, Org. Lett., 2010, 12, 884-887. 45. Ring-Opening Isomerization Based on the 3-Connecting Node: Formation of a 0-D M2L3 Cage, 1-D Loop-and-Chain, and 2-D (6, 3) Network. Qian Zhang, Jianyong Zhang, Qiong-Yan Yu, Mei Pan, and Cheng-Yong Su*, Cryst. Growth Des., 2010, 10, 4076-4084. 46. Pyridyl-substituted indenyl ruthenium complexes: Synthesis, structures, and reactivities, Chen, D.; Zhang, X.; Xu, S.; Song, H.; Wang, B.* Organometallics 2010, 29, 3418-3430. 47. Alkyne-functionalized zirconocene complexes: synthesis, structures, and reactivities, Li, M.; Song, H.; Xu, S.; Wang, B.* Organometallics 2010, 29, 6092-6096. 48. Rh(I)-catalyzed carbonylative carbocyclization of tethered ene- and yne-cyclopropenes. Changkun Li, Hang Zhang, Jiajie Feng, Yan Zhang and Jianbo Wang* Org. Lett. 2010, 12, 3082-3085. 49. Microwave-Assisted, Pd(0)-Catalyzed Cross-Coupling of Diazirines with Aryl Halides. Xia Zhao, Guojiao Wu, Chong Yan, Kui Lu, Hui Li, Yan Zhang and Jianbo Wang* Org. Lett. 2010, 12, 5580-5583. 50. InI3- or ZnI2-Catalyzed Reaction of Hydroxylated 1,5-Allenynes with Thiols: a New Access to 3,5-Disubstituted Toluene Derivatives. Jie Ma, Lingling Peng, Xiu Zhang, Zhe Zhang, Melody Campbell and Jianbo Wang* Chem. Asian J. 2010, 5 (10), 2214- 2220. 39 51. Enantioselective Synthesis of Condensed and Transannular Ring Skeletons Containing Pyrrolidine Moiety. Fanyang Mo, Fei Li, Di Qiu and Jianbo Wang* Tetrahedron, 2010, 66, 1274-1279. 52. Pd-Catalyzed Oxidative Cross-Coupling of N-Tosylhydrazones with Arylboronic Acid Xia Zhao, Jing Jing, Kui Lu, Yan Zhang and Jianbo Wang* Chem. Commun. 2010, 46, 1724-1726. 53. Catalytic [2,3]-Sigmatropic Rearrangement of Sulfur Ylide Derived from Metal Carbene. Yan Zhang and Jianbo Wang* Coord. Chem. Rev. 2010, 254, 941-953. 54. Sugar-Based Pyrrolidine as a Highly Enantioselective Organocatalyst for Asymmetric Michael Addition of Ketones to Nitrostyrenes. Lei Wang*, Jie Liu, Tao Miao, Wei Zhou, Pinhua Li, Kai Ren, and Xiuli Zhang. Adv. Synth. Catal. 2010, 352, 2571–2578. 55. Iron-catalyzed Regio- and Stereoselective Addition of Acid Chlorides to Alkynes. Bo Wang, Shihua Wang, Pinhua Li, and Lei Wang* Chem. Commun. 2010, 46(32), 5891–5893. (Highlighted by: SYNFACTS 2010, 11, 1288–1288) 56. Exploration of Amino-functionalized Ionic Liquids as Ligand and Base for Heck Reaction. Jie Liu, Hongqiang Liu and Lei Wang* Appl. Organomet. Chem. 2010, 24(5), 386–391. 57. Iron-Catalyzed Synthesis of Selenoesters from Diselenides and Acyl Chlorides or Acid Anhydrides in the Presence of Magnesium Dust. Kai Ren, Min Wang, Pin Liu and Lei Wang* Synthesis 2010, (7), 1078–1082. 58. Recyclable Merrifield Resin-Supported Organocatalysts Containing Pyrrolidine Unit through A3-Coupling Reaction Linkage for Asymmetric Michael Addition. Jie Liu, Pinhua Li, Yicheng Zhang, Kai Ren, Lei Wang* and Guanwu Wang. Chirality 2010, 22, 432–441. 40 59. FeX3-Promoted Intermolecular Addition of Benzylic Alcohols to Aromatic Alkynes: A Mild and Efficient Strategy for the Synthesis of Alkenyl Halides. Kai Ren, Min Wang and Lei Wang* Eur. J. Org. Chem. 2010, 565–571. 60. Synthesis of 1,4-Disubstituted 1, 2, 3-Triazoles by Use of Copper(I) and Amino Acids Ionic Liquid Catalytic System. Jincan Yan and Lei Wang* Synthesis 2010, (3), 447–452. 61. An Efficient and Practical Synthesis of Benzoxazoles from Acyl Chlorides and 2-Aminophenols Catalyzed by Lewis Acid In(OTf)3 under Solvent-Free Reaction Conditions. Bo Wang, Yicheng Zhang, Pinhua Li and Lei Wang* Chin. J. Chem. 2010, 26(1),1697–1703. 62. Efficient Construction of Five-membered Aromatic and Nonaromatic Heterocycles from 1,6-Enynes by a Palladium-Catalyzed Domino Coupling/Cycloisomerization Process. Tuan-Jie Meng, Yimin Hu and Shaowu Wang* J. Org. Chem. 2010, 75, 582-588. 63. Coupling/Cyclization of 1,6-Enynes with Aryl Halides: an Efficient and General Route for the Synthesis of Functionalized Hexahydroindole and Hexahydrobenzofuran Derivatives.Tuan-Jie Meng, Yimin Hu, Yongjie Sun, Tao Zhu, Shaowu Wang* Tetrahedron 2010, 66, 8648-8653. 64. Rare Earth Metal Bis(trimethylsilyl)amido Complexes Bearing Pyrrolyl-methylamide Ligand. 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An efficient route to 4-subsituted coumarins, 2(5H)-furanones, and pyrones via palladium-catalyzed couplings of alkenyl tosylates with organoindium reagents. Wei Gao, Yong Luo, Qiuping Ding, Yiyuan Peng* and Jie Wu*, Tetrahedron Lett. 2010, 51, 136-138. 81. Silver-catalyzed decarboxylative halogenation of carboxylic acids. Yong Luo, Xiaolin Pan and Jie Wu*, Tetrahedron Lett. 2010, 51, 6646-6648. 82. Cleavage and Re-organization of Zr-C/Si-C Bonds Leading to Zr/Si-N Organometallic and Heterocyclic Compounds, Shaoguang Zhang, Wen-xiong Zhang, Jin Zhao, and Zhenfeng Xi* J. Am. Chem. Soc. 2010, 132, 14042-14045. 83. Efficient One-pot Multi-Component Synthesis Coupling of of N-Containing Silicon-tethered Heterocycles Diynes, Nitriles by and Isocyanides via Intramolecular Cyclization of Iminoacyl-Zr Intermediates, Shaoguang Zhang, Wen-Xiong Zhang and Zhenfeng Xi* Chem. Eur. J. 2010, 43 16, 8419-8426. 84. 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Ed. 2010, 49, 5792-5797. 88. Iron(III)-Catalyzed Cyclization of Alkynyl-aldehyde Acetals: Experimental and Computational Studies. Xu, T. Y; Yang, Q.; Li, D. P.; Dong, J. H.; Yu, Z. K.*; Li, Y. X.*, Chem. Eur. J. 2010, 16, 9264-9272. 89. RuCl3.xH2O-Catalyzed Direct Arylation of Arenes with Aryl Chlorides in the Presence of Triphenylphosphine. Luo, N.; Yu, Z. K.*, Chem. Eur. J. 2010, 16, 787-791. 90. Rhodium-Catalyzed Direct Alkenylation and Arylation of Arene C-H Bonds via Decarbonylation of Cinnamoyl Chlorides, Cinnamic Anhydrides and Poly(aroyl) Chlorides. Ye, W. J.; Luo, N.; Yu, Z. K.*, Organometallics 2010, 29, 1049-1052. 91. Diastereo- and Enantioselective Gold(I)-Catalyzed Intermolecular Tandem Cyclization/[3+3]Cycloadditions of 2-(1-Alkynyl)-2-alken-1- ones with Nitrones. Feng Liu, Deyun Qian, Lei Li, Xiaoli Zhao, and Junliang Zhang* Angew. Chem. Int. Ed. 2010, 49, 6669 –6672. 44 92. Catalytic Regioselective Control in the Diastereoselective 1,3-Dipolar Cycloaddition Reactions of 1-(1-Alkynyl)cyclopropyl Ketones with Nitrones. Yanqing Zhang, Feng Liu, and Junliang Zhang* Chem. Eur. J. 2010, 16, 6146 – 6150. 93. Gold-catalyzed Domino Reactions consisting of Regio- and Stereoselective 1,2-Alkyl Migration. Wenbo Li, Yuying Li, and Junliang Zhang* Chem. Eur. J. 2010, 16, 6447-6450. 94. One-pot Tandem Catalysis: A Concise Access to Fused Bicyclic Scaffold from Acyclic β-ketoesters and Alkynyl Aldehydes. Lu Liu, Lai Wei, Yong Lu and Junliang Zhang* Chem. Eur. J. 2010, 16, 11813-11817. 95. Tetrasubstituted allenes by Pd0-catalyzed three-component tandem Michael addition/cross-coupling reaction. Yuanjing Xiao and Junliang Zhang* Chem. Commun., 2010, 46, 752–754. 96. Rhodium-catalyzed tandem nucleophilic addition/bicyclization of diyne-enones with alcohols: a modular entry to 2,3-fused bicyclic furans. Wanxiang Zhao and Junliang Zhang* Chem. Commun., 2010, 46, 4384–4386. 97. Product-selectivity control by the nature of the catalyst: Lewis acid-catalyzed selective formation of ring-fused tetrahydroquinolines and tetrahydroazepines via intramolecular redox reaction. Guanghu Zhou and Junliang Zhang* Chem. Commun., 2010, 46, 6593–6595. 98. Exo/endo selectivity-control in Lewis-acid catalyzed tandem heterocyclization/ formal [4+3] cycloaddition: synthesis of polyheterocycles from 2-(1-alkynyl)-2-alken-1-ones and 1,3-diphenylisobenzofuran. Hongyin Gao, Xingxing Wu, and Junliang Zhang* Chem. Commun., 2010, 46, 8764–8766. 99. A Facile Route to Polysubstituted Naphthalenes and Benzofluorenols via Scandium Triflate- and Triflic Acid-Catalyzed Benzannulation of 2-(2-Alkynylarylidene)- 1,3-Dicarbonyl Compounds. Lu Liu, Lai Wei, and Junliang Zhang* Adv. Synth. Catal. 2010, 352, 1920 – 1924. 100.An Unexpected Phosphine-Catalyzed Regio- and Diastereoselective [4+1] Annulation Reaction of Modified Allylic Compounds with Activated Enones. 45 Zuliang Chen and Junliang Zhang*. Chem. Asian. J. 2010, 5, 1542-1545. 101.Organocatalytic hetero 2-(1-alkynyl)-2-alkene-1-ones: [4+2] cycloaddition metal-free access to reactions highly of substituted 4H-pyrans. Xiuzhao Yu, Zhongyan Cao and Junliang Zhang* Org. Biomol. Chem., 2010, 8, 5059–5061. 102.Rhodium-catalyzed synthesis of γ-butyrolactams and pyrrolidines via cycloisomerization of N-tethered 1,6-enynes. Wang, J.; Xie, X.; Ma, F.; Peng, Z.; Zhang, L. Zhang, Z*. Tetrahedron, 2010, 66, 4212. 103.“Water works: an efficient palladium-catalyzed cross-coupling reaction between boronic acids and bromoacetate with aminophosphine ligand”, Peng. Z.-Y.; Wang, J.-P.; Cheng, J.; Xie, X.; Zhang, Z*. Tetrahedron, 2010, 66, 8238. 104.Reactions of Cp3Y with Benzophenone: A simple and Efficient Method for Transformation of Unsubstituted Cyclopentadienyl to Bridged ansa-Cyclopentadienyl/alkoxyl Ligand. Xiaoqing Li, Jianquan Hong, Ruiting Liu, Linhong Weng, Xigeng Zhou* Organometallics, 2010, 29, 4606-4610. 105.A New Strategy for Ring Modification of Metallocenes: Carbodiimide Insertion into the 5-YC5H5 Bond and Subsequent Isomerization. Chengfu Pi, Xiaoqing Li, Lili Zhang, Ruiting Liu, Linhong Weng, Xigeng Zhou* Inorg. Chem. 2010, 49, 7632-7634. 106.Switching from Dimerization to Cyclotrimerization Selectivity by FeCl3 in the Y[N(TMS)2]3-Catalyzed Transformation of Terminal Alkynes: A New Strategy for Controlling the Selectivity of Organolanthanide-based Catalysis. Xiuli Bu, Zhengxing Zhang, Xigeng Zhou* Organometallics, 2010, 29, 3530-3534. 107.Unexpected Tandem Reactions of Tris(cyclopentadieny1)Lanthanide with Diphenylketene and Regeneration of the 5-Bonding Mode: One-pot Synthesis of Heteroleptic Yttrocenes from Simple (C5H5)3Y Precursor. Xiaoqing Li, Ruiting Liu, Zhengxin Zhang, Xiaoming Mu, Linhong Weng, Xigeng Zhou* Organometallics, 2010, 29, 3298-3302. 108.Synthesis and controlled hydrolysis of organolanthanide complexes with mono- and dianionic benzimidazole-2-thiolate ligands. Ruiting Liu, Xiaoqing 46 Li, Houcai Zhang, Linhong Weng, Xigeng Zhou* Dalton Trans. 2010, 39, 11053-11059. 109.Activation of Bis(guanidinate)lanthanide Alkyl and Aryl Complexes on Elemental Sulfur: Synthesis and Characterization of Bis(guanidinate)lanthanide Thiolates and Disulfides. Zhengxing Zhang, Lixin Zhang, Yanrong Li, Longcheng Hong, Zhenxia Chen, Xigeng Zhou* Inorg. Chem. 2010, 49, 5715-5722. 110.Recent Advances in Reaction of Organolanthanides Containing the NH Bonds with Unsaturated Organic Small Molecules. Jie Zhang and Xigeng Zhou* Comptes rendus Chim. 2010, 13, 633-650 111.Insertion of Ketenimines into the Ln−C σ-Bond of Organolanthanides: A New Strategy for Synthesis of Lanthanide 1-Azaallyl Complexes. Zhengxing Zhang, Xiuli Bu, Jie Zhang, Ruiting Liu, Xigeng Zhou* and Linhong Weng Organometallics, 2010, 29, 2111-2117. 112.-Deprotonation of Anionic Bis(trimethylsilyl)amido Lanthanide Complexes with a Countered [(TpMe2)2Ln]+ Cation. Fuyan Han, Jie Zhang*, Weiyin Yi, Zhengxing Zhang, Jingyi Yu, Linhong Weng, and Xigeng Zhou* Inorg. Chem. 2010, 49, 2793-2798. 113.Synthesis and Reactivities of Guanidinate Dianion Complexes of Heterobimetallic Lanthanide–Lithium Cp2Ln[(CyN)2CNPh]Li(THF)3. Pengzhi Zheng, Jianquan Hong, Ruiting Liu, Zhengxing Zhang, Zhen Pang, Linhong Weng and Xigeng Zhou* Organometallics, 2010, 29, 1284-1289. 114.Isocyanate diinsertion into the N–H bond of 2-pyridylamino ligand of organolanthanides. Yan Sun, Zhengxing Zhang, Xu Wang, Xiaoqing Li, Linhong Weng, Xigeng Zhou* Dalton Trans. 2010, 39, 221. 115.Bifunctional AgOAc-catalyzed Asymmtric Reactions. Qing-An Chen, Duo-Sheng Wang and Yong-Gui Zhou*. Chem. Commun. 2010, 46, 4043-4051 (Feature Articles) 116.Highly Effective and Diastereoselective Synthesis of Axially Chiral Bis-sulfoxide Ligands via Oxidative Aryl Coupling. Qing-An Chen, Xiang Dong, Mu-Wang Chen, Duo-Sheng Wang, Yong-Gui Zhou* and Yu-Xue Li.* Org. Lett. 2010, 12, 1928-1931. 47 117.Asymmetric Hydrogenation of Quinolines Activated by Bronsted Acids. Duo-Sheng Wang, Yong-Gui Zhou* Tetrahedron Lett. 2010, 51, 3014-3017. 118.Direct asymmetric a-amination of aldehydes with azodicarboxylates in ionic liquids catalyzed by imidazolium ion-tagged proline organocatalyst. Xiong Ding, Hong-Lai Jiang, Cheng-Jian Zhu*, Yi-Xiang Cheng Tetrahedron Letters, 2010, 51, 6105–6107. 119.Direct substitution of propargylic alcohol with oxygen, nitrogen and carbon nucleophiles catalyzed by molybdenum(Ⅵ). Ming Zhang, Hongwei Yang, Yixiang Cheng, Yuhua Zhu, Chengjian Zhu* Tetrahedron Letters, 2010, 51, 1176–1179. 48 49