金属有机化学国家重点实验室2015年年度进展报告.docx

学科带头人现状与需求 现有人员 目前学科方向 陆熙炎院士 过渡金属有机化学 戴立信院士 不对称催化 麻生明院士 过渡金属有机化学 丁奎岭院士 不对称催化 侯雪龙研究员 不对称催化 施敏研究员 过渡金属有机化学 唐勇研究员 主族金属有机化学，高分子化学 刘元红研究员 钛、锆金属有机化学，过渡金属催化 陈耀峰研究员 稀土金属有机化学 游书力研究员 过渡金属有机化学，不对称催化 刘国生研究员 过渡金属有机化学 邓亮研究员 廉价金属有机化学 李玉学研究员 计算金属有机化学 黄正研究员 金属有机化学和催化 张国柱研究员 过渡金属催化 梅天胜研究员 过渡金属催化的小分子活化 余金权研究员 碳氢键活化反应 发展学科方向 需求计划人数 金属催化的小分子活化 1 金属络合物及反应化学 1 后过渡金属有机化学 1 前过渡金属有机化学 1 主族元素金属有机化学 1 金属有机计算化学 1 一、科研工作与成果 按照国家科技部最新要求和规定，2015 年自主研究课题共计资助 599.7 万元，包括 自由探索课题 16 项，资助 200 万，团队重点课题 5 项，资助 249.7 万元，人才引进项目 3 项，资助 60 万；2015 年实验室面向所外单位设立的开放基金项目有 29 项，资助总额 149.69 万元。 2015 年实验室共发表 305 篇论文（含客座人员发表论文）。以实验室为第一作者单 位的论文 104 篇（包括 J. Am. Chem. Soc. 13 篇，Angew. Chem. Int. Ed. 14 篇，Chem. Sci. 4 篇，ACS Catalysis 2 篇，Chem. Commun. 8 篇，Org. Chem.Front. 10 篇，Org. Lett. 14 篇，Chem. Eur. J. 8 篇，Adv. Synth. Catal. 3 篇，Organometallics 8 篇），І 区论文占总论 文数的 29.8%，编著英文专著 1 部，撰写专著章节 2 章，申请专利 25 项，授权发明专 利 12 项。 2015 年实验室在研各级各类科研任务 94 项，研究任务总经费达 12428.6 万元（合 同签订额），已拨付到位 2975.4491 万元。具体情况如下： 主持的国家和省部委的重大重点项目有：基金委创新群体项目 1 项、重大研究计划 重点支持项目 1 项、重点项目 3 项、杰出青年基金项目 3 项、优秀青年基金项目 2 项、 国际合作项目 4 项；中科院重点部署项目 1 项、科技创新交叉与合作团队项目 1 项；上 海市基础研究项目 1 项。作为课题负责人承担的有：科技部 973 课题 4 项、国家科技重 大专项课题 1 项、科技支撑计划项目课题 1 项、中科院院重点部署项目课题 1 项。作为 骨干成员参加的有：科技部 973 课题 2 项、基金委重点项目 3 项。另外还承担了基金委、 中科院、上海市及其他省部委项目 53 项；横向项目 12 项。 实验室今年在金属有机配合物的合成、结构及反应化学，过渡金属参与的新反应， 不对称催化等方面取得了一些突出的成果： (1) 金属有机配合物合成、结构及反应化学：通过钪甲基膦基配合物和钪双甲基配 合物的反应合成了一个新颖的稀土钪亚甲基膦宾配合物，该配合物可以快速地和不饱 和底物，如 CO2、CS2、苯基氰以及叔丁基异腈等发生亲核加成反应，有趣的是反应高 选择性地发生在 Sc-C 键，展示了配合物中亚甲基的反应性要明显高于膦宾基团，相关 结果发表在 Organometallics 2015, 34, 470，并被选为 ACS Editors' Choice；利用大位阻 氮杂环卡宾配位的钴(0)配合物[(IPr)Co(vtms)2]和大位阻的有机叠氮 DmpN3 反应，成功 实现了首例含钴-主族元素多重键的两配位配合物，通过理论计算表明该配合物符合 Co-N 多重键性质，并进而研究了该配合物与一氧化碳、乙烯、对甲基苯乙炔、二苯基 硅烷等的反应，展现了低配位后过渡金属亚胺基物种的高反应活性，相关研究成果发表 在 Angew. Chem. Int. Ed. 2015, 54, 12640；以大位阻氮杂环卡宾稳定的零价铁配合物作为 反应前体，成功合成了系列三配位四价铁亚胺基化合物，并以[(IMes)Fe(NDipp)2]为代表， 系统地研究了这类配合物的反应性质，该配合物在加热下转化为罕见的分子内烷基链脱 氢产物，与 PhSiH3 的反应生成二价铁胺基配合物，与亲核试剂 PhNCNPh 可以发生[2+2] 环加成反应，生成形式上的四价铁单亚胺基配合物，相关研究成果发表在 J. Am. Chem. Soc. 2015, 137, 14196。 (2) 过渡金属参与的新反应：在前期工作的基础上，研究了烯基氮杂环丙烷与缺电 子烯烃的反应，利用已发展的 SIOCPhox 配体，实现了钯催化下氮杂环丙烷与 α,β-不饱 和酮的不对称 Michael 加成－分子内烯丙基烷基化反应，以良好到优秀的产率及非对映 选择性和对映选择性得到了 2，3－二取代四氢吡咯，这是第一例使用单一活化基团的缺 电子烯烃与烯基氮杂环丙烷的催化不对称 Michael 加成-分子内烯丙基化反应，进而研究 了产物的转化，显示了这一方法在有机合成中的价值，相关研究结果发表在 Angew. Chem. Int. Ed. 2015, 54, 1604；利用联吡啶膦[PNN]钴催化剂，对芳香基乙烯类单体的硼 化反应进行了研究，将芳基乙烯与联硼酸频哪醇酯反应得到 1,1,1-三硼烷基化合物，并 进行了机理研究，该类反应弥补了合成此类化合物的常规方法，机理研究表明此类反应 涉及一价钴硼物种，并通过两步脱氢硼化和一步硼氢化反应得到产物，1,1,1-三硼烷基 化合物可以方便的制备非末端的二硼烷基化合物，工作发表在 J. Am. Chem. Soc. 2015, 137，15600；利用自由基与金属中心结合的模式，发展了苯乙烯的高区域选择性的氟硫 化反应，针对苯乙烯类内烯烃，反应能兼具高区域和立体选择性（J. Am. Chem. Soc. 2015, 137, 2468） ；以 AgOCF3 为 OCF3 来源，Selectfluor 为氧化剂，实现了首例钯催化非 活性烯烃的氧三氟甲基化反应，并对 C-OCF3 键的形成进行了研究，认为是通过 Pd(IV) 中心的还原消除形成的（J. Am. Chem. Soc. 2015, 137, 15648）；金催化的反应是目前有机 合成中的研究热点，尤其是多种新型的串联环化反应和氧化条件下的新型重排反应，设 计合成了多种 2-炔基-1,2-二氢吡啶衍生物并发现其在金催化剂和吡啶氮氧化物作用下， 可以发生叁键的高区域选择性氧化和 1,2-烯基迁移反应，并以良好至优秀的收率得到了 一系列苯并氮杂卓类衍生物，该反应具有条件温和、官能团兼容性强等优点，该工作发 表在 Angew. Chem. Int. Ed. 2015, 54, 1200。 (3) 不对称催化：在 SKP/Pd(II)/Cu(II)催化下，末端联烯与芳胺、CO 和甲醇顺利 地发生四组份一锅法反应，以良好的收率和优秀的区域/对映选择性获得一系列手性 α亚甲基取代的 β-氨基酸酯衍生物。该反应同时实现了对多组分不对称催化反应的化学、 区域、和对映选择性的多层次控制，这在(联烯)多组分不对称催化反应研究中具有很大 的挑战性且十分罕见，该工作作为封面文章发表在 J. Am. Chem. Soc. 2015, 137, 15346， 被 JACS 2015 第 49 期的 Spotlights 栏目以“TRIPLE ALLENE ADDITION IN ONE SHOT” 为题做特色介绍，并获 SynFacts 好评(H. Yamamoto, A. Banjergee, SynFacts 2015, 11, 1280)；以边臂修饰的手性噁唑啉为配体，实现了共轭双烯体与推拉电子环丙烷的不对 称[4+3]环加成反应，取得了最高 98%的分离产率，和最高 85:15 的 dr 值，为多官能团 化的七元环化合物的合成提供了一种新的途径，并对机理进行了研究，工作发表在 J. Am. Chem. Soc. 2015, 137, 8006；采用高氯酸铜水合物既作为 Lewis 酸催化剂也作为体系 中水的存储器，利用其缓释作用调节催化体系中水的浓度，首次实现了水对环丙烷的高 活性对映选择性开环，为高效合成一系列具有光学活性的 γ-羟基酸衍生物提供了新的 方法，研究结果发表在 J. Am. Chem. Soc.2015, 137, 14594；在催化不对称去芳构化反应 研究方面，实现了铑催化不对称 C-H 键活化/环化萘酚去芳构化反应，成功制备一系列 含有全碳季碳手性中心的 2-萘酮类化合物，工作发表在 J. Am. Chem. Soc. 2015, 137, 4880；实现了金属铱催化的对吡啶，吡嗪，喹啉以及异喹啉等贫电子芳环的烯丙基去芳 构化反应，能够以高达 99%的收率以及 99% ee 的对映选择性得到相应去芳构化的产物， 并对反应的机理进行了探究，进而完成了对天然产物 Gephyrotoxin 的形式不对称合成， 相关结果发表在 J. Am. Chem. Soc. 2015, 137, 15899；通过合作研究报道了首例铜催化的 炔丙基去芳构化反应，使用简单易得的色醇或色胺等吲哚衍生物与炔丙基醋酸酯，在廉 价的铜源和 Pybox 手性配体的催化下， 实现了吲哚分子间的不对称炔丙基去芳构化反应， 工作发表在 Angew. Chem. Int. Ed.2015, 54, 7684。 二、队伍建设与人才培养 实验室目前有 16 个课题组，学术骨干队伍以中国科学院院士、杰出青年基金获得 者、青年千人和中科院百人计划入选者为主体。实验室现有在职固定人员 73 人，其中 副高级以上研究人员 46 人，院士 5 名（含 1 名特聘研究员），国家杰出青年基金获得 者 9 名（含 1 名特聘研究员），国家优秀青年基金获得者 2 名，中科院“百人计划”入选 者 7 名，“青年千人计划”入选者 3 名，“万人计划”入选者 1 名，多名研究员被聘为国内 外学术组织的成员和著名学术期刊的主编、副主编和编委，拥有了一支学术思想活跃、 勇于创新、学风严谨、结构合理的高水平研究队伍。 2015 年实验室固定人员中唐勇研究员入选 2015 年度 “中国科学院院士”，获“第十 四届上海市科技精英”；丁奎岭研究员获 “the First Yoshida Prize”、“十佳全国优秀科技 工作者提名奖”、“全国优秀科技工作者”；游书力研究员获“RSC Merck Award”、"上海 市领军人才"、“WuXi PharmaTech Life Science and Chemistry Award”；梅天胜研究员入 选 2015 年度“青年千人计划”；戴辉雄副研究员获 2015 年度中国科学院“卢嘉锡青年人 才奖”。 2015 年实验室在读硕士研究生 52 名，博士研究生 67 名，在站博士后 3 名；毕业硕 士 4 名，博士 22 名，出站博士后 1 名。 2015 年卓春祥、王晓明的博士论文获 2015 年度中国科学院优秀博士学位论文，王 守国、张雷获中科院院长奖学金优秀奖，王盼获中科院朱李月华奖，高得伟等 4 人获国 家奖学金，王守国、王盼获上海市高校优秀毕业生称号，陈铭获国科大优秀毕业生称号， 林渭龙获国科大三好学生标兵，梁兆利获国科大优秀学生干部称号，汤鑫军等 19 人获 国科大三好学生称号。 三、对外开放与学术交流 2015 年的开放项目有 29 项，资助总额 149.69 万元，均按照预定的研究目标顺利执 行，由开放基金资助完成的代表性优秀成果如下： (1) 从简单的炔烃和烯烃原料出发，通过串联的[2+2+1]反应一步连续构建了四根化 学键，合成了结构复杂且具有生物活性的 4,5-二氢异噁唑类分子，并成功地拓展至相应 的螺环类生物活性分子的简捷合成中。该研究首次利用廉价的三水合硝酸铜作为氧化腈 类化合物的新颖前体，实现了对简单炔烃的活化及化学转化，以良好的区域选择性和立 体选择性完成了对目标分子的快速简捷合成。该反应具有广泛的底物适用范围和良好的 官能团兼容性，同时，通过对反应机理的研究，该合成策略将有助于其他活性分子骨架 的高效合成。相关工作发表在 Angew. Chem. Int. Ed. 2015, 54, 8795。该研究被 ACIE 的 主编推荐为该期刊的封面文章重点介绍，文章发表后已被教育部科技发展中心、中国科 学报、科学网和 X-mol 等十多家媒体网站作为科研亮点重点介绍。 (2) 研究发现，联烯胺在金的催化下和共轭烯炔酮反应得到多取代的呋喃并五元环 产物。这是第一例在金化学反应中，联烯胺的内烯参与反应，而不同于之前报道的联烯 胺的端烯参与反应的例子。这一例子也说明了共轭烯炔酮在金催化下环化得到的呋喃金 物种的活性远远大于联烯基金物种。这一发现也极大的丰富了大家对联烯胺的认知，对 联烯胺在今后参与的反应中的应用有着非常好的设计思想和指导意义。值得注意的是， 还通过一对非对映异构体 BINOL 配体的调控，能得到一对对映异构体产物，这在金催 化的反应中也是不多见的。而且这个反应条件温和，同时具有很好的官能团兼容性，产 物具有很高的收率和对映选择性。该结果发表在 Angew. Chem. Int. Ed. 2015, 54, 14849。 (3) 过渡金属催化的偶联反应为碳氢键的活化提供了有效的手段，尤其是富电子芳 环的碳氢键的活化有了比较充分的研究报道，相对而言，缺电子芳环比如多氟芳烃类化 合物的偶联反应研究相对局限，尤其是多氟芳烃的简单烷基化反应一直没有得到很好的 解决。通过近年来深入研究过渡金属催化的涉及金属卡宾转移插入过程的偶联反应，由 易得的对甲苯磺酰腙或者重氮类化合物为金属卡宾前体，发展了多种碳碳键形成反应。 基于此，研究了一价铜催化的多氟芳烃与对甲苯磺酰腙或重氮类化合物的偶联反应，该 反应原料易得，操作简单，条件比较温和，以较高产率实现多氟芳烃烷基化过程，并且 该反应可以成功实现克级制备，相关工作发表在 Angew. Chem. Int. Ed. 2015, 54, 4669。 学术交流对于提高重点实验室的研究水平具有重要意义。2015 年实验室主办了 2 次国际会议：第五届上海-香港-明斯特金属有机化学研讨会（The 5th Shanghai-Hong Kong-Münster Joint Trilateral Symposium on Organometallic Chemistry）和国家自然科学基 金委-英国皇家化学会国际学术研讨会：有机合成的新兴前沿（NSFC-RSC International Symposium on Emerging Frontiers in Organic Synthesis），实验室学术带人头作为会议共 同主席组织了第 267 期东方科技论坛“碳循环中的分子转化科学与工程”学术研讨会；2015 年实验室学术带头人应邀在国内外学术会议上作邀请及大会报告 56 人次；有来自美国、 日本、德国、英国等国以及包括中国台湾在内的 25 位科学家来室访问交流并作学术报 告。 第五届上海-香港-明斯特金属有机化学研讨会 2015 年 3 月 31 日至 4 月 1 日，第五届上海-香港-明斯特金属有机化学研讨会（The 5th Shanghai-Hong Kong-Münster Joint Trilateral Symposium on Organometallic Chemistry） 在上海有机所君谋楼一楼报告厅成功召开。上海有机所所长丁奎岭院士担任会议主席， 金属有机化学国家重点实验室陈耀峰研究员任会议秘书长。来自德国明斯特大学、香港 大学、香港中文大学、香港城市大学、香港理工大学、复旦大学、华东师范大学、上海 有机所等高校和科研院所的两百多名专家、学者和学生参加了本次研讨会。 丁奎岭在开幕式上致辞，表达了对与会专家、学者的热烈欢迎和诚挚感谢。本次会 议邀请了来自德国、中国以及中国香港地区的 34 名专家学者作精彩的学术报告，主要 围绕金属有机化学前沿领域进行交流与探讨，突出金属有机化学领域的最新发展和未来 态势。整个会议反响热烈，很多听讲的学生和科研人员表示有这样的机会了解学科前沿 的相关知识受益匪浅，同时结合自己在科研工作过程中遇到的问题与专家进行了积极沟 通和交流。 上海-香港-明斯特金属有机化学研讨会是金属有机化学领域的系列研讨会，已在上 海、香港和德国明斯特成功举办了四届。该系列会议旨在为来自德国、中国以及中国香 港地区的金属有机化学领域的中外学者搭建桥梁，提供交流化学新思想、新成果的机会， 促进学术交流，探讨及建立合作。 国家自然科学基金委-英国皇家化学会国际学术研讨会：有机合成的新兴前沿 2015 年 10 月 8 日至 10 月 10 日，国家自然科学基金委-英国皇家化学会国际学术 研讨会：有机合成的新兴前沿(NSFC-RSC International Symposium on Emerging Frontiers in Organic Synthesis)在上海有机所君谋楼一楼报告厅成功召开。上海有机所金属有机国 家重点实验室游书力研究员和北京大学天然药物及仿生药物国家重点实验室焦宁教授 担任会议共同主席。来自美国、德国、英国、日本以及中国的 515 名专家、学者和学生 参加了本次研讨会。 丁奎岭院士在开幕式上致辞，表达了对与会专家、学者的热烈欢迎和诚挚感谢。会 议邀请 2 位大会报告人，16 位邀请报告人，8 位口头报告人作精彩的学术报告，并有 50 多个墙报，主要围绕有机合成的新兴前沿领域(包括新型化学转化、可持续性催化和天 然产物全合成)进行交流与探讨，突出有机合成领域的最新发展和未来态势。这次会议 受到了国家自然科学基金委、英国皇家化学会、上海有机所、金属有机国家重点实验室、 天然药物及仿生药物国家重点实验室以及多个化学公司的资助，对于所有参会人员均免 收注册费。整个会议反响热烈，很多听讲的学生和科研人员表示有这样的机会了解学科 前沿的相关知识受益匪浅，同时结合自己在科研工作过程中遇到的问题与专家进行了积 极沟通和交流。 国家自然科学基金委-英国皇家化学会国际学术研讨会：有机合成的新兴前沿是由 国家自然科学基金委倡导并发起与英国皇家化学会合作举办的系列国际会议之一。该会 旨在为全球有机合成领域的中外学者搭建桥梁，提供交流化学新思想、新成果的机会， 促进学术交流，探讨及建立合作，同时为中国的青年有机合成科学家提供了一个展示自 己的平台，搭建了一架走向国际舞台的桥梁。 第 267 期东方科技论坛学术研讨会“碳循环中的分子转化科学与工程” 第 267 期东方科技论坛学术研讨会“碳循环中的分子转化科学与工程”于 2015 年 12 月 08 日在上海沪杏科技图书馆举行。上海有机所丁奎岭院士和华东师范大学何鸣元院 士担任会议执行主席。上海有机所戴立信院士、林国强院士等来自国内科研单位、高校 的 50 余位专家应邀参加了此次会议。 会议围绕“碳循环中的分子转化科学与工程”展开讨论。碳循环是自然界最为重 要的物质转化之一，和人类生活密切相关。当今社会面临生态环境污染、化石能源枯竭、 战略资源供需矛盾日益尖锐等诸多问题，实现碳循环的合理调控，使其更加可持续发展 则为这些问题提供了一个可能的解决途径。金属有机化学在碳循环过程中起到了非常重 要的作用，如何实现从二氧化碳到有机化合物更为高效的转化方法；如何实现烃类化合 物直接、高效、高选择性转化；如何以生物质为原料生产生物基液体交通燃料和生物质 基化学品，对于发展可持续性碳循环具有重要的意义。 丁奎岭院士和何鸣元院士在会上分别作了题为“碳循环中的分子转化”以及“绿色 碳科学”的主题报告，从不同角度理解碳循环中的分子转化的科学基础，探讨可持续性 碳循环技术应用的前景和瓶颈问题。上海有机所麻生明院士、唐勇院士、黄正研究员， 中科院化学所韩布兴院士，中科院上海高研院孙予罕研究员，大连理工大学吕小兵教授， 北京大学刘海超教授分别结合各自研究领域作了专题报告。与会专家围绕二氧化碳的高 效利用、烃类化合物的高选择性转化、生物质的高效转化等议题展开深入的讨论进行了 充分讨论。本次论坛为有机合成、催化、物化、化工等领域的专家提供了一个交流平台， 促进各领域专家在科研与社会服务方面的合作。 实验室非常注重与国内外相关研究机构的合作研究。积极组织和参与国际重大研究 计划，2015 年主持基金委国际合作项目 4 项（合作方：以色列 Technion 技术研究院、 香港中文大学、美国北卡来罗纳教堂山分校、巴西金边大学），通过组织和参与以上重 大科学研究计划，实验室作为第一作者单位共发表合作研究论文 4 篇；实验室内部课题 组之间也开展了一些合作研究，合作发表论文 3 篇。 此外，实验室也积极与鲁西化工集团股份有限公司、江苏华昌化工股份有限公司、 中国石油化工股份有限公司、浙江九洲药业股份有限公司、汉高（中国）投资有限公司、 九江中科鑫星新材料有限公司、巴斯夫新材料有限公司、舒兰市金马化工有限公司、上 海华拓医药科技发展股份有限公司以及大赛璐药物手性技术（上海）有限公司等国内外 8 家企业进行了密切的合作研究。2015 年在研企业合作项目为 12 项，总研究经费达 970 万元（合同签订额），实到经费 190.9 万元。 为普及科学知识、弘扬科学精神、传播实验室文化，2015 年实验室积极组织开展 和参与了丰富多彩的公众开放活动。 (1) 大学生夏令营 在 2015 年中国科学院上海有机化学研究所暑期大学生夏令营活动中，实验室积极 参与，接待了来自全国 80 多所高校的 277 名大学生营员。通过介绍实验室历史、发展 规划，课题组介绍研究方向及进展，安排参观实验室，展示实验室的研究工作和成果及 互动交流环节，让来大学生营员了解实验室以及金属有机学科，激发从事化学研究的兴 趣和向往。 (2) 科技活动周 按照国务院规定，每年 5 月的第三周为科技活动周，实验室精心准备，主动参与， 积极响应实施“科技活动周”活动，取得了积极有效的成果。在 2015 年的公众开放日科 普活动中，实验室共接待了上海地区中小学的同学及家长共 600 余人。实验室专门制作 了题为《化学的世界》的幻灯片，向参观者展示了绚丽多彩的世界与化学之间的紧密联 系；实验室的研究生志愿者们为来访的参观者精心准备了十个非常有趣的化学小实验： 浴水重生、酸碱心里美、胶水制弹球、水中花园、生活中的 Vitamin C、谁灭了蜡烛、 颜色秋千、彩色温度计、隐形墨水、可乐变雪碧，通过寓教于乐的活动方式，吸引了很 多参观者的兴趣，得到了参观者的积极参与和响应，传播了化学知识，让参观者在在轻 松、有趣的氛围中加深了对化学乃至金属有机化学的认识和理解。 (3) 科普课程 2015 年实验室还组织科研骨干和研究生到西南位育中学作“魅力有机化学”系列科普 拓展课程，收效良好；同时参加了“玻玻璃璃实验室”系列科普课程，让高深的化学知识 走出冷冰冰的实验室，在欢乐轻松的氛围中让小朋友们了解化学的有趣一面；还积极参 加了“徐汇区第十届学习节”、“大手握小手—中科院博士义乌校园行 ”等科普活动。 四、实验室学术委员会工作 金属有机化学国家重点实验室第四届学术委员会第一次会议于 2015 年 11 月 20-22 日在上海有机所召开。中国科学院前沿科学与教育局数理化学处刘耀虎处长应邀参加了 此次会议。 在会议上，实验室主任唐勇研究员汇报了重点实验室 2015 年度工作进展，北京大 学深圳研究生院的吴云东教授和中国石油化工集团公司科技开发部的谢在库教授分别 作了题为“实验与理论结合研究催化反应机理” 和“由烃加工到烃合成——目标导向与 催化前沿”的专家报告，麻生明研究员、王磊教授、张兆国教授、张俊良教授、张国柱 研究员分别汇报了各自的课题组工作进展及研究计划，此外，丁奎岭研究员、游书力研 究 员 、 陈 耀 峰 研 究 员 以 及 黄 正 研 究 员 分 别 进 行 了 有 关 The 44th National Organic Chemistry Symposium 、 The 16th Tetrahedron Conference 、 The 5th Asian Conference on Coordination Chemistry 以及 The Gordon Research Conference: Organometallic Chemistry 的国际会议介绍。 11 月 22 日上午，与会的领导、专家、学术委员以及老师等进行了热烈的讨论和充 分的交流。大家充分肯定了金属有机化学国家重点实验室近年来在保持学科优势和特色 方面取得的成绩。同时，大家也对实验室未来的发展进行了深入探讨，就如何拓宽实验 室研究领域以及提升国际影响力等方面提出了建设性的建议和意见，希望实验室能在新 的高度上做出更有影响力和代表性的原创性研究成果。同时，希望实验室能在继续大力 引进优秀人才的同时，综合考虑引进人才的研究方向和发展潜力。 五、2015 年度研究生获奖情况表 序号 获奖名称 获奖人员 指导教师 1 2015 年中科院优秀博士学位论文奖 卓春祥 游书力 2 2015 年中科院优秀博士学位论文奖 王晓明 丁奎岭 3 中科院院长奖学金优秀奖 王守国 游书力 4 中科院院长奖学金优秀奖 张雷 黄正 5 中科院朱李月华奖 王盼 唐勇 6 2015 年度国家奖学金 高得伟 游书力 7 2015 年度国家奖学金 袁浙梁 刘国生 8 2015 年度国家奖学金 汪辰 陈耀峰 9 2015 年度国家奖学金 姜兴国 麻生明 10 上海市高校优秀毕业生 王守国 游书力 11 上海市高校优秀毕业生 王盼 唐勇 12 国科大优秀毕业生 陈铭 刘元红 13 国科大三好学生标兵 林渭龙 麻生明 14 国科大优秀学生干部 梁兆利 刘国生 15 Dalton Transactions Poster Prize at ACCC5 王磊 邓亮 16 国科大三好学生 汤鑫军 麻生明 17 国科大三好学生 程家顺 刘国生 18 国科大三好学生 陈根强 施敏 19 国科大三好学生 周吉亮 陈耀峰 20 国科大三好学生 王旭斌 丁奎岭 21 国科大三好学生 潘伟 丁奎岭 22 国科大三好学生 郑军 游书力 23 国科大三好学生 程强 游书力 24 国科大三好学生 孙宁 刘元红 25 国科大三好学生 左自青 黄正 26 国科大三好学生 黄建强 侯雪龙 27 国科大三好学生 孙健 邓亮 28 国科大三好学生 汪辰 陈耀峰 29 国科大三好学生 柴永帅 陈耀峰/李玉学 30 国科大三好学生 孔维俊 余金权 31 国科大三好学生 袁玉超 施敏 32 国科大三好学生 潘东 施敏 33 国科大三好学生 冯良文 唐勇 34 国科大三好学生 刘琼杰 唐勇 2015 年团队重点研究项目（2012-2016 年） 项目一：基于金属有机化学的反应设计与控制 课题负责人：侯雪龙 研究队伍：戴立信，侯雪龙，丁奎岭，王正，丁昌华 经费总额: 400 万 项目二：金属配合物的合成及其促进的高选择性合成反应 课题负责人：刘元红 研究队伍：刘元红，邓亮，李玉学，孙杰 经费总额: 300 万 项目三：金属催化的不饱和烃的合成和反应研究 项目负责人：麻生明 研究队伍：陆熙炎，麻生明，韩秀玲，张雪，余世超 经费总额: 400 万 项目四：新型烯烃聚合催化剂的研究 项目负责人：唐勇 研究队伍：唐勇，陈耀锋，黄正，孙秀丽，李军方 经费总额: 350 万 项目五：惰性化学键及体系的活化与官能团化中的金属有机化学 课题负责人：游书力 研究队伍：游书力，施敏，刘国生，段伟良，张玮 经费总额: 300 万 2015 年自由探索项目（2014-2015 年） 序 号 姓 名 2015-01 陆熙炎 题 目 过渡金属催化的芳烃 C-H 活化启动的对贫电子烯烃的 1,4-加成反应 研究 2015-02 麻生明 末端炔的联烯基化反应 2015-03 侯雪龙 钯催化烯丙基试剂的不对称环丙烷化研究 2015-04 施 2015-05 丁奎岭 二氧化碳的直接与间接催化氢化转化 2015-06 唐 2015-07 刘元红 金催化的炔烃的氧化/重排及氧化/环化反应研究 2015-08 陈耀峰 稀土金属末端卡宾配合物化学研究 2015-09 游书力 过渡金属催化的芳香化合物选择性官能团化 2015-10 刘国生 金属钯催化烯烃的不对称氧化官能化反应研究 2015-11 李玉学 Cu 催化的末端烯烃三氟甲基化反应机理的理论研究 2015-12 邓 敏 基于环丙烯分子的串联反应研究 勇 新型聚烯烃催化剂的设计、制备及其催化的乙烯聚合研究 亮 重第四主族元素配位边臂修饰的氮杂环卡宾-过渡金属配合物的合 成、表征和反应性质探索 2015-13 段伟良 无导向基团芳烃碳氢键活化反应的研究 2015-14 黄 2015-15 张国柱 双金属催化的不对称碳碳，碳杂成键及关环反应研究 2015-16 余金权 芳烃区域选择性交叉脱氢偶联反应的研究 正 新型烷烃转化体系：烷烃硼化、硅化以及二聚反应 2015 年开放项目（2015-2017 年） （经费单位：万元） 本年度经费 序号 课题名称 开始时间 结束时间 总经费 负责人 课题经费 论文奖励 6 2 0 曹卫国 6 2 0 陈忠宁 2015.01.01 2017.12.31 12 4 1.3 甘良兵 2015.01.01 2017.12.31 12 4 0 姜雪峰 研究及其在生物活性分 2015.01.01 2017.12.31 15 5 5.5 焦宁 2015.01.01 2017.12.31 9 3 0.18 金国新 组装及其孔内可控有机 2015.01.01 2017.12.31 12 4 2.8 郎建平 9 3 0.27 雷爱文 15 5 8.2 施章杰 金属催化的全氟烷基炔 1 酸酯砌块用于合成含氟 2015.01.01 2017.12.31 杂环化合物的研究 金属有机磷光材料在有 2 机发光器件中的应用探 2015.01.01 2017.12.31 索 3 富勒烯衍生物的制备以 及性能研究 4 金属催化硫转移反应研 究 简洁、高效的合成方法学 5 子合成中的应用 6 杂多核有机金属框架的 构筑及其应用 纳孔配位聚合物的合理 7 反应研究 X-射线吸收谱对铜催化 8 Glaser-Hay 偶 联 反 应 的 2015.01.01 2017.12.31 机理研究 通过碳氢键活化实现氨 9 基酸及肽类的直接官能 2015.01.01 2017.12.31 团化 10 手性双核铑配合物的合 2015.01.01 2017.12.31 6 2 0.27 苏成勇 2015.01.01 2017.12.31 12 4 0 涂涛 向的 C-H 键活化及环化 2015.01.01 2017.12.31 9 3 1.7 王佰全 9 3 0 王春江 12 4 3.88 王剑波 12 4 4.4 王磊 12 4 0.9 王绍武 2015.01.01 2017.12.31 12 4 7.5 吴劼 2015.01.01 2017.12.31 15 5 4.2 席振峰 2015.01.01 2017.12.31 9 3 0.27 肖文精 2015.01.01 2017.12.31 9 3 0 徐政虎 2015.01.01 2017.12.31 6 2 1.4 许斌 2015.01.01 2017.12.31 9 3 0 叶龙武 成与性质研究 11 自负载钳型氮杂环金属 卡宾催化剂设计与应用 过渡金属催化的成键导 12 反应研究 亚甲胺叶立德参与的催 13 化 不 对 称 [3+m]- 环 加 成 2015.01.01 2017.12.31 反应研究 14 15 基于金属卡宾的惰性 2015.01.01 2017.12.31 C-H 键活化反应研究 新导向基在碳-氢键活化 及官能化反应中的应用 2015.01.01 2017.12.31 新型含吲哚基稀土金属 16 有机配合物合成、反应及 2015.01.01 2017.12.31 性能研究 17 基于二氧化硫的若干插 入反应 18 氮杂半瞬烯的合成、结构 与反应 19 可见光敏化的可控自由 基环化反应初探 20 串联的金属接力催化在 有机合成中的应用研究 21 金属催化下异腈参与的 含氮杂环合成 22 酸促进的均相金催化反 应研究 23 N−杂环双金属配合物催 2015.01.01 2017.12.31 12 4 2.2 余正坤 2015.01.01 2017.12.31 9 3 1.1 张俊良 化合物不对称异构化及 2015.01.01 2017.12.31 9 3 0.27 张兆国 9 3 0 周剑 9 3 0.18 周锡庚 2015.01.01 2017.12.31 9 3 0.27 周永贵 2015.01.01 2017.12.31 15 5 2.29 朱成建 300 100 49.69 --- 化剂研究 24 不对称金催化的环化与 环加成反应研究 过渡金属催化的烯丙基 25 动力学拆分研究 金和汞催化在重氮参与 26 的一些构建季碳手性中 2015.01.01 2017.12.31 心反应中的比较研究 稀土有机化合物与 CO2 27 和 CO 分子的新反应研 2015.01.01 2017.12.31 究 28 酸促进的不对称氢解研 究 29 光敏配合物的合成及其 C-H 键活化性能研究 合计 --- --- --- 2015 年申请专利 序号 1 专利名称 具有 3,4-二氢异喹啉骨架的手性氮杂 环卡宾前体盐、合成方法及用途 2 3 一种制备甲酰胺类化合物的方法 具有光学活性的环己基噁唑啉配体的 合成方法及其用途 4 金属铱络合物、单晶、苯并吲哚类化 合物及合成方法和应用 5 金属铱络合物、单晶、苯并吲哚类化 合物及合成方法和应用 6 一种手性螺二氢茚骨架化合物的高效 不对称合成方法 7 手性螺二氢茚骨架化合物及其制备方 法 8 一种敞开式火焰离子化装置及使用该 装置实现离子化的方法 9 一种支链烯丙基化合物、制备方法及 应用 10 11 一种离子化方法及装置 一种平面手性二茂铁化合物、合成方 法及用途 12 13 申请号 发明人 201510054189.7 游书力、李国泰、顾庆 201510086625.9 201510293494.1 丁奎岭,张磊，韩召斌，王 正，赵晓宇 唐勇、胡江林，谢作伟， 康麒凯，刘琼杰，程雨晶 201510305993.8 游书力、叶克印、吴可嘉 201510305993.8 游书力、叶克印、吴可嘉 201510438450.3 201510974151.1 201510442402.1 201510570521.5 201510730846.5 201510757648.8 内酰胺类化合物及其制备方法 201510882223.x 一种敞开式火焰离子化装置 201520544461.5 丁奎岭，曹予曦，郑治尧， 崇庆雷，王正 丁奎岭，曹予曦，郑治尧， 崇庆雷，王正 郭寅龙、刘小潘、王昊阳、 涂奇奇 侯雪龙、白大昌、丁昌华 郭寅龙、刘小潘、王昊阳、 涂奇奇 游书力、高得伟、顾庆 余金权、戴辉雄、孔维俊、 刘悦进、徐辉 郭寅龙、刘小潘、王昊阳、 涂奇奇 14 15 16 17 一种离子化装置 新型聚烯烃油催化剂及其应用 一种离子化方法及装置 一种依泽替米贝的合成方法及该方法 中所用的中间体 18 一种依泽替米贝的合成方法及该方法 中所用的中间体 19 一种依泽替米贝的合成方法及该方法 中所用的中间体 20 手性芳香螺缩酮骨架双膦配体及其制 备方法和应用 21 手性芳香螺缩酮骨架双膦配体及其制 备方法和应用 22 手性芳香螺缩酮骨架双膦配体及其制 备方法和应用 23 新型钌络合物及制备甲醇和二醇的方 法 24 新型钌络合物及制备甲醇和二醇的方 法 25 新型钌络合物及制备甲醇和二醇的方 法 201520861732.x PCT/CN2015/092201 PCT/CN2015/094079 郭寅龙、刘小潘、王昊阳、 涂奇奇 唐勇、刘加帅、陶闻杰， 孙秀丽，李军方 郭寅龙、刘小潘、王昊阳、 涂奇奇 EP13819243.0 丁奎岭、王晓明、王正 JP2015-521944 丁奎岭、王晓明、王正 US14/415,891 丁奎岭、王晓明、王正 EP13820327.8 US14/415,857 JP2015-521943 丁奎岭、王晓明、韩召斌、 王正 丁奎岭、王晓明、韩召斌、 王正 丁奎岭、王晓明、韩召斌、 王正 EP13847202.2 丁奎岭、韩召斌 JP2015-537109 丁奎岭、韩召斌 US14/436,842 丁奎岭、韩召斌 2015 年授权专利 序号 1 2 3 4 5 专利名称 一类由烯烃制备高支化 烷烃的催化体系 哌嗪基嘧啶类同位素标 记试剂的用途 氟代异喹啉类化合物及 专利号 授权日期 ZL 201110126431.9 2015-01-14 发明人 唐勇、陶闻杰、孙秀丽、李 军方 郭寅龙、冷嘉鹏、张立、张 ZL 201210249584.7 2015-02-18 菁、王昊阳、张芳、康文昱、 许楚 ZL 201210194986.1 2015-02-18 刘国生、徐涛 ZL 201210195020.x 2015-02-18 刘国生、徐涛 ZL 201110385610.4 2015-04-01 金属配合物、制备方法和 ZL 201110326452.5 2015-04-01 陈耀峰、孙逸琳、王利民 ZL 201310024285.8 2015-07-08 麻生明、朱灿 ZL 201210243736.2 2015-07-08 丁奎岭、王正、贾肖飞 ZL 201310191121.4 2015-07-08 ZL 201210461660.0 2015-08-05 其制备方法 氟代异喹啉[a]吡咯类化 合物及其制备方法 一类单中心催化剂在乙 烯溶液聚合中的应用 唐勇、万大维、孙秀丽、李 军方 基于席夫碱配体的稀土 6 用途 多取代吲哚、合成方法及 7 其应用于吲哚美辛的合 成 螺缩酮骨架的双齿亚磷 8 酰胺配体及其制备方法 和应用 一种溶剂辅助电喷雾离 9 子化方法及实现该方法 的装置 食用油中甾醇的电喷雾 10 离子化-四极杆-飞行时 间串联质谱分析方法 郭寅龙、张骏婷、王昊阳、 张立、张菁 郭寅龙、汪航、张立、张菁、 王昊阳、贺小双、陆森森 一类烯烃聚合催化剂及 11 超低支化度超高分子量 ZL 201110109884.0 2015-08-05 ZL 201210489246.0 2015-09-16 聚乙烯 12 一种平面手性二茂铁化 合物、合成方法及用途 唐勇、卫兵、李军方、孙秀 丽 游书力、顾庆、高得伟、石 延超、赵正乐 2015 年实验室来访人员报告 序号 报告题目 C-H Oxidation Inspired by 1 Biological Oxidation Catalysis Publishing 2 in Wiley Materials Science Journals and Books Sustainable Concepts for 3 C-C and C-Heteroatom Bond Formation Carbon-Carbon 4 Formation by Bond Catalytic 1,4-Metal Migration Chemical Professes at the 5 Surface of Colloidal Objects C-H 单位 夏纪宝 Texas Southwestern Medical 博士 Center, USA Dr. Peter 主持人 游书力 Wiley-VCH Wernheinm, Germany Gregory 游书力 Technical University, Prof. Lukas Kaiserslautern J. Gooben Prof. Hon University Wai Lam UK of Nottingham, 刘国生 游书力 Prof. Hai-Lung Temple University 丁奎岭 Dai Ruthenium(II)-Catalyzed 6 报告人 Activation and Beyong Prof. Lutz Ackermann Georg-August-Universitat Gottingen 顾庆 时间 2015.02.04 09:30 2015.03.16 15:00 2015.03.20 10:00 2015.04.08 15:30 2015.04.24 10:00 2015.04.25 15:30 Multifunctional Organoboron Compounds 7 through Single-Catalyst-Controlled Multicomponent Reactions 孟繁柯 博士 Boston College 唐勇 2015.04.27 10:00 Structure, 8 Bonding and Mechanism in Iron-Catalyzed Polymerize University of Rochester, USA 邓亮 2015.04.27 15:00 the Unpolymerizable: Non-Traditional Polymers Accessed Michael L. Neidig Cross-Coupling 9 Prof. by Novel Prof. Yan Xia Stanford University, USA 邓亮 2015.05.15 16:00 Catalytic Polymerizations New 10 Adventures in Organic Chemistry: Synergistyc Catalysis, Ramon Rios Photoorganocatalytic and Prof. Torres University of Southampton, 刘国生 UK 2015.05.18 14:00 Heterogenous Chemistry Controlling Stereochemistry 11 at the Prof. Department of Organic Quaternary Center: From Santanu Chemistry, Indian Institute of Olefin Functionalization to Mukherjee Science 游书力 2015.05.19 14:00 Desymmertrization 12 Sulfinamide and 13 苏伟平 基于脱羧的交叉偶联 C-H and 刘国生 2015.06.01 15:00 Chemistry Bond Prof. for Jonathan Nitrogen Ellman Functionalization Amine 研究员 中科院福建物质结构研究所 Yale University, USA 游书力 2015.06.05 10:00 Heterocycle Synthesis Biosynthesis of the Loline 14 Alkaloids Prof. Robert B. Grossman University of Kentucky 游书力 2015.06.11 10:00 Cationic Iridium(III) Complexes as Nonlinear Absorbing 15 Materials: Understanding the Structure-Property Prof. Wenfang Sun North Dakota State 施敏 University 2015.06.24 09:30 Correlations Computational to 16 Spectra Approach Assignment, Mechanism Study and Dr. Qian Peng University of Oxford 唐勇 2015.06.25 09:00 Ligand Design 自溶霉素的全合成与氢 17 键促进的钌催化烯烃复 分解反应研究 Low 18 20 Valent 授 f-element Prof. Chemistry: Insights from Laurent Theory Maron and Phosphinocatalysis Dr. Ohyun Kwon Iodine Reagents in Prof. Dr. Synthesis and Flow Thomas Chemistry Science and of Technology, Chenggong Campus, 游书力 University of Toulouse 丁奎岭 University of California, Los 施敏 Angeles Cardiff University, UK 游书力 Wirth Rhodium-Catalyzed Addition 21 沈悦海 教 University 2015.06.25 10:00 Kunming Phosphines 19 Kunming of Pronucleophiles to Alkynes and Allenes Prof. Dr. Bernhard Breit University of Germany Freiburg, 游书力 2015.07.09 10:00 2015.09.10 14:30 2015.09.18 16:00 2015.10.12 10:00 Palladium(0)-catalyzed C(sp3)-H Activation: A 22 Powerful Tool for the Construction Systems of Cyclic Prof. Oliver Baudoin University of Basel 黄正 2015.10.20 10:00 Bond 23 Activation and Catalysis by Main Group Systems 24 Complexes Heteronuclear to Metal String Complexes 量子点激发态合成化学： 25 Uwe Schneider From Homonuclear Metal String Prof. Dr. 方法、材料与应用 The University of Edinburgh, UK 游书力 Prof. Shie-Ming National Taiwan University 唐勇 Peng 彭笑刚 教授 浙江大学 丁奎岭 2015.11.04 14:00 2015.11.09 15:00 2015.12.29 13:00 2015 年会议报告 序号 报告名称 Scandium 1 Imido Alkylidene Synthesis, 报告人 Structure Organometallic and Complexes: and Coordination 2 Terminal Complexes: Structure 时间 Chemistry: Nizhni and Novgorod, Challenges (VI Razuvaev 2015.09.18-23 Russia Lectures) Imido Synthesis, and 地点 and 陈耀峰 Achievements Reactivity (Plenary Lecture) Scandium 会议名称 Reactivity 陈耀峰 5th Asian Conference on Coordination Chemistry 香港 2015.07.12-16 (Invited Lecture) Scandium 3 Terminal Complexes: Structure Imido Synthesis, and Reactivity Hawaii, 陈耀峰 Pacifichem 2015 USA 2015.12.13-20 (Invited Lecture) Scandium 4 Terminal Complexes: Structure Imido Synthesis, and Reactivity The 11th 陈耀峰 Chemistry Sino-US Professors 中国苏州 2015.06.21-23 中国西安 2015.09.17-20 中国南昌 2015.07.25-29 中国苏州 2015.06.21-23 Conference (Invited Lecture) Low-Coordinate Late 3d Metal 5 Complexes with NHC Ligation: Synthesis, Reactivity and 邓亮 2015 中 韩 配 位 化 学 双 边 会议 Catalytic Application 6 7 低配位铁钴金属有机配合物 研究（主题报告） Low-Valent Iron and Cobalt Complexes with NHC Ligation 邓亮 第九届全国无机化学学术 会议 The 邓亮 11th Chemistry Conference Sino-US Professors Iron and Cobalt Complexes with 8 Monodentate N-heterocyclic Carbene 邓亮 Ligation: Synthesis, Structure, 第一届《中国化学快报》 化学化工前沿研讨会 中国天津 2015.06.05-07 and Reactivity 9 Bridging the Gap Homo & Heterogeneous Asymmetric between Catalysis Organometallics with 丁奎岭 Pacifichem 2015 (Invited Hawaii, USA 2015.12.13-20 Lecture) Cooperative Catalysis in Asymmetric Synthesis: Case 10 Studies of Catalyst Design and 丁奎岭 Pacifichem 2015 Process Innovation (Invited Hawaii, USA 2015.12.13-20 Lecture) 中国化学会第十届全国磷 The Design, Synthesis and 11 Application of Several Types of Phosphorus Containing 丁奎岭 Ligands (Plenary Lecture) From Mechanistic Understanding to and Transformation 2015.10.23-26 中国北京 2015.09.17-20 中国武汉 2015.03.19-20 中国兰州 2015.07.18-19 New Case Studies of Asymmetric 丁奎岭 Synthesis 间生命起源于进化专委会 中国新乡 年会 Catalytic Process Innovation: 12 化学化工学术讨论会暨空 CO2 中国化学会第十一届全国 物理有机化学学术会议 (Plenary Lecture) 13 14 协同催化成就手性药物合成 优势工艺（大会报告） 从基础研究到绿色催化技术 创（大会报告） 丁奎岭 丁奎岭 手性技术与制药化学国际 高峰论坛 2015 绿 色 催 化 技 术 产 学 研论坛 Cooperative Catalysis in Asymmetric Synthesis: Case 15 Studies of Catalyst Design and 丁奎岭 Process Innovation, keynote IUPAC-2015, 45th World Busan, Chemistry Congress Korea 2015.08.09-14 lecture. Cooperative Catalysis in Asymmetric Synthesis: Case 16 Studies of Catalyst Design and 丁奎岭 Process Innovation, Plenary 44th National Organic Maryland, Chemistry Symposium USA 1st Kyoto, 2015.06.28-07.02 lecture. Chiral 17 Catalyst Evolution: Rational Design & Serendipity, 丁奎岭 Prize Lecture. Catalytic 18 Asymmetric Synthesis of Chiral Phosphorus 段伟良 Compounds(Invited Lecture) 19 20 21 22 手性膦化合物的不对称催化 合成（邀请报告） 离子淌度质谱在有机分析中 应用（邀请报告） 钯催化烯丙基底物与亲核试 剂反应的选择性 （邀请报告） π-烯丙基钯络合物与亲核试 剂反应的选择性（邀请报告） Reactions of Allyl Substrates with Lecture) Nucleophiles(Invited Prize Symposium Japan Asian International Symposium - Organic Chemistry/Green Chiba, Japan 2015.01.30 2015.03.26-29 Chemistry 段伟良 郭寅龙 侯雪龙 侯雪龙 Selectivities in Pd-Catalyzed 23 Yoshida 中国化学会第十届全国磷 化学化工学术讨论会 中国化学会第二届全国质 谱分析学术报告会 第九届全国有机化学学术 讨论会 第十二届全国有机合成化 学学术讨论会 The 侯雪龙 Golden 中国新乡 2015.10.23-26 中国杭州 2015.10. 中国长春 2015.07.28-31 中国桂林 2015.10.15-18 Singapore 2015.08.06-08 Jubilee Chemistry Conference – Commemorating Singapore’s 50th Birthday Selectivities in Pd-Catalyzed 24 Reactions of Allyl Substrates with Nucleophiles(Invited The 25 iron and China-Italy 侯雪龙 Bilateral Symposium on Italy 2015.04.19-25 Organic Chemistry Lecture) Pincer 2th cobalt complexes for catalytic alkene hydrofunctionalizations(Invited 黄正 249th ACS National Meeting Denver, USA 2015.03.22-26 Lecture) The 5th Shanghai-Hong 26 Highvalent Metal Catalysis in Difunctionalization of Alkenes 刘国生 Kong-Münster Joint Trilateral Symposium on 中国上海 2015.04.30-05.01 Organometallic Chemistry Highly 27 Efficient The Highly Organic Chemistry Efficient Difunctionalization of Alkene 刘国生 using Transition Metal Catalyst Transition 29 Metal-Catalyzed Oxidative Difunctionalization Transition 11th Padova, Italy 2015.04.19-25 中国长春 2015.07.28-31 中国北京 2015. 09.17-20 中国上海 2015.10.08-10 National on Physical Organic Chemistry NSFC-RSC International Metal-Catalyzed Oxidative Difunctionalization 刘国生 Copper-catalyzed Fluorination of Arylhalides Frontiers in Organic Hawaii, 刘国生 Pacifichem 2015 Multicomponent Reactions of 刘元红 Conjugated Organic Substrates Symposium on Emerging Synthesis Early-transition-metal-mediated 32 机化学学术会议 刘国生 Conference of Alkenes 31 中国化学会第九届全国有 The of Alkenes 30 China-Italy Difunctionalization of Alkene 刘国生 Bilateral Symposium on using Transition Metal Catalyst 28 2th USA 2015.12.15-20 The 5th Shanghai-Hong Kong-Münster Joint Trilateral Symposium on Organometallic Chemistry 中国上海 2015.03.30-04.01 Gold-Catalyzed 33 Reactions Cascade of The Sino-US Functionalized 刘元红 Chemistry Alkynes Professors The Efficiency in Synthesis of 麻生明 Target Molecules 第十二届全国有机合成化 学学术研讨会 Zwitterion Directed Regio- and 35 中国苏州 2015.06.21-23 中国桂林 2015.10.15-18 Conference Methodology Development and 34 11th Enantioselective Cyclizations 施敏 Hawaii, Pacifichem 2015 USA (Invited Lecture) 2015.12.13-20 Spiro-Diol--Diimine Dinickel Tetranuclear Nickel 36 Complexes as Catalysts for Olefin Ethylene Polymerization. Sidearm 唐勇 Asian Polyolefin Workshop 2015 Tokyo, Japan 2015.11.23-27 Effects (Invited Lecture) 37 38 39 Sidearm Approach to Catalysts 第四届 Grubbs 论坛：聚 for Olefin Polymerization ： 合 物 及 产 业 创 新 Controllable Synthesis of 唐勇 （ Polymers and Industrial Polyethylene (Plenary Lecture) Innovations） Quick ICHAC-XI, Construction of Polycyclic Spiroindolines via a 唐勇 International Conference on Heteroatom Tandem Strategy Chemistry 基于膦叶立德的串联环化反 中国化学会第十届全国磷 应 唐勇 化学化工学术讨论会 中国宁波 Caen, France 中国新乡 2015.04.10-11 2015.06.14-19 2015.10.23-26 Sidearm Approach to Catalysts 40 for Olefin Controllable Polymerization: Synthesis of 唐勇 Pafichem 2015 Hawaii, USA 2015.12.15-19. Polyethylene Asymmetric 41 Transformation Direct of Aromatic 游书力 Compounds (Plenary Lecture) 第十四届全国均相催化学 术讨论会 中国大连 2015.09.22-25 Catalytic 42 Dearomatization Asymmetric Reactions 游书力 (Keynote Lecture) 不对称去芳构化与碳氢键直 43 接 官 能 团 化 反 应 (Invited 游书力 Lecture) Transition-Metal-Catalyzed 44 Asymmetric Dearomatization Allylic Reactions 45 Dearomatization 游书力 46 Dearomatization Asymmetric Reactions 游书力 Asymmetric Reactions 游书力 (Invited Lecture) Catalytic 47 Dearomatization 48 Asymmetric Dearomatization 49 Dearomatization 50 Asymmetric Dearomatization (Invited Lecture) Kong-Münster Joint Trilateral Symposium on 2015 国际（河南）新药研 发论坛与技术转移对接会 康龙化成化学与生命科学 论坛 Reactions 游书力 坛：“一带一路 ”国家战略 下化学工的机遇与挑战 Catalyzed Allylic Reactions The 游书力 2015.06.16-19 中国武汉 2015.03.19-20 中国上海 2015.03.30-04.01 中国郑州 2015.06.06 中国宁波 2015.06.26 45th 中国石河 子 2015.07.29-31 International Union of Pure and Applied Busan, Chemistry (IUPAC) World Korea 2015.08.09-14 Chemistry Congress The Asymmetric Reactions 游书力 (Invited Lecture) Transition-metal 35 期) 2015 年 化 学 前 沿 论 (Invited Lecture) Organocatalytic Germany 手性会议(同写意论坛第 Asymmetric (Invited Lecture) Transition-metal Symposium Berlin, Organometallic Chemistry (Invited Lecture) Catalytic Tetrahedron The 5th Shanghai-Hong (Invited Lecture) Catalytic 16th 45th International Union of Pure and Applied Busan, Chemistry (IUPAC) World Korea 2015.08.09-14 Chemistry Congress Catalyzed Allylic Reactions The 游书力 6th Japanese-Sino Symposium on Organic Akiu, Chemistry for Young Japan Scientists 2015.09.06-09 Catalytic 51 Asymmetric Dearomatization Reactions 游书力 (Invited Lecture) 手性磷配体在金属铱催化的 52 烯 丙 基 取 代 反 应 中 的 应 用 游书力 (Invited Lecture) Asymmetric 53 Direct Transformation of Aromatic 游书力 Compounds (Keynote Lecture) Asymmetric 54 of Aromatic 游书力 Compounds (Invited Lecture) Soc. Rev. Symposium 中国化学会第十届全国磷 化学化工学术讨论会 The 16th Tetrahedron Symposium Asia Edition SIOC Direct Transformation Chem. & Mini-Symposium 中国兰州 2015.09.21 中国新乡 2015.10.23-26 中国上海 2015.11.11-13 中国北京 2015.11.25 Bayer on Synthetic and Medicinal Chemistry Transition-metal-catalyzed 55 Asymmetric Allylic Dearomatization Reactions 游书力 Pacifichem 2015 Hawaii, USA 2015.12.14-20 (Invited Lecture) Sequential Catalysis via the 56 Combination of Ru/chiral Phosphoric Acid (Invited Lecture) 游书力 Pacifichem 2015 Hawaii, USA 2015.12.14-20 2015 年发表专著(章节) 序号 1 著作名称 The Chemistry of Gold-NHC Carbene Complexes ( in The Chemistry of Organogold Compounds) 作者 出版单位 出版日期 Jun Zhang, Peng Gu, Kai Chen, Min Shi John Wiley & Sons, Ltd. 2014 Thieme 2015 C-C and C-X Bond Formation by Allylic C-H 2 Activation（in Catalytic Transformations via C-H Pinhong Chen, Guosheng Liu Activation） Asymmetric 3 Functionalization of C-H Bonds Shuli You Royal Society of Chemistry 2015 2015 年论文目录 固定人员论文目录（按通讯作者姓氏首字母排序） 1. A Scandium Complex Bearing Both Methylidene and Phosphinidene Ligands: Synthesis, Structure and Reactivity. Jiliang Zhou, Tengfei Li, Laurent Maron, Xuebing Leng, Yaofeng Chen* Organometallics 2015, 34, 470-476. (ACS Editors’ Choice) 2. Tris(boratabenzene) Lanthanum Complexes: Synthesis, Structure and Reactivity. Chunhong Wang, Xuebing Leng, Yaofeng Chen* Organometallics 2015, 34, 6166-6169. 3. Mono(boratabenzene) Rare-earth Metal Dialkyl Complexes: Synthesis, Structure and Catalytic Behaviors for Styrene Polymerization. Xiufang Wang, Xuebing Leng, Yaofeng Chen* Dalton Trans. 2015, 44, 5771-5776. 4. Substitution Reaction of Triphenylphosphine Oxide with Rare-earth Metal Phosphido Methyl Complexes. Yingdong Lv, Jiliang Zhou, Xuebing Leng, Yaofeng Chen* New J. Chem. 2015, 39, 7582-7588. (For the themed issue entitled Frontiers of Organo-f-element Chemistry) 5. Three-Coordinate Iron(IV) Bisimido Complexes with Aminocarbene Ligation: Synthesis, Structure, and Reactivity. Lei Wang, Lianrui Hu, Hezhong Zhang, Hui Chen*, Liang Deng* J. Am. Chem. Soc. 2015, 137, 14196-14207. 6. A Two-Coordinate Cobalt(II) Imido Complex with NHC Ligation: Synthesis, Structure, and Reactivity. Jingzhen Du, Linbo Wang, Meihua Xie, Liang Deng* Angew. Chem. Int. Ed. 2015, 54, 12640-12644. 7. Three-Coordinate Iron(II) Dialkenyl Compound with NHC Ligation: Synthesis, Structure, and Reactivity. Yuesheng Liu, Lei Wang, Liang Deng* Organometallics 2015, 34, 4401-4407. 8. Linear and T-Shaped Iron(I) Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis and Structure Characterization. Zhenwu Ouyang, Jingzhen Du, Lei Wang, Jared L. Kneebone, Michael L. Neidig, Liang Deng* Inorg. Chem. 2015, 54, 8808-8816. 9. High-Spin Iron(II) Alkynyl Complexes with N-Heterocyclic Carbene Ligation: Synthesis, Characterization, and Reactivity Study. Xiaojie Wang, Jia Zhang, Lei Wang, Liang Deng* Organometallics 2015, 34, 2775-2782. 10. Four-Coordinate Iron(II) Diaryl Compounds with Monodentate N-Heterocyclic Carbene Ligation: Synthesis, Characterization, and Their Tetrahedral-Square Planar Isomerization in Solution. Yuesheng Liu, Lun Luo, Jie Xiao, Lei Wang, You Song, Jingping Qu, Yi Luo*, Liang Deng* Inorg. Chem. 2015, 54, 4752-4760. (cover article) 11. Silane-Functionalized N-Heterocyclic Carbene-Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co-Si Bond. Jian Sun, Chong Ou, Chao Wang*, Masanobu Uchiyama, Liang Deng* Organometallics 2015, 34, 1546-1551. 12. Carbon-Carbon Bond Formation Reactivity of a Four-Coordinate NHC-Supported Iron(II) Phenyl Compound. Yuesheng Liu, Jie Xiao, Lei Wang, You Song, Liang Deng* Organometallics, 2015, 34, 599-605. 13. Highly Regio- and Enantioselective Alkoxycarbonylative Amination of Terminal Allenes Catalyzed by a Spiroketal-Based Diphosphine/Pd(II) Complex. Jiawang Liu, Zhaobin Han, Xiaoming Wang, Zheng Wang,* Kuiling Ding* J. Am. Chem. Soc. 2015, 137, 15346-15349. 14. Minimizing Aryloxy Elimination in RhI-Catalyzed Asymmetric Hydrogenation of b-Aryloxyacrylic Acids using a Mixed-Ligand Strategy. Yang Li, Zheng Wang, Kuiling Ding* Chem. Eur. J. 2015, 21, 16387-16390. 15. Highly Efficient Ruthenium-Catalyzed N-Formylation of Amines with H2 and CO2. Lei Zhang, Zhaobin Han, Xiaoyu Zhao, Zheng Wang, Kuiling Ding* Angew. Chem. Int. Ed. 2015, 54, 6186-6189. 16. Highly Enantio‐ and Diastereoselective Reductive Aldol Reactions Catalyzed by Chiral Spiro Bisphosphine Oxides. Panke Zhang, Jiawang Liu, Zheng Wang, Kuiling Ding*. Chin. J. Catal. 2015, 36, 100-105. 17. Palladium-Catalyzed Enantioselective C–H Arylation for the Synthesis of P-Stereogenic Compounds. ZiqiLin, Weizhen Wang, Shaobai Yan, Weiliang Duan* Angew. Chem. Int. Ed. 2015, 54, 6265-6269. 18. Palladium-Catalyzed Asymmetric Arylation of C(sp3)–H Bonds of Aliphatic Amides: Controlling Enantioselectivity Using Chiral Phosphoric Amides/Acids. Shaobai Yan, Song Zhang, Weiliang Duan* Org. Lett. 2015, 17, 2458-2461. 19. Study on the Accelerated Gutknecht Self-Cyclocondensation of Amino-sugars at Atmospheric Pressure Chemical Ionization Condition. Haoyang Wang*, Junting Zhang, Shihao Sun, Shusheng Zhang, Fang Zhang, Hui Zhu, Yinlong Guo* RSC Advances, 2015, 5, 105079-105083. 20. Palladium-Catalyzed Asymmetric Allylic Alkylation of 2-Monosubstituted Indolin-3-ones. Tiegen Chen, Ping Fang, Li Xin Dai, Xuelong Hou* Synthesis 2015, 47, 134-140. 21. Palladium-Catalyzed Highly Diastereo- and Enantioselective [3+2] Cycloaddition of Vinyl Aziridines and α,β-Unsaturated Ketones. Chaofan Xu, Baohui Zheng, Jiajia Suo, Changhua Ding*, Xuelong Hou*Angew. Chem. Int. Ed. 2015, 54, 1604-1607. 22. Kinetic Resolution of Unsymmetrical Acyclic Allyl Carbonates Using Trimethylsilyl Cyanide via Pd-Catalyzed Asymmetric Allylic Alkylation. Dachang Bai, Wanying Wang, Changhua Ding, Xuelong Hou* Synlett 2015, 26, 1510-1514. 23. Palladium-Catalyzed Asymmetric Intermolecular Mizoroki–Heck Reaction for Construction of a Chiral Quaternary Carbon Center. Qingsong Zhang, Shili Wan, Di Chen, Changhua Ding*, Xuelong Hou* Chem. Commun. 2015, 51, 12235-12238. 24. A General and Mild Catalytic α-Alkylation of Unactivated Esters Using Alcohols. Le Guo, Xiaochen Ma, Huaquan Fang, Xiangqing Jia, Zheng Huang* Angew. Chem. Int. Ed. 2015, 54, 4023-4027. 25. Iron-Catalyzed Asymmetric Hydrosilylation of Ketones. Ziqing Zuo, Lei Zhang, Zheng Huang* Chem. Commun. 2015, 51, 5073-5076. 26. A General, Practical Triethylborane-Catalyzed Reduction of Carbonyl Functions to Alcohols. Dongjie Peng, Mintao Zhang, Zheng Huang* Chem. Eur. J. 2015, 21, 14737-14741. 27. Synthesis and Characterization of a Tetradentate PNCP Iridium Complex for Catalytic Alkane Dehydrogenation. Xiangqing Jia, Zheng Huang* Sci. China Chem. 2015, 58, 1340-1344. 28. Synthesis of 1,1,1-Tris(boronates) from Vinylarenes by Co-Catalyzed Dehydrogenative Borylations-Hydroboration. Lei Zhang, Zheng Huang* J. Am. Soc. Chem. 2015, 137, 15600-15603. 29. The Real Role of N-Heterocyclic Carbene in Reductive Functionalization of CO2: An Alternative Understanding from Density Functional Theory Study. Qinghai Zhou, Yuxue Li* J. Am. Chem. Soc. 2015, 137, 10182-10189. 30. General Reaction Mode of Hypervalent Iodine Trifluoromethylation Reagent: A Density Functional Theory Study. Lin Ling, Kun Liu, Xinqian Li, Yuxue Li* ACS Catal. 2015, 5, 2458-2468. 31. Pd-catalyzed Intramolecular Aminofluorination of Allylic Sulfamides. Jiashun Cheng, Pinhong Chen, Guosheng Liu* Chin. J. Catal. 2015, 36, 40-47. 32. Palladium-Catalyzed Intermolecular Aminocarbonylation of Alkenes: Efficient Access of β-Amino Acid Derivatives. Jiashun Cheng, Xiaoxu Qi, Ming Li, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2015, 137, 2480-2483. 33. Highly Selective Pd-Catalyzed Intermolecular Fluorosulfonylation of Styrenes. Zheliang Yuan, Haoyang Wang, Xin Mu, Pinhong Chen, Yinlong Guo, Guosheng Liu* J. Am. Chem. Soc. 2015, 137, 2468-2471. 34. Palladium-Catalyzed Intramolecular Aminoacetoxylation of Unactivated Alkenes with Hydrogen Peroxide as Oxidant. Haitao Zhu, Pinhong Chen, Guosheng Liu* Org. Lett. 2015, 17, 1485-1488. 35. Copper-Catalyzed Intermolecular Trifluoromethylthiocyanation of Alkenes: Convenient Access to CF3-Containing Alkyl Thiocyanates. Zhaoli Liang, Fei Wang, Pinhong Chen, Guosheng Liu* Org. Lett. 2015, 17, 2438-2441. 36. Advancements in Aminofluorination of Alkenes and Alkynes: Convenient Access to beta-Fluoroamines. Pinhong Chen*, Guosheng Liu* Eur. J. Org. Chem. 2015, 4295-4309. 37. Advances and Challenges in Palladium-catalyzed Intermolecular Selective Allylic C-H Functionalization of Alkenes. Xiaoxu Qi, Pinhong Chen, Guosheng Liu* Sci. China Chem. 2015, 58, 1249-1251. 38. Copper-Catalyzed Trifluoromethylazidation of Alkynes: Efficient Access to CF3-Substituted Azirines and Aziridines. Fei Wang, Na Zhu, Pinhong Chen, Jinxing Ye, Guosheng Liu* Angew. Chem. Int. Ed. 2015, 54, 9356-9360. 39. Pd(II)-catalyzed Intermolecular Enantioselective Hydroamination of Styrenes. Feng Yu, Pinhong Chen*, Guosheng Liu* Org. Chem. Front. 2015, 2, 819-822. 40. Abnormal Mesoionic Carbene Silver Complex: Synthesis, Reactivity, and Mechanistic Insight on Oxidative Fluorination. Qilun Liu, Zheliang Yuan, Haoyang Wang*, Yang Li, Yicheng Wu, Tao Xu, Xuebing Leng, Pinhong Chen, Yinlong Guo, Zhenyang Lin*, Guosheng Liu* ACS Catal. 2015, 5, 6732-6737. 41. Palladium-Catalyzed Intramolecular Aminotrifluoromethoxylation of Alkenes. Chaohuang Chen, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2015, 137, 15648-15651. 42. Gold-Catalyzed Oxidative Ring Expansion of 2-Alkynyl-1,2-Dihydropyridines or -quinolines: Highly Efficient Synthesis of Functionalized Azepine or Benzazepine Scaffolds. Ming Chen, Yifeng Chen, Ning Sun, Jidong Zhao, Yuanhong Liu*, Yuxue Li* Angew. Chem. Int. Ed. 2015, 54, 1200-1204. 43. Gold(I)-Catalyzed 1,4 and/or 1,5-Heteroaryl Migration Reactions via Regiocontrolled Cyclizations. Chengyu Wang, Xin Xie, Jun Liu, Yuanhong Liu*, Yuxue Li* Chem. Eur. J. 2015, 21, 559-564. 44. Gold(I)-Catalyzed 1,2-Acyloxy Migration/[3+2] Cycloaddition of 1,6-Diynes with an Ynamide Propargyl Ester Moiety: Highly Efficient Synthesis of Functionalized Cyclopenta[b]indoles. Jun Liu, Ming Chen, Liangwei Zhang, Yuanhong Liu* Chem. Eur. J. 2015, 21, 1009-1013. 45. Zirconium-Mediated Multicomponent Ylidenemalononitriles to Form Reactions of Functionalized 1,3-Butadiynes with 1,8-Naphthyridine and Cyclopenta[b]pyridine Derivatives. Shasha Yu, Renhong Sun, Haoyi Chen, Xin Xie, Yuanhong Liu* Chem. Eur. 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Synth. Catal. 2014, 356, 3799-3808. 63. Intramolecular Annulation of Aromatic Rings with N-Sulfonyl 1,2,3-triazoles: Divergent Synthesis of 3-Methylene-2,3-dihydrobenzofurans and 3-Methylene-2,3-dihydroindoles. Xiangying Tang, Yongsheng Zhang, Lv He, Yin Wei, Min Shi* Chem. Commun. 2015, 51, 133-136. 64. RhII-Catalyzed [3 + 2] Cycloaddition of 2H-azirines with N-Sulfonyl 1,2,3-Triazoles. Yunzhou Zhao, Haibin Yang, Xiangying Tang*, Min Shi* Chem. Eur. J. 2015, 21, 3562-3566. 65. Amine-catalyzed Tunable Reactions of Allenoates with Dithioesters: Formal [4+2] and [2+2] Cycloadditions for the Synthesis of 2,3-dihydro-1,4-oxathiines and Enantioenriched Thietanes. Haibin Yang, Yuchao Yuan, Yin Wei*, Min Shi* Chem. Commun. 2015, 51, 6430-6433. 66. Palladium-catalyzed intramolecular rearrangement of vinylidenecyclopropanes through C-C bond activation. Dong Pan, Genqiang Chen, Xiangying Tang, Min Shi* Org. Chem. Fron. 2015, 2, 792-796. 67. Gold(I)-Catalyzed 1, 3-O-Transposition Reactions: Ynesulfonamides to Ynamides. Deyao Li, Yin Wei*, Min Shi* Eur. J. Org. Chem. 2015, 4108-4113. 68. Catalyst-dependent Stereodivergent and Regioselective Synthesis of Indole-fused Heterocycles through Formal Cycloadditions of Indolyl-allenes. Liangyong Mei, Yin Wei, Xiangying Tang*, Min Shi* J. Am. Chem. Soc. 2015, 137, 8131-8137. 69. Reactions of Cyclopropenethiones and Acetylenedicarboxylate: Synthesis of Substituted Thioethers and Thiocyclobutanones. Wentao Zhao, Min Shi* Tetrahedron Lett. 2015, 56, 5086-5089. 70. Solvent-controlled Nucleophilic Trifloromethylthiolation of Morita-Baylis-Hillman Carbonates: Dual Roles of DABCO in Activating the Zard’s Trifluoromethylthiolation Reagent and the MBH Carbonates. Haibin Yang, Xing Fan, Yin Wei*, Min Shi* Org. Chem. Fron. 2015, 2, 1088-1093. 71. Gold(I)-Catalyzed Cycloisomerization of Vinylidenecyclopropane-enes via Carbene or non-Carbene Processes. Deyao Li, Yin Wei, Ilan Marek, Xiangying Tang*, Min Shi* Chem. Sci. 2015, 6, 5519-5525. 72. Synthesis of Allenic Esters via Lewis Base-catalyzed Reactions of Cyclopropenones: Substrate Scope, Asymmetric Variant via DYKAT, and Mechanistic Studies. Yin Wei, Wentao Zhao, Yuanliang Yang, Zhen Zhang, Min Shi* ChemCatChem. 2015, 7, 3340-3349. 73. NHC-Oxazoline Gold(III) Complexes Generated in situ for Gold(III)-catalyzed Cycloaddition/oxidation Reaction of Enynones with Alkenes. Qin Xu, Peng Gu, Feijun Wang*, Min Shi* Org. Chem. Fron. 2015, 2, 1475-1484. 74. Divergent Synthesis of Indole-fused Polycycles via a Rh(II)-Catalyzed Intramolecular [3+2] Cycloaddition of Indolyltriazoles. Yongsheng Zhang, Xiangying Tang*, Min Shi* Org. Chem. Fron. 2015, 2, 1516-1520. 75. Chiral Phosphine-Catalyzed Tunable Cycloaddition Reactions of Allenoates with Benzofuranone Derived Olefins for Highly Regio-, Diastereo- and Enantioselective Synthesis of Spiro-Benzofuranones. De Wang, Guopeng Wang, Yaoliang Sun, Shoufei Zhu, Yin Wei*, Qilin Zhou*, Min Shi* Chem. Sci. 2015, 7, 7319-7325. 76. Asymmetric H2O-Nucleophilic Ring Opening of D−A Cyclopro-panes: Catalyst Serves as a Source of Water. Qikai Kang, Lijia Wang, Qiongjie Liu, Junfang Li, Yong Tang * J. Am. Chem. Soc. 2015, 137, 14594-14597. 77. Asymmetric Annulation of Donor-Acceptor Cyclopropanes with Dienes. Hao Xu, Jianglin Hu, Lijia Wang, Saihu Liao, Yong Tang* J. Am. Chem. Soc. 2015, 137, 8006-8009. 78. Asymmetric 1,2-Perfluoroalkyl Migration: Easy Access to Enantioenriched alpha-Hydroxy-alpha-perfluoroalkyl Esters. Pan Wang, Liangwen Feng, Lijia Wang, Junfang Li, Saihu Liao, Yong Tang* J. Am. Chem. Soc. 2015, 137, 4626-4629. 79. Asymmetric Hydroamination Catalyzed by a New Chiral Zirconium System: Reaction Scope and Mechanism. Xiaoguang Zhou, Bing Wei, Xiuli Sun, Yong Tang*, Zuowei Xie* Chem. Commun. 2015, 51, 5751-5753. 80. Highly Diastereoselective and Enantioselective Formal [4+3] Cycloaddition of Donor-Acceptor Cyclobutanes with Nitrones. Jianglin Hu, Lijia Wang, Hao Xu, Zuowei Xie*, Yong Tang* Org. Lett. 2015, 17, 2680-2683. 81. One-Pot Catalytic Asymmetric Synthesis of Tetrahydrocarbazoles. Qiongjie Liu, Wenguang Yan, Lijia Wang, X. Peter Zhang*, Yong Tang* Org Lett. 2015, 17, 4014-4017. 82. Efficient Catalytic Enantioselective Nazarov Cyclizations of Divinyl Ketoesters. Zhou Xu, Hai Ren, Lijia Wang*, Yong Tang* Org. Chem. Front. 2015, 2, 811-814. 83. Copper(I)/SaBOX Catalyzed Highly Diastereo- and Enantio-selective Cyclopropanation of cis-1,2-disubstituted Olefins with α-nitrodiazoacetates. Liangwen Feng, Peng Wang, Lijia Wang, Yong Tang* Sci. Bull. 2015, 60, 210-215. 84. Catalytic Asymmetric Synthesis of 3-Hydroxy-3-trifluoromethyl Benzofuranones via Tandem Friedel-Crafts/Lactonization Reaction. Hai Ren, Pan Wang, Lijia Wang*, Yong Tang* Org. Lett, 2015, 17, 4886-4889. 85. Iridium-Catalyzed Intramolecular Asymmetric Allylic Dearomatization Reaction of Pyridines, Pyrazines, Quinolines, and Isoquinolines. Zepeng Yang, Qingfeng Wu, Wen Shao, Shuli You* J. Am. Chem. Soc. 2015, 137, 15899-15906. 86. Asymmetric Dearomatization of β-Naphthols through a Bifunctional-Thiourea-Catalyzed Michael Reaction. Shouguo Wang, Xijia Liu, Qunchao Zhao, Chao Zheng, Shaobo Wang, Shuli You* Angew. Chem. Int. Ed. 2015, 54, 14929-14932. 87. Enantioselective Construction of Spiroindolines with Three Contiguous Stereogenic Centers and Chiral Tryptamine Derivatives: Reactive Spiroindolenine Intermediates. Chunxiang Zhuo, Yong Zhou, Qing Cheng, Lin Huang, Shuli You* Angew. Chem. Int. Ed. 2015, 54, 14146-14149. 88. Dearomatization of Indoles via a Phenol-Directed Vanadium-Catalyzed Asymmetric Epoxidation and Ring-Opening Cascade. Long Han, Wei Zhang, Xiaoxin Shi, Shuli You* Adv. Synth. Catal. 2015, 357, 3064-3068. 89. Pd-Catalyzed Highly Enantioselective Synthesis of Planar Chiral Ferrocenyl Pyridine Derivatives. Dewei Gao, Chao Zheng, Qing Gu*, Shuli You* Organometallics 2015, 34, 4618-4625. 90. Ligand-Enabled Ir-Catalyzed Intermolecular Diastereoselective and Enantioselective Allylic Alkylation of 3-Substituted Indoles. Xiao Zhang, Wenbo Liu, Hangfei Tu, Shuli You* Chem. Sci. 2015, 6, 4525-4529. 91. Enantioselective Synthesis of Pyrrole Based Spiro- and Polycyclic Derivatives by Ir-catalyzed Asymmetric Allylic Dearomatization and Controllable Migration Reactions. Chunxiang Zhuo, Qiang Cheng, Wenbo Liu, Qiang Zhao, Shuli You* Angew. Chem. Int. Ed. 2015, 54, 8475-8479. 92. Organocatalytic Asymmetric Chlorinative Dearomatization of Naphthols. Qin Yin, Shouguo Wang, Xiaowei Liang, Dewei Gao, Jun Zheng, Shuli You* Chem. Sci. 2015, 6, 4179-4183. 93. Copper-Catalyzed Intermolecular Asymmetric Propargylic Dearomatization of Indoles. Wen Shao, He Li, Chuan Liu, Chenjiang Liu*, Shuli You* Angew. Chem. Int. Ed. 2015, 54, 7684-7687. 94. Asymmetric Dearomatization of Naphthols via a Rh-Catalyzed C(sp2)–H Functionalization/Annulation Reaction. Jun Zheng, Shaobo Wang, Chao Zheng, Shuli You* J. Am. Chem. Soc. 2015, 137, 4880-4883. 95. Enantioselective Synthesis of 4,5,6,7-Tetrahydroindoles via Olefin Cross-Metathesis/Intramolecular Friedel–Crafts Alkylation Reaction of Pyrroles. Junwei Zhang, Xiaowei Liu, Qing Gu, Xiaoxin Shi, Shuli You* Org. Chem. Front. 2015, 2, 476-480. 96. Synthesis of Pyrroloindolines and Furoindolines via Cascade Dearomatization of Indole Derivatives with Carbenium Ion. Chuan Liu, Qin Yin, Lixin Dai, Shuli You* Chem. Commun. 2015, 51, 5971-5974. 97. Highly Regio- and Enantioselective Synthesis of N-Substituted 2-pyridones via Ir-Catalyzed Intermolecular Asymmetric Allylic Amination. Xiao Zhang, Zepeng Yang, Lin Huang, Shuli You* Angew. Chem. Int. Ed. 2015, 54, 1873-1876. 98. Asymmetric Dearomatization of β-Naphthols via Chiral Phosphoric Acid-Catalyzed Amination Reaction. Shouguo Wang, Qin Yin, Chunxiang Zhuo, Shuli You* Angew. Chem. Int. Ed. 2015, 54, 647-650. 99. Ligand-Controlled Para-Selective C–H Arylation of Monosubstituted Arenes. Hui Xu, Ming Shang, Huixiong Dai, Jinquan Yu* Org. Lett. 2015, 17, 3830-3833. 100. Transition-Metal- Catalyzed C–H Alkynylation. Mingming Wang, Zixiao Wang, Ming Shang, Huixiong Dai* Chin. J. Org. Chem. 2015, 35, 570-577(in Chinese). 101. Cu(II)-Catalyzed Coupling of Aromatic C–H Bonds with Malonates. Honhli Wang, Ming Shang, Shangzheng Sun, Zengle Zhou, Brain. N. Laforteza, Dai, Huixiong Dai*, Jinquan Yu* Org. Lett. 2015, 17, 1228-1231. 102. Gold (I)-Catalyzed Tandem Transformation with Diynes: Rapid Access to Cyclopentenone-Fused, Linear Polycyclic Molecules. Congjun Yu, Bin Chen, Tian Zhou, Qinshan Tian, Guozhu Zhang* Angew. Chem. Int. Ed. 2015, 37, 10903-10907. 103. Enantioselective Synthesis of α-exo-Methylene γ-Butyrolactones via Chromium Catalysis. Weiqiang Chen, Qin Yang, Tian Zhou, Qingshan Tian, Guozhu Zhang* Org. Lett. 2015, 17, 5236-5239. 104. A Novel Method to Prepare Multisubstituted Pyrazoles. Bin Chen, Congjun Yu, Guozhu Zhang* Chin. J. Org. Chem. 2015, 35, 625-632(in Chinese). 以下论文重点实验室非第一单位： 1. Observation of the Single-ion Magnet Behavior of d8 Ions on Two-coordinate Co(I)-NHC Complexes. Yinshan Meng, Zhenbo Mo, Bingwu Wang, Yiquan Zhang*, Liang Deng*, Song Gao* Chem. Sci. 2015, 6, 7156-7162. 2. Efficient Production of Methanol and Diols via the Hydrogenation of Cyclic Carbonates using Copper–silica Nanocomposite Catalysts. Hailong Liu, Zhiwei Huang, Zhaobin Han, Kuiling Ding*, Haichao Liu, Chungu Xia*, Jing Chen* Green Chem. 2015, 17, 4281-4290. 3. Zwitterionic Nickel(II) Catalyst for CO−Ethylene Alternating Copolymerization. Xiaofei Jia, Mengru Zhang, Fan Pan, Ilknur Babahan, Kuiling Ding, Li Jia*, Laura A. Crandall, Christopher J. Ziegler Organometallics 2015, 34, 4798-4801. 4. 若干功能体系的定向设计与构筑。李激扬, 王栋, 王远, 杜红宾, 邓亮, 侯雪龙, 于 吉红* 科学通报 2015, 60, 1987-1991。 5. Kinetic Resolution of 2-substituted-2,3-dihydrofurans by a Palladium-catalyzed. Asymmetric Heck Reaction. Hao Li, Shili Wan, Changhua Ding*, Bin Xu*, Xuelong Hou RCS Adv. 2015, 5, 75411-75414. 6. Catalytic Alkane Dehydrogenations. Yuxuan Zhang, Wubing Yao, Huaquan Fang, Aiguo Hu*, Zheng Huang* Sci. Bull. 2015, 60, 1316-1331. 7. Copper-Catalyzed Intermolecular Trifluoromethylazidation and Trifluoromethylthiocyanation of Allenes: Efficient Access to CF3-Containing Allyl Azides and Thiocyanates. Na Zhu, Fei Wang, Pinhong Chen, Jinxing Ye*, Guosheng Liu* Org. Lett. 2015, 17, 3580-3583. 8. Palladium-catalyzed Highly Efficient Synthesis of Functionalized Indolizines via Cross-coupling/cycloisomerization Cascade. Liangwei Zhang, Xiangdong Li, Yuanhong Liu*, Dayong Zhang* Chem. Commun. 2015, 51, 6633-6636. 9. 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Xin Huang, Tao Cao, Yulin Han, Xingguo Jiang, Weilong Lin, Jiasheng Zhang, Shengming Ma* Chem. Commun. 2015, 51, 6956-6959. 15. Rhodium-catalyzed C–H Functionalization-based Approach to Eight-membered Lactams. Shangze Wu, Rong Zeng, Chunling Fu, Yihua Yu, Xue Zhang*, Shengming Ma* Chem. Sci. 2015, 6, 2275-2285. 16. Cyclopropene Derivatives as Precursors to Enantioenriched Cyclopropanols and n-Butenals Possessing Quaternary Carbon Stereocenters. Marwan Simaan, Pierre-Olivier Delaye, Min Shi, Ilan Marek,* Angew. Chem. Int. Ed. 2015, 54, 12345-12348. 17. Enantioselective Annulation of Enals with 2-Naphthols by Triazolium Salts Derived from L-Phenylalanine. Guotai Li, Qing Gu, Shuli You* Chem. Sci. 2015, 6, 4273-4278. 18. Enantioselective Synthesis of 4-Substituted Tetrahydroisoquinolines via Palladium-Catalyzed Intramolecular Friedel-Crafts Type Allylic Alkylation of Phenols. Zhengle Zhao, Qinglong Xu, Qing Gu, Xinyan Wu*, Shuli You* Org. Biomol. Chem. 2015, 13, 3086-3092. 19. Intermolecular Dearomatization Reaction of Pyrroles Promoted by Silica Gel. Yong Zhou, Chunxiang Zhuo, Qing Gu, Shuli You* Adv. Synth. Catal. 2015, 357, 912-916. 20. Pd(0)-Catalyzed Benzylation of Indole through η3-Benzyl Palladium Intermediate. Zhengle Zhao, Qing Gu, Xinyan Wu*, Shuli You* Chin. J. Catal. 2015, 36, 15-18. 21. Cu(II)-Mediated C(sp2)−H Hydroxylation. Shangzheng Sun, Ming Shang, Hongli Wang, Haixia Lin*, Huixiong Dai*, Jinquan Yu* J. Org. Chem. 2015, 80, 8843-8848. 客座人员论文目录（按通讯作者姓氏首字母排序） 1. Facile Diastereoselective Synthesis of cis-Perfluoroalkylated Fused [1,3]Oxazines from Aromatic Aldehydes, Methyl Perfluoroalk-2-ynoates and Quinolines. Tianqi Sun, Qiuqi Cai, Minjie Li, Zewei Wang, Jie Chen, Hongmei Deng, Min Shao, Hui Zhang*, Weiguo Cao* Tetrahedron 2015, 71, 622-629. 2. An Efficient One-pot Two-step Three-component Process for the Synthesis of Perfluoroalkylated Biphenyls. Yuhong Xu, Jing Han, You Lv, Renming Pan, Jie Chen, Hongmei Deng, Min Shao, Hui Zhang*, Weiguo Cao* Tetrahedron 2015, 71, 820-825. 3. Cu(II)-catalyzed Aerobic Cascade Reactions of 2-Alkynylanilines with Methyl Perfluoroalk-2-ynoates: En Route to 4-Carbonyl-2-perfluoroalkyl Quinolines. Jing Han, Yangyong Shen, Xuechun Sun, Qiuxia Yao, Jie Chen, Hongmei Deng, Min Shao, Bozhen Fan*, Hui Zhang*, Weiguo Cao* Eur. J. Org. Chem. 2015, 2061-2065. 4. Facile Synthesis of Both Perfluoroalkyl and Phosphonate Groups Substituted trans-1,5-Benzodiazepine and Its Derivatives via a One-pot Catalyst-free Process. Yangyong Shen, Jing Han, Xuechun Sun, Xiaojun Wang, Jie Chen, Hongmei Deng, Ming Shao, Hong Shi*, Hui Zhang*, Weiguo Cao* Tetrahedron 2015, 71, 4053-4060. 5. Mild and Efficient One-pot Synthesis of 2-(Perfluoroalkyl)indoles by Means of Sequential Michael-type Addition and Pd(II)-catalyzed Cross-Dehydrogenative Coupling (CDC) Reaction. Dandan Shen, Jing Han, Jie Chen, Hongmei Deng, Ming Shao, Hui Zhang*, Weiguo Cao* Org. Lett. 2015, 17, 3283-3285. 6. An Efficient Route to 3-Trifluoromethylpyrazole via Cyclization/1,5-H Shift and Its Applications in the Synthesis of Bioactive Compounds. Yongdong Wang, Jing Han, Jie Chen, Weiguo Cao* Tetrahedron 2015, 71(43), 8256-8262. 7. One-pot Metal-free Cascade Synthesis of 2-Perfluoroalkyl Pyrroles. Xuechun Sun, Jing Han, Jie Chen, Hongmei Deng, Min Shao, Hui Zhang*, Weiguo Cao* Eur. J. Org. Chem. 2015, 7086-7090. 8. Phosphorescent Cationic Au4Ag2 Alkynyl Cluster Complexes for Efficient Solution-Processed Organic Light-Emitting Diodes. Liangjin Xu, Jinyun Wang, Xiaofeng Zhu, Xianchong Zeng, Zhongning Chen* Adv. Funct. Mater. 2015, 25, 3033-3042. 9. Release of the Water Molecule Encapsulated Inside an Open-Cage Fullerene through Hydrogen Bonding Mediated by Hydrogen Fluoride. Liang Xu, Hongjiang Ren, Sisi Liang, Jiahao Sun, Yajun Liu*, Liangbing Gan* Chem. Eur. 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A Simple Base-mediated Synthesis of Diverse Functionalized Ring-fluorinated 4H-pyrans via Double direct C–F Substitutions. Jieru Yang, Ao Mao, Zhenting Yue, Wenxuan Zhu, Xuewei Luo, Chuwei Zhu, Yuanjing Xiao*, Junliang Zhang* Chem.Commun. 2015, 51, 8326-8329. 151. Design, Synthesis, and Application of a Chiral Sulfinamide Phosphine Catalyst for the Enantioselective Intramolecular Rauhut–Currier Reaction. Xiao Su, Wei Zhou, Yangyan Li, Junliang Zhang* Angew. Chem. Int. Ed. 2015, 54, 6874-6877. 152. Gold(I)-catalyzed asymmetric [3 + 2]-cycloadditions of γ-1-ethoxyethoxy- propiolates and Aldehydes. Feng Liu, Yidong Wang, Weiming Ye, Junliang Zhang* Org. Chem. Front. 2015, 2, 221-225. 153. Metal-free Dehydrogenative Diels-Alder Reactions of 2-Methyl, 3-Aryl-methyl- indoles and Dienophiles: A Rapid Access to Tetrahydrocarbazoles, Carbazoles and Heteroacenes. Liejin Zhou, Bing Xu, Junliang Zhang* Angew. Chem. Int. Ed. 2015, 54, 9092-9096. 154. 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Highly Efficient Mukaiyama-Mannich Reaction of N-Boc Isatin Ketimines and Other Active Cyclic Ketimines using Difluoroenol Silyl Ethers Catalyzed by Ph3PAuOTf. Jinsheng Yu, Jian Zhou* Org. Biomol. Chem. 2015, 13, 10968-10972. 163. Catalytic Asymmetric Synthesis of Polysubstituted Spirocyclopropyl Oxindoles: Organocatalysis Versus Transition Metal Catalysis. Zhongyan Cao, Jian Zhou* Org. Chem. Front. 2015, 2, 849-858. 164. Ga(OTf)3 Catalyzed Highly Efficient Substitution Reaction of 3-Hydroxyoxindoles Using TMSN3. Xiaoping Yin, Pengwei Xu, Kun Dong, Kui Liao, Feng Zhou, Jian Zhou* Acta Chim. Sinica 2015, 73, 685-689.(in Chinese) 165. Catalytic Asymmetric Strecker Reaction: Bifunctional Chiral Tertiary Amine/Hydrogen-Bond Donor Catalysis Joins the Field. Yunlin Liu, Jian Zhou* Synthesis, 2015, 47, 1210-1226. 166. A Journey in the Catalytic Synthesis of 3-Substituted 3-Aminooxindoles. Jinsheng Yu, Feng Zhou, Yunlin Liu, Jian Zhou* Synlett, 2015, 26, 2491-2504 167. Catalytic Asymmetric Sulfenylation to Structurally Diverse Dithioketals. Kui Liao, Feng Zhou*, Jinsheng Yu, Weiming Gao, Jian Zhou Chem. Commun. 2015, 51, 16255-16258. 168. Cycloamidination of Aminoalkenes with Nitriles: Synthesis of Substituted 2-Imidazolines and Tetrahydropyrimidines. Shujian Huang, Yinlin Shao, Lixin Zhang, Xigeng Zhou* Angew. Chem. Int. Ed. 2015, 54, 14452-14456. 169. Facile Access to Oxazolidin-2-imine, Thiazolidin-2-imine and Imidazolidin-2-imine Derivatives bearing an Exocyclic Haloalkyliene via Direct Halocyclization between Propargylamines, Heterocumulenes and I2 (NBS). Shujian Huang, Yinlin Shao, Ruiting Liu, Xigeng Zhou* Tetrahedron, 2015, 71, 4219-4226. 170. Palladium-Catalyzed Cycloaminocarbonylation of 2-Aminomethyl- and 2-Alkylcarbamoylaryl Tosylates with CO. Bin Liu, Yan Wang, Benren Liao, Chunlei Zhang*, Xigeng Zhou* Tetrahedron Lett. 2015, 56, 5776-5780. 171. C-H Oxidation/Michael Addition/Cyclization Cascade for the Enantioselective Synthesis of Func- tionalized 2-Amino-4H-chromenes. Bo Wu, Xiang Gao, Zhong Yan, Muwang Chen, Yonggui Zhou* Org. Lett. 2015, 17, 6134-6137 172. Synthesis of Chiral Trifluoromethyl Substituted Hydrazines via Pd-Catalyzed Asymmetric Hydroge- nation and Reductive Amination. Zhangpei Chen, Shubo Hu, Ji Zhou, Yonggui Zhou* ACS Catal. 2015, 5, 6086-6089. 173. Enantioselective Synthesis of Functionalized 2-Amino-4H-chromenes via the o-Quinone Methides Generated from 2-(1-Tosylalkyl)phenols. Bo Wu, Xiang Gao, Zhong Yan, Wenxue Huang, Yonggui Zhou* Tetrahedron Lett. 2015, 56, 4334- 4338. 174. Visible-Light-Induced Radical Tandem Aryldifluoroacetylation of Cinnamamides: Access to Difluoroacetylated Quinolone-2-ones And 1-Azaspiro[4.5]decanes. Zhangxi Gu, Honglin Zhang, Pan Xu, Yixiang Cheng, Chengjian Zhu* Adv. Synth. Catal. 2015, 357, 3057-3063.(VIP) 175. A Novel Visible Light Mediated Radical Cyclization of Enol Lactones: A Concise Method for Fluorinated Polycyclic Lactone Scaffolds. Chuanhua Qu, Pan Xu, Wujiang Ma, Yixiang Cheng, Chengjian Zhu* Chem. Commun. 2015, 51, 13508-13510. 176. Monofluoromethylation of Tetrahydroisoquinolines by Visible Light Induced Direct C(sp3) C-H Bond Activation. Weipeng Li,Yunhuang Zhu, Yingqian Duan, Muliang Zhang, Chengjian Zhu* Adv. Synth. Catal., 2015, 357, 1277-1282. 177. Visible Light Promoted Carbodifluoroalkylation of Allylic Alcohols via Concomitant 1,2-aryl Migration. Pan Xu, Kaidong Hu, Zhangxi Gu, Yixiang Cheng, Chengjian Zhu* Chem. Commun. 2015, 51, 7222-7225. 178. Rhodium-Catalyzed Direct C7 Alkynylation of Indolines. Ning Jin, Changduo Pan, Honglin Zhang, Pan Xu, Yixiang Cheng, Chengjian Zhu* Adv. Synth. Catal. 2015, 357, 1149-1153. 179. CO-Enabled Rhenium Hydride Catalyst for Directed C(sp2)-H bond Alkylation with Olefins. Hongming Jin, Zhengbo Zhu, Ning Jin, Jin Xie, Yixiang Cheng, Chengjian Zhu* Org.Chem.Front. 2015, 2, 378-382. 180. Metal-free Cascade Construction of C-C Bond by Activation of Inert C(sp3)-H Bond. Honglin Zhang, Changduo Pan, Ning Jin, Zhangxi Gu, Hongwen Hu, Chengjian Zhu* Chem. Commun. 2015, 51, 1320-1322. 固定人员代表性论文复印件 目录（按通讯作者姓氏首字母排序） 1. Three-Coordinate Iron(IV) Bisimido Complexes with Aminocarbene Ligation: Synthesis, Structure, and Reactivity. Lei Wang, Lianrui Hu, Hezhong Zhang, Hui Chen*, Liang Deng* J. Am. Chem. Soc. 2015, 137, 14196-14207. 2. A Two-Coordinate Cobalt(II) Imido Complex with NHC Ligation: Synthesis, Structure, and Reactivity. Jingzhen Du, Linbo Wang, Meihua Xie, Liang Deng* Angew. Chem. Int. Ed. 2015, 54, 12640-12644. 3. Highly Regio- and Enantioselective Alkoxycarbonylative Amination of Terminal Allenes Catalyzed by a Spiroketal-Based Diphosphine/Pd(II) Complex. Jiawang Liu, Zhaobin Han, Xiaoming Wang, Zheng Wang,* Kuiling Ding* J. Am. Chem. Soc. 2015, 137, 15346-15349. 4. Highly Efficient Ruthenium-Catalyzed N-Formylation of Amines with H2 and CO2. Lei Zhang, Zhaobin Han, Xiaoyu Zhao, Zheng Wang, Kuiling Ding* Angew. Chem. Int. Ed. 2015, 54, 6186-6189. 5. Palladium-Catalyzed Enantioselective C–H Arylation for the Synthesis of P-Stereogenic Compounds. ZiqiLin, Weizhen Wang, Shaobai Yan, Weiliang Duan* Angew. Chem. Int. Ed. 2015, 54, 6265-6269. 6. Palladium-Catalyzed Highly Diastereo- and Enantioselective [3+2] Cycloaddition of Vinyl Aziridines and α,β-Unsaturated Ketones. Chaofan Xu, Baohui Zheng, Jiajia Suo, Changhua Ding*, Xuelong Hou*Angew. Chem. Int. Ed. 2015, 54, 1604-1607. 7. A General and Mild Catalytic α-Alkylation of Unactivated Esters Using Alcohols. Le Guo, Xiaochen Ma, Huaquan Fang, Xiangqing Jia, Zheng Huang* Angew. Chem. Int. Ed. 2015, 54, 4023-4027. 8. Synthesis of 1,1,1-Tris(boronates) from Vinylarenes by Co-Catalyzed Dehydrogenative Borylations-Hydroboration. Lei Zhang, Zheng Huang* J. Am. Soc. Chem. 2015, 137, 15600-15603. 9. The Real Role of N-Heterocyclic Carbene in Reductive Functionalization of CO2: An Alternative Understanding from Density Functional Theory Study. Qinghai Zhou, Yuxue Li* J. Am. Chem. Soc. 2015, 137, 10182-10189. 10. Palladium-Catalyzed Intermolecular Aminocarbonylation of Alkenes: Efficient Access of β-Amino Acid Derivatives. Jiashun Cheng, Xiaoxu Qi, Ming Li, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2015, 137, 2480-2483. 11. Highly Selective Pd-Catalyzed Intermolecular Fluorosulfonylation of Styrenes. Zheliang Yuan, Haoyang Wang, Xin Mu, Pinhong Chen, Yinlong Guo, Guosheng Liu* J. Am. Chem. Soc. 2015, 137, 2468-2471. 12. Copper-Catalyzed Trifluoromethylazidation of Alkynes: Efficient Access to CF3-Substituted Azirines and Aziridines. Fei Wang, Na Zhu, Pinhong Chen, Jinxing Ye, Guosheng Liu* Angew. Chem. Int. Ed. 2015, 54, 9356-9360. 13. Palladium-Catalyzed Intramolecular Aminotrifluoromethoxylation of Alkenes. Chaohuang Chen, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2015, 137, 15648-15651. 14. Gold-Catalyzed Oxidative Ring Expansion of 2-Alkynyl-1,2-Dihydropyridines or -quinolines: Highly Efficient Synthesis of Functionalized Azepine or Benzazepine Scaffolds. Ming Chen, Yifeng Chen, Ning Sun, Jidong Zhao, Yuanhong Liu*, Yuxue Li* Angew. Chem. Int. Ed. 2015, 54, 1200-1204. 15. Catalyst-dependent Stereodivergent and Regioselective Synthesis of Indole-fused Heterocycles through Formal Cycloadditions of Indolyl-allenes. Liangyong Mei, Yin Wei, Xiangying Tang*, Min Shi* J. Am. Chem. Soc. 2015, 137, 8131-8137. 16. Asymmetric H2O-Nucleophilic Ring Opening of D−A Cyclopro-panes: Catalyst Serves as a Source of Water. Qikai Kang, Lijia Wang, Qiongjie Liu, Junfang Li, Yong Tang * J. Am. Chem. Soc. 2015, 137, 14594-14597. 17. Asymmetric Annulation of Donor-Acceptor Cyclopropanes with Dienes. Hao Xu, Jianglin Hu, Lijia Wang, Saihu Liao, Yong Tang* J. Am. Chem. Soc. 2015, 137, 8006-8009. 18. Asymmetric 1,2-Perfluoroalkyl Migration: Easy Access to Enantioenriched alpha-Hydroxy-alpha-perfluoroalkyl Esters. Pan Wang, Liangwen Feng, Lijia Wang, Junfang Li, Saihu Liao, Yong Tang* J. Am. Chem. Soc. 2015, 137, 4626-4629. 19. Iridium-Catalyzed Intramolecular Asymmetric Allylic Dearomatization Reaction of Pyridines, Pyrazines, Quinolines, and Isoquinolines. Zepeng Yang, Qingfeng Wu, Wen Shao, Shuli You* J. Am. Chem. Soc. 2015, 137, 15899-15906. 20. Asymmetric Dearomatization of β-Naphthols through a Bifunctional-Thiourea-Catalyzed Michael Reaction. Shouguo Wang, Xijia Liu, Qunchao Zhao, Chao Zheng, Shaobo Wang, Shuli You* Angew. Chem. Int. Ed. 2015, 54, 14929-14932. 21. Enantioselective Construction of Spiroindolines with Three Contiguous Stereogenic Centers and Chiral Tryptamine Derivatives: Reactive Spiroindolenine Intermediates. Chunxiang Zhuo, Yong Zhou, Qing Cheng, Lin Huang, Shuli You* Angew. Chem. Int. Ed. 2015, 54, 14146-14149. 22. Enantioselective Synthesis of Pyrrole Based Spiro- and Polycyclic Derivatives by Ir-catalyzed Asymmetric Allylic Dearomatization and Controllable Migration Reactions. Chunxiang Zhuo, Qiang Cheng, Wenbo Liu, Qiang Zhao, Shuli You* Angew. Chem. Int. Ed. 2015, 54, 8475-8479. 23. Copper-Catalyzed Intermolecular Asymmetric Propargylic Dearomatization of Indoles. Wen Shao, He Li, Chuan Liu, Chenjiang Liu*, Shuli You* Angew. Chem. Int. Ed. 2015, 54, 7684-7687. 24. Asymmetric Dearomatization of Naphthols via a Rh-Catalyzed C(sp2)–H Functionalization/Annulation Reaction. Jun Zheng, Shaobo Wang, Chao Zheng, Shuli You* J. Am. Chem. Soc. 2015, 137, 4880-4883. Highlighted by Synfacts, Mark Lautens, Thomas Johnson, Synfacts, 2015, 0721. (Synfacts of the month) 25. Highly Regio- and Enantioselective Synthesis of N-Substituted 2-pyridones via Ir-Catalyzed Intermolecular Asymmetric Allylic Amination. Xiao Zhang, Zepeng Yang, Lin Huang, Shuli You* Angew. Chem. Int. Ed. 2015, 54, 1873-1876. 26. Asymmetric Dearomatization of β-Naphthols via Chiral Phosphoric Acid-Catalyzed Amination Reaction. Shouguo Wang, Qin Yin, Chunxiang Zhuo, Shuli You* Angew. Chem. Int. Ed. 2015, 54, 647-650. 27. Gold (I)-Catalyzed Tandem Transformation with Diynes: Rapid Access to Cyclopentenone-Fused, Linear Polycyclic Molecules. Congjun Yu, Bin Chen, Tian Zhou, Qinshan Tian, Guozhu Zhang* Angew. Chem. Int. Ed. 2015, 37, 10903-10907.