金属有机化学国家重点实验室2001年年度进展报告.doc
金属有机化学国家重点实验室2001年年度进展报告.doc
2OO1 年重大记事 一．正式升级为国家重点实验室 根据科技部<<关于批准金属有机化学开放实验室、高分子物理联合开放实验室升级建 设国家重点实验室的通知>>，征得科技部同意，科学院于 2001 年 4 月 16 日组织专家对实 验室一年多来的升级建设工作进行验收。验收专家委员会认真听取了实验室主任的国家重 点实验室的建设总结报告和三个学术报告，参观了实验室，重点检查了建设期间购置的仪 器的运转情况，对实验室建设期间的工作进行了认真的讨论，认为金属有机化学国家重点 实验室按计划完成了建设任务。最后由科技部基础司基地建设处彭以祺处长和验收专家组 组长黄志镗院士共同为金属有机化学国家重点实验室揭牌，宣告金属有机化学国家重点实 验室正式成立。 二．项目资助 继续资助 2000－2001 年的室基金项目 29 个，按照对年青人的年度资助制度，接受年 青学科带头人的申请，并增加了 2 个资助项目，共资助 31 个项目，资助总额 76.6 万元。 三．实验室新的装备 年初我室订购的 300 兆核磁共振仪(DPX300)一台, Weissenberg 面探仪一台, 手套箱 两套都按时到货，完成调试，目前仪器运行正常，为全室的科研人员服务。 四．创新群体的申请 今年 4 月份，我室牵头申请国家自然科学基金委创新研究群体计划，七月底通过国家 基金委化学部的初审和答辩，11 月 26 日接受基金委组织的专家到我所进行实地考核，专 家们和研究群体的学科带头人、研究骨干、主要参加人员、所管理人员等进行面对面的座 谈，了解群体计划参与人员的学术研究状况等。2002 年 2 月得知此研究群体已获得 2001 年度“创新研究群体科学基金”的资助。 1 五. 实验室承担的科研项目运行正常 今年我室麻生明研究员作为首席科学家之一的 973 项目“创造新物质的分子工程学研 究”、麻生明主持的基金委重点项目、基金委优秀实验室重点项目、施敏和丁奎岭主持的 中科院知识创新方向性重大项目、唐勇主持的国家“863”计划等实验室学术带头人共同 承担的项目运行正常，发表了不少高质量的论文，其中全室 I 区论文有 6 篇，部分工作还 受到美国化学会 C § EN News 的专文评论。 六．实验室学委会工作 实验室经常与学术委员保持联系，听取他们对实验室发展的建议，请他们为实 验室出谋划策。实验室在今年每年一次的年度学委会会议上，首次以国家重点实验 室的名义邀请了科技部领导参加，请他们为实验室以国家重点实验室作为起点更好 发展提了不少建设性意见。 七、对外开放 实验室今年除继续出资和课题组共同邀请一些国外学者专家到有机所进行顺访 外，还以实验室名义邀请了美国、德国、瑞士和荷兰的 5 名比较著名的科学家到实 验室进行专门的访问，在作学术报告后，还与所内尤其是实验室内的科学家进行面 对面的工作访谈，使我们科研人员不用出国，就可以了解一些国际学科发展动态。 2 金属有机化学国家重点实验室学术委员会 第一届第一次会议简报 金属有机化学国家重点实验室第一届学术委员会第一次会议于今年 10 月 30 －31 日在浙江杭州金都宾馆召开。十四位委员中除两位因另有会议等原因未能到 会外，共有十二位出席会议，国家科技部基础司基地建设处彭以祺处长、中科院基 础局黄勇副局长、中科院高技术局实验室处邢如云处长和化工处白路娜处长与会指 导。会议由学术委员会主任钱长涛研究员主持。会上彭处长介绍了国家科技部十五 期间实验室的建设规划，使我们更加清楚十五期间我们实验室应在原有基础上如何 发展。然后黄勇副局长在会上介绍了十五期间基础局在化学方面准备支持一批项目 的情况，希望我们实验室努力争取。这次会议的议程是 1) 室主任汇报实验室一年 来的工作情况，2) 专家学术报告和交流，3) 部分课题组工作进展汇报，4) 国际 学术会议介绍，5)今后工作讨论。 一.实验室主任麻生明研究员汇报了实验室室一年来的工作 麻生明主任首先欢迎并感谢各位领导和专家的到会，指出我们实验室今年能正 式升级成为国家重点实验室，离不开大家的指导和支持。我们终于实现了几代人为 之奋斗的梦想，今后应该更加努力，不断发展。会上麻生明研究员汇报了实验室一 年来的工作，重点介绍实验室一年来在实验室建设及仪器装备添置、国家重点实验 室验收、项目申请、成果、人才培养和课题管理等方面的工作。 二．专家学术报告和交流 会上由浙江大学沈之荃院士和上海有机所陆熙炎院士做了两个精彩的学术报 告。沈之荃院士的题为“金属有机与高分子化学”的学术报告，首先提出有机化学 尤其是金属有机化学是高分子化学的基础，高分子化学脱胎于有机化学。然后沈先 生介绍了她课题组在稀土化合物配位催化烯烃聚合、炔烃聚合、开环聚合、环氧丙 烷聚合等方面的工作。陆熙炎院士的题为“二价钯催化的反应研究”的报告中，首 先提出了二价钯催化反应的优点：可以在空气中操作；不需要氧化剂。接着介绍了 他们课题组在二价钯催化反应方面取得的系列研究成果。 3 三. 课题组工作进展汇报和讨论 这次会上共有五个课题组进行工作汇报，分别由上海有机所赵刚研究员(手性 磺酰胺促进酮的不对称还原)、上海有机所麻生明研究员(金属参与的碳-碳键形成 反应研究)、安徽师范大学王绍武教授(镧系金属络合物引发的单电子转移反应)、 北京化学所刘汉范研究员(纳米金属簇催化酮酸酯及二酮的不对称氢化)、南开大学 化学系王佰全教授(桥连双环戊二烯基羰基铁和钌化合物的合成、结构、反应及催 化性能研究)到会汇报。委员们认真听取了他们的进展情况和今后工作设想，并就 研究工作中的问题提出了中肯的意见和建议，进行了广泛的学术交流。 四．国际学术会议介绍和讨论 本次会上共介绍了五个国际会议的内容： 1. 北京大学的席振峰教授介绍了 2001 年 4 月在荷兰阿姆斯特丹召开的第 2 届中荷 双边会议的情况, 此会由荷兰基金委主办，中方 10 人、荷兰方 13 人参加，会上两 国的科学家进行了充分的交流，反应良好，大家准备 2003 年继续召开此会。 2. 上海有机所的麻生明研究员介绍了今年 7 月底 8 月初在日本横滨召开的 18th International Congress of Heterocyclic Chemistry 会议，会议共有 913 人参加，其中日 本人 701 名。整个会议报告中传统杂环合成工作的报告减少，金属有机化学成分增 加。会议报告还涉及自由基、配位键和金属杂环状反应中间体方面的工作。 3. 上海有机所的唐勇研究员介绍了今年 6 月在波兰召开的第 6 届杂原子会议的情 况。此次会议的学术交流重点是：(1)基本杂原子化学；(2)导向有机合成的杂原子 化学；(3)生物有关的杂原子化学；(4)杂原子的超分子化学和配位化学；(5)杂原 子材料。 4. 上海有机所的侯雪龙研究员介绍了今年 7 月在台湾召开的第 11 届 OMCOS 会议， 会上共有 2 个主题报告、5 个大会报告和 19 个邀请报告。侯雪龙介绍了大会的概 况和此次会议的学术交流重点。 4 通过这些介绍和讨论，使到会委员们及时了解国际上金属有机化学研究的热点 和掌握目前文献还来不及报道的热门资料，大家一致认为收益非浅。 五．今后工作讨论 会上委员们对实验室的学术方向、发展方针、研究课题设置和国际学术交流等 方面进行了讨论。对实验室的建设和管理，尤其是所内项目与所外客座项目的管理 提出了很多中肯的建议。 总之，本次学委会会议讨论热烈，交流充分，学术气氛浓厚，与会者都认为收 获较大。最后大家一致认为国家重点实验室来之不易，今后一定要坚持“金属有机 化学”的学术方向，作为学科发展的目标，吸引国内最优秀的人才到实验室来工 作。即坚持基础研究的特点不变，又要多考虑把研究工作与国家现代化建设和国民 经济发展需求相结合。希望金属有机化学国家重点实验室成为一个国际一流的国家 重点实验室，成为我国金属有机化学研究基地，为国家解决重大科学问题，发展金 属有机化学，在世界金属有机化学研究领域占有一定的地位。 5 2000～2001 资助课题一览表 序 号 姓 名 单 位 题 目 2000-01 陆熙炎 上海有机所 二价钯的不对称催化反应 2000-02 钱长涛 上海有机所 单原子桥联芴基环戊二烯基稀土配合物的 合成、结构及催化活性研究 2000-03 麻生明 上海有机所 金属参与的碳-碳键形成反应研究 2000-04 侯雪龙 上海有机所 氮杂环丙烷化合物的去对称化反应及在有 机合成中的应用 2000-05 沈延昌 上海有机所 金属有机参与的高选择性合成方法学研究 2000-06 陈家碧 上海有机所 (杂)烯炔配位的金属卡宾和卡拜络合物及其 在合成中应用 2000-07 邓敏智 上海有机所 手性环丙基硼化物的新反应及其在天然产 物合成中的应用 2000-08 姜 标 上海有机所 手性配体的制备及其在不对称反应中的应用 2000-09 施 敏 上海有机所 膦酰胺类手性配体的设计合成及其在不对称 催化反应中的应用 2000-10 丁奎岭 上海有机所 基于 NOB 衍生物为配体的金属络合物催化的 不对称反应研究 2000-11 唐 勇 上海有机所 可溶性高聚物负载叶立德的合成及其在有机 合成中的应用 2000-12 廖世键 大化所 1、通过金属有机中间体合成纳米尺寸的稀土 金属和稀土氢化物粉末 2、高选择性有机合成反应中双金属催化的协 同效应 2000-13 宋礼成 南开大学 两类单蝶状铁硫络盐的新反应及其在合成多蝶 状簇合物中的应用研究 6 2000-14 黄 宪 -杂原子或金属取代的、-不饱和砜及膦酸 浙江大学 脂的合成及其在立体选择合成反应中的应用 2000-15 沈 琪 苏州大学 稀土和后过渡金属化合物的合成及催化聚合活 性的研究 2000-16 康北笙 中山大学 含咪唑基三角架型氮杂化合物的亲金属性研究 2000-17 沈之荃 浙江大学 钐化合物催化极性单体聚合研究 2000-18 张永敏 浙江大学 稀土金属和过渡金属试剂在有机合成中的应用 2000-19 张良辅 成都有机所 多相不对称催化反应的研究 2000-20 刘汉范 北化所 纳米金属簇催化酮酸酯及二酮的不对称氢化 其对催化反应的影响 2000-21 王积涛 南开大学 金属有机试剂在-氨基酸手性合成中的的应用 2000-22 徐善生 南开大学 单桥及双桥连二环戊二烯基双核过渡金属 化合物的研究 2000-23 周其林 南开大学 螺旋型手性催化剂的设计合成及其应用 性研究 2000-24 曹卫国 上海大学 胂叶立德在高选择性合成中的应用――立体 选择性合成γ-丁内酯及γ-丁内酰胺类化合物 2000-25 周锡庚 复旦大学 炔丙基稀土金属有机物的合成、结构及其反应 2000-26 席振峰 北京大学 过渡金属促进的利用二氧化碳作为碳源的新型 碳－碳键形成反应 2000-27 江焕峰 广化所 过渡金属化合物在超临界二氧化碳介质中的 催化行为研究 2000-28 庞 震 复旦大学 2000-29 张兆国 上海有机所 亚胺及烯胺的氢甲酰化反应 2000-30 赵 上海有机所 Lewis 酸参与的羰基化合物的不对称还原反应研究 2000-31 王绍武 刚 含半活性配位基团的金属有机配合物的合成及 其对催化反应的影响 安徽师大 IVB 族元素双桥茚基金属有机化合物的合成、 有机所 结构及反应性研究 7 二 00 一年论文目录 课题负责人：陆熙炎 课题编号： 2000-01 1. Effect of Ligands on the Divalent Palladium-Catalyzed Carbon-Carbon Coupling Reactions. Highly Enantioselective Synthesis of Optically Active -Butyrolactones Lu, X.*; Zhang, Q. Pure Appl. Chem. 2001, 73, 247-250. 31 2. Reactions of Electron-Deficient Alkynes Under Phosphine Catalysis Lu, X.*; Zhang, C.; Xu, Z. Acc. Chem. Res. 2001, 34, 535-544. 35 3. Role of Halide Ions in Divalent Palladium-Mediated Reactions: Competition between -Heteroatom Elimination and -Hydride Elimination of a Carbon-Palladium Bond Zhang, Z.; Lu, X.*; Xu, Z.; Zhang, Q.; Han, X. Organometallics 2001, 20, 3724-3728. 45 4. Palladium(II)-Catalyzed Synthesis of -Alkylidene--butyrolactams from N-Allylic 2-Alkynamides. Total Synthesis of (+)-Isocynodine and (+)-Isocynometrine Xie, X.; Lu, X.*; Liu, Y.; Xu, W. J. Org. Chem. 2001, 66, 6545-6550. 50 5. Palladium(II)-Catalyzed Tandem Reaction of Intramolecular Aminopalladation of Allenyl N-Tosylcarbamates and Conjugate Addition Liu, G.; Lu, X.* Org. Lett. 2001, 3, 3879-3882. 56 6. Palladium(II) Catalyzed Asymmetric Cyclization of (Z)-4’-Acetoxy-2’-butenyl 2Alkynoates. Role of Nitrogen Containing Ligands in Palladium(II) Mediated reactions Zhang, Q.; Lu, X.*; Han, X. J. Org. Chem. 2001, 66, 7676-7684. 60 7. Palladium(II)-Catalyzed Cyclization of N-(2’,4’-Dienyl)alkynamides to Alkylidene--butyrolactones Xie, X.; Lu, X.*; Liu, G. Chin. J. Chem. 2001, 19, 1285-1288. 69 8. 从贫电子炔烃出发的合成方法学研究 陆熙炎 有机化学 2001, 21, 769-783. 73 9. Reaction of Palladium Enolate Intermediate with Electrophiles under Divalent Palladium Catalyst 8 Zhang, Q.; Lu, X.* Huaxue Xuebao 2001, 59, 1702-1706. 课题负责人：钱长涛 88 课题编号： 2000-02 1. Ruifang Chen,Changtao Qian,J.G.dr Vries Highly Efficient Enantioselective Epoxidation of a,b-Enones Catalyzed by Cheap Chiral Lanthanum and Gadolinium Alkoxides Tetrahedron 2001, 57, 9837-9842 . 93 2. Yb(OiPr)3 Highly Efficient Catalyst for Nitro-Mannich Reaction Changtao Qian,Feifenf Gao,Ruifang Chen Tetrahedron Letters, 200142,4673-4675. 99 3. The First Example of a Dinuclear Anionic Lanthanoidocene Complex:[K(18-crown6){(C13H8)CPh2(C5H4)Nd(BH4)2}]2C4H8O2 Changtao Qian, Wanli Nie and Jie Sun J. Organomet Chem., 2001, 626,171-175. 102 4. Synthesis,Structure,and Catalytic Behavior of rac-1,1-(3-Oxapentamethylene)Bridged Bis(Indenyl) ansa-Lanthanidocenes Changtao Qian,Gang Zou,Yaofeng Chen,and Jie sun Organometallics, 2001, 20, 3106-3112. 107 5. Polymeric Chain Structures of Substituted (Dimethyl-fluorenylsilyl)cyclopentadienyl Lithium and Sodium Complexes Wanli Nie,Changtao Qian,Jie Sun Organometallics, 2001, 20, 5780-5783. 114 6. Bis-(2-diphenylphosphinoethyl)cyclopentadienylchlorolutetium:synthesis and dynamic behavior in solution D.M.Roitershtein,D.P.Krutko,E.N.Vekster,D.A.Lemenovskii,W.Nie,and C.Qian Russian Chemical Bulletin, International Edition, 2001, 50, 1295-1298. 118 7. Ruifang Chen,Changtao Qian,J.G.de Vries Asymmetric Epoxidation of -Unsaturated Ketones Catalyed by Chiral Ytterbium Complexes Tetrahedron Letters, 2001,42,6919-6921 122 8. Formation and molecular structure of an ion pair iron (II) compound derived from 2,6[1-(2,6-dibromo-phenylimino)ethyl]pyridine and 2-acetyl-6-[1-(2,6dibromophenylimino)ethyl]pyridine Chen,Ruifang; Qian,Changtao; Jie,Sun Chin. J. Chem., 2001, 19, 866-869. 125 9 9. Asymmetric Hetero Diels-Alder Reaction of Chiral Imines with Danishefsky’s Diene Catalyzed by Yb(OTf)3 Qian Chang-Tao, Wang Long-Cheng ,Chen Rui-Fang Chin. J. Chem., 2001, 19, 419. 129 10. 1,-3-Dipolar Cycloaddition of Nitrones with Electron-rich Alkenes Catalyzed by Yb(OTf)3 Qian Chang-Tao ,Wang long-Cheng ,Chen Rui-Fang Chin.J.Chem., 2001, 19, 412. 133 11. Ruifang Chen,Changtao Qian,J.G.de Vries,Peipei Sun, Liming Wang Asymmetric Catalytic Epoxidation of Enones by Chiral Binaphthol-Derived Lanthanum Catalyst Chin.J.Chem., 2001, 19, 1225-1231. 140 12. 钱长涛，陈耀峰，高飞峰 稀土金属有机化学的最新进展 有机化学 2001，21，997－1008 课题负责人：麻生明 147 课题编号： 2000-03 1. Hydrohalogenation Reaction of Electron-Deficient Allenes Shengming Ma,* Lintao Li, Qi Wei, Hexin Xie, Guangwei Wang, Zhangjie Shi, and Junliang Zhang Pure & Appl. Chem. 2000, 72, 1739. 159 2. CuCl-Catalyzed Cycloisomerization Reaction of 1,2-Allenyl Carboxylic Acids. A Cost-Effective Synthesis of -Unsubstituted Butenolides Shengming Ma,* Zhangqian Yu, and Shulin Wu Tetrahedron 2001, 57, 1585-1588. 164 3. The Chemistry of 1,2-Allenyl/Propargyl Metal Species-A Personal Account Shengming Ma* and Aibin Zhang Pure & Appl. Chem. 2001, 73, 337-341. 168 4. Hydrohalogenation Reaction of 1,2-Allenic Carboxylic Acids, Esters, Amides, Nitriles, and Diphenyl Phosphine Oxides Shengming Ma,* Hexin Xie, Guangwei Wang, Junliang Zhang, and Zhangjie Shi Synthesis 2001, 713. 173 5. Novel CuX2-Mediated Cyclization of Acid-Base Salts of (L)Cinchonidine or (D)-/(L)--Methylbenzylamine and 2,3-Allenoic 10 Acids in Aqueous Medium. An Efficient Entry to Optically Active –Halobutenolides Shengming Ma* and Shulin Wu Chem. Commun. 2001, 441. 191 6. CuBr2-Mediated Direct Aqueous Bromolactonization Reaction of 2,3-Allenoates. An Efficient Access to -Bromobutenolides Shengming Ma* and Shulin Wu Tetrahedron Lett. 2001, 42, 4075. 193 7. Enantioselective Synthesis of Arylbutenolides via Palladium(0)-Catalyzed Asymmetric Coupling-Cyclization Reaction of Racemic Allenic Carboxylic Acids with Aryl Iodides Shengming Ma*, Zhangjie Shi, and Shulin Wu Tetrahedron:Asymmetry 2001, 12, 193. 196 8. Novel Substituent and Chelating Effects in the Pd-Catalyzed Reaction of 2,3-Allenols, Aryl Iodides, and Amines. Highly Regio- and Stereo-selective Synthesis of -Amino3-alken-1-olsorAmino-2alken-1-ols Shengming Ma* and Shimin Zhao J. Am. Chem. Soc. 2001，123，5578. 199 9. An Efficient New Methodology for the Synthesis of 1-Functionalized 2-Halo-1alkenes via Hydro-halogenation Reaction of Electron-Deficient Allenes Shengming Ma* and Lintao Li Synlett 2001, 1206. 201 10. Synthesis and structural characterization of infinite single-stranded coordination polymers of optically active bis(oxazoline) ligands with silver trifluoromethanesulfonate Shengming Ma* and Shulin Wu New J. Chem. 2001, 25, 1337. 209 11. Synthesis of 4-Halo-2(5H)-furanones and Their Suzuki-Coupling Reactions with Organoboronic Acids. A General Route to -Aryl-2(5H)-furanones Shengming Ma* and Zhangjie Shi Chin. J. Chem., 2001, 19, 1280. 214 12. Study of 2-Iodo-3-(phenylsulfinyl)-2-propen-1-ol and its Analogues by Self-chemical Ionization Mass Spectrometry Fang Zhang, Yinlong Guo*, Qi Wei, and Shengming Ma* Chin. J. Chem. 2001, 19, 851. 219 13. 金属氮宾与亚胺的复分解反应 李林涛，龚华，麻生明* 有机化学, 2001, 21, 398-402. 224 11 14. Organic Transformations Catalyzed by N-Heterocyclic Carbene-Metal Complexes Lintao Li and Shengming Ma* 有机化学, 2001, 21, 75. 229 15. Transition Metal-Catalyzed Alkyne Metathesis Reaction Zibin Zhang, Hua Gong, and Shengming Ma* 有机化学, 2001, 21, 541-548. 236 16. 导向有机合成的金属有机化学研究初探 Shengming Ma* 有机化学, 2001, 11, 833-841. 244 17. 1, 1-二卤代－1－烯烃的制备及其在有机合成中的应用 许斌，麻生明* 有机化学, 2001, 21, 252-262. 253 18. Gas Chromatographic Enantiomeric Separation of Propargylic Alcohols and 2,3Allenoic Alcohols Dong Xiao-Wei, Xu Xu*, Hou Hai-long, Wei Wi, Xu, Dai-Wang, Jiao Ning, Zhang Ai-Bin, Zhao Shi-Min, Shengming Ma* 有机化学, 2001, 21, 1142. 264 课题负责人：侯雪龙 课题编号： 2000-04 1. Highly Efficient Ligands for Palladium Catalyzed Asymmetric Alkylation with Ketone Enolates Shu-Li You, Xue-Long Hou, Li-Xin Dai and Xia-Zhen Zhu Org. Lett. 2001, 3, 149. 269 2. Novel ferrocene modified P, N-ligands for enantioselective palladium-catalyzed allylic substitution reactions Shu-Li You, Xue-Long Hou and Li-Xin Dai J. Organomet. Chem. 2001, 637-639, 762. 272 3. Synthesis of Novel N,O-Planar Chiral [2,2]Paracyclophan Ligands and Their Application in Addition of Diethylzinc to Aldehydes Xun-Wei Wu, Xue-Long Hou, Li-Xin Dai, Ju Tao, Bo-Xun Cao and Jie Sun Tetrahedron: Asymmetry 2001, 12, 529. 277 4. An Efficient Procedure for Cleavage of Aziridines with Various Thiols Promoted by ZnCl2 Jie Wu, Xue-Long Hou, and Li-Xin Dai J. Chem. Soc., Perkin 1 2001, 1314. 281 12 5. Importance of planar chirality in chiral catalysts with three chiral elements: The role of planar chirality in 2’-substituted 1,1’-P, N-ferrocene ligands on the enantioselectivity in Pd-catalyzed allylic substitution W. P. Deng, S. L. You, X. L. Hou, L. X. Dai, Y. H. Yu, W. Xia and J. Sun J. Am. Chem. Soc. 2001, 123, 6508. 285 6. Highly Regio- and Enantioselective Palladium-Catalyzed Allylic Alkylation and amination of Monosubstituted Allylic Acetates with Novel Ferrocene P, N- Ligands Shu-Li You, Xia-Zhen Zhu, Yu-Mei Luo, Xue-Long Hou and Li-Xin Dai J. Am. Chem. Soc. 2001, 123, 7471. 297 7. Palladium-catalyzed asymmetric allylic alkylations of cycloalkenyl acetates with planar chiral phosphino-ferrocene carboxylic acids Shu-Li You, Yu-Mei Luo, We-Ping Deng, Xue-Long Hou and Li-Xin Dai J. Organomet. Chem. 2001, 637-639, 845. 299 8. 新型双膦配体及钯催化的烯丙基烷基化反应用于构筑季碳手性中心 游书力,朱霞珍,侯雪龙,戴立信 化学学报 2001, 59, 1667. 课题负责人：沈延昌 304 课题编号： 2000-05 1. A Novel One-pot Conversion of Aldehydes to Trifluoromethylated Bromoallylic Alcohols Yanchang Shen, Yuming Zhang Organic Lett., 2001, 3, 2805. 312 2. Stereocontrolled Synthesis of Trifluoromethylated (E)- or (Z)-ynenyl Sulfones via Sequential transformation Yanchang Shen, Guoping Wang, Jie Sun J. Chem. Soc. Perkin Trans 1, 2001, 519. 314 3. A Novel Stereoselective Route to Trifluoromethylated Vinyl Sulfones Yanchang Shen, Guoping Wang, Jie Sun Synthesis, 2001, 389. 318 4. A New “One-pot” Conversion of Trifluoroacetic Esters to -Fluoro-trifluoromethyl--oxy-vinylphosphonates Yanchang Shen, Yuming Zhang J. Fluorine Chem. 2001, 108, 69. 322 13 5. Synthesis, Reactivity, and Crystal Structure of Perfluoroalkylated Diethoxyphosphinyl triphenylphosphorane Guo-Fang Jiang, Jie Sun, Yanchang Shen, J. Fluorine Chem. 2001, 108, 207. 325 6. A Novel Synthesis of Functionalized gem-difluoro-penta-1,4-dienes Yanchang Shen, Guo-Fang Jiang, Guoping Wang, Yuming Zhang J. Fluorine Chem. 2001, 109, 141. 329 7. Stereoselective Synthesis of 3-Trifluoromethylated-2E, 4E-dienyl carboxylates Yanchang Shen, Zenghong Zhang, Jie Sun J. Fluorine Chem. 2001, 111, 189. 333 8. New Synthetic Methodologies Based on the Participation of Organometallic and Elementoorganic Compounds Shen Yan-chang Chinese J. Org. Chem., 2001, 21, 816. 337 课题负责人：陈家碧 课题编号：2000-06 1. Remarkable Reactions of Cationic Carbyne Complexes of Manganese and Rhenium with Diiron Anions [Fe2(-CO)(-SeR)(CO)6]-. A Route to RSe-Bridged Dimetal Bridging Carbene Complexes Ruitao Wang, Qiang Xu, Yoshie Souma, Li-Cheng Song, Jie Sun, Jiabi Chen* Organometallics, 2001, 20, 2226-2233. 345 2. Remarkable Reactions of (4-1-azadiene)-Fe(CO)3 Complexes with Aryllithium Reagents. Syntheses and Structures of Novel Chelated Furanyl-coordinated Akoxy(amino)carbeneiron, 4-azadiene-coordinated 17e Acyliron, and Iron Inner Salt Complexes Shu Zhang, Qiang Xu, Jie Sun, Jiabi Chen* Organometallics, 2001, 20, 2387-2399. 353 3. Unusual Reactions of Cationic Bridging Carbyne Complexes of Dimethylsilanebridged Bis(5-cyclopentadienyl)-diiron Tricarbonyl with Nucleophiles. A Route to Iron-sulfur Cluster Bridging Carbene Complexes Ruitao Wang, Qiang Xu, Jie Sun, Li-Cheng Song, Jiabi Chen* Organometallics, 2001, 20, 4092-4099. 366 4. Unexpected Metallosite-Selective CO Substitution of Heteronuclear Tetrahedral (3S)FeCoM (M = Mo, W) Carbonyl Clusters with Cyclohexyl Isocyanide:59Co NMR and 57Fe Moessbauer Spectra of (3-S)FeCoMo(CO)8-n(5-C5H4COMe)(C6H11NC)n (n = 1-3) and Crystal Structures of (3-S)FeCoMo(CO)8-n(5-C5H4R)(C6H11NC)n (M = Mo, W; R = MeCO, MeO2C; n = 1, 2) 14 Li-Cheng Song, Chun-Cheng Luo, Qing-Mei Hu, Jiabi Chen, Hong-Gen Wang Organometallics, 2001, 20, 4510-4516. 374 5. Synthesis of single and double butterfly iron carbonyl complexes by reactions of [(SeR)(-CO)Fe2(CO)6]- anions. Crystal Structurs of (-p-MeC6H4Se)[PhCH2N(H)C=S]Fe2(CO)6 and [-PhSe)(-MeAs)Fe2(CO)6]2 Li-Cheng Song, Guo-Liang Lu, Qing-Mei Hu, Hong-Tao Fan, Jiabi Chen, Jie Sun, Xiao-Ying Huang J. Organomet. Chem., 2001, 627, 255-262. 381 课题负责人：邓敏智 课题编号： 2000-07 1. Cross-coupling reaction of cyclopropylboronic acids with aryl ω-halo-oxoperfluoroalkylsulfonates Yao Minliang, Wang jiapo & Deng Minzhi Chinese Science Bulletin, 2001, 15, 1277-1280. 课题负责人：姜 标 389 课题编号： 2000-08 1. Enantioselective Synthesis for the (-)-Antipode of the Pyrazinone Marine Alkaloid, Hamacanthin A Biao Jiang,* Cai-Guang Yang, and Jun Wang Journal of Organic Chemistry, 2001, 66(14), 4865-4869. 393 2. Enantioselective Synthesis for the Antipodes of Slagenins B and C: Establishment of Absolute Stereochemistry Biao Jiang,* Jia-Feng Liu, and Sheng-Yin Zhao Organic Letters, 2001, 3(25), 4011-4013. 398 3. Catalytic enantioselective synthesis of secondary alcohols using C2-symmetric diamino diol ligands Biao Jiang, Yan Feng & Jian-Feng Hang Tetrahedron: Asymmetry, 2001, 12(16), 2323- 2329. 401 4. A highly stereoselective synthesis of indolyl N-substituted glycines Biao Jiang, Cai-Guang Yang & Xiao-Hui Gu Tetrahedron Letters, 2001, 42(13), 2545 – 2547. 408 Synthesis and cytotoxicity evaluation of novel indolylpyrimidines and indolylpyrazines as potential antitumor agents Biao Jiang, Cai-Guang Yang, Wen-Nan Xiong & Jun Wang, Bioorganic and Medicinal Chemistry, 2001, 9(5), 1149-1154. 411 5. 15 6. Synthesis and antitumor evaluation of novel monoindolyl-4-trifluoromethylpyridines and bisindolyl-4-trifluoromethylpyridines Biao Jiang, Xen-Nan Xiong & Cai-Guang Yang, Bioorganic and Medicinal Chemistry Letters, 2001, 11(4), 475-477. 417 7. -(Trifluoromethyl)ethenyl boronic acid as a useful trifluoromethyl containing building block. Preparation and palladium-catalysed coupling with aryl halides Biao Jiang, Quan-Fu Wang, Cai-Guang Yang & Min Xu, Tetrahedron Letters, 2001, 42(24), 4083 – 4085. 420 8. Stereoselective synthesis of kurzilactone and determination of its absolute configuration Biao Jiang, Zili Chen Tetrahedron: Asymmetry, 2001, 12(20), 2835-2843. 9. 423 Synthesis of dialkyl cyanoboronates and their application in palladium-catalyzed cyanation of aryl halides Biao Jiang, Ying Kan & Ao Zhang Tetrahedron 2001, 57, 1581-1584. 432 10. Convenient Approaches to 4-Trifluoromethylpyridine Biao Jiang,* Wennan Xiong, Xiaobing Zhang, and Fangjiang Zhang Organic Process Research & Development, 2001, 5(5), 531-534. 436 11. Rh-catalyzed asymmetric hydrogenation by using a new family of C2-symmetric bisphosphinites and a bisaminophosphine as ligands Ao Zhang & Biao Jiang Tetrahedron Letters 2001, 42(9), 1761 – 1763. 440 12. Asymmetric hetero-Diels–Alder reaction of chiral pinanediol 1,3-dienylboronates with azo-compounds Ao Zhang, Ying Kan & Biao Jiang Tetrahedron 2001, 57(12), 2305-2309. 443 13. Synthesis of Novel Analogues of Marine Indole Alkaloids: Mono(indolyl)-4trifluoromethylpyridines and Bis(indolyl)-4-trifluoromethylpyridines as Potential Anticancer Agents Wen-Nan Xiong, Cai-Guang Yang & Biao Jiang Bioorganic and Medicinal Chemistry 2001, 9(7), 1773-1780. 448 14. 三氯甲基吡啶液相法氟化反应的研究 沈彪，张芳江，姜标，司玉贵，徐德伟 有机氟工业， 2001，3，1. 课题负责人：施 敏 课题编号： 2000-09 16 456 Commented [jiangb1]: Page: 16 1. Titanium(IV) Chloride, Zirconium(IV) Chloride or Boron Trichloride and PhosphinesPromoted Baylis-Hillman Reaction of Aldehydes with ,-Unsaturated Ketone Min Shi,* Jian-Kang Jiang, Shi-Cong Cui, and Yan-Shu Feng J. Chem. Soc., Perkin Trans I, 2001, 390. 460 2. Titanium(IV) Chloride and Quaternary Ammonium Salt Promoted Baylis-Hillman Reaction Min Shi* and Yan-Shu Feng J. Org. Chem., 2001, 66, 406. 464 3. Chiral C2-Symmetric 2,3-Disubstituted Aziridine and 2,6-Disubstituted Piperidine as Chiral Ligands in the Addition Reaction of Diethylzinc with Arylaldehydes Min Shi,* Jian-Kang Jiang and Yan-Shu Feng Tetrahedron:Asymmetry, 2000, 11, 4923. 470 4. Oxidation of Benzyl Chlorides and Bromides to Benzoic Acids with 30% Hydrogen Peroxide in the Presence of Na2WO4, Na2VO4, or Na2MoO4 under Organic SolventFree Conditions Min Shi* and Yan-Shu Feng J. Org. Chem., 2001, 66, 3235. 481 5. New Discovery in the traditional Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone Min Shi,* Chao-Qun Li, and Jian-Kang Jiang J. Chem. Soc., Chem. Commun., 2001, 833. 484 6. Perfluorinated rare earth metals catalyzed reactions of 5-methylene-2-oxazolidinone and 5-methylene-1, 3-thiazolidine-2-thione with isocyanates Min Shi,* Yu-Mei Shen J. Fluor. Chem., 2001, 109, 195. 486 7. Titanium(IV) chloride and oxy-compounds promoted Baylis-Hillman reaction Min Shi,* Jian-Kang Jiang and Shi-Cong Cui Tetrahedron, 2001, 57, 7343. 492 8. Synthesis of chiral C2-symmetric bidentate ligands having different ring sizes of cyclic amines and their catalytic abilities on enantioselective cyclopropanation of styrene catalyzed by copper(I) triflate Min Shi,* Jian-Kang Jiang, Yu-Mei Shen, and Yan-Shu Feng J. Chem. Res., 2001, 375. 497 9. An Interesting Dihedral Angle Expansion in a Series of Monophosphoramides of (R)- 17 (+)-1,1'-Binaphthyl-2,2'-diamine Min Shi,* and Wen-Sheng Sui J. Chem. Res., 2001, 336. 500 10. Reactions of 5-Methylene-1,3-thiazolidine-2-thione and 5-Methylene-2oxazolidinone with Isocyanates Catalyzed by Bases Min Shi* and Yu-Mei Shen Heteroatom Chemistry, 2001, 7, 610. 503 11. Enantiodifferentiating Photoisomerization of (Z)-Cyclooctene Sensitized by Chiral C2-Symmetric Phosphoramide Min Shi* and Yoshihisa Inoue Aust. J. Chem., 2001, 54, 113. 510 12. Lewis base effects in the Baylis-Hillman reaction of imines with cyclohex-2-en-1-one and cyclopent-2-en-1-one. Min Shi,* Yong-Mei Xu J. Chem. Soc., Chem. Commun., 2001, 1876. 513 13. Photolysis of oxygen saturated ethers in the presence of Sn(II) or Cu(II) salts. Min Shi,* Chin. J. Chem., 2000, 18, 936. 515 14. The mechanistic insights of an unexpected carbon dioxide insertion reaction through the crystal structures of carbamic diphenylthiophosphinic anhydride and trans-2,5pyrrolidine dicarboxylic acid, 1-[(4-nitrophenyl) sulfonyl]-, methyl ester Min Shi,* Y.-M. Shen, J.-K. Jiang Chin. J. Chem., 2001, 19, 404. 519 课题负责人：丁奎岭 课题编号： 2000-10 1． Engineering the catalysts for enantioselective addition of diethylzinc to aldehydes with racemic amino alcohols: nonlinear effect in asymmetric deactivation of racemic catalysts J. Long, K. Ding* Angew. Chem. Int. Ed. Engl., 2001, 40, 544-547. 527 2． Asymmetric Activation of Chiral Alkoxy-Zinc Catalysts by Chiral Nitrogen Activators for Dialkylzinc Addition to Aldehydes: Super High Throughput Screening of Combinatorial Libraries of Chiral Ligands and Activators by HPLCCD/UV and HPLC-OR/RIU K. Mikami*, R. Angelaud, K. Ding, A. Ishii, A. Tanaka, N. Sawada, K. Kudo, and M. Senda 18 Chem. Eur. J., 2001, 7, 730-737. 531 3． Highly regio- and enantioselective palladium-catalyzed allylic amination with sodium diformylamide Y. Wang, K. Ding* J. Org. Chem. 2001, 66, 3238-3241. 539 4． Pd-Catalyzed asymmetric allylation with a novel C2-symmetric bisphosphinite ligand: 3R,3’R-bis- (diphenylphosphinoxy)- 6,6,6’,6’-tetramethyl-2R,2’R-di-4Hpyan R. Zhang, L. Yu, L. Xu, Z. Wang, K. Ding* Tetrahedron Lett. 2001, 42, 7659-7662. 543 5． Molecular assembly in an inclusion crystal of tris(2-benzimidazylmethyl)amine with 4-nitrobenzoic acid B. Ji, C. Du, Y. Zhu, K. Ding* J. Chem. Cryst. 2000, 30, 783-788. 6． Solid-state asymmetric reduction of (S)-1,1’-bi-2-naphthol-acetylferrocene molecular compound with sodium borohydride H. Du, K. Ding*, J. Meng Chin. J. Chem. 2001, 19, 716-718. 547 7． Engineering chiral catalysts through asymmetric activation and super high throughput screening K. Mikami*, T. Korenaga, S. Matsukawa, K. Ding*, J. Long Chin. J. Chem. 2001, 19, 545-557. 550 8． Synthesis of Some Novel Amino Phenols with Octahydro-1,1’-binaphthyl Backbone H. Guo, Y. Wang, K. Ding* Chin. J. Chem., 2001, 19, 52-57. 562 9． 催化不对称 Friedl-Crafts 反应 王以，丁奎岭* 有机化学，2001，21，763-767. 课题负责人：唐 勇 568 课题编号： 2000-11 1. Highly diasteraoselective Synthesis of Trimethylsilylvinyl-cyclopropane Derivatives S. Ye, Y. Tang*, L.-X. Dai J. Org. Chem., 2001, 66, 1517. 573 2. A Practical Catalytic Ylide Reaction 19 Zheng-Zheng Huang, Song Ye, Wei Xia, Yong Tang* Chem. Commun. 2001, 1384-1385. 课题负责人： 廖世健 579 课题编号： 2000-12 1. Isospecific polymerization of styrene with modified Ziegler-type catalysts Qi Sun, Yinheng Fan, Shijian Liao, Fudong Wang, Jie Xu. Polymer., 2001, 42, 4087-4090. 581 2. Chemical reactivities of magnesium nanopowders Yuankui Zhang, Shijian Liao, Yinheng Fan, Jie Xu, Fudong Wang. J. Nanoperticle Research 2001, 3, 23-264. 585 3. 纳米 LiH 的热稳定性与催化加氢反应活性 范荫恒, 廖世健, 李伟娜, 徐杰, 王复东. 应用化学, 2001，18(5), 389-392. 589 课题负责人： 宋礼成 课题编号： 2000-13 1. Synthesis of Double and Quadruple Butterfly Fe/E Cluster Complexes via a New Type of Selenium-Centered Anions (-RE)(-Se-)[Fe2(CO)6]2(4-Se) (E=S, Se, Te) Derived from Novel Reaction of [(-RE)(-CO)Fe2(CO)6]- with (-Se2)Fe2(CO)6. Crystal Structures of 4-Se-Containing Double Clusters (-EtS)(PhCH2Se)[Fe2(CO)6]2(4-Se), (-p-MeC6H4Se)(-MeSe)[Fe2(CO)6]2(4-Se) and (-p-MeC6H4Te)(-MeSe)[Fe2(CO)6]2(4-Se) Li-Cheng Song,* Jing Yang, Qing-Mei Hu and Qiang-Jin Wu Organometallics, 2001, 20, 3293. 592 2. Unexpected Metallosite-Selective CO Substitution of Heteronuclear Tetrahedral (3S)FeCoM (M=Mo, W) Carbonyl Clusters with Cyclohexyl Isocyanide: 59Co NMR and 57Fe Mössbauer Spectra of (3-S)FeCoMo(CO)8-n(5-C5H4COMe) (C6H11NC)n (n=1-3) and Crystal Structures of (3-S)FeCoM(CO)8-n(5-C5H4R) (C6H11NC)n (M=Mo, W; R=MeCO, MeO2C; n=1, 2) Li-Cheng Song,* Chun-Cheng Luo, Qing-Mei Hu, Jiabi Chen and Hong-Gen Wang Organometallics, 2001, 20, 4510. 374 3. Synthesis of Double and Multiple Butterly Fe/E(E=S, Se, Te) Cluster Complexes via Reactions of Complex Anions [(-RE)(-CO)Fe2(CO)6]- (E= S, Se, Te). Crystal Structures of (-p-MeC6H4Se)(-MeS)[Fe2(CO)6]2(4-S) and {(-t-BuS) [Fe2(CO)6]2 (4-S)}2[(-p-SCH2)2C6H4] Li-Cheng Song,* Guo-Liang Lu, Qing-Mei Hu, Jing Yang and Jie Sun J. Organomet. Chem., 2001, 623, 56. 598 20 4. Synthesis of Single and Double Butterfly Iron Carbonyl Complexes by Reactions of [(-RSe)(-CO)Fe2(CO)6]- Anions. Crystal Structures of (-p-MeC6H4Se)[-PhCH2 N(H)C=S]Fe2(CO)6 and [(-PhSe)(-MeAs)Fe2(CO)6]2 Li-Cheng Song,* Guo-Liang Lu, Qing-Mei Hu, Hong-Tao Fan, Jiabi Chen, Jie Sun and Xiao-Ying Huang J. Organomet. Chem., 2001, 627, 255. 381 5. Reactions of Metal-Metal Triply Bonded Complexes [(5-RC5H4)2M2(CO)4](M = Mo, W) with diphenyl ditelluride. Crystal Structures of [(5-MeC5H4)Mo2(CO)4 (TePh)3] and [(5-EtO2CC5H4)2W2(CO)4(-TePh)2] Li-Cheng Song,* Yao-Cheng Shi, Qing-Mei Hu, Yu Chen and Jie Sun J. Organomet. Chem., 2001, 626, 192 . 607 6. Synthesis and Electrochemical Properties of Organometallic Macrocyclic Crown Ethers Containing Redox-Active Tetrahedral Mo2Fe(3-S) Cluster Cores. Crystal Structures of [Mo2Fe(3-S)(CO)7][5-C5H4CH2(CH2OCH2)nCH2C5H4-5] (n=1-3) Li-Cheng Song,* Dian-Shun Guo, Qing–Mei Hu, Fu-Hai Su, Jie Sun, and Xiao-Ying Huang J. Organomet Chem., 2001, 622, 210. 614 7. Syntheses, Spectroscopic Characterization and Electrochemical Properties of Organometallic Crown Ethers Containing Tetrahedral W2Fe(3-S) Cluster Cores [W2Fe(3-S)(CO)7][5-C5H4CH2(CH2OCH2)nCH2C5H4-5] (n=1-3). Crystal Structures of [W2Fe(3-S)(CO)7][5-C5H4CH2(CH2OCH2)nCH2C5H4-5] (n=2，3) Li-Cheng Song,* Dian-Shun Guo, Qing-Mei Hu and Jie Sun J. Organomet. Chem., 2001, 616, 140. 625 课题负责人： 黄 宪 课题编号： 2000-14 1．Alkyne-Based, Highly Stereo- and Regioselective Synthesis of Stereodefined Functionalized Vinyl Tellurides Xian Huang, Chun-Gen Liang, Qing Xu, Qi-Wen He J. Org. Chem. 2001, 66, 74. 634 2．Reactions of aldehydes with polymer-supported selenoalkylidenetriphenylphosphoranes. A facile method for the synthesis of carbonyl compounds Xian Huang, Shou-Ri Sheng Tetrahedron Letters, 2001, 42, 9035. 641 3．Preparation of resin-bound alkynyl iodonium salts and their application in organic synthesis as alkynyl transfer reagents Xian Huang, Qing Zhu Tetrahedron Letters, 2001, 42, 6373. 644 21 4．Polymer-Supported Selenol Esters as Useful Acylating Reagents. Application to ,Acetylenic Ketones Synthesis Hao Qian, Li-Xiong Shao, Xian Huang Synlett, 2001, 1571. 647 5．Polystyrene-supported selenosulfonates: Efficient reagents for regio- and stereocontrolled synthesis of vinylsulfones Hao Qian, Xian Huang Synlett, 2001, 1913. 课题负责人： 沈 琪 649 课题编号： 2000-15 1. Insertion Reaction of Phenyl Isocyanate and Phenyl Isothiocyanate into the Nd-S Bond of [(CH3C5H4)2Nd(-SPh)(THF)]2: Synthesis and Crystal Structures Qi Shen, Huanrong Li, Changsheng Yao, Yingming Yao, Lilu Zhang, Kaibei Yu, Organometallics, 2001, 20(14), 3070. 653 2. Syntheses of {(MeC5H4)2Ln[O C N(CH2)4CH2]}2 (Ln=Yb, Y, Er) and the X-ray Crystal Structure of the Ytterbium Complex Yaorong Wang, Qi Shen, Liping Wu, Yue Zhang, Jie Sun J. Organomet. Chem., 2001, 626, 176. 657 3. Synthesis and reactivities of bisaryloxo lanthanide chlorides and crystal structures of [Ln(ArO)2Cl(THF)2](MePh) (Ln = Er, Yb) and [Sm(ArO)2(THF)3](MePh) (ArO = 2,6-di-tert-butyl-4-methylphenoxo) Yingming Yao, Qi Shen, Yue Zhang, Ming-Qiang Xue, Jie Sun Polyhedron, 2001, 20(26/27), 3201. 662 4. Syntheses and crystal structures of four-coordinate aryloxo neodymium complexes Li-Lu Zhang, Ying-Ming Yao, Yun-Jie Luo, Qi Shen, Jie Sun Polyhedron, 2000, 19(20/21), 2243. 670 5. Efficient polymerization of acrylonitrile catalyzed by divalent lanthanide complex/sodium phenolate systems Yao yingming, Shen Qi, Zhang Lilu Chin. Sci. Bull., 2001, 46(17), 1443. 675 6. 二价稀土配合物/酚钠体系催化的丙烯腈高效聚合 姚英明，沈琪，张黎路 科学通报，2001，46(11)，906. 678 7. Synthesis and Crystal Structure of [Nd(6-1,3,5-C6H3Me3)(AlCl4)3](C6H6) and Structural Comparison of Ln(6-arene)(AlCl4)3 Yao Yingming, Zhang Yue, Shen Qi, Liu Qiancai, Meng Qingjin, Lin Yonghua 22 Chin. J. Chem., 2001, 19(6), 588. 682 8. 二价钐配合物和异氰酸苯酯的反应－[(CH3C5H4)2(THF)Sm]2[-4(PhN)OCCO(NPh)]·2THF 的合成、晶体结构及其催化性能 袁福根，沈琪，孙杰 高等学校化学学报，2001，22(9)，1501. 课题负责人： 康北笙 687 课题编号： 2000-16 1. Syntheses and characterization of copper(II) complexes of bisacetylacetonetrimethylenediimine (H2acactn) Cai, Y. P., Su, C. Y., Xu, A. W., Kang, B. S.*, Tong, Y. X., Liu, H. Q., Sun, J., Polyhedron, 2001, 20 (8), 657-662. 692 2. Construction of tetranuclear lanthanide Schiff base complexes Cai, Y. P., Ma, H. Z., Kang, B. S.*, Su, C. Y., Zhang, W., Sun, J., Xiong, Y. L. J. Organometallic Chem., 2001, 628 (1), 99-106. 698 3. Self-assembly of silver(I) polymers with single strand double-helical structures containing the ligand O,O’-bis(8-quinolyl)-1,8-dioxaoctane Cai, Y. P., Su, C. Y., Zhang, H. X., Chen, C. L., Liu, H. Q., Zhang, L., Kang, B. S.* J. Chem. Soc. Dalton Trans., 2001, ( ), 2429-2434. 706 4. Assembly of a novel cyclic dimer encapsulating PF6- into the brick wall network Liu, J., Liu, H. K., Feng, X. L., Zhang, H. X., Zhou, Z. Y., Chan, A. S. C., Kang, B. S.* Inorg. Chem. Commun., 2001, 4 (11), 674-677. 712 5. Molecular and crystal sturcture of 1,3,5-tris(benzimidazol-1-ylmethyl)- 2,4,6trimethylbenzene Cai, Y. P., Kang, B. S.*, Su, C. Y., Zhang, H. X., Yang, X. P., Deng, L. R., Xu, A. W., Zhou, Z. Y., Chan, A. S. C. 结构化学 Jiegou Huaxue, 2001, 20(4), 262-265. 716 6. 含咪唑基配体的笼状双核铜超分子配合物的合成与晶体结构 Liu, J., Liu, H. K., Feng, X. L., Zhang, H. X., Zhou, Z. Y., Chan, A. S. C., Kang, B. S.* 化学学报，2001, 59(12), 2209-2212. 720 课题负责人： 沈之荃 课题编号： 2000-17 23 课题负责人： 张永敏 课题编号： 2000-18 1. Intramolecular and intermolecular reductive coupling reactions of ketone-ester promoted by SmI2 刘运奎, 张永敏* Tetrahedron Lett., 2001, 42, 5745. 724 2.Ytterbium metal promoted reaction of diselenides with allyl bromide 苏为科,张永敏* , 李永曙 J. Indian Chem. Soc., 2001, 78, 313. 728 3. A novel one pot synthesis of cyclopentanol derivative from aldehydes and αhaloketones by samarium(III) iodide and samarium(II) iodide 范学森, 张永敏* J. Chem. Res.(S), 2001, 104. 731 4. Samarium diiodide mediated simultaneous reduction of nitro group and the azide group in o-nitrophenylazide: a new access to 2,3-dihydro-1H-1,5-benzodiazepines 钟为慧,张永敏*,陈小原 J. Chem. Res(S), 2000, 532. 733 5. A novel method for the synthesis of allylic sulfides from disulfides and allylytterbium bromide 苏为科, 李永曙, 张永敏* J. Indian Chem. Soc., 2001, 78, 263. 736 6. Simultaneous reduction of the nitro group and the azide group in O-nitrophenylazide induced by the TiCl4/Sm system; a novel Synthesis of 2,3-dihydro-1H-1,5benzodiazepines 钟为慧,张永敏* ,陈小原 Tetrahedron Lett., 2001, 42, 73. 738 7. Samarium diiodide promoted reductive cyclization of nitrodisulfides with nitriles: A new route to benzothiazoles 钟为慧,张永敏* ,陈小原 J. Indian Chem. Soc., 2001, 78, 316. 741 8. Synthesis of 2H-1,4-benzothiazin-3(4H)-ones and 2H-1,4-benzoselenazin-3(4H)-ones with the aid of samarium (Ⅱ)iodide. 钟为慧,张永敏* Tetrahedron Lett., 2001, 42, 3125. 744 9. Convenient one pot synthesis of α-selenonitriles, α-selenoesters and asymmetrical 24 selenides by a Sm/ZnCl2 system in DMF-H2O 郭红云, 郑云法,张永敏* J. Chem. Res.(S), 2001, 160. 747 10. Synthesis of quinolines: reductive coupling reactions of 2-nitro-1,3-diphenyl-2propen-1-one induced by low-valent Titanium. 马永敏,张永敏* J. Chem. Res.(S), 2001, 108. 749 11. Low valent titanium induced one-pot synthesis of imidazolidines 李志芳, 张永敏* Org. Prep. Proced. Int., 2001, 33(2), 185. 751 12. Reductive coupling of ketones with imines promoted by the titanium tetrachloride/samarium system 马永敏, 张永敏* Org. Prep. Proced. Int., 2001, 32(6), 567. 754 13. Convenient preparations of polysubstituted 3H-pyrroles promoted by SmI2 许孝良, 张永敏* J. Chem. Soc. Perkin 1, 2001, 2836. 758 14. SmI3 catalyzed reaction of salicyaldehydes with active methylene compounds 陈珏, 张永敏* J. Chem. Res.(S), 2001, 394. 762 15. Synthesis of dihydrofurans from diaryl ketones and chalcones promoted by samarium diiodide/samarium 马永敏,张永敏*, 陈珏 Synthesis, 2001,(7), 1004. 764 16. Samarium(III) iodide promoted preparation of α, α’-bis(substituted benzylidene) cyclohexanones from benzaldehydes and cyclohexanenone 李志芳,张永敏*, 李巧玲 J. Chem. Res.(S), 2000, 580. 767 17. Samarium diiodide induced reductive coupling of nitriles with azides 苏为科, 李永曙, 张永敏*, J. Chem. Res.(S), 2001, 32. 769 18. SRN1 reaction of haloarenes with benzenethiolate, benzeneselenolate and benzenetellurolate ions 张永敏*,郭红云 Heteroatom Chem., 2001, 12(6), 539. 771 25 19. Direct construction of a quaternary center utilizing an organosamarium reagent 李志芳， 张永敏* Tetrahedron Lett. 2001, 42, 8507. 774 20. Stereoselective synthesis of (2E)-cinnamanilides via desulfonylation of (2E)-αamino-α,β-unsaturated silfones 刘运奎, 张永敏* Org. Prep. Proced. Int., 2001, 33(4), 372. 778 21. A convenient method for the reductive desulfonylation of some sulfones by the Sm/HOAc system 郭红云, 张永敏* J. Chem. Res.(S), 2001, 26. 782 22. Intermolecular heterocoupling reaction between N-sulfonylimines and aliphatic ketones romoted by samarium(II) iodide 刘运奎,张永敏*, 刘希 Chin. J. Chem., 2001, 19(5), 500. 784 23. Samarium diiodide mediated coupling of aryl chlorides 李志芳,张永敏* Chin. J. Chem., 2001, 19(6), 634. 788 24. Low-valent titanium induced reductive coupling of o-nitrophenyl azide with benzoyl substituted ketene dithioacetals: a novel synthesis of 4-aryl-2-methylthio-3H-1,5benzodiazepines 李志芳, 张永敏* Chin. J. Chem., 2001, 19, 996. 791 25. Mono-allylation of gem-diacetates with allylsamarium bromide 王小霞, 张永敏* Chin. Chem. Lett., 2001, 12(11), 943. 794 26. Steroselective synthesis of (E)-cinnmates with the Sm/HOAc system 范学森, 张永敏* Chin. J. Chem., 2001, 19, 914. 796 27. Selective deoxygenation of nitrones mediated by Sm/.CoCl2·6H2O reductive system 张纪明, 张永敏* Chin. Chem. Lett., 2001, 12(11), 945. 799 28. Synthesis of allyl selenides promoted by an Sm/ZnCl2 bimetal system in the presence of water 郑云法, 郭红云, 张永敏* Chin. J. Chem., 2001, 19(5), 530. 801 26 29. Allylation of Imines with allylytterbium bromide 苏为科,张永敏* , 李永曙 Chin. J. Chem., 2001, 19, 205. 804 30. Allylation of diselenides aldehydes and ketones with ytterbium/allyl bromide system 苏为科,张永敏* , 李永曙, Chin. J. Chem., 2001, 19(4), 381. 809 31. Application of Sm0/auxiliary and Sm0/MCln system in organic synthesis 张永敏*,刘运奎 Chin. J. Chem., 2001, 19, 123. 812 32. 锰试剂在有机合成中的应用 范学森，张永敏* 有机化学, 2001, 564. 820 33. Reductive Cyclodimerization of α,β-unsaturated ketones promoted by AlCl3/Sm System: A Facile Synthesis of 2-Aroyl-1,3,4-triaryl Cyclopentanol Derivatives. 范学森,张永敏* Chin. J. Chem., 2001, 19(6), 616. 829 34. A New Approach to 2,3-Dihydro-1H-1,5-Benzodiazepines from the Reaction of ONitrophenylazide with a,b-Unsaturated Ketones Promoted by Samarium Diiodide 陈小原, 钟为慧 , 张永敏* Chin. Chem. Lett., 2001, 12(1), 5. 833 35. Low-valent Titanium induced simultaneous reduction of nitro group and S-S bond in nitrodisulfides: a facile synthesis of 2H-1,4-benzothiazines 张永敏*,钟为慧,陈小原 Chin. J. Chem. 2001, 19, 189. 835 课题负责人： 张良辅 课题编号： 2000-19 1．平面手性二茂铁的合成及其在不对称催化反应中应用的最新进展 张俊龙，董长娥，韩杰，于作龙，张良辅* 有机化学，2001，22，573-588. 课题负责人： 刘汉范 839 课题编号： 2000-20 27 1 ． Modification of metal cations on the stereoselective hydrogenation of 2,3butanedione Xiaobin Zuo, Yan Li and Hanfan Liu Catal. Lett., 2001, 71/3-4, 177-180. 855 2 ． Improvement in the enantioselective hydrogenation of methyl pyruvate over platinum clusters by addition of rare earth metal cations Xiaoping Yan, Hanfan Liu* and Ji Zhao Catal. Lett., 2001, 74/ 1-2, 81-83. 859 3．Enantioselective hydrogenation of trifluoroacetophenone over polymer-stabilized platinum nanoclusters Jie Zhang, Xiao-Ping Yan and Hanfan Liu* J. Mol. Catal., A: Chem.,2001, 175/1-2, 125-130. 862 4 ． The effects of tin on the hydrogenation of -diketones over platinum nanoclusters Jie Zhang, Xiao-Ping Yan and Han-Fan Liu* J. Mol. Catal., A: Chem., 2001, 176/1-2, 279-284. 868 课题负责人： 王积涛 课题编号： 2000-21 课题负责人： 徐善生 课题编号： 2000-22 1. Synthesis and structures of doubly bridged biscyclopentdienyl tetracarbonyl diiron complexes, Xu, S., Zhang, J., Zhu, B., Wang, B., Zhou, X., Weng, L. J. Organomet. Chem., 2001, 626, 186-191. 874 2. Ethylene polymerizations with cycloalkylidene-bridged cyclopentadienyl metallocene catalysts, Xu, S., Deng, X., Wang, B., Zhou, X., Yang, L., Li, Y., Hu, Y., Macromol. Rapid Commun., 2001, 22, 708-709. 880 3. Unexpected formation of the ruthenium carbonyl cluster with a trigonal-bipyramidal Ge2Ru3 core accompanied by loss of germanium methyl groups Zhang, Y., Wang, B., Xu, S., Zhou, X. Organometallics, 2001, 20, 3829-32. 882 28 4. 四甲基硅锗桥连双环戊二烯基及双(四甲基环戊二烯基)四羰基二铁的合成、结构 及热重排反应 孙秀丽, 王佰全, 徐善生, 周秀中, 翁林虹 化学学报, 2001, 59, 1639-1645. 886 5. 碳锗双桥连二环戊二烯与羰基铁的反应 朱柏林, 张建勇, 徐善生, 王佰全, 周秀中, 翁林虹 高等学校化学学报增刊, 2001, 22(10 增), 77-80. 课题负责人： 周其林 893 课题编号： 2000-23 1．Synthesis of chiral 2-alkyl substituted 8-quinolinyl-oxazoline ligands: Reversal of enantioselectivity in the asymmetric palladium-catalyzed allylic alkylation Xiao-Guang Li, Xu Cheng, Jun-An Ma and Qi-Lin Zhou J. Organomet. Chem., 2001, 640, 65-71. 897 2．Chiral camphor derivatives as new catalysts for asymmetric phase-transfer alkylation Jie Zhang, Xin-Yan Wu, Qi-Lin Zhou and Jie Sun Chin. J. Chem., 2001, 19(6), 630-633. 904 课题负责人： 曹卫国 课题编号： 2000-24 1. Study on the Reaction of Electron-Deficient Cyclo-propane Derivatives with Amines Chen Yali, Ding Weiyu, Cao Weiguo* and Lu Cheng Chin. J. Chem., 2001, 19(9), 901-6. 908 课题负责人： 周锡庚 课题编号： 2000-25 1. Insertion Reaction of Phenyl Isocyanate into LnC -Bond of Organolanthanide Complexes: Synthesis, Characterization, and Crystal Structures of {(C5H4CH3)2Ln[1:3-OC(R)NPh]}2 (Ln = Sm, Dy, Er, Ho; R = n-Butyl, -naphthyl) Xigeng Zhou, Libei Zhang, Ming Zhu, Ruifang Cai, Linhong Weng, Zixiang Huang, Qiangjin Wu Organometallics, 2001, 20, 5700. 914 课题负责人： 席振峰 课题编号： 2000-26 29 课题负责人： 江焕峰 课题编号： 2000-27 课题负责人： 庞 课题编号： 2000-28 震 1. Preparation, Crystal Structure and Spectroscopic Studies of Mixed Valences Compound [(Cp4iRh)2(-Cl)3][Rh(CO)2Cl2] Xu,You-Feng, Pang, Zhen*, Chen, Ming-Q Chin. J. Chem., 2001, 4, 356. 课题负责人： 张兆国 课题编号： 2000-29 课题负责人： 赵 刚 课题编号： 2000-30 课题负责人： 王绍武 课题编号： 2000-31 30 921